Sinole

t,
Answer Type
L Bohr's i\:lodel of Atom
..
l Which hydrooen like snecies
1-1
will
•
have
'
same radius as that of Bohr orbit of hydro"en::
_ •
ato,n'>
(a) n = 2~ Li:!+ (b) 11 = 2~ BeJ-; ~c) n.= 2. I-le · (d) n == 3, u 2• ·

The shortest wa·velength of He atom in Balmer series is x, th en longeSl wavelength in the Pa

series of Li+ 2 is. · . . .· · · · · 5'i. t.
16-x : . . ., ·. 9x ._..... , · 5x ·
36x · (d)--- .
(a)· -: - . (b) -. . . : : . ' _, · (C)'5 . , _9
. .· 5 7 .. . . . .. : .
. . . .. .
Ahydtogen -. lik~ ·atom has ground.·srate .bi11ding-en.~rgy )22.4-eV, Then : . . . . ...
~·tjfomic ri·umberis
. (~) ·it_ J ,··; _·_· . .. . _.(b):_a·JJh~tpn 'of 90 eV ~ancxcit~: it~til,_~--hig~~ w

: . ·.(~J~. 80
. .·
eV. photoi;
. .
~cinnorexci(e '.irfo;a'higher:srate
.: . . . .. . ·
. . . . . . .
.
. •, ;

·.. (d)None..;_.. . : ·._· · - - - . ·.· .·

•. • • _• • •.• ~-:- - . • ' "."' • • ••• • · •• .: • • ••. • • • • • • • .' • • r • • • • • • ••

· " ii . • Por-:H~°!jke atoms; :the grotrnd §J~te endgy'is pi·oponionano _ . . _. . .

.. . .. .....".. ,. .. '. -(a)-'~t-Zf'..- (b}~z.1-1µ·,:,:'.:.-:.:· -:----- ~ :, .:·:tc}pZ1 ·· : _:; .: : :.: --~ . .... (df 1/fl.2 :
C •• :' .: · :- '. : .. . . . ' . . . .. . . . .

. . . .. .S.: . , : . t\doubly1oilized-litliimii·aroi~'t
. ..
111:·afrexcited:statc'-(n'~-ij) ·eti-iits' irphbtbri 6t-energ/4Js·ev.\vhata.rc-,
. . . . . . . . . . . . . . . . . . .

the qu~ntuni number (n) and .the energ_y (E) of the _final state? . .
(a) n =2, E =-30.6 ev_·. (b) n = 3. E = -13.6 eV
(c) n = 4, E = -7.65 eV .. (d) 11= 5. E = -4.90 eV ..
6. · _The
.
de~Brnglie. vvavelengti1
.
fix aHe
.
'att)m ·.travelling
·- . .
at I000
. .
mis
. .
(typical speed
. . . . . . .
at room temperature) . . . .

lS

7I . The- velo.citv of the. electron. in1he hvdrOuei1mom :.. .. ... . ... . .

- . ·. . . .. . :

: • • •• • . .,,.. . . J '---"

(a) increases with .increasing principal qw111~11n number

. . . . .· - . . .

(b) decreases vvith i,kreasing principal quantum number

(c) is uniform for any value of the principal qL;ali~Ulll numbe1~
.. . (d) first increases and .then decreases with principal quantum number · .
8. The energies of the Is orbital in H. He· and Li-: are inthe ratio
=I : I : I
(a_) H : Hc' : L F' (b) H : He·· : Li2' =I :1:3
. : Li • = I : 4 : 9 ·
(c) H : He. 2
(cl) H: He· : Li 2 • = I : I /4 : 1/9 .
9. If ., - ... at)l m ·15· , J. . . 6 ev, the expected third
. energy of· hvdro£!.en
. h.the · ionization • 1ornzat1on
- • · ener!!V of·the
lIt IUITI atom IS . ~-

