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The document provides an extensive overview of various chemical properties, configurations, and reactions related to elements in Group 415, including arsenic (As), antimony (Sb), and bismuth (Bi). It discusses atomic size, bond angles, solubility, and oxidation states, along with specific reactions and compounds associated with these elements. Additionally, it covers oxo acids and their respective formulas, highlighting the chemical behavior and interactions of these elements in various contexts.
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Group - 415
p
Grane CledticontaConfigueckion | tnsnp?
a
— “Element (atoniienl.) | Bleeheonte Configinton
oN! Cher 25*2p3
e (15) [Ne] 3573
10
As (33) [arilad 48% 4P?
i! Sp?
Sb (54) [ee] ha OS er
pi (83) [xe] og!¥ 5a!6s cp?
Me (115) [ee] sf 4 Gal's "7p?
# Mescoviun (Me)
Hemost 289
_ tye voy
hytel Propucin ; (DORR ECE]
2 Atoria fodit + Snes dou tha group
Lew Seuarsiing feck of AZ Onbitals hampu
nonmal Iran:
* Demitg ; Downsne Gr => Momiamas> Atomic Volume ae Grenson
cea es Pea
+ Ie /EN — [Fes deexaoaa]
+ EA oe [War] Prowl >
[Pe Ai] > [oacmaa. | oy [Fey teoeoee] © Melo ltt —— : _
Chonaclen » bel As. Sb
Uttal
16 Allobinpy =p [ile Allobeney
dor NY air
o @atanalion Properhy “+ PSNSAs) sb) Bt
" oN a7 ae
Tain (eis
Chemie Propardien :
| + Renekivily Order PYNDAS> Sb BL
© Oxeddion stall +
|
\
|
|
| lament | Opdidelinn stale |
nN V5 ty 4302, 1-1-2773 |
|
P | 45, +4, 43,0, 72,7 3. |
| As | 5, 3, 0,73.
sh 45, 42, 9-3 |
|
bi. | 3,0, 3 Grant forty |
Hohe Dilip Oxial
> N : pire pr} ‘a, Srnall Size,
bond, 1b) EN hey:
a Otho \ [pid
| [Raeineta| (ea 14
\
re
a
* [i
Moto ' ——— ———_—____—_-
Pishroportionation Readtton
Pa ud, + oN + HP
He 3hd4 — Bugh0% + PMs
80> Ge) + aaa) 4
p Hysbites + Bond Angle > NH) Pia» Asis) SbH3 Y i Hs
107? 93-6" el 31-3" 91°
VSEPR > Exch Quitialatom
Soke io
nu [SRP] als [ROTI]
Casie characlin. 2 ati? Pils (Asis, Sbiad Bibs onenot baaie)
2 density % Bamdd
Atomic Size © eg Lamy
eThomel Stabilily Ng > PHS > ten SbH3 > Bits
Bond Length oc se
e Reclusing chonastin } Nis CPH3 CAsHsSbHa < BiH3
© Bp Fe MHZ PH3 CASH3 CNNs (sbi C Bing
4 hake :
Low [Link] dingy. ads ) H-bonding
Fores. forme.
oe MP > pH3 CA6hg PHg, Ass , Sbis, Hy
eee Insoluble»
Eas Ig
Oxides, E03 , E05 \
Acidic Svength py N03 2,06 > ASqO6 S$b406
EN of
Contra ce
odpm
N,O dso Cun03 Pela) PBs) PTs
e Leusis Bare Nig YN Brg SNCs NF3 cvse PR)
4 Bond Angle Np 4220 + Nok
"Reactions 3my + Na A> gan,
| Ny +07 280% NO
+ te O
Ng + Preparudldon! : [Link] el + Gol) DNHg + AA * a
= Maloon's Proees { N2(5) + N2(9) = 2NHs (9), any > — be wstot
w Condition. ¢ Teunp- ssv'e, 260 alm Prusune,Po - Cally,
(Kyp + 41,03) or Mo PromaDr |
| Reactions 2 Nit Wyo @ Nigh + OH” (Borie Nolivw:)
Q Feel, + 3Ntgr > anger + FeConyg
Bricum prt
> CurCon),, + MHA) 2804 + NOH > (Cu (nus)g]sog + 44?
