Date : 05-03-2025 STD 11 Science Chemistry Total Marks : 40

SECTION A

* Choose The Right Answer From The Given Options.[1 Marks Each] [40]

1. Which one of the following has maximum number of atoms?

(A) 1g of Li(s) [Atomic mass of Li = 7]

(B) 1g of Ag(s) [Atomic mass of Ag = 108]

(C) 1g of M g(s) [Atomic mass of M g = 24]

(D) 1g of O2 (g) [Atomic mass of O = 16]

Ans. : a
Number of atoms
=
w

molar mass
× NA × atomicity
1
(1) × NA × 1
7

1
(2) × NA × 1
108

1
(3) × NA × 1
24

1
(4) × NA × 2
32

2. A hydrocarbon contains 85.7 %C . If 42 mg of the compound contains 3.01 × 10

20

molecules, the molecular formula of the compound will be

(A) C 3
H6 (B) C 6
H12 (C) C12
H24 (D) C 2
H4

Ans. : b
85.7% carbon ⇒ 100 − 85.7 = 14.3% Hydrogen gram molecular weight = 6.023 × 10
23

20
⇒ 42mg = 3.018 × 10

20
⇒ 84mg = 6.02 × 10

23
84g = 6.02 × 10

85.7
∴ 85.7% = × 84 = 72g
100

1moleof C = 12g
6 moles of C = 12 × 6 = 72g
∴ There are 6 carbons in each molecule

84 − 72 = 12g of H = 12H atoms in each molecule

∴ Molecular formula = C H 6 12

3. How much volume of 5 M HN O is required to oxidise 3

16 g
+2
Fe if HN O3 is
converting into N O .............. ml
(A) 16 (B) 19.05 (C) 38.1 (D) 32
Ans. : b
16
5×3×V = × 1 × 1000
56

V = 19.05 mL

Page 1
4. The molality of 1M solution of N aCl (specific gravity 1.0585 g/ml ) is
(A) 1.0585 (B) 1 (C) 0.10 (D) 0.0585
Ans. : b
mole of NaCl 1
m = = = 1
Weight of solvent in kg. 1

weight of solvent = weight of solution − weight of NaCl

= 1.0585 × 1000 − 58.5

= 1058.5 − 58.5 = 1000 g = 1 kg

5. The amount of water that should be added to 500 ml of 0.5 N solution of N aOH

to give a concentration of 10 mg per ml is

(A) 100 (B) 200 (C) 250 (D) 500
Ans. : d
(d) N = 0.5 N
1 → 10mg per mL

−3
10× 10 gm
N2 = × 1000 = 0.25 N
40×1

V1 = 500 ml ,V 2 =?

N1 V1 = N2 V ; 2

0.5 × 500 = 0.25 × V2

V2 = 1000 mL final volume water added = 1000 − 500 = 500 mL.

6. Volume of air required to completely burn 10 litres of C H is ................ 2 4 L

(assume all volumes are measure at same temperature and pressure)

(A) 15 (B) 150 (C) 100 (D) 200

Ans. : b
C2 H4 + 3O2 → 2CO2 + 2H2 O

1L 3L

10 L 30 L

30×100
Vair = = 150 L
20

7. If M is the molecular weight of K M nO4 , its equivalent weight will be when it is

converted into K M nO 2 4

(A) M (B) M /3 (C) M /5 (D) M /7

Ans. : a
(a)Equivalent wt. = molecular wt.

[Link]
−
− gainedorlost
=
M

1
= M

8. Which of the following statements is correct about equivalent weight of K M nO4

(A) It is one third of its molecular weight in alkaline medium

(B) It is one fifth of its molecular weight in alkaline medium
(C) It is equal to its molecular weight in acidic medium
(D) It is one third of its molecular weight in acidic medium

Page 2
 Ans. : a
(a)It is one third of its molecular weight in alkaline medium because it gives 3

nascent oxygen in alkaline medium.