(a) 13.6;J_eV _-::-(b) 13.6x2eV

. (c)IJ.6x6eV (d)l3.6x9e\/
10. The_mJJo of (E 2 - E,) to (E-1 - E,) for He+ion is 8 . - . . • ,.;,
orbit) . · pp,oximately equal to (where E 1s the energy ol !, 11

(a) 10 (b) 15 (c) t] . (d)12·

. - . . . . .. .
 ·_:" :_~-...~·'···r:: \ /:;.. . .··: .
,;. ),... 101 . . .
If the binding.enetgy of2 nd excited stat f' . . . -:. ·. 'Atom.ic:St . . · -
I .. . f - e o a hydroo l'k . . . . ructure & Qu· t
J· ionisation energy o the sample is app.1 . :::en I e sample is ?4 V · an um
_ oximately - e approximate! , ti -
(a) 54.4 eV (b) 24 eV · ), 1enllie
. . . (c) 122.4 eV
The 10111sat1on en~~g~ofH atom is 21. 79 x _19 J . (d)216eV
12 10
· excited state of L,-+ 10n _ · Then the value of b' d' ·
- m mg enerov of
(a) 32 x 21.7 x 10-19 J . . · :::,. second
· ('b) _21.79 x IQ-19 J
1 .
{C) J X 21.79 X JO-l9 j 1
. . . . . . .. . (d) J2 X2l.79x IQ-19J
. . f . . .
of
J3~·-· -'The \Vave number the -fi~st:line in the:Baim·<. •<· · , · , · ,•· ·. . ·
. ·. e1 se1 ies of hydrooe 111. I~ . .1 .
· . ·. ·
..
. · wavenumber: o the fir~t line mthe L)iman .s _;., r· . . .., .: :, s )200cm~ • Wl1at would be th.
.. .. . . . -1 . : . . • . 1 Be" ion?
. ~11es o . tie . . e.
... (a)'2.4 X l_O·cm . . . (b) 24.3 X rnscm-1 . (. ) 6 08 . 5 1 .· .
• · · . . · .- . c • x IO·cm- {d) 1,, 1,,
1.4. ·. - What .would be ·the maxirnum lilimber , of' "'1n·1ss· ,.- . · f:. .J _ J XIQI> cm-I
· ·· ·• · ion mes·- 1or 1 · 1
·• . • · ·• • J,,
expect to see· with llkflaked ·e);e if the 0- nl •1 ·. . a omic iydrogen that you would
. · . · .· . ·, · · · -. Ye ecti on1c enerov I I5 · 1
111 the Figure? ·. · · · . ·· ·· . .. . ~- .-: . • eve mvo
0
.
v~d are those as shown
, •.

. '. '

-:-~~~.:.:..;_;~n=6
. •·-.-. ....·, _..-....
. .... . -·....
...
- ·. -·.. . ·--· . . . . :·---·. :: :.- .-.·---~--- . -····· --- :·..:-.:: :.- ·. ....... :. _
:.,.__.._-_:__. --~-=
.: _s_ ..~- -- -
..... . _;. , .,.- ·, ., .. ,_ .. ···· ·•· .·. . -·_.. .,_..

------n=2

.n = 1
(a) 4 -. {brG · . (c)) (d) 15
. .JS . . ..·Jhe.de Brogile:wav@l~1igth ofan ·electron m'o•v,ri:g fa'a ci1;ci'ila1: cibit is 'f... ;~rhc 1ni11i;11u·1~ rndiu~ ~r .·.
orbit is
. . ), }, ).. }c
(a) - . ) .
.

