Physics - Chapter14
Physics - Chapter14
INTRODUCTION
Vacuum tubes
Devices in which a controlled flow of electrons can be obtained, are the basic building blocks
of all the electronic circuits. Before the discovery of transistor in 1948, such devices were
mostly vacuum tubes (also called valves) like the vacuum diode which has two electrodes, viz.,
anode (often called plate) and cathode ; triode which has three electrodes – cathode, plate and
In a vacuum tube, the electrons are supplied by a heated cathode and the controlled flow of
these electrons in vacuum is obtained by varying the voltage between its different electrodes.
Vacuum is required in the inter-electrode space ; otherwise the moving electrons may lose
their energy on collision with the air molecules in their path. In these devices the electrons can
flow only from the cathode to the anode (i.e., only in one direction). Therefore, such devices
These vacuum tube devices are bulky, consume high power, operate generally at high voltages
The seed of the development of modern solid-state semiconductor electronics goes back to
1930’s when it was realised that some solid state semiconductors and their junctions offer the
possibility of controlling the number and the direction of flow of charge carriers through
them. Simple excitations like light, heat or small applied voltage can change the number of
e
ut
Note that the supply and flow of charge carriers in the semiconductor devices are within the
solid itself, while in the earlier vacuum tubes/valves, the mobile electrons were obtained from
tit
a heated cathode and they were made to flow in an evacuated space or vacuum. No external
ns
heating or large evacuated space is required by the semiconductor devices.
lI
They are small in size, consume low power, operate at low voltages and have long life and
ru
high reliability.
A
ARUL INSTITUTE, CHENNAI
CLASSIFICATION OF METALS, SEMICONDUCTORS & INSULATORS
On the basis of the relative values of electrical conductivity (σ) or resistivity (ρ = 1/σ), the
(1) Metals: They possess very low resistivity (or high conductivity).
(2) Semiconductors: They have resistivity or conductivity intermediate to metals & insulators.
e
ut
(3) Insulators: They have high resistivity (or low conductivity).
Most of the currently available semiconductor devices are based on elemental semiconductors
However after 1990, a few semiconductor devices using organic semiconductors and
semiconducting polymers have been developed signalling the birth of a futuristic technology
According to the Bohr atomic model, in an isolated atom the energy of any of its electrons is
decided by the orbit in which it revolves. But when the atoms come together to form a solid
they are close to each other. So the outer orbits of electrons from neighbouring atoms would
come very close or could even overlap. This would make the nature of electron motion in a
Inside the crystal each electron has a unique position and no two electrons see exactly the
e
same pattern of surrounding charges. Because of this, each electron will have a different
ut
energy level. These different energy levels with continuous energy variation are called energy
tit
bands. The energy band which includes the energy levels of the valence electrons is called the
ns
valence band. The energy band above the valence band is called the conduction band.
With no external energy, all the valence electrons will reside in the valence band. Normally
lI
the conduction band is empty. But when the conduction band overlaps on the valence band,
ru
electrons can move freely into it. This is the case with metallic conductors.
If there is some gap between the conduction band and the valence band, electrons in the
A
valence band all remain bound and no free electrons are available in the conduction band.
In semiconductors, some of the electrons from the valence band may gain external energy to
cross the gap between the conduction band and the valence band. Then these electrons will
move into the conduction band. At the same time they will create vacant energy levels in the
valence band where other valence electrons can move. Thus the process creates the possibility of
conduction due to electrons in conduction band as well as due to vacancies in the valence band.
