Chemistry MCQ (PFSA) : Compiled by
Chemistry MCQ (PFSA) : Compiled by
A. ionic bonding
B. amphoteric nature
C. covalent bonding
Answer. C
d) Aldehydes
3. Acetic acid is weak acid than sulphuric acid because which of the following reasons?
Answer. Answer: b
Explanation: CH3COOH is slightly ionised than H2SO4. Acetic acid is weak acid than sulphuric acid
because It has less degree of ionization.
Point to ponder
Presence of methyl group decreases the acidic character of acetic acid due to positive inductive effect
(+I). inductive effect
a) electronegative
b) electropositive
c) metallic
d) semi-metallic
Answer. A
5. Which bond acts like a bridge two molecules formed by a covalent bond?
b) Ionic bond
c) Hydrogen bond
d) Metallic bond
Answer. C
a) True
b) False
Answer. A
Bcz hydrogen directly attach to electronegativity atom causing slightly positive charge on it.
a) intermolecular examples
aspirin?
b) intramolecular
In a water molecule, the hydrogen bonds are formed between other molecules but not within the same
molecule. The presence of hydrogen between molecules is intermolecular hydrogen bond and
presence of hydrogen bond in the molecule itself is intramolecular hydrogen bond.
8. Which of the following molecule can form a hydrogen bond with hydrogen?
a) Sodium
b) Oxygen
c) Aluminium
d) Rubidium
Ans. B
F, O, N
Most Electronegative elements can only form hydrogen bonds with hydrogen, Among Sodium,
Oxygen, Aluminium, and Rubidium, Oxygen is the electronegative element. So only oxygen can form
a hydrogen bond.
A. 0.2m
B. 0.2mm 10-3
C. 0.2nm
D. 0.2pm
Ans. B
10. The mass spectrometer is used to determine the Mass number of isotopes and
A. Atomic number
B. Relative abundance
C. Electronic configuration
Answer. B
The basic principle of mass spectrometry (MS) is to generate ions from either inorganic or organic
compounds by any suitable method, to separate these ions by their mass-to-charge ratio (m/z) and to
detect them qualitatively and quantitatively by their respective m/z and abundance.
here are four stages in a mass spectrometer which we need to consider, these are – ionisation,
acceleration, deflection, and detection.
11. m/z represents mass divided by charge number and the horizontal axis in a mass spectrum is
expressed in units of m/z. Since z is almost always 1 with GCMS, the m/z value is often considered to
be the mass. unipoitive ions are formed, so these ions are
deflected and separated based on teir mass
B. – particle
C. X-rays
Answer. D
13. The number of peaks obtained in mass spectrometry shows
C. Number of isotopes
Ans. C
same protons
A. Same number of neutrons same electrons
different neutrons
B. Same mass number same atomic number
different mass number
same chemical properties
C. Same physical properties different physical properties
D. Isotopes of an element have same atomic number but different mass number. Hence, they have
same number of electrons. Chemical properties are related to the number of valence electrons. Thus,
isotopes have similar chemical properties.
Isotopes with an even atomic number and even mass number are abundant
D. all
Answer. D
atomicity?
A. Atomicity
C. Both a and b
D. Difficult to predict
Answer. C
17. Which of the following is not a macromolecule?
B. Haemoglobin
C. Diamond
D. Maltose disaccharide
Answer. D
18. Which of the following methods is used to estimate hydrogen in an organic compound?
B. Dumas method
C. Kjeldahl’s method
Answer. A
A. 5
B. 4
C. 3
D. 2
Answer. A
20 The property of a substance to absorb moisture from the air on exposure is called______?
A. Osmosis
B. Deliquescence
C. Efflorescence
D. Desiccation
Answer. B
Answer. B
22. The fraction of petroleum having boiling range 40-200°C is called _____?
A. Kerosene
B. Gasoline
C. Petroleum ether
Answer. Gasoline
B. Iron
C. Mercury
D. Copper
Answer. A
Answer. C
25. Which element does not occur in nature but can be produced artificially?
B. Uranium
C. Radium
D. Thorium Thalium
Answer. A
A. Tin
Zn????
B. Silver
C. Zinc
D. Chromium
Answer. B
A. Shine Silver
B. Quick Silver
C. Slow Silver
D. Slippery Silver
Answer. C
B. Slate
C. Gneiss
D. Schist
Answer. A
29. One of the following ways of expressing the concentration of a solution does not depend on
temperature. It is____?
A. Molarity
B. Molality
C. Normality
D. Formality
Ans. B
A. Promoter
B. Activator
C. Retarder
D. Super catalyst
Ans. b
B. Brass
C. Tape water
D. Graphite
E. Sand
Ans. D
Ans. C
D. may be greater or less than the first ionization energy depending on the nature of the element
Ans. B
A. Nitric oxide
B. Nitrogen dioxide
C. Nitrogen pentoxide
A. Chemical
B. Biochemical
C. Physical
D. Nuclear
36. How many methods of removing the radio active impurities are there?
a) 2
b) 3
c) 3
d) 4
Ans. 2
37. The treatment of water with ___ improves the taste of water
a) Oxygen
b) Chlorine
c) KMnO4
d) Ozone
Ans. D
Because of its excellent disinfection and oxidation qualities, ozone is widely used for drinking water
treatment. Ozone can be added at several points throughout the treatment system, such as during pre-
oxidation, intermediate oxidation or final disinfection.
38. Reacting the water with ___ removes the odour due to the phenols
a) KMnO4
b) MnO4
c) Potassium
d) Magnesium
Ans. A
b) Detergents
c) Phenols
d) Dissolved oxygen
Ans. B Detergents
a) Fertilizer
b) Pesticide
c) Reagent
d) Medicine
Ans. A
41. In the trickling filter process, the ___build up and they block the passage
a) Sludge formed
b) Dissolved impurities
c) Dissolved solids
d) Micro organisms
Ans. D
a) Increase efficiency
b) Decrease efficiency
c) Increase pressure
Ans. A
43. The depth of the rectangular circular tanks in the trickling filters method is having the depth of
____
a) 4m
b) 3m
c) 2m
d) 1m
Ans. C
44. Trickling filter method is _____ than the activated sludge process
a) Fast
b) Slow
c) Very fast
d) Moderate
Ans. B
45. The water after removing of sludge in the biological oxidation process is treated with ____
a) Chlorine
b) Bromine
c) Fluorine
d) Iodine
Ans. A
46. All impurities are oxidised into the ___ and _____ in the biological oxidation process
Ans.
