PM/11356 (Part 2)/2

Nov 2023

[Link]

उत्पाद मैनुअल
Styrene-Butadiene Rubber Latex — Specification
Part 2 Carboxylated
IS 11356 (Part 2) : 2023 के
अनसार

PRODUCT MANUAL
FOR Styrene-Butadiene Rubber Latex — Specification
Part 2 Carboxylated
ACCORDINGTO IS 11356 (Part 2) : 2023

विविन्न उत्पादोों के वलए िारतीय मानक ब्यूरो (अनुरूपता मूल्ाोंकन) विवनयम, 2018 की योजना- I के तहत
प्रमाणन के सोंचालन में अभ्यास और पारदवशिता के सोंचालन में पारदवशिता सु वनवित करने के वलए इस उत्पाद
मैनुअल का उपयोग सिी क्षेत्रीय / शाखा कायािलयोों और लाइसेंसधाररयोों द्वारा सोंदिि सामग्री के रूप में वकया
जाएगा। दस्तािेज़ का उपयोग बीआईएस प्रमाणन लाइसेंस/प्रमाणपत्र प्राप्त करने के इच्छु क सोंिावित आिेदकोों
द्वारा िी वकया जा सकता हैI

This Product Manual shall be used as reference material by all Regional/Branch Offices &
licensees to ensure coherence of practice and transparency in operation of certification
under Scheme-I of Bureau of Indian Standards (Conformity Assessment)Regulations,2018 for
various products. The document may also be used by prospective applicants desirous of
obtaining BIS certification licence/certificate.

1. उत्पाद : IS 11356 (Part 2) : 2023

Product
शीर्िक : Styrene-Butadiene Rubber Latex — Specification
Part 2 Carboxylated
Title
: NIL
सोंशोधनोों की सोंख्या
No. of amendments
2. नमूना वदशावनदे श
Sampling Guidelines
कच्चामाल No specific requirement
a) :
Raw material
b) समूहीकरण वदशावनदे श : NA
Grouping Guidelines
c) नमूने का आकार : 2 litres

Sample Size
3. परीक्षण उपकरणोों की सूची : Please refer Annex-A
List of Test Equipment

4. वनरीक्षण और परीक्षण की स्कीम : Please refer Annex-B

Scheme of Inspection
and Testing
5. एक वदन में सोंिावित परीक्षण
Possible tests in a day
All tests

6. लाइसेंस का दायरा /Scope of the Licence:

“Licence is granted to use Standard Mark as per IS 11356 (Part 2) : 2023 with the
following scope:

