15-06-2025

2302CJA101021250012 JA

PART-A-PHYSICS

SECTION-I(i)

1) In the circuit shown in figure the reading of ideal ammeter is :-

(A) 1A
(B) 2A
(C) 3A
(D) 4A

2) Two bulbs of (50W, 100V) and (100W, 150V) are taken. Correct relation for their resistances:-

(A) R50 > R100

(B) R50 < R100
(C) R50 = R100
(D) Nothing can be predicted.

3) A Wheatstone's bridge is balanced with a resistance of 625 Ω in the third arm, where P, Q and S
are in the 1st, 2nd and 4th arm respectively. If P and Q are interchanged, the resistance in the third
arm has to be increased by 51Ω to secure balance. The unknown resistance in the fourth arm is :-

(A) 625 Ω
(B) 650 Ω
(C) 676 Ω
(D) 600 Ω

4) In the given circuit, the value of R so that thermal power generated in R will be maximum (in Ω),
is :

(A) 3
(B) 4
(C) 2
(D) 20

5) Two identical metal plates are given positive charges Q1 and Q2 (< Q1) respectively. If they are
brought close together to form a parallel plate capacitor with capacitance C, the potential difference
between them is :-

(A)

(B)

(C)

(D)

SECTION-I(ii)

1) Three capacitors each having capacitance are connected with a battery of emf 30 V as

shown in figure. Select the correct statement(s), after the switch S is closed.

(A) The amount of charge flown through the battery is .

(B) The heat generated in the circuit is 0.6 mJ.
(C) The energy supplied by the battery is 0.6 mJ.
(D) The amount of charge flown through the switch S is .

2) In the circuit shown in the figure C1 = C, C2 = 2C, C3 = 3C, C4 = 4C. Then select correct
alternative(s):

(A) Maximum potential difference is across C1.

(B) Minimum potential difference is across combination of C3 and C4.
(C) Maximum potential energy is in C1.
(D) Minimum potential energy is in C2.

3) A parallel plate air capacitor is connected to a battery. If plates of the capacitor are being slowly

moved closer, then which of the following statements is/are CORRECT ?

(A) During the process, work done by an external agent is negative.

(B) Strength of electric field between the plates increases.
(C) Potential energy in the capacitor decreases.
(D) Force between the plates remains constant.

4) A conical shaped wire of uniform resistivity has ratio of radius of end cross-section 1 : 3.
Resistance of wire is 8Ω. Section PQ divides the wire into two equal halves. Choose the correct

option(s).

(A) Resistance of first half is 6Ω

(B) Resistance of second half is 3Ω
(C) Potential at PQ is 2.25V
(D) Potential at PQ is 6V

SECTION-I(iii)

Common Content for Question No. 1 to 2

Ammeter is a device to measure an electric current. In order to convert a galvanometer into an
ammeter, a resistance having small value is connected in parallel with the galvanometer coil. This
resistor is called the shunt. The current to be measured in passed through the ammeter by
connecting it in series with the segment which carries the current. When the ammeter is connected
in a segment of circuit, the resistance of the segment increases, which reduces the main current to
be measured. To minimize the error, the equivalent resistance of ammeter circuit should be small.
This is one reason why the shunt having a small resistance r is connected in parallel to the coil.
A galvanometer of resistance 100 Ω gives a full scale deflection for a current of 1 mA.

1) Shunt required to convert it into an ammeter giving full scale deflection for a current of 10 amp is

(A)

(B)

(C)

(D)

2) When the current through ammeter is giving full scale deflection then heat generated by shunt
per unit time is

(A) 1 Watt
(B) 0.9999 Watt
(C) 1.0001 Watt
(D) no heat will be dissipated

Common Content for Question No. 3 to 4

Two identical capacitor A and B, each of capacitance 'C' are connected in series. The combination
connected to a battery of emf E. A dielectric slab of dielectric constant K is introduced between the

plates of capacitor B to cover entire space between the plates.

