130 Nootan ISC Cherristry

QUESTIONS FROM ISCEXAMINATION PAPERS

following solutions, the 8. (a) Out of the one having the
1. The freezing point of nitrobenzene is 2 78.8 K.
025 molal solution a substance (mol
boiling point will be higre
wt. 120) in nitrobenzene has a freezing Doint of 276.8 K.
() 0.1 M NaCI (i)) 0.1 MBaCl,
Calculate the molal depression constant of nitrobenzene. (ii) 0.1 MKNO, (iv) 0.1 MKafetCN),
(2002) |An 80 (b) Answer the following question
2. Calculate the osmoticpressure of a solution containing 3.42 & 0.1 Murea solution shows less depression in
of sucrose in 1litre of water at 400 K. (2002) point tharn 0.1 MMgCl, solution. Explain.
|Ans 0.33 atol 9. (a) 46 g of ethyl alcohol is dissolved in 18 g of (2011)
Calculate the mole fraction of ethyl alcohol. water
3. (a) What is a colligative property ? Give two examples. (at. wt.
(b) The OSmotic pressure of blood is 7.65 atm at 27°C. How
C= 12, 0= 16, H= 1).
much glucose should be used per litre to prepare an (b) The osmotic pressure of 0.01 molar solution
intravenous injection that has the same osmotic pressure electrolyte is found to be 0.65 atm at 27°C. Calculate
te
as blood ? (2003) van't Hoff factor. Whatt conclusion can you draw about the
molecular state of the solute in the solution ?
4. (a) Molarity of a solution is independent of temperature. (2011,
IAns. I 2.639 diss0Ciattr
Comment. 1
10. (a) Fill in the blanks
(b)Calculate the nmole fraction of water in a sodium hydroxide
solution which has 80 g of NaOH and 54 g of H0.
Solutions which strictly obey..law are called
solutions.
(Relative atomic masses : Na = 23, 0= 16, H= 1)
(b) Asolution X is prepared by dissolving three moloe.
(2005)
5. (a) The depression in the freezing point of a sugar solution glucose in one litre of water and a solution Yis prepared
was found to be O.402°C. Calculate the osmotic pressure
by dissolving 1.5 moles of sodium chloride in one litre af 20

water. Will the osmotic pressure of Xbe higher, lower w

of the sugar solution at 27°C. (K, = 1.85 Kkg molr) equal to that of Y? Give a reason tor your answer. (20121
(b) A solution is prepared by dissolving 2.0 gof sucrose and
2.0 g of urea in 100 g of water at 298 K. Calculate the
11. (a) Asolution of urea in water has aboiling point of 100. 18
Calculate the freezing point of the solution. (Kt for wateri 2
vapour pressure of the solution, if the vapour pressure of 1.86 Kkg mol and K, for water is 0.512 Kkg mor
pure water at 298 Kis 23.756 torr. (Mol. wt. of urea = 60 [Ans. -0.6537 C
and sucrose = 342) (2006)
6. (a) (i) Ifthe molality of an aqueous solution of cane sugar is (b) Asolution of lactose containing 8.45 gof lactose in 100g
0.4445, what is the mole fraction of cane sugar? of water has a vapour pressure of 4.559 mm of Hg a
o°C. If the vapour pressure of pure water is 4.579 mm df
(i) Albumins are the most abundant proteins in blood. At
2
Hg, calculate the molecular weight of lactose. (2012)
25°C, 3.5g of albumin in 100 mL of water produces an [Ans. 347.04 g mol
osmotic pressure of 0.014 atm. What is the molecular 12. (a) Fill in the blanks
weight of albumin? An aqueous solution of sugar boils....100°C and
(b) Schenmatically represent the temperature-composition freezes ......0°C.
curve for the vapour in equilibrium with an ideal mixture (b) Among equimolal solutions of MgClT, NaCI, FeCla and
of two completely miscible liquids of diferent boiling C12H2011, which willshow minimum osmotic pressure!
points. Explain with the aid of this diagram how fractional Why? (Specimen paper, 2013)
distillation is done. (2008)
13.(a) A certain aqueous solution boils at 100.303°C. What is
7. (a) The boiling point of pure water is 373K. Calculate the
boiling point of an aqueous solution containing 18 g of
its freezing point? Kb for water = 0.5 K kg mol and
glucose (MW = 180) in 100g of water. Molal elevation Kf = 1.87 Kkg mol-?
Constant of water is 0.52 Kkg mol, (b) A solution containing lg of sodium chloride in 100g
(b) Equal weights of two substances X and Yare dissolved of water freezes at 0.604°C. Calculate the degree of
in equal volumes of water. The osmotic pressure of the
dissociation of sodium chloride. (Na = 23, CI -35.5,
solution containing Yis five times the osmotic pressure of K, for water = 1.87 Kmol) (Specimen paper, 2013)
the solution containingX. What is the molecular weight of
Xif that of Yis 60? 14. Complete the following statements by selecting the correct
(c) Which of the following solutions will have a lower vapour alternative from the choices given
pressure and why? Of the following terms used for denoting concentration of a
(i) A5% solution of cane sugar (Ci2H22011) solution, the one which does not get affected by temperature is
(i) A5% solution of urea (NH,CONH2) (b) molality
(Relative atomic masses : H = 1,C= 12, O = 16, N= 14) (a) molarity
(2014)
(c) normality (d) formality.
(2009)
 131
Solutions