47. In reverse osmosis, the membrane pores are smaller in size about ____
a) 0.04 to 600nm
b) 0.08 to 500nm
c) 0.1 to 600nm
d) 0.2 to 500nm
Ans. A
b) Styrene
c) Benzoyl peroxide
d) Phenol
Ans. A
a) 100%
b) 99%
c) 98%
d) 97%
50. The semi permeable membranes used in the reverse osmosis is ___
a) Cellulose
b) Glucose
c) Cellulose acetate
d) Glucose acetate
ans. C
a) Reverse osmosis
b) Multi flash distillation
c) Electro dialysis
d) Smelting
Ans. D
a) 22oC
b) 23oC
c) 24oC
d) 25oC
Ans.D
53. 100 parts of CaCO3 is equivalent to the ____ parts of sodium carbonate
a) 103
b) 104
c) 105
d) 106
ans. D
a) 10
b) 20
c) 30
d) 40
Ans. A
a) 5
b) 10
c) 15
d) 20
ans. B
a) Malleability
b) Ductility
c) Conductivity
d) Colour
ans. D
57. Iron undergoes corrosion to produce ____ coloured hydrated ferric oxide
a) Red
b) Brown
c) Green
d) Blue
Ans. B
Macromolecules
1. A polymer in which three different monomers combine called.
A. Copolymer
B. Terpolymer
C. Homopolymer
D. Biopolymer
Ans. B
A. Vinyl chloride
B. Styrene
C. Methyl methacrylate
D. Hexamethylenediamine
Ans. C
B. Epoxy paints
C. Polyamide resins
D. Polyvinyl chloride
Ans. B
A. Glucose
B. Glyceraldehydes
C. Oligosaccharides
Ans. D
A. Acrylic acid
B. Epichlorohydrin
C. Vinyl chloride
Ans. D
7. Amylose is
A. Soluble in water
B. Insoluble in water
C. Soluble in alcohol
Ans. A
A. Strecker
B. Sabatier
C. Runge
D. W. H. Carothers
Ans. D
B. Sample protein
C. Proteases
D. Conjugated protein
Ans. D
10. Regular coiling or zigzagging of the polypeptide through hydrogen bonding is its.
A. Quantum structure
B. Secondary structure
C. Tertiary structure
D. Primary structure
Ans. A
11. Ergosterol is
A. Ergocalciferol
B. Vitamin D2
C. Sterol
Ans. C
A. Organic solvents
C. Inorganic solvents
A. Glycerols
B. Fatty acids
Ans. C
A. Derived lipids
B. Simple lipids
C. Compound lipids
Ans. C
A. Lyases
B. Ligases
C. Lipases
D. Hydrolases
Ans. C
A. Acid
B. Alkali
Ans. B
17. Enzymes that catalyze the transfer of groups within a molecule are called
A. Isomerases
B. Lyases
C. Transferases
D. Ligases
Ans. C
A. Enzyme
B. Substrate
Ans. B
A. Lactic dehydrogenase
B. Alkaline phosphatase
C. L-asparaginase
D. Cellulase
Ans. C
A. Pus cells
B. Sperm heads
C. 1872
Ans. A
21. The mechanism by which the genetic information can be duplicated is called
A. Duplication
B. Transcription
C. Replication
D. Mutation
Ans. C
A. Cytosine
B. Thymine
C. Adenine
D. Guanine
Ans. B
2. Types of bonds
1............ is the expression of the number of moles of solute dissolved per litre of solution.
A. Molarity
B. Molality
C. Normality
D. Mole fraction
Ans. A
2. It is defined in terms of
A. Molality
B. Normality
C. Molarity
Ans. B
A. Normality
B. Molality
C. Formality
Ans. A
5......... is the ratio of the number of moles of one component to the total moles of a mixture or
solution
A. Molality
B. Mole fraction
C. Solution
Ans. B
A. Pi (π)
B. Sigma(Σ)
C. Both
D. Neither
Ans. B
6. The complete transfer of one or more electrons between atoms constitutes informing
A. ionic bond
B. covalent bond
C. coordinate covalent bond
D. dative bond
Ans. A
A. protons
B. electrons
C. neutrons
D. none of above
Ans. B
8. Ionic and covalent bonds requires a lot of energy to break them because they are very
A. strong
B. volatile
C. weak
D. efficient
Ans. Strong
10........... is an amide type of covalent chemical bond linking two consecutive alpha-amino acids from
C1 of one alpha-amino acid and N2 of another, along a peptide or protein chain.
11. Is a type of covalent bond that joins a carbohydrate (sugar) molecule to another group, which may
or may not be another carbohydrate.
12. A coordinate bond (also called a dative covalent bond) is a covalent bond (a shared pair of
electrons) in which both electrons come from the same atom. True/False
13. ....... is a primarily electrostatic force of attraction between a hydrogen (H) atom which is
covalently bound to a more electronegative atom or group, particularly the second-row elements
nitrogen (N), oxygen (O), or fluorine (F)—the hydrogen bond donor (Dn)—and another.
14. When an acid reacts with metal carbonate, the products are
salt
water
carbon dioxide
all of above
Ans. A
colorless
pink colored
yellow colored
orange colored
Ans. A
16. The process in which acids (H+) and bases (OH-) react to form salts and water is called
neutralization
hydrogenation
halogenation
sublimation
Ans. A
17. A substance that donates a pair of electrons to form a coordinate covalent bond is called
Lewis acid
Lewis base
Bronsted-Lowry acid
Bronsted-Lowry base
Ans.
A. Covalent bond
B. Ionic bond
Ans. A
A. 2
B. 3
C. 4
Ans. 3
A. 2
B. 3
C. 4
Ans. 3
B. 3
C. 4
Ans. A
A. Zero
B. One
C. Three
Ans. A
23....... of a chemical element is the number of protons found in the nucleus of every atom of that
element.
Topics
1. Distillation, types
2. Filtration
3. Sublimation
4. Potentiometry
A. diesel
B. petrol
C. paraffin
D. all of above
A. diluted solution
B. impure solution
C. condensed solution
D. concentrated solution
A. exact temperature
D. high pressures
5. If a substance decomposes when heated to its boiling point, the suitable method is
A. simple distillation
B. fractional distillation
C. vacuum distillation
D. crystallization
A. mixes together
B. condenses after distillation
A. thermometer
B. water bath
C. fractionating column
D. reflux condenser
a) 0.25 µm
b) 0.22 µm
c) 0.27 µm
d) 0.26 µm
a) Sterilization of media
b) Removal of debris
c) Plasma clarification
d) Off-gas analysis
11. Which of the following filters are ideal for vitamin sterilization?
b) Oxalate filters
A drying
B. filtration
C. sieving
D. extraction
A. splashing
B. bubbling
C. bumping
D. backflow
15. To cover one-fourth of filter paper with precipitate filter paper should be
large
small
medium
light
3-4cm
1-2cm
4-5cm
5-6cm
five times
four times
thrice
twice
18. a change directly from the solid to the gaseous state without becoming liquid
when a gas or vapor changes directly into a solid without first changing to a liquid (ex. frost)
20. The use of electrodes to measure voltages that provide chemical information and Based on the
measurement the potential of electrochemical cells without drawing appreciable current.
22. Prevents the components of the analyte solution for mixing with those of the reference electrode
A. Salt bridge
B. Indicator electrode
Answer Key
1. D
2. C
3. C
4. A
5. C
6. B
7. C
8. B
9. D
10. C
11. A
12. B
13. A
14. Large
15. 1-2 cm
16. 4-times
17. Sublimation
18. Deposition
19. Potentiometry
20. A
21. A
A. Shape
B. Phase
C. Mechanism
D. All
A. Filter paper
B. Vacuum desiccators
C. Oven
D. None of these
4. A substance having a very high vapour pressure at its melting point on heating will show
A. Melting
B. Sublimation
C. Decomposition
D. Condensation
A. Crystallization
B. Sublimation
C. Solvent extraction
D. Filtration
6.A technique of partition chromatography in which the solvent is in a pool at the bottom of container
A. Adsorption chromatography
B. Ascending chromatography
C. Radial chromatography
D. Descending chromatography
D. Distributive law
A. Quantitative analysis
B. Qualitative analysis
C. Stoichiometry
D. Physical chemistry
A. Quantitative analysis
B. Qualitative analysis
C. Stoichiometry
D. Physical chemistry
[Link] solid which is left over the filter paper as a result of filtration
A. Insoluble Particles
B. Residue
C. Crystals
D. Mud
A. Solution
D. Amount of solvent
A. Plastic
B. Fibre
C. Porcelain
D. Steel
A. Vapourization
B. Solvent extraction
C. Filtration
D. Crystallization
[Link] of the following is used as an indicator in the titration of iodine with hypo?