3) After introduction of dielectric slab in B, the ratio of capacitance of A and B is

(A) 1:1
(B) 1:K
(C) K:1
(D)
4) After introduction of dielectric slab in B, the ratio of potential differences across A and B will be

(A) 1:1
(B) 1:K
(C) K:1
(D)

SECTION-III

1) A cell of resistance 5Ω is connected with a battery of constant emf. Internal resitance of the
battery is given by r = 1 + αt where t is time. At what time power in the 5Ω resistor is maximum
(where α = 1 Ω/s)

2) The current supplied to the circuit is I ampere as shown. Assuming both cells as ideal find 4I.

3) Two large conducting plates, identical in size, are placed parallel to each other at a separation d.
Each plate has an area A. One of the plates is cut into two equal parts and then a battery of emf V is
connected across these two pieces. The work done by the battery in supplying charge to the plates is

. Find x.

4) There are six plates of equal area A and separation between the plates is d (d << A) are arranged
as shown in the figure. Plate no. 2 and 4 are connected and plate no. 3 and 5 are connected. The

equivalent capacitance between points 1 and 6 is . Find .

SECTION-IV

1) All capacitors have capacitance of 1μF. Find equivalent capacitance between points A & B.
 Column-I (Circuit) Column-II (Capacitance)

(A) (P)

(B) (Q)

(C) (R)

(D) (S)

(T) None of these

PART-B-CHEMISTRY

SECTION-I(i)

1) The major product obtained in this reaction

is

(A)
(B)

(C)

(D) None of these

2) Product ?

(A)

(B)

(C)

(D)

3) Which among the following will show highest rate of on hydrolysis

(A)

(B)

(C)

(D)
4) Which of the following sets of groups contain only electrophiles?

(A)
(B)
(C)
(D)

5) Choose the major product of the following reaction sequence.

(A)

(B)

(C)

(D)

SECTION-I(ii)

1) Predict the products expected in given reaction

2-Bromo-1, 1-dimethylcycopentane

(A)
(B)

(C)

(D)

2)

Which of the following statements are correct

(A) In SN2 reaction inversion of configuration would take place

In SN2 hydrolysis on akyl halide having R configuration will convert into an alcohol of S-
(B)
configuration
(C) In SN1 reaction, 100% racemisation takes place
(D) In SN1 reaction, racemisation takes place with inversion of configuration.

3) Which of the following statement(s) is/are correct about SN1 mechanism among the following?

(A)

Rate of SN1 is higher for II than I

(B)

Rate of solvolysis of I is greater than that of II

(C)

Rate of SN1 is higher for II than that of I

(D)
Rate of solvolysis is greater for I than that of II

4) Which of the following products are expected from the solvolysis of bromomethyl cyclopentane?

(A)

(B)

(C)

(D)

SECTION-I(iii)

Common Content for Question No. 1 to 2

A base shares its non-bonding electrons with a proton, basicity is a measure of how will the base
shares those electrons with a proton. The stronger the base, the better it shares its electrons
basicity is measures by an equilibrium constant (Ka) that indicates the tendency of the conjugate acid
of the base to lose a proton. A nucleophile uses its non-bonding electrons to attack an electron
deficient atom other than a proton. Nucleophilicity is a measure of how readily the nucleophile is
able to attack such an atom. It is measured by a rate constant (K).

1) Which of the following is correct order of decreasing nucleophilicity in an aqueous solution for the
given species.
(A) IV > III > V > II > I
(B) V > III > I > IV > II
(C) V > IV > I > II > III
(D) V > III > II > I > IV

2)
What is the final product (Y) in the following reaction

(A)

(B)
(C)
(D)

Common Content for Question No. 3 to 4

By considering equilibrium between the two opposite processes of adsorption & desorption,

Langmuir obtained that extent of adsorption can be obtained as.

where 'a' & 'b' are constants.

Based on this info, answer the questions that follow.

3) Which is not the assumption of Langmuir adsorption isotherm ?

(A) The adsorption consists entirely of monolayer at the surface.

There is no interaction between molecules on different sites and each site can hold only one
(B)
adsorbed molecule.
(C) The adsorption consist entirely of multiplayer at the surface.
(D) The enthalpy of adsorption does not depends on number of sites and is equal for all sites.

4) Which of the following options is correct for Langmuir isotherm.

(A)
At very low pressure will become constant.

(B)
At moderate pressures will be linearly dependent on pressure.

