Name………………………………………………………..Class………………...
Class No……………………
233 Candidate’s signature…………………………….
CHEMISTRY Date: ………………………………........................
2 Hours
LORETO HIGH SCHOOL LIMURU REVISION EXAMS - 003
For examiners use only
Questions Topic (s-topic) Maximum score Candidate’s score
1 Solvay process 11
2 Thermochemistry 14
3 Organic chemistry 14
4 Metals (Iron) 11
TOTAL 50
1 (a) Below is a flow diagram for the manufacture of sodium carbonate by the solvay process. Study it and
answer the questions that follow.
(a) Name the raw materials in the Solvay process. (1mark)
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(b) Write the equation for each of the following steps:
(i) the carbonation tower. (1mark)
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(ii) the heating of limestone (1mark)
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(iii) the production of soda ash (1mark)
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(iv) the slaker (1mark)
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(v) the ammonia recovery (1mark)
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(v) Which substances are recycled in the process? (1mark)
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(e) State one use of:
(i) Sodium carbonate. (1mark)
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(ii) Calcium chloride. (1mark)
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(f) Write the chemical formula of Trona. …………………………………………………………….. (1mark)
2 (a) A sample of Propanol (C3H7OH) was completely burnt in air in an improvised lamp and the heat evolved was used to
warm 500g of water. Study the data below and answer the questions that follow:
Initial temperature of water 25.0oC
Final temperature of water 44.0oC
Initial mass of lamp + propanol 49.0g
Specific heat capacity of water 4.2J/g/K
(i) Find the quantity of heat energy evolved from the amount of Propanol burnt. (2 marks)
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(ii) Determine the molar-enthalpy of combustion of Propanol. (H = 1.0, C = 12.0, O = 16.0) (2 marks)
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(iii) Explain why the value obtained in (II) above is less than the actual molar enthalpy of combustion of Propanol. (-
2004kJMole-1) (1mark)
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(b) Use the information below to answer the questions that follow:
Equation: Enthalpy of formation
H2(g)+ ½ O2 (g) H2O(l) ∆H1 = -283kJMol-1
C(s)+ O2(g) CO2(s) ∆H2 = -393kJmol-1
3C(s) + 4H2(s) + ½ O2(s) C3H2OH (l) ∆H3 = -307kJMol-1
(i) Define the term enthalpy of formation of a compound. (1mark)
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(ii) Calculate the molar enthalpy of combustion of Propanol. (3 marks)
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(c) 400cm3 of 2M NaOH(aq) was placed in the flask and its temperature was carefully noted to be 21.5 oC. Then 200cm3 of
2M H2SO4(aq) whose temperature was 23.5oC was added through the funnel, and the highest temperature after mixing was
36.0oC
(i) Write an ionic equation for the neutralization reaction. (1mark)
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(ii) Calculate molar heat of neutralization for the above reaction. (2 marks)
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(iii) The theoretical value of heat of neutralization for formation of 1 mole of water is 56kJmol -1
(I) Give two reasons why the value in (ii) is lower than this value. (2 marks)
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(II) Suggest a reason for the lower ∆H value in the following case.
NH4OH(aq) + CH3COOH(aq) CH3COONH4(aq)+ H2O(l) H = -5.5KJmol-1 (1mark)
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3 (a.) An alcohol G can be dehydrated to form an unsaturated compound H which can be polymerized to give polymer I.
(i) Explain what is meant by the term unsaturated. (1mark)
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(ii) Describe a simple chemical test to show unstauration. (2 marks)
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(iii) Circle the repeating unit of polymer I in the diagram above. (1mark)
(iv) Identify the unsaturated compound H and draw its structure. (2 marks)
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(v) Suggest the identity of alcohol G and draw its structure. (2 marks)
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(b) A student found a bottle containing CH3CH2COOCH3
(i) Name the process of formation of the substance above. (1mark)
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(ii) Identify the two substances from which the substance in (d) (i) above is derived. (1mark)
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(iii) Name the conditions necessary for the formation of CH3CH2COOCH3 (1mark)
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(c) Dichlorocfluoromethane, CCl2F2, is an example of a chlorofluorocarbon, CFC, that was commonly used as a propellant
in aerosols.
(i) Draw a dot (.) and cross (x) diagram to show a molecule of CCl2F2. (2 marks)
(ii) Nowadays CFCs have limited use. Give a reason for this. (1mark)
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4. Iron is extracted from the oxide Fe2O3 by reduction with carbon and carbon (II) oxide in a Blast Furnace.
(a) In the Blast Furnace, carbon (II) oxide is produced from carbon in a two-stage process. Write equations to
show these two stages. (2 marks)
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(b) Write an equation for the reduction of Fe2O3 by carbon and an equation for the reduction of Fe2O3 by carbon (II) oxide.
(2 marks)
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(c) Limestone is added to the Blast Furnace to remove impurities present in the iron ore.
(i) Identify the main impurity removed by limestone. (1mark)
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(ii) Write an equation or equations to show how limestone acts to remove this impurity. (2 marks)
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(d) (i) State the main impurity in iron obtained from the Blast Furnace. (1mark)
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(ii) Explain how this impurity is removed in the conversion of impure iron into steel. (3 marks)
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