(c) Starch
[Link] will be the pH at the equivalence point in the titration of a weak acid and a strong base?
(a) 0
(b) >7
(c) 7
(d) <7
(a) 3-5
(b) 8-9
(c) 2-4
(d) 6-8
a) Ion-exchange
b) Exclusion principle
c) Differential adsorption
d) Absorption
18. Arrange the following compounds in order of their increasing adsorption tendencies.
a) Cellulose >> starch >> calcium carbonate >> alumina
a) The lesser the polarity of solute, more strongly it will be adsorbed on a polar surface
b) The greater the polarity of solute, more weakly it will be adsorbed on a polar surface
c) The greater the polarity of solute, more strongly it will be adsorbed on a polar surface
Answer Key
1. D
2. C
3. B
4. B
5. C
6. B
7. C
8. B
9. A
10. B
11. B
12. C
13. D
14. C
15. B
16. A
17. C
18. A
19. B
20. C
A. Spectroscopy
1. UV-Visible Spectroscopy
1 What is the wavelength range for vacuum UV spectrum of light?
a) 400 nm – 700 nm
b) 700 nm to 1 mm
c) 0.01 nm to 10 nm
d) 10 nm to 200 nm
Answer- D
2 The intensity of an absorption band is always proportional to which of the following factor?
a) Atomic population
d) Temperature
Answer-B
b) dyne Å-1
c) Nm-1
d) kp
Answer-D
(All of the above units are correct for force constant except kp, i.e. kilogram force or kilopond, which
is the unit of force.)
4 The vibrations, without a center of symmetry are active in which of the following region?
c) Raman and IR
Answer: c
Explanation: If a molecule has COS, then its vibrational mode will either IR active or Raman Active
5 Which of the following compounds does not absorb light in the UV/visible spectrum?
a) Aspirin
b) Paracetamol
c) Chloral hydrate
d) Phenobarbitone
Answer-C.
In order to absorb light in the UV/visible spectrum, a molecule must possess a chromophore e.g. a
benzene ring or conjugated double bonds. Chloral hydrate does not possess a chromophore.
6 : Beer Lambert’s law gives the relation between which of the following?
Answer-C
Transmittance is the ratio of the radiant power transmitted by a sample to the radiant power
incident on the sample. Absorption is the negative logarithm of transmittance.
8 Beer’s law states that the intensity of light decreases with respect to _____
a) Concentration
b) Distance
c) Composition
d) Volume
Answer-A
9 Lambert’s law states that the intensity of light decreases with respect to ____
a) Concentration
b) Distance
c) Composition
d) Volume
Answer-B
10 The representation of Beer Lambert’s law is given as A = abc. If ‘b’ represents distance, ‘c’
represents concentration and ‘A’ represents absorption, what does ‘a’ represent?
a) Intensity
b) Transmittance
c) Absorptivity
d) Admittance
Answer-C
a) It involves transmission
Answer: c
Explanation: In Absorption spectroscopy, reflection must also be kept minimum along with
scattering. Amount of absorption depends on the number of molecules in the material.
12 Transmittance is given as T = P/Po. If Po is the power incident on the sample, what does P
represent?
Answer-P represents radiant power transmitted by the sample. Transmittance is the ratio of radiant
power transmitted by the sample to the radiant power that is incident on it.
13 What is the unit of absorbance which can be derived from Beer Lambert’s law?
a) L mol-1 cm-1
b) L gm-1 cm-1
c) Cm
d) No unit
a) L mol-1 cm-1
b) L gm-1 cm-1
c) Cm
d) No unit
Answer-A.
The unit of absorptivity is L mol-1 cm-1. If the concentration is represented as gm per litre it
becomes L gm-1 cm-1.
14 Which one of the following arrangements for the sequence of the main components of
Answer-A
Answer-D
2. NMR Spectroscopy
1. NMR spectroscopy is used for determining structure in which of the following materials?
a) Radioactive materials
c) Liquids
d) Gases
a) Radioactive radiation
b) IR radiation
d) Microwaves
3. NMR spectrometer provides ____ and _____ method of determining structure in soluble chemical
compounds.
a) Accurate, destructive
b) Accurate, non-destructive
c) Inaccurate, destructive
d) Inaccurate, non-destructive
4. NMR spectroscopy indicates the chemical nature of the ____ and spatial positions of
___
a) Electrons, Protons
b) Neutrons, electrons
c) Nuclei, electrons
5. In NMR spectroscopy, the spinning nuclei in strong magnetic field must be irradiated by which of
the following?
6. Interaction between matter and electromagnetic radiation can be observed by subjecting a substance
to magnetic fields in which of the following manner?
7. When energy is absorbed by the sample, the absorption can be observed as a change in signal
developed by which of the following components?
a) Amplifier
b) Photodetector
c) GM counter
d) Radiofrequency detector
8. Which of the following are considered to be the lowest form of Electromagnetic radiation?
a) IR radiation
b) Micro waves
c) UV radiation
d) Radio waves
9. The amount of energy available in radio frequency radiation is sufficient for which of the
following?
a) Excite an atom
b) Vibrate an atom
c) Vibrate a molecule
10. Nuclei having either the number of protons or neutrons as odd have ___ spin.
a) Integral spin
d) Positive spin
11. If the number of protons or neutrons is even the spin of the nucleus will be which of the
following?
a) Integral spin
c) Zero spin
d) Positive spin
12. The difference between the field necessary for resonance in the sample and in some arbitrary
chosen compound is which of the following?
a) Field shift
b) Matrix effects
c) Chemical shift
d) Resonance shift
14. Elementary particles such as electrons and nucleus have the property of spin.
a) True
b) False
(A) 1.3
(B) 1.5
(C) 0.9
(D) 2.5
(A) The relative no. of protons present in the excited state and ground state
(B) Relative no. of neutrons present in the excited state and ground state
(C) Relative no. of nucleus present in the excited state and ground state
(A) 15N
(B) 11B
(C) 19F
(D) 31P
(B) Gauss
(C) Joule/gauss
a) Radioactive materials
c) Liquids
d) Gases
Answer: c
a) Radioactive radiation
b) IR radiation
d) Microwaves
Answer: c
3. NMR spectrometer provides ____ and _____ method of determining structure in soluble chemical
compounds.
a) Accurate, destructive
b) Accurate, non-destructive
c) Inaccurate, destructive
d) Inaccurate, non-destructive
Answer: b
4. NMR spectroscopy indicates the chemical nature of the ____ and spatial positions of
___
a) Electrons, Protons
b) Neutrons, electrons
c) Nuclei, electrons
Answer: d
Explanation: NMR spectroscopy indicates the chemical nature of the nuclei and spatial positions of
neighbouring nuclei. It is one of most powerful techniques for chemical analysis.
5. In NMR spectroscopy, the spinning nuclei in strong magnetic field must be irradiated by which of
the following?
Answer: b
Explanation: In NMR spectroscopy, the spinning nuclei in strong magnetic field must be irradiated by
a weaker field which is perpendicular to it. This permits the identification of atomic configurations in
molecules.