(b)- . ·(c. 4rr (d).-3j{

i[
2n
. 16· Lncertaimy in position of a:hypothetical subato111ic particle is IA and uncertainty in velocity is
3.3 . .· . . •, . .· . . ..· ... ' . . . . . .

x I05 mis then the mass of the particle is approximately [h = 6.6 x_ t0-3-1 Js]
29
. (a) 2 x I Q-c28 kg ..· (b) 2 x rn- 27 kg (c) rx I 0::29 kg (d) 4 x I0- kg
17· 1f Ao is the threshold wavelength for photoelectric emission, A wavelength of light falling_ on the
surface of metal: and m: mass of electron, then de Broglie wavelength of emitted electron is

.. .I I

h(A -11.)]2 h(11.-11. )] 2 --

-
(b) o ( ) 0
[ 2mc)J1. c [ 2mc11-11. 0
0
 . : . .. . • • . 101 · . · 1uom1c .Sttuc.torc & Q· .,, .
. . . . . . . . uaq1u
What 1s_1!le-rat101J'fvelocities of electron & proton when the De-Brog Ire wavelength ass .• -~rn
0
an_electron \Vould be et1ual lo thal associated with a proton if a proton is 1836 friWes Ile ~'atedWith
av,er th
electron·; anan
(a) 1836 (b) !/1836 (c) I (d) 2
2. Quantum Model of Atom
The value of the magnetic quantum number of a.Px orbital is·
(a)-1 (b)O (c)+I (d) undefined ·
20. Any p-orbital ca~1 accommodate up to ·
(a) four electrons .· .· (b) six electi·cms .
(c) two electrons ·\.vith·parallel spins· . (d) two' electrons :\vith 6ppos1t.e,spin; .
21. foe pi"incipal quantum numbe,: of an atom is reiatcd to f/1e
(a) size of the orbital . :; (b)spin.angularmon1~11fmn' ·: ·
0
(C) orie11tat ion of the ?rbi1'1,I .in space . . . · ...•. (cl) ()l;b.itaLc1ngu.lai'_1H()nje9tu1~.. ..·
· . 22. · . The orb_itnl.·:anb~i=lai:n1onie~1tu111~f;n ~fectr·o.n in-~s ofbital ,is ••· · ·.. · .. · .•
(a) +}·!__ .
. ·:. ,· .. :. ·: .. ::·. . .. · , ...·.. :. _. ) _n _.
;b)Z~ro -s · ·;c)~I, : : . . '.(d) f22'__
. . . ·· .2rr. ..:.·..- .: ...: . .2n .... . .. . ... .

.. . :·.· . ._ _. - :. 2_3--. . ._r.,~e.. ?,lll~l:b~r..9l~radic)I :°?d.e~ i,1)·s.~·~·~d2p :;:~spe~·ti~;1; ;.r~ :.·:.. .; .:__. .·_:- -..
(a) 2 and.O (b) 0 and 2 (c) I and 2 · (d_) 2 and I
}'!. If each Ol;bital can hold a maximuni of three electrons. the mu11bei· ofelements in 9111 period or
periodic table (long fonn) .are ·
(a) 48 . (b) 162 (c) 50 · (cf) 75
2 _; An electron. a proton and an alpha pa,tidc h~lVC kinetic :~nfrgieS or 16E, .4E. and Erespectivcly. .
What is the qualitative order of their de Broglie wavelengths? .
..
(b)\~i-.,.>)\ :. ·. ·-(c)\1>\><~:
.
. . . .
. ·u•P~c>\1~).,,.· .. ._(d:>}\1.<?\.»ip .. .
2c;: ..Tlie riunil;c;-of1~oclal planes in a p._ orbital is:
(a)one (b)1wo . · (c)three ·· (d)zero ·
27. · Tlie quantum numbers +1/2 and -in for the electron spin represent:
. (a) rotation of the electron in clochvise and anticlock\,;ise clirectio 11 respectively.
. tb) rotation of the electron in aniitlocb\'ise and clockwise direc1ion respe~tively.
(c) magnetic moment Of the dcc1ron pointing up and down resprct ive.ly.
. (d) two quar~t.um n~eclrnnical spi11 s1.ate~ which ha.ve no classical analogue. .