ARUL INSTITUTE, CHENNAI
Let us consider what happens in the case of Si or Ge crystal containing N atoms. For Si, the
outermost orbit is the third orbit (n=3), while for Ge it is the fourth orbit (n=4). The number
of electrons in the outermost orbit is 4. Hence, the total number of outer electrons in the
crystal is 4N. The maximum possible number of electrons in the outer orbit is 8. So, for the 4N
valence electrons there are 8N available energy states. These 8N discrete energy levels can
either form a continuous band or they may be grouped in different bands depending upon the
In the crystal lattices of Si and Ge, the energy band of these 8N states is split apart into two
which are separated by an energy gap Eg (shown in the Figure). The lower band which is
completely occupied by the 4N valence electrons at temperature of absolute zero is the valence
band. The other band consisting of 4N energy states, called the conduction band is completely
valence band is shown as EV. Above EC and below EV there are a large number of closely
spaced energy levels, as shown in Figure. The gap between the top of the valence band and
bottom of the conduction band is called the energy gap (Eg). It may be large, small or zero
e
Case I : Energy Band Structure of Metals
ut
In this case, as shown in the figure (a), either metals can have their conduction band partially
tit
filled and partially empty or their conduction and valance bands overlap. When there is
ns
overlap, electrons from valence band can easily move into the conduction band. This situation
lI
makes a large number of electrons available for electrical conduction. When the valence band
is partially empty, electrons from its lower level can move to higher level making conduction
ru
possible. Therefore, the resistance of such materials is low or the conductivity is high.
A
ARUL INSTITUTE, CHENNAI
Case II : Energy Band Structure of Insulators
In this case, as shown in the figure (b), a large band gap Eg exists (Eg > 3 eV). There are no
electrons in the conduction band and therefore no electrical conduction is possible. Note that
the energy gap is so large that electrons cannot be excited from the valence band to the
In this case, as shown in Figure (c), a finite but small band gap (Eg < 3 eV) exists. Because of
the small band gap, at room temperature some electrons from valence band can acquire
enough energy to cross the energy gap and enter the conduction band. These electrons
(though small in numbers) can move in the conduction band. Hence, the resistance of
respective lattice spacing ‘a’ equal to 3.56 Å, 5.43 Å and 5.66 Å is shown in the figure (a).
Figure (a)
Each atom is surrounded by four nearest neighbours. Si and Ge have four valence electrons.
In its crystalline structure, every Si or Ge atom tends to share one of its four valence electrons
with each of its four nearest neighbour atoms and also to take share of one electron from each
such neighbour. These shared electron pairs are involved in the formation of covalent bonds.
ARUL INSTITUTE, CHENNAI
Figure (b) shows the 2-dimensional representation of Si or Ge structure. It shows an idealised
picture in which no bonds are broken (all bonds are intact). Such a situation arises at low
temperatures.
Figure (b)
As the temperature increases, more thermal energy becomes available to these electrons and
some of these electrons may break–away (becoming free electrons contributing to conduction)
Figure (c)
When the free electron (with charge –e) has come out leaves a vacancy with an effective
charge (+e). This vacancy with the effective positive electronic charge is called a hole. The
ne = nh = ni
Semiconductors possess the unique property in which, apart from electrons, the holes also
move. Suppose there is a hole at site 1 as shown in the figure (c). The movement of holes can
Figure (d)
An electron from the covalent bond at site 2 may jump to the vacant site 1 (hole). Thus, after
such a jump, the hole is at site 2 and the electron at site 1. Therefore, apparently, the hole has
moved from site 1 to site 2. Note that the electron originally set free is not involved in this
Under the action of an electric field, the free electrons move towards the positive potential
giving rise to an electron current (Ie) and the holes move towards negative potential giving
rise to the hole current (Ih). The total current I is thus the sum of the electron current Ie and
I = Ie + Ih
ARUL INSTITUTE, CHENNAI
It may be noted that apart from the process of generation of conduction electrons and holes, a
simultaneous process of recombination occurs in which the electrons recombine with the
holes. At equilibrium, the rate of generation is equal to the rate of recombination of charge
An intrinsic semiconductor will behave like an insulator at T = 0 K as shown in the figure (e).
At higher temperatures (T > 0K), due to thermal energy some electrons are excited from the
valence band to the conduction band. These thermally excited electrons at T > 0K, partially
will be as shown in the figure (f). Here, some electrons are shown in the conduction band.
These have come from the valence band leaving equal number of holes there.