6. Interaction between matter and electromagnetic radiation can be observed by subjecting a substance
to magnetic fields in which of the following manner?
Answer: c
Explanation: Interaction between matter and electromagnetic radiation can be observed by subjecting
a substance to two magnetic fields. One magnetic field must be stationary and the other field must be
varying at some radio frequency.
7. When energy is absorbed by the sample, the absorption can be observed as a change in signal
developed by which of the following components?
a) Amplifier
b) Photodetector
c) GM counter
d) Radiofrequency detector
Answer: d
Explanation: When energy is absorbed by the sample, the absorption can be observed as a change in
signal developed by radiofrequency detector. It is then given to an amplifier.
8. Which of the following are considered to be the lowest form of Electromagnetic radiation?
a) IR radiation
b) Micro waves
c) UV radiation
d) Radio waves
Answer: d
Explanation: Radio waves are considered to be the lowest form of Electromagnetic radiation. NMR
uses radio frequency radiation for detection of structure of substances.
9. The amount of energy available in radio frequency radiation is sufficient for which of the
following?
a) Excite an atom
b) Vibrate an atom
c) Vibrate a molecule
Answer: d
Explanation: The amount of energy available in radio frequency radiation is sufficient for affecting
the nuclear spin of an atom. It constitute the most fundamental part of spectroscopy.
10. Nuclei having either the number of protons or neutrons as odd have ___ spin.
a) Integral spin
c) Zero spin
d) Positive spin
Answer: b
Explanation: Nuclei having either the number of protons or neutrons as odd have half-integral spin.
Examples are H1 and B11.
11. If the number of protons or neutrons is even the spin of the nucleus will be which of the
following?
a) Integral spin
d) Positive spin
Answer: c
Explanation: If the number of protons or neutrons is even the spin of the nucleus will be zero.
Examples are C12 and O16.
12. The difference between the field necessary for resonance in the sample and in some arbitrary
chosen compound is which of the following?
a) Field shift
b) Matrix effects
c) Chemical shift
d) Resonance shift
Answer: c
Explanation: The difference between the field necessary for resonance in the sample and in some
arbitrary chosen compound is called as chemical shift. Chemical shift is expressed in parts per
million.
13. Chemical shift allows a chemist to obtain the idea of how atoms are joined together.
a) True
b) False
Answer: a
Explanation: Chemical shift allows a chemist to obtain the idea of how atoms are joined together. It is
also possible to know the number of particular atoms present in a molecule.
14. Elementary particles such as electrons and nucleus have the property of spin.
a) True
b) False
Answer: a
Explanation: Elementary particles such as electrons and nucleus have the property of spin. They are
known to behave as if they rotate about an axis.
(A) Tesla
(B) Gauss
(C) Joule/gauss
(A) 1.3
(B) 1.5
(C) 0.9
(D) 2.5
(A) The relative no. of protons present in the excited state and ground state
(B) Relative no. of neutrons present in the excited state and ground state
(C) Relative no. of nucleus present in the excited state and ground state
(A) 15N
(B) 11B
3. Mass Spectroscopy
1. Mass spectrometers are used to determine which of the following?
a) Composition in sample
d) Properties of sample
a) J.J Thompson
b) Goldstein
c) Nikola Tesla
d) Aston
3. In mass spectrometer, the sample that has to be analysed is bombarded with which of the
following?
a) Protons
b) Electrons
c) Neutrons
d) Alpha particles
a) Mass
b) Charge
c) Molecular weight
5. In mass spectrometer, the ions are sorted out in which of the following ways?
6. No two molecules will be fragmented and ionized in exactly the same manner.
a) True
b) False
7. The procedure for mass spectroscopy starts with which of the following processes?
b) The ions are separated by passing them into electric and magnetic field
8. In mass spectrometer, the ion currents are measured using which of the following?
a) Scintillation counter
b) Ion counter
c) Electrometer tube
d) Electric fields
9. Which of the following ions pass through the slit and reach the collecting plate?
10. Which of the following statements is not true about mass spectrometry?
a) Impurities of masses different from the one being analysed interferes with the result
11. In mass spectrometer, the sample gas is introduced into the highly evacuated spectrometer tube
and it is ionised by electron beam.
a) True
b) False
a) Inlet system
b) Sweep generator
c) Ion transducer
d) Mass analyser
13. Which of the following can be introduced into the ionization chamber directly?
a) Solid samples with low vapour pressure
a) Initial system
b) Sample reservoir
15. Which of the following is normally done to convert the sample into gaseous state?
a) Sample is pressurized
c) Sample is heated
d) Sample is cooled
16. Which of the following probes are used for the introduction of the sample?
a) Silica
b) Quartz
c) Graphite
d) Silver
a) Field ionisation
b) Spontaneous ionisation
c) Spark ionisation
d) Chemical ionisation
b) Monochromator
c) Detector
d) Sample
20. Which of the following is not a type of ion detector used in mass spectrometers?
a) Electron multiplier
d) Photographic plates
a) Hypodermic needle
b) Glass bulb
c) Capillary tube
d) Curvette
a) Composition in sample
d) Properties of sample
Answer: c
Explanation: Mass spectrometers are used to determine the relative mass of atoms and molecules.
Aston made the instrument more accurate.
a) J.J Thompson
b) Goldstein
c) Nikola Tesla
d) Aston
Answer: a
Explanation: J.J Thompson introduced mass spectrometers. Aston modified the instrument to make it
more accurate.
3. In mass spectrometer, the sample that has to be analysed is bombarded with which of the
following?
a) Protons
b) Electrons
c) Neutrons
d) Alpha particles
Answer: b
Explanation: In mass spectrometer, the sample which is to be analysed is bombarded with electrons.
As a result, ions are produced.
b) Charge
c) Molecular weight
Answer: d
Explanation: Mass spectrometer separates ions on the basis of mass to charge ratio. Most of the ions
are singly charged. Hence, the mass to charge ratio is equal to the mass.
5. In mass spectrometer, the ions are sorted out in which of the following ways?
Answer: c
Explanation: In mass spectrometer, the ions are sorted out by accelerating them through electric and
magnetic field. A record of number of different kinds of ions is called mass spectrum.
6. No two molecules will be fragmented and ionized in exactly the same manner.
a) True
b) False
Answer: a
Explanation: No two molecules will be fragmented and ionized in exactly the same manner. This is
how different molecules are identified in a complex mixture.
7. The procedure for mass spectroscopy starts with which of the following processes?
b) The ions are separated by passing them into electric and magnetic field
Answer: c
Explanation: The procedure for mass spectroscopy starts with converting the sample into gaseous
state. This is done by chemical processes.
8. In mass spectrometer, the ion currents are measured using which of the following?
a) Scintillation counter
b) Ion counter
c) Electrometer tube
d) Electric fields
Answer: c
Explanation: The ion currents are measured using sensitive electrometer tube. The ions reaching the
collecting plate are measured.
9. Which of the following ions pass through the slit and reach the collecting plate?
Explanation: Positive ions of specific mass pass through the slit and reach the collecting plate. These
ions are measured.
10. Which of the following statements is not true about mass spectrometry?
a) Impurities of masses different from the one being analysed interferes with the result
Answer: a
Explanation: Impurities of masses different from the one being analysed does not interfere with the
result in mass spectroscopy. This is a major advantage of this technique.