−
+3e

2K M n O4 + H2 O −−−→ 2K OH + 2M n O2 + 3[O]

Equivalent weight = M

9. In acidic medium potassium dichromate acts as an oxidant according to the

equation, Cr 2O
7
2−
+ 14H
+
+ 6e
−
→ 2C r
3+
+ 7H2 O . What is the equivalent weight of
K2 C r2 O7 ? (mol. Wt. = M )
(A) M (B) M /2 (C) M /3 (D) M /6
Ans. : d
(d)Since it accept 6e
−
its
Equivalent weight =
M

6
.
10. Rearrange the following (I to I V ) in the order of increasing masses:
(I )0.5 mole of O3 (I I )0.5 gm atom of oxygen (I I I )3.011 × 10
23
molecules of O2

(I V )5.6 litre of CO2 at ST P

(A) I I < IV < III < I (B) I I < I < IV < III

(C) I V < II < III < I (D) I < II < III < IV

Ans. : a
(a) (I ) 0.5 mole O3 = 24 g O3

(I I ) 0.5 g atom of oxygen = 8g

23
3.011×10
(I I I ) 23
× 32 = 16 g O2
6.022×10

5.6
(I V ) × 44 g CO2 = 11 g CO2
22.4

11. The mass of 112 cm

3
of CH4 gas at ST P is ............. g
(A) 0.16 (B) 0.8 (C) 0.08 (D) 1.6

Ans. : c
(c) n =
W

M
=
22400
V
; W

16
=
112

22400
; W = 0.08 gm .
12. At ST P the moles of oxygen in 2.8 L of CO2 gas is
(A) 1 (B) 0.5 (C) 0.25 (D) 0.125

Ans. : c
moles of CO2 =
Volume

22.4
=
2.8

22.4
= 0.125 mol

Moles of oxygen = 0.125 × 2 = 0.25 mol

13. Which has highest number of atoms ?

(A) 11.2 L of CO2 gas at ST P (B) 2 g of H2

(C) 2 g− atom of C (D) 3 g− molecule of SO2

Page 3
 Ans. : d
CO2 ⇒
11.2

22.4
× NA × 3 = 1.5NA atoms
atoms
2g
H2 ⇒ × NA × 2 = 2NA
2

C ⇒ 2 × NA atoms
SO2 ⇒ 3 × NA × 3 = 9NA atoms
14. Which has the maximum number of molecules among the following ?
(A) 64 g SO 2 (B) 44 g CO 2 (C) 48 g O 3 (D) 8 g H 2

Ans. : d
Moles ∝ molecules
64
= 1 mol SO2
64

44

1
= 1 mol of CO2

48

48
= 1 mol of O3

2
= 4 mol of H2

15. How many H− atoms are present in 0.046 g of ethanol

(A) 6 × 10 20
(B) 1.2 × 10 21

(C) 3 × 10 21
(D) 3.6 × 10 21

Ans. : d
(d) Mol. wt of C2 H5 OH = 2 × 12 + 5 + 16 + 1 = 64

∵ 48 g C2 H5 OH has H atom = 6 × NA

has atoms
23
6×6.02× 10 ×0.046 21
∴ 0.046 g C2 H5 OH H = = 3.6 × 10
46

16. Which of the following contains maximum number of atoms

(A) 6.023 × 10 21
molecules of CO2

(B) 22.4 L of CO2 at ST P

(C) 0.44 g of CO2

(D) None of these

Ans. : b
(a) 6.023 × 10
23
molecules of CO2

No. of atoms = 3 × 6.023 × 10

21
=18.069 × 10 21
atoms
(b) 22.4 L of CO2

No. of atoms =6.023 × 10 23

× 3 = 18.069 × 10
23
atoms
(c) 0.44 gm of CO2

No. of moles =
0.44

44
=
1

100
× 6.023 × 10
23
moles
= 6.023 × 10
21
moles = 3 × 6.023 × 10
21
atoms 18.069 × 10
21
atoms
17. The mass of sodium acetate (CH3 COONa) required to prepare 250 mL of 0.35 M

aqueous solution is ____g. (Molar mass of CH3 COONa is 82.02 g mol

−1
)
(A) 6 (B) 7 (C) 8 (D) 9

Page 4
 Ans. : b
Moles = Molarity × Volume in litres

= 0.35 × 0.25

Mass = moles × molar mass

= 0.35 × 0.25 × 82.02 = 7.18 g

Ans. 7
18. Choose the Incorrect Statement about Dalton's Atomic Theory
(A) Compounds are formed when atoms of different elements combine in any ratio
(B) All the atoms of a given element have identical properties including identical mass
(C) Matter consists of indivisible atoms
(D) Chemical reactions involve recorganization of atoms

Ans. : a
In compound atoms of different elements combine in fixed ratio by mass.
19. Which of the following have same number of significant figures?
(A) 0.00253 (B) 1.0003 (C) 15.0 (D) 163
Choose the correct answer from the options given below
(A) A, B and C only (B) C and D only
(C) A, C and D only (D) B and C only
Ans. : c
All non zero digits are significant.
0.00253

Significant figures = 3(2, 5, 3)

1.0003

Zeros between non-zero digit are significant.

