Black Body Radiation - Short Notes
Definition
A Black Body is a body that absorbs and emits all types of electromagnetic radiation
such as X-rays, gamma rays, microwaves, UV, IR, etc.
Properties of Black Body
• A black body is a perfect absorber and perfect emitter.
• Examples: Platinum black, Sun, and nearly perfect black bodies.
Ideal Black Body
An ideal black body has emissivity ε = 1.
Intensity and Emissive Power
E
Intensity, I =
tA
E
Emissive Power, P =
A
Emissive Power vs Wavelength Curve
• The black body radiation curve is continuous.
• Emissive power increases, reaches a peak at certain wavelength, and then de-
creases.
• As temperature increases:
– The peak shifts to lower wavelengths.
– T3 > T2 > T1 implies λm3 < λm2 < λm1 .
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Wien’s Displacement Law
Statement: The wavelength λm at which maximum emission occurs is inversely
proportional to the absolute temperature T of the black body.
b
λm =
T
Where b = 2.898 × 10−3 m·K
Conclusion: As temperature increases, the peak wavelength shifts to shorter values
(blue shift).
Area Under Black Body Curve
The total emissive power is equal to the area under the spectral energy curve:
Z ∞
E= Eλ dλ
0
Temperature Dependence & Stefan–Boltzmann Law
As temperature increases, the total emissive power increases:
E = εσT 4
Where:
• ε: Emissivity ( = 1 for ideal black body)
• σ = 5.67 × 10−8 W/m2 K4 : Stefan–Boltzmann constant
Also,
uν = 6T, uλ = εσT 4
Peak Emissive Power
Emax ∝ T 5
Wien’s Displacement Law – Intensity Form
A −B/(λT )
Eλ dλ = e dλ
λ5
• Valid at short wavelengths (high frequencies)
• A, B: Wien’s constants
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Rayleigh–Jeans Law – Classical Derivation
When a black body is heated:
• Atoms and molecules vibrate like simple harmonic oscillators (SHO)
• Emit electromagnetic waves
No. of modes of vibration:
8π
Nλ dλ = dλ
λ4
Average energy per mode:
⟨E⟩ = kT
Energy density:
8πkT
uλ dλ = (Nλ dλ)(⟨E⟩) = dλ
λ4
Conclusion:
1
uλ ∝
λ4
Limitation of Rayleigh–Jeans Law
• Valid only at long wavelengths or low frequencies
• Fails at short wavelengths → Ultraviolet catastrophe
Failure of Classical Physics: Ultraviolet Catastrophe
The Rayleigh–Jeans law predicts:
uν ∝ ν 2
So as ν → ∞, uν → ∞
This leads to infinite energy at high frequency → Not possible.
Conclusion: Classical theory fails at short wavelength (high-frequency) limit.
Planck’s Hypothesis
• Energy is emitted or absorbed in discrete packets (quanta)
• Each packet: E = hν
• Energy is not continuous
Average Energy per oscillator:
hν
⟨E⟩ =
ehν/kT − 1
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Planck’s Radiation Law – Spectral Energy Density
8πhν 3 dν
uν dν = 3
· hν/kT
c e −1
Planck’s Radiation Law – In Terms of Wavelength
8πhc 1
E(λ, T ) = 5
· hc/(λkT )
λ e −1
Planck’s Law Explains Full B.B. Radiation Curve
Solves ultraviolet catastrophe and matches experiment across all wave-
lengths.
Special Cases of Planck’s Law
Case 1: hν ≫ kT
A −B/λT
uλ dλ = e dλ (Wien’s Law)
λ5
Case 2: hν ≪ kT
8πkT
uλ dλ = dλ (Rayleigh–Jeans Law)
λ4
Case 3: For uν = max
λm T = b (Wien’s Displacement Law)
Case 4: Total energy density
Z ∞
u= uλ dλ ∝ T 4 (Stefan–Boltzmann Law)
0
Note: Average Energy Limit Behavior
hν
⟨E⟩ =
ehν/kT
−1
If h → 0 ⇒ ⟨E⟩ → kT , which agrees with classical equipartition theorem.QM→CM
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