Deep blur,
Soliio~ Oxides of Nibsagen "
alien Creprocation
Mane Fevemuata |
|
Dintnagr O82 NO |
| utgntog A> NO “hI,
° | |
f+ an "i a
ibeepenloweriee AD 42, | ANANDS + 2ASCHV3tRSO}—> Feskon,
; He D2 NetSO4 4 ONO 2No
Dinilreger Tot N,O3
oxide. <
Nino gen Bi Oxide NO
|
| +3) onto pe nyO4 252K, 2N203,
bp [Link] (Nog), FFE 9 pho -- 4 ND9 109
Diriieagen aside yo, | 4) ONoy, SS N04
Dinitregen Rntoxk
gen Pntoxidk NOS +5 L4HNOZ + P,010. > AH POR tb 2. NyO5
Nilnie Acia
Prepenathion :
reparation: NGNDs + BUSO4 —> Nabso4 + HNDs
;
Ost walds fro 2 4 NHy +50, ———> 4 NO + 61130
2ND +0, 2NDL
BND. + Hy)O = —> 2HND, + NO
Realien: Ty +ID HNDZ —> ZHTO, + 10ND + 4H)0
C+ A HNDZ CO, + 2H)0 + NOL
Sgt GRHNIDZ > @HSOq +4 BRD, 116 HO.
Pa + zopnsoz —> 4HSPog + 2onDy b4H2©
crite [ Whetat | Main Pande
ALUM tng | mg, Hn | Hy Metat nitrate,
ey ~ - | faan Se | Nigenog + Meat nibute
Pb, Cu, A, NO Wattad vibieabe.
oS re [No + Mela nitreabe
Nib ND3 + Se (O92
Non € Meal nib
SND, Hy. Sn0 3,
Metastamie acid. | f recom Ring Tek N03 +3 yt» wO-+ BRO + QH,O
+ or
[Fe Chao) é]" 410 > [Fe (ind so] “+H20
# HNDy to unstable 9 excel in Solution Only
| a white phosphowus. .
@) * Soluble CS,
*Glocd fn dark,
KE Yp sete Sti org ei
a NaHyPO
. 3 NaHPOr
Pa + BNaoH +30 — PH, + Sola
© Pat 502 -» Pyds0o hypo
:
| a Red- phosphorus ca
+ Insoluble in td £ C8.
* Less vearfiye
Bi phosphine .
Preponabebu * GaP, + 6H)0 > G(on), + 2PHs
Preporties * Rotlen fish Smelt
Reactions 2 +4 PHy SoPy tH
3Cus0g + 2PH3 —> CUgh, + 3H2SDm
PH3 + Hii —> PHaBy
an
: Pent
0 pls (rae)! Treparaledn 1 Pat loch —> & pets
Ren aes +440 > Hap0g 4 SHR.
Pele san Batt Pets
*502 > Soel, + pot,
pets U8 Praponilion Pat beh > La Poty
aa iat Ran 2 PAS BHO Ha pos + BHek
3GH5 60 + Pols SZ Ghee + Hypo,
a Oxo acids
4
H3P02
“Shypophosrhorous acid
(phos phinic o#%4)
43
Ha POs
Crthophes phoreuse-e
[phosprenie ot )
43
Hz, P05
Fyeernssprowesnasid
+h
Ha P206
Siypophesphowic aca
+
H3P 4
Onthophesphonic oid
45
Hay OF.
Pprophosphente act
45
(H PO3)n
Mefaphesphonie asid
N20
(Niieo uo Oxide)
NO
| N03
NO»
N04
N05,
W
BN
u7\, OH
o
uw
oN
7 hy oH
oO o
u M
4070-7408
H H
n
Pro hN
wo hyo Yow 8
ee)
Lok
S07 PN 01 S07
OW OH
Ne _v.2
°
u
f.
INo~
on