Thus,1.0003 has 5 significant figures.
15.0

Significant number = 3

163

Significant number = 3
Options (3) - A, C and D
20. A commercially sold conc. HCl is 35%HCl by mass. If the density of this
commercial acid is 1.46 g/mL , the molarity of this solution is ....M
(Atomic mass : Cl = 35.5 amu, H = 1 amu )
(A) 10.2 (B) 12.5 (C) 14.0 (D) 18.2

Ans. : c
Let total volume = 1000 mL = 1 L

total mass of solution = 1460 g

mass of HCl =
35

100
× 1460

Page 5
 moles of HCl =
35×1460

100×36.5

So molarity =
35×1460

100×36.5
= 14 M

21. 250 mL of 0.5 M NaOH was added to 500 mL of 1 M HCl The number of unreacted
HCl molecules in the solution after complete reaction is 21
. . . . . . ×10 . (Nearest
integer) (NA = 6.022 × 10
23
)

(A) 226 (B) 235 (C) 462 (D) 521

Ans. : a
We known that no. of moles
= Vlitre × Molarity and No. of millimoles = Vml × Molarity

so millimoles of NaOH = 250 × 0.5 = 125

Millimoles of HCl = 500 × 1 = 500

Now reaction is

NaOH + HCL → NaCl + H2 O

t = 0 125 500 0 0

t = 0 0375 125 125

so millimoles of HCl left = 375

−3
Moles of HCl = 375 × 10

23 −3
No. of HCl molecules = 6.022 × 10 × 375 × 10

21
= 225.8 × 10

21
≈ 226 × 10 = 226

22. When 35 mL of 0.15 M lead nitrate solution is mixed with 20 mL of 0.12 M

chromic sulphate solution, ....... ×10 −5

moles of lead sulphate precipitate out.
(Round off to the Nearest Integer).
(A) 565 (B) 525 (C) 235 (D) 412
Ans. : b
3P b(N O3 )2 + C r2 (S O4 )3 → 3P bS O4 + 2Cr(N O3 )3

35 ml 20 ml

0.15 M 0.12 M

5.25 m ⋅ mol = 2.4 m ⋅ mol 5.25 m ⋅ mol

−3
= 5.25 × 10 mol

therefore moles of P bSO4 formed = 5.25 × 10

−3
= 525 × 10
−5

23. The number of atoms in 8 g of sodium is x × 10

23
. The value of x is ...... .(Nearest
integer)
[ Given : NA = 6.02 × 10
23
mol
−1
, Atomic mass of Na = 23.0 u]

(A) 6 (B) 8 (C) 2 (D) 34

Ans. : c
8 23 23
No. of atoms = × 6.02 × 10 = 2.09 × 10
23

Page 6
 23
≃ 2 × 10

23
= x × 10

x = 2

24. For per gram of reactant, the maximwn quantity of N gas is produced in which 2

of the following thermal decomposition reactions? (Given: Atomic wt. :

Cr = 52 u, Ba = 137 u ).

(A) Ba(N 3
)2 (s) → Ba(C) + 3N2 (g)

(B) (N H 4
)2 C r2 O7 (s) → N2 (g) + 4H2 O(g) + C r2 O3 (s)

(C) 2N H 3
(g) → N2 (g) + 3H2 (g)

(D) 2N H 4
N O3 (s) → 2N2 (g) + 4H2 O(g) + O2 (g)

Ans. : c
(a) Molar mass of Ba(N3 )2 (s) = 221 g/mol

1 mole of Ba(N3 )2 (s) will give 3 moles of N2

hence 1 g

221 g/mol
moles of Ba(N3 )2 (s) will give 3×
1

221
= 0.014 moles of N2

(b) Molar mass of (N H4 )2 C r2 O7 = 252 g/mol.

1 mole of (N H4 )2 C r2 O7 will give 1 mole of N2

hence 1 g

252 g/mol
moles of (N H4 )2 C r2 O7 will give 1×
1

252
= 0.0039 moles of N2

(c) Molar mass of N H = 17 g/mol. 3

2 mole of N H will give 1 mole of N

3 2

hence moles of will give moles of

1 g 1
N H3 = 0.0297 N2 .
17 g/mol 2×17

(d) Molar mass of N H N O = 80 g/mol. 4 3

1 mole of N H N O will give 1 mole of N

4 3 2

hence moles will give moles of

1 g
1
N H4 N O3 1× = 0.0125 N2
80 g/mol 80

Hence Thermal decomposition of N H3 will produce maximum amount of N2

25. A + 2B + 3C ⇌ AB2 C3 Reaction of 6.0 g of A, 6.0 × 10 atoms of B, and 0.036 mol

23

of C yields 4.8 g of compound AB 2

C3 . If the atomic mass of A and C are 60 and
80 amu , respectively, the atomic mass of B is .............. amu (Avogadro no .
= 6 × 10
23
)
(A) 50 (B) 60 (C) 70 (D) 40
Ans. : a
A + 3B + 3C ⇌ AB2 C3 . . . . . (1)

