Date:

Chapte5 CooHngthon Compo unds

Dauble Salt A comelex saltwhich
Cam lete dicsociatieta thei eostitue
9geoes medU iA khoNn aDouble

Dosble salt ie posfve teat ale its ion

Moha calt, fesoNH), SOyH

fe

Co-oHcín ate ampovnc A tomplex Salt which

doe not Unenga eomplete oiisoej ationintu
tu tonstiteot etenet iona e dim. aq
Co-odinate Coroound ooes not bas a pacrtve tut
102

aenetheg
Tke naun postulates a

hay and
Seconlay
 Date

hesta okeolen_
eetet Satisfied by
ikos valenw i
e io The secondoay
egval to te condshtin no- ano
fixtal es a metale

The ienm axps buund by the sccondary inlktu

to the tal have chanteatie Syata anoea

Definatioos of some TImpo-dant tex s

Conoxalinaton ettty
A càohdinhoo eoityConstttes a Cetral ateea
metal ato eA bonde to a fe no

b ig andA -The
central attm i to H
Co0ydinatim
otty

Jnidentate wen q
ligand bound to
atum
Sing
tc

didestote w hen a
kgant can hnd thavgh two

ote. when Sevenal dono

 Page No.:

Date:

Ambidestate igan nich has two donor atorny

ligande
bt et two 4iqeteA in complex

Coosaton Dunbex y The not Liqand

bonded

djlCa0dinaticn Sphee-) The Central atom en n

liganda atutc he d to it

enclose to in Squate brac kot

e) X doto Deined
chançe, it woutd tasy

nth Cental orn

Chanec

(E) Home le ic and beteole pti compkexeA

Campleu io uaeh a metal ik boundto ony
+3
kint dono
homokeptic tomplek

Cumplere in ahith

sheterolesbie Carmple

poty
poly hed an Th special aeneent
Contciatie ro

wieh ahe diecly nttache to

cordýnh poly beon

a ).

tae oestad atom 10n denes

Totx abeationA

compounda
Tetraamainedi asua Chlsioe
Coba lt (TT

Potassnur ttayanidonickelatelT)

7v) Arominchidochlon deitxito -N-Platnatr

(v)Dichloxidabs f ettane -l,2,dammine
()
platnm )n

(i) Ee, [e(cN)6

5-2

Herimmine coheult(L)eChlawa
tin Pestaamoecolondo Cibalt() Chslond

i) Putbaiun tsiogalatulexabeti

Mi)
fodamiuren
tetrachlaidapalst ()
biamninchlando(natlommin)Platnumluy chlmd
 Page No.:

Date:

51 SxCeciAe

TUPAC anewite
syctemic
3+

2+

Soln )Hextîe h eram ctattttehtoncte

Diammtne chomdo mett armie PlainvfT) Chlaou

Hexa agva titeaivm fnthin

3 Hexoerormie cobalt tL) Chloiola

chlomale
) Diammine. chlondo methydaOe plahowm1)

chlonlo nitito- N- cobalt (n) chlogole

y tetaammioe
S) Hetagua mangaAAeI)
S Tetachlomdoprckelate
()
nìckel (er) chlobal
1Hexaamnine (m)
,2-eiaminc) eabalb
8) TiKethae
} Tea Caxband hickle.
 V-6-T

diangnetice Pananeth
-(oloudes Coloud
spin
hish spin.
Explain

Ag pen vBT
tonflex

Co-oxobnation) 23
Hybidisaho dp

NHn NA NM, NH NH NH,

2 Diarnag netie
3 St does not chauw ol-otraition
colou sles
)Law spin complen,
 Page No.:

Date:

(na ns

IDne cob) ta 6ufer d-oGbta

9
Ca-ondinshion. dsp?
Tetradl
-bute dabta)

AA pes VeT tm ovter obrtal complex

Shew d- trawiton

hiph spio, cm phek

 Tytex Page

Date:
No.:

tGrcuncie +2
bt a 5
salvtion o (Nici)] ialouclus explain
Golehon [Ni(H,0),1*
ba
N()

As pex VBI, H, O foms etey o aobital Compler

Due to
2
Unped CA
S
Tf shous d-d tanshon

itis paano 9neti

- les high spin complex

CN o) IoneY tomplex

CN CN CN CNle)
 Page No:
Date:

diamagmhie and N C)
aremashc

CI form outey erhrtl compler

Squae panaY Ttraedra

thugh both a tra hedral, ixplas

licla

Tem butr oybitat torpeT

ny
tetd HybTh., sp
fom inner obrbitacmplex
CO

Coandn y Hyhxn Sp

So, feenaqo ehic

vaired
1111
Co COCo (o
Diagnaphe

3
S-7Fe dH,o)< fpauananohie

A eaky paramagoe hplain

 SolhiCPeo);)

Celc),]

fe

CN CaN CN CN

ib is Ceakly paaana gnatic

Explain alH),) is n oer d-orbital complky

avter rhita cmp
Sotn

Squart planer fpCeN) fon.