Name of the product Styrene-Butadiene Rubber Latex - Carboxylated

BUREAU OF INDIAN STANDARDS

MANAK BHAVAN,9, BAHADUR SHAH ZAFAR MARG,
NEW DELHI-110002
 ANNEX – A

LIST OF TEST EQUIPMENTS

Major test equipment required to test as per the Indian Standard

Sl. Tests Used In Test Equipment Chemicals

No. With Clause
Reference
Flat-bottomed dishes, lipless, of
diameter approximately 60 mm
Analytical balance with accuracy 0.1
mg. Pipette 1 ml
Total Solid, Percent
Glass Rod
(Clause
Desiccator
3.1 Table 1) IS 9316
Ovens, capable of being maintained
(Part 4) / ISO 124
at 70
°C ± 5 °C, 105 °C ± 5 °C, or at
another selected temperature
between 100 °C and 160 °C
accurate to ±5 °C/ Vacuum
Oven
pH-meter with temp indicator
Buffer solution, of nominal
(with accuracy 0.01 pH)
pH at 25 °C pH 7, Buffer solution, of
Combined electrode
(Clause 3.1 nominal pH 4, Buffer
Magnetic stirrer and magnetic
Table 1), IS solution, of nominal pH 9
bar Thermometer (1 °C)
9316 (Part 6) Reference electrolyte
dry glass or inert plastic vessel
(potassium chloride +
Electrode holder
silver chloride) Distilled
Water
Distilled water, carbon-
Tensiometer (Du Noüy type), with a
dioxide-free Toluene, of
platinum or platinum-iridium alloy
recognized analytical purity
ring of either 60 mm or 40 mm
Surface Tension,
nominal circumference / Tensiometer
Dynes/cm, at 25 °C,
(Wilhelmy type), with a flat, thin plate
(Clause
made of platinum or platinum-iridium
3.1 Table 1), IS
alloy Glass dish or vessel, of 50 cm3
9316 (Part 1) / ISO
capacity Pipette
1409
Filter Paper
Bunsen or ethanol
lamp Thermostatic
bath
gas burner or Bunsen
Specific Gravity
Hydrometer
(Clause 3.1
Hydrometer Distilled Water
Table 1), IS
Vessel
3104 (Part 2)
 Thermometer with 0.1 °C
accuracy loop stirrer
Residual Styrene, IS 4511 (Part 3) IS 4511 (Part 3)
percent by mass Dean and Stark-Distillation Methanol Reagent
(Clause Apparatus (capacity 500-ml) (containing 100 mg/kg p-tert
3.1 Table 1), IS Iodine Flask - 250-ml capacity butyl catechol or an
4511 (Part 3)/ ISO Weighing Balance equivalent polymerization
13741-1 Burette inhibitor)
Flask with Standard Potassium
stopper Stop Bromide Potassium
Watch Bromate Solution
funnel lip/vapour (potassium bromate +
seal Pipette potassium bromide)
Arrangement for cooling solution to Sulphuric Acid Solution - 18
27+- 2 degree percent (m/m).
Potassium Iodide
ISO 13741-1 Solution - 10 percent
Gas Chromatograph as per Cl 6 of (m/m)
the ISO Standard Sodium
Carrier gas Nitrogen, helium of Thiosulphate Solution -
hydrogen Micro syringe 0.1 N
Analytical balance Volumetric flasks Starch Indicator Solution

ISO 13741-1
Propionitrile (internal
Standard) Dimethyl
formamide
Tetra hydrofuran
Certified Reference material
Brookfield Viscometer as per IS 9316 (Part
Viscosity, 2) Spirit level or Bubble level
mPa.s, Glass Beaker of min 85 mm dia,
SP.1, 12 RPM/ capacity min 600 ml
SP2, 12 rpm at Rectangular Bar of 9.5 mm x 3.0
25°C, (Clause mmWater Bath (1 °C accuracy)
3.1 Table 1), IS Glass Rod/Stirrer
9316 (Part Screen with aperture approx 500
2) / ISO 1652 µm Stop watch
IS 101: Part 10: Sec 1
Instrument for determination of
IS 101: Part 10: Sec 1
PSD (monochromatic light source
Average particle Dispersants (wetting
[laser], photo detectors)
size, nm, (Clause agents; stabilizers) and/
Preparation of Sample (a rotating
3.1 Table 1), IS or mechanicalforces
riffler) Dispersion gases
101 (Part 10/Sec (agitation; sonication)
1) / ISO 22412 Dispersion liquids
ISO 22412
dry powder feeder and a
Optical apparatus for Dynamic disperser
Light Scattering
 Dispersion of particles by procedures
like
sonication, filtration, etc
Test Filter (SS wire cloth with
aperture width 180 ± 10 µm/ 80
Coagulum content,
mesh sieve) Two SS rings (ID
percent by mass,
between 25 mm to 50mm) Water Soluble
(Clause
Beaker (min 600 Etholxylated Alkyl Phenol
3.1 Table 1), IS
ml) Oven (5 percent m/m)
9316 (Part 3) / ISO
Desiccator Distilled
706
Filter Water
Paper Litmus
Weighing Balance paper
Stop Watch

The list above is indicative only and may not be considered as exhaustive
 ANNEX B

SCHEME OF INSPECTION AND TESTING

1. LABORATORY- A laboratory shall be maintained, which shall be suitably equipped (as

given in column 2 of Table 1) and staffed, where different tests given in the specification
shall be carried out in accordance with the method given in the specification.

1.1 The manufacturer shall prepare and implement a calibration plan for the test equipment.

2. TEST RECORD- The manufacturer shall maintain test records for the tests carried out to
establish conformity.

3. PACKING AND MARKING – When material is supplied in containers, the Standard Mark as
given in the Schedule of the licence shall be incorporated legibly and indelibly on each
container of the product provided always that the material so marked conforms to each
requirement of the specification. Marking shall be done as per Cl. 4.2.