11. In mass spectrometer, the sample gas is introduced into the highly evacuated spectrometer tube
and it is ionised by electron beam.
a) True
b) False
Answer: a
Explanation: The sample gas is introduced into the highly evacuated spectrometer tube and it is
ionised by electron beam. The sample has to be in gaseous state.
a) Inlet system
b) Sweep generator
c) Ion transducer
d) Mass analyser
Answer: b
13. Which of the following can be introduced into the ionization chamber directly?
Answer: a
Explanation: Solid samples with low vapour pressure can be introduced into the ionization chamber
directly.
a) Initial system
b) Sample reservoir
Answer: c
Explanation: Inlet system introduces the sample into the ion source. Hence, it is called sample
handling system.
15. Which of the following is normally done to convert the sample into gaseous state?
a) Sample is pressurized
c) Sample is heated
d) Sample is cooled
Answer: c
Explanation: The sample must always be in gaseous state. Hence, liquid sample must be heated before
introducing them into the ionization chamber.
16. Which of the following probes are used for the introduction of the sample?
a) Silica
b) Quartz
c) Graphite
d) Silver
Answer: a
Explanation: Solid samples with low vapour pressure are introduced into the entrance of the chamber.
They are introduced using silica or platinum probe.
a) Field ionisation
b) Spontaneous ionisation
c) Spark ionisation
d) Chemical ionisation
Answer: b
Explanation: Spontaneous ionisation is not a type of ionisation. In mass spectrometer, ionisation is
brought about by thermal or electrical energy.
a) Source
b) Monochromator
c) Detector
d) Sample
Answer: b
19. Which of the following is not one of the types of mass analyser?
Answer: b
Explanation: Frequency sweep analyser is not a type of mass analyser. There are many devices
available for mass analysis.
20. Which of the following is not a type of ion detector used in mass spectrometers?
a) Electron multiplier
Answer: b
Explanation: Flame emission detector is not a type of ion detector used in mass spectrometers. Ion
detectors produce current on the output side when there are ions on the input side.
a) Hypodermic needle
b) Glass bulb
c) Capillary tube
d) Curvette
Answer: a
Explanation: Liquid samples are injected through hypodermic needles. It is vaporized at low pressure.
4. IR Spectroscopy
1 Which of the following statements is true concerning infrared spectroscopy?
A. Functional groups can be identified by looking in the fingerprint region of the spectrum.
B. IR spectroscopy is useful in determining the size and shape of a compound's carbon skeleton.
C. An IR spectrometer shines infrared light on a compound and records the positions where the light
is blocked by the compound. This results in the spectrum's peaks.
D. When the infrared light frequency matches the frequency of bond vibration in a molecule, a peak
is recorded on the spectrum.
Possible Answers:
C. The fingerprint region is most easily used to determine the functional groups in the molecule
Possible Answers:
4 Which of the following functional groups exhibits the highest frequency in an infrared (IR)
spectrum?
Possible Answers:
A. Aldehyde
B. Ester
C. Ketone
D. Alcohol
E. Nitrile
5 An alcohol group in a compound would result in a broad dip around what part of the
infrared (IR) spectrum?
Possible Answers:
A. 2800cm-1
B. 1200cm-1
C. 1700cm-1
D. 3400cm-1
Possible Answers:
A. The peak location will vary depending on the compound being analyzed.
B. 1000cm-1
C. 2800cm-1
D. 1700cm-1
(A) mid IR
(B) far IR
(D) near IR
(A) mid IR
(B) Far IR
(C) Close IR
(D) Near IR
(C) Pyrrolysis
(A) Spectrofluorometer
(B) Spectrophotometer
(A) 14,000 cm -1
(C) 3,600 cm -1
(A) 2
(B) 3
(C) 5
(D) 4
(B) Rocking
(C) Scissoring
(D) Twisting
(A) Source
(B) Detector
(C) Cell
(D) Monochromator
18 Variable path length cells can be produced by filling the space material
(A) KBr
(B) Quartz
(D) Teflon
(C) A @ B
(D) FTIR
B. Chromatography
5. Paper Chromatography
1 What is paper chromatography?
B. It is widely used for the separation and identification of compounds of biochemical interest.
C. Both
D. None
Answer- C
D. None of these
Answer A
A. By capillary action
B. By heat
C. By energy
D. By cooling
Answer A
[Link]
5 The distance the solute travels is relative to the distance the solvent
moves is called the
Answer-Rf value
C. Both
D. None
Answer-A
Answer-Stationary phase
Answer-B
Answer-A
Answer. Chromatoghraphy
As the ____ phase migrates through the ____ phase, separation occurs
because the solutes have different affinities for the two-phased system.
A. Mobile, Stationary, Mobile, Stationary
D. None of these
Answer -A
12 In this lab, the paper used is made of ____ which has a surface
covered in polar -OH groups.
A. Copper
B. Cellulose
C. Tin
D. Sucrose
Answer C
Answer-C
E. All of these
Answer-E
Ans-True
A. 60°
B. 90°
C. 100°
D. 180°
Answer-B
Answer-True
18 If Rƒ value = 1 then the solute has no affinity for the stationary phase
and travels with the solvent front.
Answer-True
Ascending chromatography
Ascending-Descending Chromatography
Answer-D
6. Thin Layer Chromatography
e. Measure Rf
Possible Answers
i. a, b, c, d, e, f
II.c, b, a, d, f, e
III.d, b, f, a, e, c
IV. e, b, f, a, e, c
(A) 5cm
(B) 2cm
(C) 1cm
(D) 10cm
3. In TLC, initially the sample is
A. Platinium-iridium capillary
B. Micropipette
C. Both
D. None
(C) Fluorescence
(B) Iodine
(D) Ninhydrin
7 : A new student is planning to use thin layer chromatography (TLC) for his
research project. After setting up the apparatus the student forgets to place a lid on
the TLC jar. He obtains poor results after running the TLC experiment. Which of the
following can best explain his bad results?
Possible Answers:
A. The open system evaporates the solvent in the solution
B. The open system prevents the evaporation of the solvent on the TLC plate
D. The open system prevents the evaporation of the solvent in the solution
Possible Answers:
II only
I and III
II and III
a) Gas liquid
b) Column
c) Thin layer
d) Paper
10. In Thin layer chromatography, the stationary phase is made of ___ and
the mobile phase is made of ___
a) Solid, liquid
b) Liquid, liquid
c) Liquid, gas
d) Solid, gas
[Link] was developed by Izmailov in the year 1938 considering Mikhail Tswett's
description on column chromatography.
12. Higher the Rf value lesser the polarity of the substance. True/false
C. Both
D. None
14. Silica is
A. polar adsorbant
B. nonpolar adsorbant
17. Spots are applied to the plate using very thin metallic pipettes. True
/False
a. Spraying or pouring-use agents such as KIPt, Fast Blue 2B, H2SO4, KMnO4
to react with analytes. Spots appear on the plate.
19. Where does the TLC plate need to be placed to run it?
B. In a ambered bottle
C. In an oven
D. In an incubator
C. The acetic acid does not effect the polarity of the developing solvent
22. Silica gel is a form of silicon dioxide (silica). The silicon atoms are joined
via oxygen atoms in a giant covalent structure. However, at the surface of the silica
gel, the silicon atoms are attached to -OH groups. True/False
A. Slowly
B. quickly
C. No effect
D. All
A. 250 micrometer
B. 500 micrometer
C. 120 micrometer
D. 300 micrometer
25. TLC has been used for the isolation and determination of alkaloids in
toxicology where the ....... runs give a great advantage in comparison to the 12-24
hours required for paper chromatography.