At T = 0K At T > 0K
ARUL INSTITUTE, CHENNAI
EXTRINSIC SEMICONDUCTOR
temperature its conductivity is very low. As such, no important electronic devices can be
When a small amount (a few parts per million) of a suitable impurity is added to the pure
e
semiconductor, the conductivity of the semiconductor is increased many times. Such materials
ut
are known as extrinsic semiconductors or impurity semiconductors.
tit
The deliberate addition of a desirable impurity is called doping and the impurity atoms are
ns
called dopants. Such a material is also called a doped semiconductor. The dopant has to be
such that it does not distort the original pure semiconductor lattice. It occupies only a very
lI
few of the original semiconductor atom sites in the crystal. A necessary condition to attain this
ru
is that the sizes of the dopant and the semiconductor atoms should be nearly the same.
A
There are two types of dopants used in doping the tetravalent Si or Ge:
(i) Pentavalent (valency 5) ; like Arsenic (As), Antimony (Sb), Phosphorous (P), etc.
(ii) Trivalent (valency 3) ; like Indium (In), Boron (B), Aluminium (Al), etc.
Si or Ge belongs to the fourth group in the Periodic table and therefore, we choose the dopant
element from nearby fifth or third group, so that the size of the dopant atom is nearly the
A n-type semiconductor is obtained by doping a pure silicon (or germanium) crystal with
pentavalent impurity atoms such as phosphorus, arsenic and antimony as shown in the figure.
When a pentavalent atom occupies the position of an atom in the crystal lattice of Si, four of
its electrons bond with the four silicon neighbours while the fifth remains very weakly bound
to its parent atom. As a result the ionisation energy required to set this electron free is very
small and even at room temperature it will be free to move in the lattice of the semiconductor.
For example, the energy required is ~ 0.01 eV for germanium and 0.05 eV for silicon, to
separate this electron from its atom. This is in contrast to the energy required for the electron
to jump from the valence band to the conduction band (about 0.72 eV for germanium and
known as donor impurity. The number of electrons made available for conduction by dopant
atoms depends strongly upon the doping level and is independent of any increase in the
surrounding temperature.
In n-type semiconductor, the total number of conduction electrons (ne) is due to the electrons
contributed by donors and those generated by thermally broken covalent bonds, while the
e
ut
total number of holes (nh) is only due to the holes generated by thermally broken covalent
bonds. But the rate of recombination of holes would increase due to the increase in the
tit
number of electrons. As a result, the number of holes would get reduced further.
ns
∴ In n-type semiconductors, ne > > nh
lI
Hence in n-type semiconductors, electrons are majority carriers & holes are minority carriers.
ru
A
ARUL INSTITUTE, CHENNAI
p–TYPE SEMICONDUCTOR
A p-type semiconductor is obtained by doping a pure silicon (or germanium) crystal with
The dopant has one valence electron less than Si or Ge and therefore, this atom can form
covalent bonds with neighbouring three Si atoms but does not have any electron to offer to
the fourth Si atom. So the bond between the fourth neighbour and the trivalent atom has a
Since the neighbouring Si atom in the lattice wants an electron in place of a hole, an electron
in the outer orbit of an atom in the neighbourhood may jump to fill this vacancy, leaving a
vacancy or hole at its own site. Thus the hole is available for conduction.
Note that the trivalent atom becomes effectively negatively charged when it shares fourth
electron with neighbouring Si atom. Therefore, the trivalent atom of p-type material can be
treated as core of one negative charge along with its associated hole as shown in the figure (b).
trivalent atoms and those generated by thermally broken covalent bonds, while the total
number of conduction electrons (ne) is only due to the electrons generated by thermally
Hence in p-type semiconductors, holes are majority carriers & electrons are minority carriers.
e
ut
Note that the crystal maintains an overall charge neutrality as the charge of additional charge
tit
carriers is just equal and opposite to that of the ionised cores in the lattice.
ns
lI
ru
A
ARUL INSTITUTE, CHENNAI
ENERGY BAND STRUCTURE OF n–TYPE & p–TYPE SEMICONDUCTOR
In the case of extrinsic semiconductors, additional energy states due to donor impurities (ED)
In the energy band diagram of n-type Si semiconductor, the donor energy level ED is slightly
below the bottom EC of the conduction band and electrons from this level move into the
conduction band with very small supply of energy. At room temperature, most of the donor
atoms get ionised but very few (~1012) atoms of Si get ionised. So the conduction band will
have most electrons coming from the donor impurities, as shown in the figure (a).