(C)
At high pressures should be constant independent of pressure.

(D)
At high pressures should be varying linearly with pressure.

SECTION-III

1) How many of the following are electrophiles ?

(a) CH4 (b) H+ (c) (d) :CH2 (e) NH3

(f) BH3 (g) (h) H2O (i)

(j) SO3

2)
Total number of α-hydrogens in the product (P) is ____.

3) Among the following the number of curves not in accordance with Freundlich adsorption isotherm
is ______.

4) How many 1,2-shifts are involved in the following rearrangement of carbocation ?

SECTION-IV

1) Match the List I with List II and select the correct answer using the codes given below the Lists.

List I List II

(A) (P) Elimination Reaction

(B) (Q) Carbocation

(C) (R) Carbanion

 (D) (S) Free radical

PART-C-MATHEMATICS

SECTION-I(i)

1) The number of continuous functions f : R → R satisfying f(0) = 1 and f(2x) – f(x) = x, is

(A) 0
(B) 1
(C) 2
(D) Infinite

2) The sum to infinite terms of the series

is-

(A)

(B)

(C) cot–1 2
(D) –cot–1 2

3) Let f: (–2,2)→ R be defined by

Where [x] denotes the greatest integer function. If m and n respectively are the number of points in
(–2,2) at which y = |f(x)| is not continuous and not differentiable, then m + n is equal to ______.

(A) 8
(B) 6
(C) 4
(D) 10

4) Number of points of non-differentiability of the function

g(x) = [x2]{cos24x} + {x2}[cos24x] + x2 sin24x + [x2][cos24x] + {x2}{cos24x} in (–50, 50) where [x]
and {x} denotes the greatest integer function and fractional part function of x respectively, is equal
to :-

(A) 98
(B) 99
(C) 100
(D) 0
5) Value of is -

(A)

(B)

(C)

(D)

SECTION-I(ii)

1) If , &

, then

(A) α = β
(B) α + β = 3γ
(C) 4(β – γ) = α
(D) β = γ

2)

Let [x] denotes the greatest integer less than or equal to x. If f(x) = [x sin (πx)], then f(x) is

(A) Continuous at x = 0
(B) Continuous at
(C) differentiable at x = 1
(D) differentiable in

3) If , ƒ(0) = 0, (c ≠ 0) is differentiable at x = 0 and a + b + c < 4, then

a can be

(A)

(B)

(C) 1
(D) 4
4) Let (where [x] denotes greatest integer less than or equal to x), then

(A)

(B)

(C) does not exist

(D) None of these

SECTION-I(iii)

Common Content for Question No. 1 to 2

Given a function ƒ differentiable at x = 1 such that ƒ'(1) = 3 and satisfying ƒ(xy) = ƒ(x) + ƒ(y) ∀ x, y >
0.

1) Consider the following statements : (I) ƒ(x) is discontinuous at exactly one point in R+
(II) ƒ(x) is not differentiable at exactly one point in R+
(III) ƒ(x) is differentiable ∀ x ∈ R+
Identify the correct option(s) -

(A) Only statement-I is true

(B) Only statement-II is true
(C) Only statement-III is true
(D) Both statement-I & II are true

2) Which of the following is true for y = |ƒ(|x|)| -

(A) non derivable at exactly 3 points in its domain

(B) non derivable at exactly 2 points in its domain
(C) discontinuous at exactly 2 points in its domain
(D) continuous and derivable throughout its domain

Common Content for Question No. 3 to 4

If a = sin–1(sin(10)) + cos–1(cos(10))

b = cot–1 – cot–1(5)

c = cos–1 + tan

d= .sin

3) The value of a + d is -

(A) 0
(B) π
(C) 5π
(D) 7π
4) The value of c – 2b is -

(A) 0
(B) π
(C) 5π
(D) 7π

SECTION-III

1) Number of integral solutions of the equation is

2) The value of is

3) Let f be a continuous function on R such that , then find the value

of f(0).