A. 10-15 minute
B. 10-20 minute
C. 30-60 minute
D. 60-80 minute
(A) 5cm
(B) 2cm
(C) 1cm
(D) 10cm
e. Measure Rf
Possible Answers
i. a, b, c, d, e, f
II.c, b, a, d, f, e
III.d, b, f, a, e, c
IV. e, b, f, a, e, c
A. Platinium-iridium capillary
B. Micropipette
C. Both
D. None
(C) Fluorescence
(B) Iodine
(D) Ninhydrin
B. quickly
C. No effect
D. All
A. 250 micrometer
B. 500 micrometer
C. 120 micrometer
D. 300 micrometer
9 TLC has been used for the isolation and determination of alkaloids in
toxicology where the ....... runs give a great advantage in comparison to the 12-24
hours required for paper chromatography.
A. 10-15 minute
B. 10-20 minute
C. 30-60 minute
D. 60-80 minute
B. In a ambered bottle
C. In an oven
D. In an incubator
12. What will this addition of acetic acid do to help the TLC process?
C. The acetic acid does not effect the polarity of the developing solvent
13. Silica gel is a form of silicon dioxide (silica). The silicon atoms are
joined via oxygen atoms in a giant covalent structure. However, at the surface of the
silica gel, the silicon atoms are attached to -OH groups. True
16. Spots are applied to the plate using very thin metallic pipettes. False
a. Spraying or pouring-use agents such as KIPt, Fast Blue 2B, H2SO4, KMnO4
to react with analytes. Spots appear on the plate.
b. Use radio waves to visualize spots
[Link] was developed by Izmailov in the year 1938 considering Mikhail Tswett's
description on column chromatography.
20. What will this addition of acetic acid do to help the TLC process?
C. The acetic acid does not effect the polarity of the developing solvent
a) Column chromatography
b) Planar chromatography
c) Liquid chromatography
d) Gas chromatography
a) Magnesium oxide
b) Silica gel
c) Activated alumina
d) Potassium permanganate
3. In Column chromatography, the stationary phase is made of ___ and the mobile phase is made of
___
a) Solid, liquid
b) Liquid, liquid
c) Liquid, gas
d) Solid, gas
4. Which of the following is the distance that the solute moves while
undergoing one partition?
a) Retention distance
b) Distribution constant
c) Plate height
A. Adsorption chromatography.
D. Affinity chromatography.
C. Cooling
D. Boiling
A. Packed columns
B. Capillary columns
10. Decreasing particle size thus is a useful method for improving column
efficiency and providing better separations. T/F
a. 1:100
b. 1:10
c. 1:1
d. 10:1
e. 100:1
12. Polar compounds will interact with the silica more strongly than
non-polar ones so will come off the column, or elute, after non-polar
compounds.T/F
a) Column chromatography
b) Planar chromatography
c) Liquid chromatography
d) Gas chromatography
a) Magnesium oxide
b) Silica gel
c) Activated alumina
d) Potassium permanganate
b) Liquid, liquid
c) Liquid, gas
d) Solid, gas
4. Which of the following is the distance that the solute moves while
undergoing one partition?
a) Retention distance
b) Distribution constant
c) Plate height
A. Adsorption chromatography.
D. Affinity chromatography.
C. Cooling
D. Boiling
E. C&D
B. Capillary columns
9. ..... column efficiency ....., also known as plate count, is a measure of the
dispersion of a peak.
a. 1:100
b. 1:10
c. 1:1
d. 10:1
e. 100:1
12 Polar compounds will interact with the silica more strongly than non-polar ones so will come
off the column, or elute, after non-polar compounds. T
13 The most common stationary phase for column chromatography is silica gel, the next most
common being alumina. True
8. HPLC
1. The main purpose of the derivitization in HPLC is
(A) Reciprocating
(B) Displacement
4. The derivitization reagent used for detection of alcohols, amines and phenols is
(C) O-4-Nitrobezyl-N,N’-diisopropylisourea
(D) 4-Nitrobenzyl-n-propylamine hydrochloride
(C) Refractometer
(D) UV Spectrophotometer
[Link] of the following is not true about High pressure liquid chromatography (HPLC)?
c) It is performed in columns
a) True
b) False
10. Which of the following is not an advantage of Syringe type pumps used in High pressure liquid
chromatography?
a) Independent of viscosity
b) Pulse-less flow
[Link] of the following is not true about solvent programming which is done in high performance
liquid chromatography?
C. solvent diffusivity
A. 10 and 50 A°
B. 60 and 100 A°
[Link] isocratic elution in HPLC is one in which the composition of the solvent
A. remains constant
B. changes continuously
D. none of these
[Link] of the following statements is true for a refractive index detector in HPLC?
D. none of above
19.A gradient elution in HPLC is one in which the composition of the solvent
A. remains constant
B. ranks column packing material by their relative abilities to retain solutes on the column
C. the volume of the column between the point at which solvents are mixed and the beginning
of the column
A. total volume of eluent in the column the remainder being taken up by the packing material
23.
2.B
3.C
4.B
5.C
6.B
7.B
8.B
9.A
10.D
11.A
12.A
13.D
14.A
15.B
16.A
17.B
18.C
19.A
20.A
21.C
22.A
23.A
Chapter. 4
Gases
1. What is the relative rate of effusion of CO and CO2?
A. H2S
B. NO
C. Cl2
D. N2O
B. Hydrogen bonds
C. Debye forces
A. Hydrogen bonding
D. Ionic bond
C. It is a conductor of electricity
A. PVmT
B. PCT
C. PMdT
D. All above
8. Under what conditions the gases deviate from the ideal behaviour?
A. High-temperature
B. Low temperature
C. High-pressure
D. B and C
A. Ne
B. N2
C. NH3
D. CO
A. Boyles law
B. Charles law
C. Daltons law
D. Grahams law
11. 0.5 mole of nitrogen gas and 0.5 mole of carbon monoxide gas at STP have same