3.1 However, when material is supplied in tankers or bulk packaging, the Standard Mark as
given in Schedule of the licence shall be incorporated on a test certificate to be provided
along with each consignment of the product as per the format at Appendix-1 enclosed,
provided always that the product thus marked conforms to all the requirement of the
specification.

3.3 In addition, the following shall be marked on each container and/or the test certificate:

a) BIS licence number and “For BIS certification details please visit [Link]”

5. CONTROL UNIT- For the purpose of this scheme, entire quantity of the product
manufactured in single batch shall be taken as one control unit.

6. LEVELS OF CONTROL :- The tests as indicate in Table 1 and at the levels of controls in
column 3 of Table 1, shall be carried out on the whole production of the factory which is
covered by this plan and records maintained in accordance with paragraph 2 above.

6.1 All the production which conforms to the Indian Standard and covered under the scope of
this licence shall be marked with the Standard Mark.

7. REJECTION - Disposal of non-conforming product shall be done in such a way so as to

ensure that there is no violation of provisions of BIS Act,2016.
 TABLE1

LEVELS OF CONTROL

(1) (2) (3)

Test Details Test equipment Levels of Control
Test Methods R: requirement
required (or)S: No. of
Cl. Requirement Clause Sub-contracting Sample Frequency Remarks
Reference permitted
3.1, Total Solid, IS 9316 Each control
R One
Table 1 percent (Part 4) unit
3.1, IS 9316 Each control
pH at 25 °C R One
Table 1 (Part 6) unit
Surface
Once in
3.1, Tension, IS 9316
S One three
Table 1 Dynes/cm, at (Part 1)
months
25 °C
3.1, Specific IS 3104 Each control
R One
Table 1 Gravity (Part 2) unit
Residual
3.1, Styrene, IS 4511 Each control
R One
Table 1 percent by (Part 3) unit
mass
Brookfield
Viscosity,
3.1, mPa.s, SP.1,
IS 9316 Each control
Table 1 12 RPM/ R One
(Part 2) unit
SP2, 12 rpm
at 25°C
IS 101
Average Once in
3.1, (Part
particle size, S One three
Table 1 10/Sec
nm months
1)
Coagulum
3.1, content, IS 9316 Each control
R One
Table 1 percent by (Part 3) unit
mass

Note-1: Whether test equipment is required or sub-contracting is permitted in column 2 shall

be decided by the Bureau and shall be mandatory. Sub-contracting is permitted to a
laboratory recognized by the Bureau or Government laboratories empanelled by the Bureau.

Note–2: Levels of control given in column 3 are only recommendatory in nature. The
manufacturer may define the control unit/batch/lot and submit his own levels of control in
column 3 with proper justification for approval by BO Head.
 Appendix-1
TEST CERTIFICATE
XYZ COMPANY (REGISTERED OFFICE ADDRESS AND WORKS ADDRESS)

TEST CERTIFICATE FOR STYRENE-BUTADIENE RUBBER LATEX PART 2

CARBOXYLATED

TEST CERTIFICATE NO. DATED

SUPPLIED TO M/s (Name and Address of Consignee)

It is certified that the material described below fully conforms to IS 11356 (Part 2) : 2023.
The properties of the product, as tested in accordance with the Scheme of Inspection and
Testing contained in the BIS Certification Marks License No. CM/L are as indicated below
against each order no. etc.

(PLEASE REFER TO IS 11356 (Part 2) : 2023 FOR DETAILS OF SPECIFICATION

REQUIREMENTS)
TEST RESULTS
Order Name Test Requirement Observe Control Month and Quantity Remarks
no and of the d value Unit/ Year of
date material Batch manufacture
Number

Total Solid, percent

pH at 25 °C
Surface Tension,
Dynes/cm, at 25 °C
Specific Gravity
Residual Styrene,
percent by mass
Brookfield Viscosity,
mPa.s, SP.1, 12 RPM/
SP2, 12 rpm at 25°C
Average particle size,
nm
Coagulum content,
percent by mass

The material supplied conforms to specified requirements of IS 11356 (Part 2) : 2023.

REMARKS:
Tank Car / Tank Truck / Container ship no.
MATERIAL SUPPLIED BY
Signature:
Name and Address of manufacturer:
Recognized Trade Mark if any:
“For details of BIS certification please visit [Link]”