Name………………………………………………………..Class………………...
Class No……………
233 Candidate’s signature……………………..
CHEMISTRY Date: ………………………………..............
2 Hours
LORETO HIGH SCHOOL LIMURU REVISION EXAMS - 005
Candidates score
Maximum score
60
For examiners use only
1 (a) The table below shows some properties of chlorine, bromine and iodine.
Element Formula Colour and state at room temperature Solubility in water
Chlorine Cl2 (i)………………………... Soluble
Bromine Br2 Brown liquid (ii)………………………..
Iodine I2 (iii)……………………… Slightly soluble
Complete the table by giving the missing information in (i), (ii), and (iii) (3 marks)
(b) Chlorine gas is prepared by reacting concentrated hydrochloric acid with manganese (IV) oxide.
(i) Write the equation for the reaction between concentrated hydrochloric acid and manganese (IV) oxide.
(1mark)
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(ii) What is the role of manganese (IV) oxide in this reaction? (1mark)
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(c) (i) Iron (II) chloride reacts with chlorine gas to form substance E. Identify substance E. (1mark)
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(ii) During the reaction in (c) (i) above, 6.30g of iron (II) chloride were converted to 8.06g of substance E. Calculate the
volume of chlorine gas used. (Cl=35.5, Molar gas volume at room temperature = 24000cm 3, Fe = 56) (3 marks)
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(d) Draw and name the structure of the compound formed when excess chlorine gas is reacted with ethene gas.
(2
marks)
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(e) Give one industrial use of chlorine. (1mark)
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2 (a) The set-up below was used to collect gas F, produced by the reaction between water and calcium metal.
(i) Name gas F………………………………………………………………………… (1mark)
(ii) At the end of the experiment, the solution in the beaker was found to be a weak base. Explain why the solution is a
weak base. (2 marks)
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(iii) Give one laboratory use of the solution formed in the beaker. (1mark)
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(b) The scheme below shows some reactions starting with calcium oxide. Study it and answer the questions that follow.
(i) Name the reagents used in the steps 2 and 4. (2 marks)
Step 2……………………………………………………………………………………..
Step 4……………………………………………………………………………………..
(ii) Write an equation for the reaction in step 3. (1mark)
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(iii) Describe how a solid sample of anhydrous calcium sulphate is obtained in step 5. (3 marks)
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3 (a) The diagram below illustrates how sulphur is extracted by the Frasch process.
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Label the pipe through which superheated water is pumped in. (1mark)
(b) The equation below shows the oxidation of sulphur (IV) oxide to sulphur trioxide in the contact process.
(i) Name one catalyst for this reaction……………………………………………………….. (1mark)
(ii) State and explain the effect on the yield of sulphur (VI) oxide when:
I. The temperature is increased. (2 marks)
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II. The amount of oxygen is increased. (2 marks)
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(iii) Describe how sulphur (VI) oxide is converted to sulphuric (VI) acid in the contact process. (2 marks)
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(c) State two disadvantages of having sulphur (IV) oxide in the environment. (2 marks)
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(d) Ammonium sulphate is a fertilizer produced by passing ammonia gas into concentrated sulphuric acid.
(i) Write the equation for the reaction. (1mark)
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(ii) Calculate the mass in kg, of sulphuric acid required to produce 25kg of the fertilizer. (S = 32.0; O=16.0; N=14.0;
H=1.0) (3 marks)
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4 (a) The flow chart below shows some reactions starting with lead (II) nitrate. Study it and answer the questions that
follow.
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(i) State the condition necessary in step 1……………………………………………………… (1mark)
(ii) Identify (3 marks)
I reagent K………………………………………………………………………………………………………...
II gas P…………………………………………………………………………………………………………….
III acidic products S and R………………………………………………………………………………………..
(iii) Write:
I. The formula of the complex ion formed in step 3…………………………………………… (1mark)
II. The equation of the reaction in step 4. (1mark)
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(b) (i) The reaction between lad (II) nitrate and concentrated sulphuric acid starts but stops immediately. Explain.
(2 marks)
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(ii). Name one suitable reagent that can be reacted with concentrated sulphuric acid to produce nitric acid.
(1mark)
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5 (a) Crude oil is a source of many compounds that contain carbon and hydrogen only.
(i) Name the process used to separate the components of crude oil. (1mark)
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(ii) On what two physical properties of the above components does the separation depend? (2 marks)
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(b) Under certain conditions, hexane can be converted to two products.
The formula of one of the products is C3H8.
(i) Write the formula of the other product. (1mark)
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(ii) Describe a simple chemical reaction to show the difference between the two products formed in (b) above.
(2
marks)
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(c) Ethyne, C2H2 is another compound found in crude oil.
One mole of ethyne was reacted with one mole of hydrogen chloride gas and a product P1 was formed. P1 was then
reacted with excess hydrogen gas to form P2. Draw the structures of P1 and P2. (2 marks)
(e) One of the reactions undergone by ethene is addition polymerisation.
Give the name of the polymer and one disadvantage of the polymer it forms. (2 marks)
Name of polymer ………………………………………………………………..
Disadvantage of polymer
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6 (a) Brine usually contains soluble calcium and magnesium salts. Explain how sodium carbonate is used to purify brine.
(2
marks)
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(b) The diagram below represents a diaphragm cell used to electrolyse pure brine.
(i) Write the equations for the reactions that take place at:
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I. cathode (1mark)
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II. anode (1mark)
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(ii) Name:
I. another material that can be used instead of titanium. (1mark)
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II. the impurity likely to be present in the sodium hydroxide. (1mark)
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(iii) State one function of the diaphragm. (2 marks)
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(c) Give one industrial use of sodium hydroxide. (1mark)
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