A. Value of a
B. Mass
C. Atoms
D. Both B and C
12. At constant temperature the pressure of an ideal gas is doubled its density becomes
A. Half
B. Double
C. Same
D. None
A. Unchanged
B. Slightly decreased
C. Slightly increased
D. Zero
C. PV / RT = n
D. All gases cannot be liquefied through Linds Method
15. The critical temperature for different gases is different and depends upon
A. Size of molecule
B. Shape of molecule
C. Intermolecular attractions
A. Three
B. Four
C. Five
D. Two
A. Gas
B. Liquid
C. Solid
D. Semi-solid
A. Gas
B. Liquid
C. Solid
D. Plasma
A. Gas
B. Liquid
C. Solid
D. Plasma
A. Avogadro’s law
A. Translational motion
B. Vibrational motion
C. Rotational motion
A. H2S
B. NO
C. Cl2
D. N2O
B. Hydrogen bonds
C. Debye forces
A. Hydrogen bonding
C. It is a conductor of electricity
A. PVmT
B. PCT
C. PMdT
D. All above
8. Under what conditions the gases deviate from the ideal behaviour?
A. High-temperature
B. Low temperature
C. High-pressure
D. B and C
A. Ne
B. N2
C. NH3
D. CO
10. The introduction of the Kelvin scale in thermometry is according to
A. Boyles law
B. Charles law
C. Daltons law
D. Grahams law
11. 0.5 mole of nitrogen gas and 0.5 mole of carbon monoxide gas at STP have same
A. Value of a
B. Mass
C. Atoms
D. Both B and C
12. At constant temperature the pressure of an ideal gas is doubled its density becomes
A. Half
B. Double
C. Same
D. None
A. Unchanged
B. Slightly decreased
C. Slightly increased
D. Zero
C. PV / RT = n
15. The critical temperature for different gases is different and depends upon
A. Size of molecule
B. Shape of molecule
C. Intermolecular attractions
A. Three
B. Four
C. Five
D. Two
A. Gas
B. Liquid
C. Solid
D. Semi-solid
A. Gas
B. Liquid
C. Solid
D. Plasma
A. Gas
B. Liquid
C. Solid
D. Plasma
A. Gas
B. Liquid
C. Solid
D. Plasma
A. Avogadro’s law
A. Translational motion
B. Vibrational motion
C. Rotational motion
Chapter no- 5
Liquids and Solids MCQs
1. Which of the following has strongest intermolecular forces of attraction?
A. Hydrogen (H2)
B. Chlorine (Cl2)
C. iodine (I2)
D. Methane (CH4)
Answer- C
B. Chlorine (Cl2)
C. Xenon(Xe)
Answer-D
3. When substance moves from a solid to a liquid state all of the following changes occur except
Answer-B
4. In order to mention the boiling point of water at 110?C the external pressure should be
C. 765 torr
Answer-A
A. Butane
B. Methane
C. Hexane
Answer-A
A. Butane
B. Ethylene
C. Methane
Answer-B
A. Acetylene
B. Methane
C. Butane
D. Ethylene
Answer-A
8-Is used for the production of caps of bottles of acid, in making the body of the accumulator cells
etc
A. Polystyrene
B. Ethyl bromine
C. Chloroform
D. Methyl alcohol
Answer-A
A. Polystyrene
B. Ethyl bromine
C. Chloroform
D. Methyl alcohol
Answer-B
10-In surgical operation as anaesthesia, in form of solvent of rubber, fat, lac etc, as insecticide etc.
A. Polystyrene
B. Ethyl bromine
C. Chloroform
D. Methyl alcohol
Answer-C
11-In making methyleted spirit, artificial colour, barnish and polish, mixing with petrol and utilised as
fuel of engines etc.
A. Polystyrene
B. Ethyl bromine
C. Chloroform
D. Methyl alcohol
Answer-D
A. Ethyl alcohol
B. Formament
C. Glycerol
Answer-B
13-In making insecticides, in fixation of gelatine film on the photographic plates, in making
waterproof cloths by mixing it with eggs exterior whitely part etc.
A. Formaldehyde
B. Acetaldehyde
C. Acetone
Answer-A
14-As laboratory’s reagent, in the form of vinegar, in making sauces and jelly
A. Formic acid
B. Acetic acid
C. Acetyl chloride
Answer-B
15-In the form of solvent, in dry cleaning, by mixing it with petrol and used as fuel of engines etc.
A. Butane
B. Benzene
C. Ether
D. Acetone
Answer-B
A. Chloro benzene
B. Nitrobenzene
C. Aniline
Answer-A
17-Urea, is an organic compound with chemical formula CO(NH₂)₂. Find the incorrect statement
Answer-D
A. Baking soda
B. formula NaHCO3
Answer-C
A. Baking soda
B. formula NaHCO3
Answer-C
A. Surface phenomenon
B. Continuous
C. Exothermic
D. Cause cooling
Answer-C
Chapter No.6
Atomic Structure
1 The letters sp d and f are used to represent which quantum numbers
A. Principal
B. Azimuthal
C. Magnetic
D. Spin
2 The magnetic quantum number (QN) has its values determined directly by the value of
A. Principal (QN)
B. Azimuthal (QN)
C. Spin (QN)
D. Both a & b
3 The atomic number of an element having the maximum number of unpaired electrons in p-
subshell is
A. 7
B. 10
C. 12
D. 16
A. 6
B. 10
C. 14
D. 18
A. 5.761 A?
B. 4.761 A?
C. 6.671 A?
D. 3.716 A?
6 When an atom absorbs energy the lines in the spectrum will appear which are
A. Brighter
B. Darker
C. Colourless
D. Hard to locate
A. Temperature
B. Pressure
C. Volume
D. Composition of glass
A. 9.11×10-31 Kg
B. Cast shadow
D. Cannot ionize
A. By burning of gas
10 The relationship between the energy of a photon of light and its frequency is given by
B. Bohrs model
11 : Splitting of spectral lines when an atom is subjected to the magnetic field is called
A. Zeemans effect
B. Starks effect
D. Compton effect
A. Is independent of wavelength
A. Rutherford
B. Dalton
C. Bohr
D. Schrodinger
A. 10 torr
B. 1 torr
C. 0.1 torr
D. 0.01 torr
16 : The number of fundamental particles in an atom of the lightest isotope carbon are
A. 6
B. 12
C. 18
D. 20
A. Hitorff
B. Stoney
C. William Crookes
D. [Link]
A. Alpha emission
B. Beta emission
C. Both a & b
D. Radioactivity
A. AgNO3 plate
B. AgCl plate
C. ZnO
D. ZnS
A. Neutrino
B. Electron
C. Both a & b
D. Meson
A. J.J Thomson
B. Millikan
C. Rutherford
D. Perrin
A. Gamma-rays
B. Alpha-rays
C. Beta-rays
D. X-rays
A. In a continuous manner
B. Discontinuous manner
C. Simultaneously
25 : 2nd orbit is ___ away from the nucleus of H-atom as compared to 1st orbit is
A. 2-times
B. 3-times
C. 4-times
D. 6 times
A. 1
B. 3
C. 5
D. 7
2-B
3-A
4-C
5-B
6-B
7-D
8-D
9-C
10-C
11-A
12-A
13-A
14-B
15-B
16-D
17-C
18-D
19-B
20-D
21-C
22-D
23-B
24-B
25-C
26-D
Chapter. 7
Chemical Bonding
1. The relative attraction of the nucleus for the electrons in a chemical bond is called
A. Ionization energy
B. Electron affinity
C. Electronegativity
3. Which of the following will have the highest value of electron affinity
A. F
B. Cl
C. Br
D. I
A. Pi (π)
B. Sigma(Σ)
C. Both
D. Neither
5. The octet rule does not always hold for which of the following elements
A. C
B. O
C. F
D. P
B. Ice
C. Diamond
D. Graphite
7. Which of the following is the best explanation that CO2 is a non-polar molecule
A. Linear geometry
C. Sp hybridization
D. None
A. Increases
B. Decreases
C. Constant
D. None
A. Ionization energy
B. Electron affinity
C. Electronegativity
D. Atomic size
A. 6X
B. 7Y
C. 9Z
D. 13W
B. C2H6
C. O2
D. NH3
12. When 2 lone pairs and 2 bond pair are around the central atom reduction in the bond angle is up
to.