4) If the value of equal to , where p and q are relatively

prime positive integers, then the value of is :

SECTION-IV

1)

Column-I Column-II

(A) (P)
(a > 0) can be equal to

(B) (Q)
is equal to

(C) (R)
is equal to

(D) (S)
is equal to

(T) 0
 ANSWER KEYS

PART-A-PHYSICS

SECTION-I(i)

Q. 1 2 3 4 5
A. A B B A D

SECTION-I(ii)

Q. 6 7 8 9
A. A,C,D A,B,C A,B A,C

SECTION-I(iii)

Q. 10 11 12 13
A. B B B C

SECTION-III

Q. 14 15 16 17
A. 0 9 4 5

SECTION-IV

Q. 18
A. A->S,B->R,C->R,D->Q

PART-B-CHEMISTRY

SECTION-I(i)

Q. 19 20 21 22 23
A. A C B C C

SECTION-I(ii)

Q. 24 25 26 27
A. A,B,C,D A,D B,C A,B,C,D

SECTION-I(iii)

Q. 28 29 30 31
A. B B C C

SECTION-III

Q. 32 33 34 35
A. 7 6 3 4
 SECTION-IV

Q. 36
A. A->PR,B->PQ,C->P,D->PQ

PART-C-MATHEMATICS

SECTION-I(i)

Q. 37 38 39 40 41
A. B C C D B

SECTION-I(ii)

Q. 42 43 44 45
A. A,C A,B,D A,B,C A,B,C

SECTION-I(iii)

Q. 46 47 48 49
A. C B D A

SECTION-III

Q. 50 51 52 53
A. 2 1 1 0

SECTION-IV

Q. 54
A. A->PQRST,B->PR,C->PR,D->S
 SOLUTIONS

PART-A-PHYSICS

1)

Question Explanation :
We have to calculate reading of ammeter in the given circuit diagram.

Concept :
This question is based on Circuit analysis.

Solution :

The equivalent resistance between A and B = 4Ω

Current I= The current divides into different branches as shown in the figure. It is
clear that the ammeter will read

. So the correct choice is (1)

Hence,
Option (1) is correct

2) Question Explanation :
We have to obtain the relation between resistances of two bulb of given rating.

Concept :
This question is based on Electric Power of Bulb

Solution :

R50 =

R100 =
Hence R100 > R50

Hence,
Option (2) is correct.
3)

∴
S = 25 × 26
= 650 Ω

4)

5)

Within the plates electric fields due to charges Q1 and Q2 are

E1 = and E2 =
As these fields are in opposite directions and Q1 > Q2, the net electric field within the plates is

E = E1 – E2 =

Hence V = Ed = (Q1 – Q2) =

6)

Initially

Then,

Charge flow through switch

= 20 + 20 + (60 – 40) =

7) q → same in series combination of C1, C2 & (C3 || C4)

Umax in C1

8) ΔV = constant

d↓ → E↓ → Q↓ → F↓
C → ΔU → Wext = –ve

9) R =

R1 = 6Ω, R2 = 2Ω

10) Rsh (I – Ig) = RgIg

Rsh =

11) Ish = 10 – 10–3 = 9.999A

P = I2shRsh = (9.999)2 × = 0.999 W

12)

When dielectric fully filled in the capacitor then capacitance

C' = KC
CA = C
CB = KC

13)

14) Initially current is maximum hence power will be maximum initially t =0

15)
applying KCL at function A & B ;

I=

&I=

we get, x = &I=

16) There are two capacitors in series.

Equivalent capacitance is

∴ Charge supplied by the cell

0
Q=CV=

0
∴ Wbatt = QV = C V2 =

17)

18) (A)
By symmetry point C,D are at sum potential hence capacitacne between C & D has no charge.
Similarly E & F ane at same potential.
(B) By symmetry C & D are at same potential

(C) By symmetry C & D are at same potential

(D)
No charge will flow to upper loop
PART-B-CHEMISTRY

19) New Solution :

Old Solution :

20) Rxn. of TsCl2, Pyridine proceed through SN2 mechanism, Hence Walden Inversion takes
place.

21)
3o Carbocation is most stable.

22) are electrophiles.

 23)

24) All possible carbocation can give SN1 and E1 product.

25)

26) Rate of SN1 depends upon the stability of carbocation.

27)

In this reaction, is formed, which can show ring expansion and as well as rearrangement

converted into and . After this both carbocation can show elimination as well as
substitution reaction. So, all
products are formed.