law for the elevation of boiling point of a

Define
Raoult's 25. (a) Determine the freezing point of a solution containing
15. (2014)
solution. 0.625 g of glucose (C7H0) dissolved in 102.8 g of
What will
be the vapour pressure of a solution containing water.
offsucrose (C;2H22011) in 1 kg of water, if the vapour
16. (reezing point of water - 273 K. K, for water - 187K kg
5 moles
pressure of
pure water is 4.57 mm of Hg? (C = 12, H- 1 mol, at. . C- 12, H- 1,0 -16) (Ans 2937 Ki
0 - 16] (2014) (b) A 0.15 M agueOUs solution of KCI exerts an 0smotic
pressure of 6.8 atm at 310 K. Calculate the degree of
molal solution
of sodium chloride in water causesS an dissociation of KCL (R -0.0821LatmKmot).
A2
17. elevation inthe boiling point of water by 1.88 K. What is the
Value of van't Hoff factor? What does
it signify? (C) A
solution containing 8,44 gof sucrose in 100 g of water
mol) (2014) has a vapour pressure 4.56 mm of Hg at 273 K. If the
(Kh = 0.52 Kkg
|Ans. 1 801 vapour pressure of pure water is 4.58 mm of Hg at the
Aand Bform type ll non-ideal solution which same temperature, calculate the molecular weight of
18. Two liigquids SUcrose. (2017)
chows a minimum in its temperature-mole fraction plot
(T-y diagram). Can the two liquids be completely separated 26. Choose the correct alternative :
by fractional distillation? (2015)
10 Asolution containing 0.5 gof KCl dissolves in 100 g of water An aqueoUs solution of urea freezes at -0.186C, K, for water
and freezes at -0.24°C. Calculate the degree of dissociation = 1.86 Kkg mol,K, for water =0.512 Kkg mol.
The boiling point of urea solution will be
of the salt. (K, for water = 1.86°C) Atomic weights, K=39, (a) 373.065 K (b) 373.186 K
Cl= 35.5. (2015) (c) 373.512 K (d) 373.0512 K. (2018)
[Ans. 0.92] TArs (c)
20. If 1.71 g of sugar (molar mass = 342) are dissolved in
27. Calculate the osmotic pressure of a solution prepared by
500 mi of an aqueoUs solution at 300 K, what will be its dissolving 0.025 g of K,SO4 2.0 litres of water at 25°C
OSmotic pressure? (2015) assuming that K,SO4 is completely dissociated. (mol. wt of
JAns. 0.2463 atm) KzSO =174 g mol) (2018)
21. 0.70 g of an organic compound when dissolved in 32 g of [Ans. O.0053 atmi
acetone produces an elevation of 0.25°C in the boiling point. 28. An aqueous solution containing 12.48 g of barium
Calculate the molecular mass of organic compound (Kh for chloride (BaCl,) in 1000 g of water, boils at 100.0832°C.
acetone =1.72 K kg mol). (2015) Calculate the degree of dissociation of barium chloride.
[Ans. 150.5-g mol] (K, for water =0.52 Kkg mol, at. wt. Ba = 137, Cl = 35.5)
(2018)
22, Fill in the blanks
[Ans. 0.83)
Ideal solutions obey...... law and they...... form azeotropic
(2016)
29. The freezing point of a solution containing 5.85 g of NaCi in
mixtures. 100 g of water is -3.348°C. Calculate van't Hoff factor ' for
[Ans. Raoult's, do not)
this solution. What wil be the experimental molecular weight
23. (a) A10% aqueous solution of cane sugar (mol. wt. 342)is of NaCi?
isotonic with 1.754% aqueous solution of urea. Find the (K, for water = 1.86 Kkg molr,at. wt. Na = 23, Cl= 35.5)
molecular máss of urea. [Ans. 60] (2018)
(b) The molecular weight of an organic compound is [Ans. 1.8, 32.5 g mol
58 g mo-l. What will be the boiling point of a solution 30. Calculate the boiling point of urea solution when 6 g of urea
Containing 48 g of the solute in 1200g of water? is dissolved in 200 g of water.
[K, for water = 0.513°C kg mol, Boiling point of water (K, for water =0.52 Kkg mol, boiling point of pure water
= 100°cI [Ans. 100.35°C] = 373 K, mol. wt. of urea = 60) (2019)
[Ans. 373.26 K1
(c) What will be the value of van't Hoff factor (i) of benzoic
acid if it dimerises in aqueous solution? How will the 31. When 0.4 gof acetic acid is dissolved in 40 gof benzene, the
experimental molecular weight vary as compared to freezing point of the solution is lowered by 0.45 K. Calculate
the degree of association of acetic acid. Acetic acid forms
normal molecular weight ?
dimer when dissolved in benzene.
i .Expt. mol. wt. Obtained is double the normal
(Ans. = (K; for benzene =5.12 Kkg mol, at. wt. C= 12, H= 1, 0
= 16) (2019)
mol. wt.] (Ans. 0.9461
24. Why the freezing point depression (AT) of 0.4M NaCl solution
32. A solution is prepared by dissolving 9.25g of non-volatile
is nearly twice than that of 0.4M glucose solution? (2017) solute in 450 ml of water, It has an osmotic pressure of
 Nootan ISC Chemistryy
132
non (ii) The value of molal depression
350 mm of Hg at 27°C. Assuming the solute is Constant or cryosO
mass. constant (K) depends on which of the
electrolyte, determine its molecular
(R= 0.0821 Lit-atm K
mol) (2019)
(a) Nature of solvent
fol o(2021
wing? Sem1
acid (b) Heat of the solution of the solute
33. (i) The elevation in boiling point when 0.30 g of acetic in the
is dissolved in 100 g of benzene is 0.0633 C. Calculate (c) Nature of solute solvent
the molecular weight of acetic acid from this data. What (d) Vapour pressure of the solution
conclusion can youdraw about the molecular state of the (iv) According to which law the solubility
solute in the solution? equilibrium and constant temperature of
(Given K, for benzene = 2.53 K ke mol at. wt. of with the pressure of the gas, provided varies
C= 12, H= 1,0 =16) |Ans 10) the gas
undergo any chemical change during the
(ii) Determine the osmotic pressure of a solution prepared by dissolution?
dissolving 0.025 g of KoSO, in 2 litres of water at 25°C, (a) Raoult's law (b) Nernst (2021 Sem-1
assuming that KzSO4 is completely dissociated.
(R = 0.0821 Lit-atm K mol mol. wt. of KgSO4 (c) Henry's law (d) van't hoffdistribution
law
la.
= 174 g mol) (2020) (V) 0.76 g of glucose (molecular mass = 180 g mor
Ans. 5.2228 10 atml is dissolved in 20 ml of aqueous solution
(R =0.0821 Latm K mol). at
298
34. () An aqueous solution of a non-volatile solute freezes at
272.4 K, while pure water freezes at 273.0 K. Determine 1. What is the osmotic pressure of solution at 200 n-1)
(2021 Ser
the following : -1
(a)8.41 atm (b) 0.48 atm
(Given K, =1.86 Kkg mol. Ks =0.512Kkg mol and (c) 4.41 atm (d) 5.16 atm
vapour pressure of water at 298 K= 23.756 mm of Hg)
(1) The molality of solution
2. What is the molarity of glucose solution?
(a) 0.42M (b) 0.21 M
(2) Boiling point of solution (c) 4.01 M
(3) The lowering of vapour pressure of water at 298 K. (d) 2.02 M
(Ans. 0.322, 373. 1648 K, 0.1376 mm Hg] (vi) 5 moles of sucrose (molecular mass = 342 g mor
(i1) Asolution containing 1.23 g of calcium nitrate in 10 g of dissolved in 1000 g of water (molecular mass =
water, boils at 100.975°C at 760 mm of Hg. Calculate mol). Vapour pressure of pure water at 298K=418g
the van't Hoff factor for the salt at this concentration. mm Hg. (2021 Sem-1) Vers