Similarly for p-type semiconductor, the acceptor energy level EA is slightly above the top EV
of the valence band as shown in the figure (b). With very small supply of energy, an electron
from the valence band can jump to the level EA and ionise the acceptor negatively.
(Alternately, we can also say that with very small supply of energy, the hole from level EA
sinks down into the valence band. Electrons rise up and holes fall down when they gain
ARUL INSTITUTE, CHENNAI
external energy) At room temperature, most of the acceptor atoms get ionised leaving holes in
the valence band. Thus at room temperature the density of holes in the valence band is high.
nenh = n i2
The difference in the resistivity of C, Si and Ge depends upon the energy gap between their
e
conduction and valence bands.
ut
For C (diamond), Si and Ge, the energy gaps are 5.4 eV, 1.1 eV and 0.7 eV, respectively. Sn
tit
also is a group IV element but it is a metal because the energy gap in its case is 0 eV.
ns
lI
ru
A
ARUL INSTITUTE, CHENNAI
CBSE – CLASS XII – PHYSICS – CHAPTER 14
SEMICONDUCTOR ELECTRONICS – PART 2
Consider a thin p-type silicon (p-Si) semiconductor wafer. By adding precisely a small
quantity of pentavalent impurity, part of the p-Si wafer can be converted into n-Si. There are
several processes by which a semiconductor can be formed. The wafer now contains p-region
e
ut
and n-region and a metallurgical junction between p- and n- region.
tit
Two important processes occur during the formation of a p-n junction: Diffusion and Drift.
more than the concentration of electrons. During the formation of p-n junction and due to the
ru
concentration gradient across p- and n- sides, holes diffuse from p-side to n-side (p → n) and
electrons diffuse from n-side to p-side (n → p). This motion of charge carriers gives rise to
A
When an electron diffuses from n → p, it leaves behind an ionised donor on n-side. This
ionised donor (positive charge) is immobile as it is bonded to the surrounding atoms. As the
electrons continue to diffuse from n → p, a layer of positive charge on n-side of the junction is
developed.
ARUL INSTITUTE, CHENNAI
Similarly, when a hole diffuses from p → n, it leaves behind an ionised acceptor (negative
charge) which is immobile. As the holes continue to diffuse, a layer of negative charge on the
The thin region near the junction which is free from charge carriers (free electrons and holes)
The thickness of depletion region is of the order of one-tenth of a micrometre. Due to the
positive space-charge region on n-side of the junction and negative space-charge region on p-
side of the junction, an electric field directed from positive charge towards negative charge
develops. Due to this field, an electron on p-side of the junction moves to n-side and a hole on
n-side of the junction moves to p-side. The motion of charge carriers due to the electric field is
called drift. Thus a drift current, which is opposite in direction to the diffusion current starts.
Initially, diffusion current is large and drift current is small. As the diffusion process
continues, the space-charge regions on either side of the junction extend, thus increasing the
electric field strength and hence drift current. This process continues until the diffusion
current equals the drift current. Thus a p-n junction is formed. In a p-n junction under
difference of potential across the junction of the two regions. The polarity of this potential is
Figure shows the p-n junction at equilibrium and the potential across the junction. The n-
material has lost electrons and p-material has acquired electrons. The n-material is thus
positive relative to the p-material. Since this potential tends to prevent the movement of
electron from the n region into the p region, it is often called a barrier potential.
ARUL INSTITUTE, CHENNAI
SEMICONDUCTOR DIODE
A semiconductor diode is basically a p-n junction with metallic contacts provided at the ends
The direction of arrow indicates the conventional direction of current (when the diode is
The equilibrium barrier potential can be altered by applying an external voltage V across the
diode.