28) Negatively charged sulfur is the most nucleophilic because sulfur is larger than oxygen.
The poorest nucleophilic is the one with the neutrol oxygen atom. A carboxylic acid is a
stronger acid than phenol, which is stronger acid than water.

29)

30)

The adsorption consist entirely of multiplayer at the surface.

31)

At very high pressure which is constant independent of pressure.

32)

7 (b, c, d, f, g, i, j)
Electron pair acceptors are electrophile so species must have vacant p or d orbitals.

33)
Number of α-hydrogens = 6.

34)
 35)

36) (A)
Reason: F is poor LG & acidic character of H increased due to EWG Cl
So carbanion forms as intermediate
(B) Br is good LG & along with Alc. KOH is characteristic reagent for E2 ; where simultaneous
elimination occur by TS
(D) EtOH is polar protic solvent
So E1 mechanism; where Br– is snatched with help of solvent leaving carbocation
as intermediate

PART-C-MATHEMATICS

37) From f(2x) – f(x), we have f(x) – f Replacing x by repeatedly and adding, we get

+ ... + = + ... +

⇒ f(x) –f = + ... +

∴ =
⇒ f(x) – f(0) = x

⇒ f(x) = x + f(0) = x + 1
Hence number of function is 1

38) =

=
= (2r+1) – tan–1(2r)
= (tan–1 2n+1 – tan–1 2)

= – tan–1 2 = cot–1 2

39)

40)
= x2{cos24x} + x2[cos24x] + x2sin24x
= x2({cos24x} + [cos24x]) + x2sin24x
= x2cos24x + x2sin24x
g(x) = x2
∵ g(x) is differentiable in (–50, 50)
∴ No of non-differentiable points is zero

41)

42) tan22 =

sin75° = ; cos75° =

cot75° =
β = π – cot–1 + (120°)
β = 105° + 15° = 120º

γ= = 90º
α = β & 4(β – γ) = α

43)

Also x sin πx is less than 1

f(x) = [x sin π x] = –1
Thus f(x) is constant function and equal to 0 in closed internal (–1, 1)
Constant function is continuous and differentiable in this internal
⇒ [–1, 1]

44)

ƒ(0) = 0, ,
–1
⇒ c tan b = 0 ⇒ b = 0 (c ≠ 0)

ƒ'(0+) =

a + b + c < 4 ⇒ 3a < 4 ⇒

a can be

45)

46) ƒ(xy) = ƒ(x) + ƒ(y) ∀ x, y > 0. then f(x) = k ℓn(x)

f(x) = k.
f '(1) = k = 3
∴ f(x) = 3ℓnx
ƒ(x) is differentiable for all x ∈ R+

47) ƒ(xy) = ƒ(x) + ƒ(y) ∀ x, y > 0.

then f(x) = k ℓn(x)

f(x) = k.
f '(1) = k = 3
∴ f(x) = 3ℓnx
y = |ƒ(|x|)| = |3ln(|x|)|
Domain : R0
Continuous at all points in domain.
Not differentiable at x = –1 and 1

48) a = (3π – 10) + (4π – 10) = b=π– – cot–1(5) = π – (tan–15 + cot–15) =

π– =

c=
d = 20

49) a = (3π – 10) + (4π – 10) = b=π– – cot–1(5) = π – (tan–15 + cot–15) =

π– =

c=
d = 20

50) The maximum value of the function is obtained when the value of is equal to
1 and value of is equal to
are defined for x ≤ 1 and x ≥ 0
∴ and
Thus, reducing the equation to
⇒ x2 – x ≤ 0 and x2 – x ≥ 0
Thus, reducing the equation
⇒ x2 – x = 0
⇒ x = 1,0
∴ there are two solutions, both satisfies the equation

51)

52) As f is continuous on R, so f(0) = f(x)

Thus f(0) = = = 0 + 1 = 1.

53) p = 2, q = 3

54) (A) (a > 0)

Case-1 :

Case-2 : a = 1

Case-3 : a > 1

(B)

(C)
(D)

(P)

(Q) (a,b,c > 0 & abc = 1)

(R)