No. of moles of
6.0 g
A = = 0.1 mol
60 g/mol

No. of moles of
23
6.00×10
B = 23
= 1 mol
6.000×10

No. of moles of C = 0.036

AB C formed accordingly to
2 3 C which is a limiting reagent.
Since 3 moles of C are used in (1)

Page 7
 So it gives 1 mole of AB2 C3

0.036
nAB2 C3 = = 0.012
3

Given mass (4.8)

=
M olecular mass (M .M )

[Link] =
4.8

0.012
= 400

⇒ 400 = 60 + (2 × x) + (80 × 3)

⇒ x = 50

26. A gaseous hydrocarbon gives upon combustion 0.72 g of water and 3.08 g of C O2 .

The empirical formula of the hydrocarbon is :

(A) C 2 H4 (B) C 3 H4 (C) C6 H5 (D) C 7 H8

Ans. : d
18gH2 O contain 2gH

∴ 0.72gH2 Ocontain 0.08gH

44gCO contain 12gC
2

∴ 3.08gCO contain 0.84gC

2

0.84 0.08
C : H = : = 0.07 : 0.08 = 7 : 8
12 1

∴ Empirical formula = C7 H8

27. The treatment of an aqueous solution of 3.74g of Cu(N O ) with excess K I 3 2

results in a brown solution along with the formation of a precipitate. Passing

H S through this brown solution gives another precipitate X. The amount of X
2

(in g) is. . . . . [Given : Atomic mass of

H = 1, N = 14, O = 16, S = 32, K = 39, Cu = 63, I = 127 ]
(A) 0.20 (B) 0.25 (C) 0.30 (D) 0.32
Ans. : d

2Cu(N O3 )2 + 5K I ⟶ C u2 I2 + K I3 + 4K N O3
0.02

K I3 + H2 S ⟶ S ↓ +K I + 2HI

0.01

nS = 0.01 mole

weight of sulphur = 32 × 0.01 = 0.32gm

28. On reaction of 38.1 g iodine and 28.4 g chlorine, mixture of I Cl and I Cl3 is
obtained then total number of moles after reaction will be
(A) 0.45 (B) 0.40 (C) 0.30 (D) 0.25
Ans. : b
I2 + 2Cl2 → ICl + ICl3

Initially (
38.1

254
= 0.15 mol) (
28.4

71
= 0.4 mol) 0 0

L. R.

Remaining 0.15 − 0.25 0.4 − 0.3 0 + 0.15

 Moles = 0 = 0.15 mol = 0.15 mol

Total moles after reaction = 0.1 + 0.15 + 0.15

= 0.40 moles

29. The modern atomic weight scale is based on

(A) C 12
(B) O 16
(C) H 1
(D) C 13

Ans. : a
Modern atomic weight scale is based on C
12
. The standard unit for expressing the
mass of atom is amu (atomic mass unit).
It is equal to 1/12 of the mass of an atom of carbon-12.
30. Which property of an element is always a whole number
(A) Atomic weight (B) Equivalent weight
(C) Atomic number (D) Atomic volume
Ans. : c
Atomic weight is the mass of a single atom of an element. It may be fractional.
Atomic radius (distance from an atom's nucleus to the outermost orbital of
electrons) and atomic volume (average volume of one atom of an element) can be
fractional as well.
Atomic number is the number of protons or electrons in an atom. Since this is
countable, it's always a whole number. So, atomic number is the correct answer.
31. Which of the following pairs of gases contains the same number of molecules
(A) 16 g of O2 and 14 g of N2 (B) 8 g of O2 and 22 g of CO2