28. The sptn ma·gneric moment of cobalt of the compund Hg[Co(SCN).,iJ is {Given: Cof-2] ?
(a) .[J (b) .[s (c) (cl)

29. A Is orbital refers to ---

1 .
· h an electron travel
(a) a circular track in an atom rn w11c ' -
(b) a one electron wave fi111ction ·.
t (d) aHermi~ian operator
fr ) ~n observable property of the syS ern
 , u v 11 11'- 0u unure (.\£ l_luantµm
· \Vave fonctio~ in quantum meooanfus represents •
_,(). (a) a ~tate of the system ·(b) shape of the system
(c) probability of the system (d) energy of the system
A3Patomic orbital has
3I.
(a) one radi~I node and one angular node (b) two angu_lar nodes
(c)_one angular node (d) one radial 11ode
·The orbital with two radial and two angular nodes is
32.
,(a) 3p _. _ . _ _(b) 5,d .. _. _. . _ ... (c) Sf __ . (d) 8d ._
...Which' ofthe tollo\,,.-ing ·sei ofq_uantu111 1il1riibers is riot' valid.
)). . . .·. . . :_ . . .. . . . . . 1- .. . . . ... .. . ·. . . . . 1
.. (.a)'n.· ~ ·•·-J." ' _'l•:
-. ;.: ·...
_·2='-n
. ·,.·_=?-· s=·+-
·. . 2 ·. .. , ·._:·-..·. · .. (b)11 .·= ·2- £':==·0.111=0 S~- :_;__ ·.
. . .. . ., : .· . : . .- • .. .. . . 2 .
-
·'
. . _. .
.
- . .
.
; 1. . : .. ·.· .- .. . .- .. . .. ·r- . .. ~-
•.

(c)n=4, ,(=2, m =c__l, s=.+

2 (?)n 4>t-~3; ~ -:~~_,\= 2 · · ·
·. . ·· :

:· 34. · :·vvha(f~_ttie.tpt;~f -~\ni·~~Ue i~.c~~;of_ f~ 3+ ion

26 . .. ·. · · ,
. . . . .

.. - (a)+lor~l- ·(b)+2or-2 (c)+2.5or ·- 2.5 .· (d}+3or-3 ._,. _· _. -- .

35 . .·: ··The 6rbifaldfa"grai~ in.whichthe ·Autbatr\rrinc_
ipk)i ~i_o:i~:dd:is :_:_.<. '.,· .·.·
·2~~:-,: ~:·-it :·- -•~- .: · " ·-.,. . . ,. -~; ---'.,2~~-- .·:·• -2~v ~--
- .· .
. . ·'::·· :._. . ..
·.-.,. ~---•~ ._.-; _ ._: '. ::._:2s - - ~~::.:- Ip;-::..:
·.... : .··· .- ; ... ,; . _

._.2p7.
•(a) · ·.· fl·. tJ ·•· i .· . . (b) • t .· · .·ti-· t -·· t
(c) . ,j
.:
J-
.
i- .
t .
t (d) · ft . i + Jt . i
is not ,:elated with Schrodinger equation .
.

36. . Which quantum number

_. . . . .. .

. (a) Pr_incipal -· (b}A?imuthaL ·_(c) Magneti_c_ · (d)°Spiri .

a
. 37. · ~ii~( particle of mass Ill contii,cd in a box of length L. assume /~X == L Assume fi.irthe'i" I.hat ~\p(min)
-~ <p 2>112 . Use the uncertainty principle to obtain anestimate of tl~~ :e.~ergy _p{t!Jr particle. The .
< ~valtie:wilt-be· ···· -·· -~-- - __.__· ·· ·.:.-.~· -··· · ···· · ·-· · · · · · - _,. -- . -
,,2 -. . I,:-?
(c) J . ·(cl) . ;
_(b) {8mL2 ) (32mL-} {2-mL- l