A. 109.5°
B. 104.5°
C. 107.5°
D. 102°
A. sp3
B. sp2
C. sp
D. All
B. Hund’s rule
D. All these
A. Electron affinity
B. Ionic character
C. Ionization energy
D. Dipole moment
16. Which one shows high %age of the ionic character?
A. H2O
B. HF
C. HCI
D. HBr
A. F
B. H2O
C. HF
D. NH-2
18. Which of the following have their outer most shell complete in atomic form?
A. Noble gases
B. Alkali metals
C. Coinage metals
D. Gunmetal
A. Bond
B. Attractive force
C. Interaction
C. No change
D. Impossible to predict
21. In a period the atomic radii
A. Increases
B. Decreases
A. Gain stability
B. Form a bond
A. Increases
B. Decreases
C. No change
D. Variable trend
A. Ionization potential
B. Electronegativity
C. Electron affinity
D. Activation energy
A. Increases
B. Decreases
C. No change
D. Variable trend
Answers Key chapter-6
1. The relative attraction of the nucleus for the electrons in a chemical bond is called
A. Ionization energy
B. Electron affinity
C. Electronegativity
3. Which of the following will have the highest value of electron affinity
A. F
B. Cl
C. Br
D. I
A. Pi (π)
B. Sigma(Σ)
C. Both
D. Neither
5. The octet rule does not always hold for which of the following elements
A. C
B. O
C. F
D. P
A. Copper
B. Ice
C. Diamond
D. Graphite
7. Which of the following is the best explanation that CO2 is a non-polar molecule
A. Linear geometry
C. Sp hybridization
D. None
A. Increases
B. Decreases
C. Constant
D. None
A. Ionization energy
B. Electron affinity
C. Electronegativity
D. Atomic size
A. 6X
B. 7Y
C. 9Z
D. 13W
A. H2O
B. C2H6
C. O2
D. NH3
12. When 2 lone pairs and 2 bond pair are around the central atom reduction in the bond angle is up
to.
A. 109.5°
B. 104.5°
A. sp3
B. sp2
C. sp
D. All
B. Hund’s rule
D. All these
15. Measurement of the degree of polarity is
A. Electron affinity
B. Ionic character
C. Ionization energy
D. Dipole moment
A. H2O
B. HF
C. HCI
D. HBr
A. F
B. H2O
C. HF
D. NH-2
18. Which of the following have their outer most shell complete in atomic form?
A. Noble gases
B. Alkali metals
C. Coinage metals
D. Gunmetal
A. Bond
B. Attractive force
C. Interaction
C. No change
D. Impossible to predict.
A. Increases
B. Decreases
A. Gain stability
B. Form a bond
A. Increases
B. Decreases
C. No change
D. Variable trend
A. Ionization potential
B. Electronegativity
C. Electron affinity
D. Activation energy
A. Increases
B. Decreases
C. No change
D. Variable trend
Chapter No. 8
Thermochemistry
1. If the ΔH value is less than zero than reaction will be
A. Exothermic
B. Endothermic
D. None of these
D. All
A. Thermochemistry
B. Thermodynamics
C. Chemical kinetics
D. Stoichiometry
A. State function
B. Phase
C. Surrounding
D. State
5. Anything which depends upon the initial and final state of a system is
A. Environment
B. Surrounding
C. State function
D. Enthalpy
A. P.E + K.E
A. ΔH=qp
B. ΔE = q + W
C. ΔE = q x v
A. Endothermic
B. Spontaneous
C. Non-spontaneous
D. Exothermic
9. CuSO4 + Zn>>ZnSO4+Cu is
A. Spontaneous reaction
B. Non-spontaneous reaction
C. Endothermic
D. Exothermic
A. Spontaneous process
B. Non-spontaneous process
C. Irreversible process
D. Reversible process
B. Temperature
C. Enthalpy
12. When enthalpy of reactants is higher than the product then the reaction will be
A. Endothermic
B. Spontaneous
C. Non-spontaneous
D. Exothermic
A. Glass calorimeter
B. Manometer
C. Barometer
A. +787 KJ/mole
B. 787 J/mole
C. 780 KJ/mole
D. 790 KJ/mole
A. 169 °C
B. 420 °C
C. Both a and b
D. None
2. D
3. A
4. C
5. C
6. A
7. B
8. D
9. A
10. B
11. D
12. D
13. A
14. D
15. A
16. C
17. C
Chapter. 9
Chemical Equilibrium
1. If a buffer solution of higher pH than seven is to be made we use
2. Which of the following will not change the concentration of ammonia at the equilibrium?
A. Increase of pressure
B. Increase of volume
C. Addition of catalyst
D. Decrease in temperature
3. pH of an aqueous solution is 5.5. The hydroxyl ion concentration in the solution would be
A. 5.5
B. 8.5
C. 10-8.5
D. 10
A. KOH
B. NH3
C. PH3
D. BF3
A. NaCI
B. Na2SO4
C. Na2CO3
D. FeCl3
A. Reversible
B. Irreversible
C. Spontaneous
D. Non-spontaneous
A. Dynamic state
B. Static state
C. Free state
D. Unidirectional state
Chapter.10
Solutions
1 A ....... is a homogeneous system in which a solute is molecularly dispersed, or dissolved, in a
solvent
A. Solution
B. Colloidal solution
C. Solute
D. Solvent
2 are solutions that, at a given temperature and pressure, contain the maximum amount of solute
that can be accommodated by the solvent. If the saturation, or solubility, limit is exceeded, a fraction
of the solute can separate
A. Unsaturated solutions
B. Saturated solutions
D. Emulsions
3 Solutes can be
A. Gases
B. Liquids or solids
C. nonelectrolytes or electrolytes
4. Glycerin
A. Electrolyte
B. Non electrolyte
5. Weak electrolytes are partially ionized in water
A. Aspirin
B. Nacl
C. Atropine
D. Both a and c
E. None of these
6. The colligative properties of a solution depend on the total number of ionic and nonionic solute
molecules in the solution. True/False
7. These properties depend on ionization but are dependent of other chemical properties of the
solute. True/False
A. Solutions
B. Emulsions
C. Suspensions
9. Osmosis is the process by which solvent molecules pass through a semipermeable membrane (a
barrier through which only solvent molecules may pass) from a region of dilute solution to one of
more concentrated solution. True/False
A. Non-electrolyte solute
B. Non-volatile solute
C. Dilute solution
A. Opals
B. Dust particles in smoke
C. Paints
D. Fog
A. Molarity
B. Molality
C. Mole fraction
D. All
A. % w/w
B. % w/v
C. % v/v
D. % v/w
A. Normality
B. Molarity
C. Molality
D. Mole fraction
16. 58.5g of NaCl per 1 dm3 of the solution of NaCl in water the concentration of solution will be
A. 0.1 M
B. 1 m
C. 1 M
D. 0.1 N
18. If the volume of solution is equal to sum of volumes of its all components then the solution
D. Both B & C
A. Ideal solution
B. Zeotropic solution
C. Azeotropic solution
D. Non-ideal solution
A. Zeotropic mixture
B. Azeotropic mixture
C. Amphoteric mixture
D. Ideal solution
21. The concentration of solute molecule when they are in equilibrium with a solid substance at a
particular temperature is called
A. Saturated solution
B. Solubility
C. Unsaturated solution
D. Supersaturated solution
22. The determination of correct molecular weight from Raoult’s law is applicable to
A. Beckmann method
B. Landsberger method
C. Linds method
25. The compounds in which water molecules are added are called
A. Hydrated Ions
B. Double salts
C. Hydrates
D. Complexes
A. 180g/dm3
B. 170g/dm3
C. 190g/dm3
D. 195g/dm3
A. Drying
B. Heating
C. Evaporation
2. B
3. D
4. B
5. D
[Link]
7. False independent
8. A
9. True
10. B
11. D
12. D
13. B
14. C
15. C
16. C
17. A
18. A
19. B
20. B
21. B
22. D
23. B
24. B
25. C
26. C
27. A
28. B