(C) 28 g of N2 and 22 g of CO2 (D) 32 g of O2 and 32 g of N2

Ans. : a
Mole
Weight
(n) =
Molecular weight

No. of molecules
=
NA

32. CaC O3 + 2HCl → CaC l2 + C O2 + H2 O , in this chemical reaction what will be the
amount of CaCl2 . When 10 g calcium carbonate and 200 mL 0.75 M HCl is used?
............... g
(A) 83.25 (B) 16.65 (C) 11.1 (D) 8.325
Ans. : d
CaC O3 + 2HCl → CaC l2 + C O2 + H2 O

n 10
CaC O3 = = 0.1
100

n −3
HCl = 200 × 0.75 × 10 = 0.15

w 15
CaC l2 = × 111 = 8.325 g
2

33. 98 mg of H2 S O4 present in 100 g of solution then molarity of solution will be. If

density of solution is 1.25 g/mL
 (A) 12.5 M (B) 1.25 M (C) 1.25 × 10
−2
M (D) 0.125 M

Ans. : c
x(Ing)
M =
Mw × V
(InL)

−3
98× 10 g
M = g 100 g
× 1000 = 0.0125 M
98 ×
mol 1.25 g/mL

34. 5L of a gaseous mixture of ethane and propane are burnt to produce total 11 L

of CO2 . Volume percent of C2 H6 in the initial mixture is

(A) 10 (B) 20 (C) 80 (D) 60
Ans. : c
C2 H6 + C3 H8 + O2 → CO2
x litre (5−x) litre 11 litre

2 × x + 3(5 − x) = 1 × 11

2x + 15 − 3x = 11

x = 4L

Volume percentage of C2 H6 =
4

5
× 100 =

80%

35. 300 ml of a gaseous hydrocarbon when burnt in excess of O gave 2.4 lit . of CO 2 2

and 2.7 lit . of water vapour under same condition. The molecular formula of
hydrocarbon is
(A) C 4 H8 (B) C 8 H18 (C) C 6 H14 (D) C 8 H16

Ans. : b
a a
Cx Ha + (x + )O2 → xC O2 + H2 O
4 2

Here it is clear that, 1 vol of Cx Ha reacts with (x + a/4) vol of O2 is formed x vol of
CO2 and a/2 vol of H2 O .
∴ 300mL of C× Ha reacts with 300(x + a/4)mL of O2 will form 300xmL of CO2 and
300a/2 = 150amL

Given, 300xmL = 2.4L ⇒ 300 × mL = 2400mL[∵ 1L = 1000mL]

⇒ x = 8

Similarly, given, 150a mL = 2.7L ⇒ 150amL = 2700mL

⇒ a = 2700/150 = 18

Hence, molecular formula of hydrocarbon is C8 H18

36. The number of neutrons in 5 g of D2 O(D is

2
1
H) are ................ NA

(A) 0.25 (B) 2.5 (C) 1.1 (D) None of these

Ans. : b
10 g of D2 O ≡ (2 + 8)NA neutrons
37. One sample of atmospheric air is found to have 0.03% of carbon dioxide and
another sample 0.04% . This is evidence that
(A) The law of constant composition is not always true
 (B) The law of multiple proportions is true
(C) Air is a compound
(D) Air is a mixture
Ans. : d
Yes, this illustrates that air is a mixture because air is a composition of many types
of gas.
A mixture contains a combination of several elements or compounds. For a
mixture, the ratio of constituent elements or compounds is not fixed and it can
vary.
38. An element forms two oxides containing respectively 53.33 and 36.36 percent of
oxygen. These figures illustrate the law of
(A) Conservation of mass (B) Constant proportions
(C) Reciprocal proportions (D) Multiple proportions
Ans. : d
Ratio of masses of oxygen in two oxides = ≈
53.33

36.36
3

The oxygen atoms in two oxides bears a simple ratio by mass(i.e 3 : 2 )

Hence it illustrates the Law of multiple proportions
39. Assertion : Equal moles of different substances contain same number of
constituent particles.
Reason : Equal weights of different substances contain the same number of
constituent particles.
(A) If both Assertion and Reason are correct and the Reason is a correct explanation of
the Assertion.
(B) If both Assertion and Reason are correct but Reason is not a correct explanation of
the Assertion.
(C) If the Assertion is correct but Reason is incorrect.
(D) If both the Assertion and Reason are incorrect.
Ans. : c
Equal moles of different substances contain same number of constituent particles
but
equal weights of different substances do not contain the same number of
consituent particles.
40. How many molecules are present in one gram of hydrogen........ ×10 23

(A) 6.02 (B) 3.01 (C) 2.5 (D) 1.5

Ans. : b
(b) 2 gm of hydrogen = 6.02 × 10
23
molecules
of hydrogen molecule.
23
6.02×10 23
∴ 1 gm = = 3.01 × 10
2
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