Hence
panc chechonho sd obbital ont
 Page No.:

Date:

Aip'

|imitatioM at Nalance Bond Theoy (uer)

ooes not cxplain hercalou exhibited by fordincin

quntitate isteprtahon
of the theímodynathie Kioethio rtabiltis of,
Corsau nathion

wegardin tetrakedral and squaenleay

stao -cooxdi,ate comple

(
d-abitatopT#fg

Cpsfad ela
 Page No.:

Date:

SPcfocheni cal Sehes

T4cNcsKedta NHenlc Co.

dy'd yz dy2

t
at

5
ela Selr

Acc

CO

Tetrabeoral
Tayarad byeadal Co,(c0))

Galcooctabsdyal

st Sorn
uchetatve bornolertic met
 Page No.:

Date:

s9- te (o)s] and an of dffeet colaua.

AccniBT cN

sp'

2d
CN CN (N CN CN C

Jt is Dio manat

complen
bgh spin

V8T H 0 forn o fe Cormplexs

Acc. to
sp'a
Hybrstn
 Date:

(FeCHzo),9"
funpaord

.", coloules

2 hágh spin tanplex.

CETCst feildspliting
Enugy.

the

Bw Fneto ano

ahat is spectochemica
senia)

Oxden ot
be los

<NCS<edta<NH 'Sen KNCO

<CO.
) A<P, the fauth eteetron ctex ane Q
 Page No.

Date:

tlecoom to secepy a tyorbitad

tt

NH
eat ed tA

ferm
plex
oðbi tal
to tomple
CFT

dep
4,P)

fIr)
te (r)

LAeoeing to CfT
 Page No.:

Date:

Tsomexsmj0 Cooadinatan Campaund

compovndy that
havethe same cheroica fosrnula bol
atom

(b) trutual iiomuism

Linkage Tsomausm

(MNo,
its
somer Pertamine ib -N fobolHT) Clode

(MCONo)

fentaammenI-0 obet tttI) thtoyde

Coost dinate so me

Hexaammihe Cobalf(,n)
Cobalf(m) Aeuocyanido Gomat (ar)
 Page No:

Date:

Lonisation Tso mex

Iontathon icamoh ah be aLffereestat by adho

whtte ppt. obtanio l)

ance ahee tke

i8)Solvate 9somet

ionisaton isomer
ite the T pAC

bow
 Page No,

Date:

GHeomettical Lsome

GOUNd the tl
me

NH,
0ptical isomen

Co
NH, NHn

Coi

Co
NH
Co:
1

mewdonat

Ermpl
Soln
3M(LE), A, Co cl, len), 1<tras
Cis opficd iso mes

opti cal isonex

en
30, fically

bcavse f So, Dft eaty a ctie

Sopeimesale
 Page No.

Date:

(teacoy

exe
ch otheY,

active compound -
hoe

en
en

Show Geonetiea
Ko rrver, but it i

opheal atve
Draw the stYS
fe (rl),(cN)u NH
NH
Sals N

e CN
CN

rons

whi h

cooNlinaten
ettes
folloeiag ttuwe
Out of the
 Page No.:

Date:

b) trans
Cacicos
Solb The two enttle
3

cis- Cinciyo),)

Hpplicatibs a Coselinstan coapound s

Tn biala4 Seeral Bis leaical
importust natua

plants s a complex of iluxoghrpisenfin

[Link] pruseat
Camplex

E DTA or
A Used tte ttmeo or leasl

yTo estimate tte hq aehess oh wate

hotdne ol oote eto patence ot(a
ons. he
nth .Ca 21
Casbe
3 Date

Tnciectoplathg

Csancinahm
inclole
uhacitim Comple, ph, e) RhCi)a nlknsn bihlat,
96 vsee tor the A)kenca