PART III

1. 3CaCl + 2H2PO4 → Ca3 (PO4)2 + 6HCl

The molarity of CaCl2 = 0.250M The volume of CaCl2 =2.50litres

number of moles
Molarity = volume (litres)

Number of moles =0.250M × 2.50litres

In balanced equation,

If 3moles CaCl2 = 1 mole CaCl2

⸫ 0.625mole CaCl2 = less

0.625 mole CaCl2 ×1 moleCa(PO 4 )2

= 3 mole CaCl2

=0.2083mole Ca(PO4 )2

The mass of Ca(PO4)2 produced = molar mass × no. of numbers

= (40.0781+61.9481+128) × 0.2083Mole

= 47.913g

2. 14HNO3 + 3Cu2O → 6Cu(NO3)2 + 2NO &H2O

Molarity of HNO3 =1.50M

Mass of Cu2o =100g

 mass 100 g
[Link] moles Cu2O = molar mass = ( 63.546 ×2 ) +16 ¿ ¿ = 0.6989moles

3. In balanced equation,

3moles Cu2O = 14moles HNO3

⸫ 0.6989mole Cu2O = less

no . of moles 3.2615 moles ×1 litre

The volume of HNO3 = molarity = 1.50 moles
= 2.1743litres

Volume in militres =(2.1743litres × 1000) = 2174.3 litres

4. 2HNO3(aq) + Ba(OH)2(aq) → 2H2O(s) + Ba(NO3)2(aq)

C1 = 1.0M v1 = 25.0ml C2 = ? v2=

60.5ml
n1 = 1 n2 = 2

C V
1 1 2 C V2
= n = n
1 2
1 M ×25 ml × 2
C2 = = 0.8264M
1 ×60.5 ml

The molarity = 0.8264M

5. Mass of Fe = 40.0g
Mass of H2O = 16.0g
mass
Number of moles ; molar mass
40 g
Fe = 55.845 g /mole =0.7163moles
16 g
H2O = 18.02 g /mole = 0.8879moles

If 3moles Fe = I mole Fe3O4

⸫0.7163moles Fe = less
0.7163 moleFe ×1 mole Fe3 O4
= 4 moles H 2 O
=0.2388moles Fe3 O4
If 4molesH2O = I mole Fe3O4
 ⸫0.8819molesH2o = less

0.8819 moles H 2 O× 1mole Fe 3 O 4

= 4 moles H 2 O
=0.2219mole

The limiting reactant =H20

The excess reactant =Fe

6. Mass of AgNO2 =35.5g

Mass of Na2S =35.5g

The grams of 2AgNO2 =2(107.87 14.007+32) =307.75g

The grams of Na2S =78.04g

The grams of Ag2S =247.8g

If 307.75gAgNO2 =247.8g Ag2S

⸫35.5g AgNO2 = less

35.5 g Ag NO 2 ×247.8 g Ag2 s

= 307.754 Ag NO 2
=31.699Ag2S

And if 78.o4g Na2S = 247.8g Ag2S

⸫35.5gNa2S =less

35.5 g Na2 S × 247.8 g Ag2 S

= 78.04 g AgNO 2
= 102.729Ag2S

The limiting reactant is AgNO2 and the grams of Ag2S produced is 31.699g

7. No. of moles of MgCl2 = 0.01litre × 10M

No of moles of AgNO3 = 0.1litre × 2.2M

 If 2 moles AgNO3 = 2AgCl

⸫0.22mole AgNO3 = 0.22mole AgCl

If 1 mole MgCl2 = 2AgCl

⸫0.1mole MgCl2 = less

0.1 mole Mg Cl 2 ×2 AgCl

= 1 mole Ag Cl2
=0.2mole AgCl

The grams of AgCl produced= ( 0.2mole × 143.32g/mole) =28.664g AgCl

8. Masses given: Al = 75g and O2 =200g

75 g
No of moles of 75g Al = 26.982 g /mole =2.7796moles

200 g
No of moles of 200g O2 = 32 g /mole = 6.25moles

If 4moles Al = 2moles Al2O3

⸫2.7796moles Al =less

2.7796 moles Al × 2moles Al 2 O3

= =1.3898moles Al2O3
24 moles Al

If 3moles O2 = 2 moles Al2O3

⸫6.25moles O2 = more

6.25 moles O2 × 2 moles Al2 O3

= 3 moles O2
=4.1667moles Al2O3

The limiting reagent is Al

The grams of Al2O3 =(1.3898moles ×101.964g/mole) =141.7096g Al2O3

actual yield
The percent yield = theoretical yield ×100 %
 75 g
= 141.7096 g ×100 % = 52.9%

9. a. 2Cl(s) + O2 → 2CuO(s)

The grams of 2Cl =2(63.546)

The grams of 2CuO =2(63.546 +16)

If 126.92Cu =2(63.546 + 16)

13.4g of Cu =less

13.4 gCu ×159.092 g

= 126.912 g
=16.79777CuO

Actual yield
Percent yield = theoretical yield ×100 %

actaul yield
96.7% = 16.7977 g × 100 %

The actual yield (CuO) =16.243g

b. if 1000mg = 1g

5 × 1013mg = more
13
5× 10 mg ×1 g
= = 5 × 1010g
1000 mg

If 16.7977gCuO =13.4gCu

5 × 1010g CuO = more

10
5× 10 g CuO × 13.4 g Cu
= = 39886413020.83g Cu
16.7977 gCuO

PART III B
2AgNO3 + k2CrO4 → Ag2CrO4(s) + 2KNO3

From the equation,

2molesAgNO3 = 1mole Ag2CrO4

1mole k2CrO4 = 1mole Ag2Cr4

no . of moles
Molarity = litres

No. of moles of AgNO3 = (0.5M × 0.15litres)= 0.075 moles AgNO3

No. of moles of K2CrO4=(0.4M × 0.1litres) = 0.04moles K2Cr4

If 2moles AgNO3 = 1 mole AgCrO4

0.075moleAgNO3 = less

AgNO3
0.075 mol ¿
×1 mole Ag2 CrO 4 ¿ = 0.0375mole Ag2CrO4
2 mol Ag NO 3

If 1mol K2CrO4 = 1 mole AgCrO4

0.04mole k2CrO4 = less

o .04 mole K 2 CrO 4 ×7 moles Ag 2 CrO 4

= 0.04moleK2CrO4
1 mole K 2 CrO 4

The limiting reactant is Ag2CrO4

The mass of Ag2CrO4 produced = (