ARUL INSTITUTE, CHENNAI
p – n JUNCTION DIODE UNDER FORWARD BIAS
When an external voltage V is applied across a semiconductor diode such that p-side is
connected to the positive terminal of the battery and n-side to the negative terminal, it is said
to be forward biased.
Figure (a)
Figure (b)
Barrier Potential (1) Without Battery (2) Low Voltage Battery (3) High Voltage Battery
The applied voltage mostly drops across the depletion region and the voltage drop across the
p-side and n-side of the junction is negligible. This is because the resistance of the depletion
region (a region where there are no charges) is very high compared to the resistance of n-side
and p-side.
The direction of the applied voltage (V) is opposite to the built-in potential (Vo) as shown in
the figure (b). As a result, the depletion layer width decreases and the barrier height is
reduced. The effective barrier height under forward bias is (Vo – V).
ARUL INSTITUTE, CHENNAI
If the applied voltage is small, the barrier potential will be reduced only slightly below the
equilibrium value and only a small number of charged carriers will possess enough energy to
If we increase the applied voltage significantly, the barrier height will be reduced and more
number of charged carriers will have the required energy. Thus the current increases.
Due to the applied voltage, electrons from n-side cross the depletion region and reach p-side
(where they are minority carriers). Similarly, holes from p-side cross the junction and reach
the n-side (where they are minority carriers). This process under forward bias is known as
At the junction boundary, on each side, the minority carrier concentration increases
Due to this concentration gradient, the injected electrons on p-side diffuse from the junction
edge of p-side to the other end of p-side. Likewise, the injected holes on n-side diffuse from the
junction edge of n-side to the other end of n-side (as shown in the figure). This motion of
charged carriers on either side gives rise to current. The total diode forward current is sum of
hole diffusion current and electron diffusion current. The magnitude of this current is usually
in mA.
ARUL INSTITUTE, CHENNAI
p–n JUNCTION DIODE UNDER REVERSE BIAS
When an external voltage V is applied across the diode such that n-side is connected to the
positive terminal of the battery & p-side to the negative terminal, it is said to be reverse biased.
Figure (a)
Figure (b)
The applied voltage mostly drops across the depletion region. The direction of applied voltage
is same as the direction of barrier potential. As a result, the barrier height increases and the
The effective barrier height under reverse bias is (Vo + V) as shown in the figure (b).
This suppresses the flow of electrons from n → p and holes from p → n. Thus, diffusion
Due to the electric field across the junction, an electron on p-side of the junction moves to
n-side and a hole on n-side of the junction moves to p-side. This drift of carriers gives rise to
drift current. The drift current is of the order of a few µA. This is quite low because it is due
voltage is sufficient to sweep the minority carriers from one side of the junction to the other
side of the junction. The current is not limited by the magnitude of the applied voltage but is
limited due to the concentration of the minority carrier on either side of the junction.
The current under reverse bias is essentially voltage independent upto a critical reverse bias
voltage, known as breakdown voltage (Vbr). When V=Vbr, the diode reverse current increases
sharply. Even a slight increase in the bias voltage causes large change in the current. If the
e
ut
reverse current is not limited by an external circuit below the rated value (specified by the
manufacturer) the p-n junction will get destroyed. Once it exceeds the rated value, the diode
tit
gets destroyed due to overheating. This can happen even for the diode under forward bias, if
ns
the forward current exceeds the rated value.
lI
ru
A
ARUL INSTITUTE, CHENNAI
V–I CHARACTERISTICS OF A DIODE
The circuit arrangement for studying the V – I characteristics of a diode, (i.e., the variation of
current as a function of applied voltage) are shown in Figure (a) and (b).
The battery is connected to the diode through a potentiometer (or rheostat) so that the
applied voltage to the diode can be changed. For different values of voltages, the value of the
During forward bias, the current first increases very slowly, almost negligibly, till the voltage
across the diode crosses a certain value. After that characteristic voltage, the diode current
increases significantly (exponentially). This voltage is called the threshold voltage or cut-in
voltage (~0.2V for germanium diode and ~0.7 V for silicon diode).
