Aluminium Extraction
The main ore of aluminium is bauxite (impure aluminium oxide). After it is mined, it is first
purified by adding it in sodium hydroxide. The impurities do not dissolve and are filtered
off. The dissolved aluminium oxide is then precipitated out as aluminium hydroxide by
diluting with water. This is then heated to form pure white aluminium oxide, or alumina.
The aluminium is then extracted by electrolysis.
The alumina is added to and electrolytic cell and melted. A compound called cryolite
(another aluminium compound) is added to lower the melting point of the
electrolyte or operating temperature and increase conductivity. The electrodes are
made of graphite. Oxygen gas collects at the anode. Due to the high temperature, the
oxygen reacts with the carbon in the graphite anode to form CO 2/CO so the anode
must be periodically replaced.
The cathode is very interesting; it is the lining of the electrolytic cell that is made the
cathode. Molten aluminium collects here.
At cathode: Al3+ (l) + 3e- Al (l)
At anode: 2O2- (l) O2 (g) + 4e-
Properties and Uses:
Aluminium is a more reactive metal than its apparent lack of reactivity is explained by a
thin protective oxide coating. This coating (unlike iron oxide) does not flake off and
makes aluminium corrosion resistant.
Aluminium metal is relatively light, corrosion resistant, and a good conductor of heat and
electricity. When alloyed, it becomes quite resistant.
Aluminium can be used in making kitchen foils due to its malleability and heat
conducting ability, in overhead power cables due to its light weight and electrical
conducting abilities, and in aircraft construction due to its lightness and resistance to
corrosion.