(Kp for water = 0.52 K kg mol, mol. wt. of calcium 1. What will be the vapour pressure of sucrOse solution into
nitrate = 164 g mol) (2020) at the same temperature? elec
[Ans. 2.5] (b) 6.570 mm Hg
(a) 0.419 mm Hg in ti
35. Select and write the correct alternative from the choices given (c) 4.190 mm Hg (d) 0.657 mm Hg the
below IS al
()A solution containing components A and B follows 2. What willbe the mole fraction of sucrose in water?
elec
Raoult's law. With reference to the statement which of (a) 0.8261 (b) 0.0826
ofa
the following options is correct? (2021 Sem-1) (c) 0.4376 (d) 0.0435
the
(a) A--Battraction force is greater than AA and B-B (vi) Asolution containing 54 g of glucose (molecular mas : che
(b) AB attraction force is less than A-A and B-B 180 g mol) in 250 g of water (K, for water =1.86 Kke
(c) A--Battraction force remains the same as A-Aand mol'). (2021 Sem-1) elec
B-B
(a) Total volume of solution is different from sum of [Link] will be the freezing point of this glucose solution?!
volumes of both components A and B (a) 276.402 K (b) 270.768 K
(i)A solution of urea (molecular mass = 60) contains
3.
(c) 370.402 K (d) 272.563 K
8.6 g per litre. It is isotonic with a 5% solution of a non
2. What will be the molality of this glucose solution?
volatile and non-electrolytic solute. What will be the ene
molecular mass of the solute? (2021 Sem-1) (a) 1.20 m (b) 0.12 m ele
(b) 349g mol-! (c) 2.40 m (d)0.24 m foll
(a) 34.9g mor
(c) 861 g mol (d) 3490 g mol-! [Ans. (i) (c), () (b), (ii) (a), (iv) (c), (v) 1. (c) 2. (t!
(vi) 1. (c) 2. (b), (vii) 1. (b) 2 (a Con
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