During reverse bias, the current is very small (~µA) and almost remains constant with change
e
ut
in bias. It is called reverse saturation current. However, for special cases, at very high reverse
tit
bias (break down voltage), the current suddenly increases. The general purpose diode are not
only in one direction (forward bias). The forward bias resistance is low as compared to the
For diodes, we define a quantity called dynamic resistance as the ratio of small change in
A
∆V
rd =
∆I
ARUL INSTITUTE, CHENNAI
APPLICATION OF JUNCTION DIODE AS A RECTIFIER
The process in which alternating voltage or alternating current is converted into direct
voltage or direct current is known as rectification. The device used for this process is called
as rectifier.
A junction diode allows current to pass only when it is forward biased. So if an alternating
voltage is applied across a diode the current flows only in that part of the cycle when the
diode is forward biased. This property is used to rectify alternating voltages and the circuit
The half wave rectifier circuit consists of a transformer, a p-n junction diode and a load
The secondary of a transformer supplies the desired ac voltage across terminals A and B.
ARUL INSTITUTE, CHENNAI
When the positive half cycle of the AC input signal passes through the circuit, the terminal A
is positive with respect to terminal B. The diode is forward biased and hence it conducts. The
current flows through the load resistor RL and the output voltage is developed across RL as
When the negative half cycle of the AC input signal passes through the circuit, the terminal A
is negative with respect to terminal B. Now the diode is reverse biased and does not conduct.
e
The reverse saturation current of a diode is negligible and hence no current flows through RL.
ut
The output of the half wave rectifier is not a steady DC voltage but a pulsating voltage. This
tit
pulsating voltage cannot be used for electronic equipments. A steady voltage is required
ns
which can be obtained with the help of filter circuits.
lI
Since only one half of the ac input wave is rectified, it is called as half wave rectifier.
ru
A
ARUL INSTITUTE, CHENNAI
FULL WAVE RECTIFIER
The positive and negative half cycles of the AC input signal are rectified in this circuit and
Here the p-side of the two diodes are connected to the ends of the secondary of the
transformer. The n-side of the diodes are connected together and the output is taken between
this common point of diodes and the midpoint of the secondary of the transformer. So for a
full-wave rectifier, the secondary of the transformer is provided with a centre tapping and so
voltage at B will be negative (out of phase) as shown in the figure (b). The diode D1 is forward
biased and conducts whereas the diode D2 is reverse biased and does not conduct. Hence the
current flows through the load resistor RL and the output voltage is developed across RL as
At any instant if the input voltage at A is negative with respect to the centre tap, then the
e
input voltage at B will be positive. So, the diode D1 is reverse biased and does not conduct
ut
whereas the diode D2 is forward biased and conducts. Hence the current again flows through
tit
the load resistor RL and the output voltage is developed across RL as shown in the figure (c).
ns
Since both the positive and negative half cycles of the AC input signal are rectified in this
The rectified voltage is in the form of pulses of the shape of half sinusoids. Though it is
unidirectional it does not have a steady value. To get steady dc output from the pulsating
voltage normally a capacitor is connected across the output terminals (parallel to the load
RL). One can also use an inductor in series with RL for the same purpose. Since these
additional circuits appear to filter out the ac ripple and give a pure dc voltage, so they are
called filters.
When the voltage across the capacitor is rising, it gets charged. If there is no external load, it
remains charged to the peak voltage of the rectified output. When there is a load, it gets
discharged through the load and the voltage across it begins to fall. In the next half-cycle of
rectified output it again gets charged to the peak value. The rate of fall of the voltage across
the capacitor depends inversely upon the product of capacitance C and the effective resistance
RL used in the circuit and is called the time constant. To make the time constant large value,
C should be large. So capacitor input filters use large capacitors. The output voltage obtained
by using capacitor input filter is nearer to the peak voltage of the rectified voltage. This type