04-05-2025

1803CJA101001250002 JA

PART-1 : PHYSICS

SECTION-I(i)

1) In a system of units, unit of mass is 10 kg, unit of length is 5m and unit of time is 1sec what will
be unit of force ?

(A) 25 N
(B) 50 N
(C) 0.5 N
(D) 2500 N

2) If y = where F → Force, x → displacement, m → mass, v → velocity then y can be:-

(A) Velocity
(B) Momentum
(C) Angular velocity
(D) Angular momentum

3) Power delivered by a force is given by relation where 't' is time. The dimensional
formula of 'α' and 'β' will be :-

(A) [MLT–2], [LT–3]

(B) [MLT–4],[T–1]
(C) [ML2T–4],[T–1]
(D) [LT–4], [T–2]

4) Young’s modulus of steel is 1.9 × 1011 N/m2. When expressed in CGS units of dynes/cm2, it will be
equal to (1N = 105 dyne, 1m2 = 104 cm2)

(A) 1.9 × 1010

(B) 1.9 × 1011
(C) 1.9 × 1012
(D) 1.9 × 1013

5) If instead of mass, length and time as fundamental quantities, we choose velocity, acceleration
and force as fundamental quantities and express their dimensions by V, A and F respectively, then
the dimensions of pressure 'p' will be as expressed as :

(A) [FA2V–4]
(B) [F2V–1A]
(C) [FA2V–1]
(D) [FAV–2]

6) Priya says that the sum of two vectors by the parallelogram method is . Subhangi says it is
. Both used the parallelogram method, but one used the wrong diagonal. Which one of the
vector pairs below contains the original two vectors?

(A) ;
(B)
(C)
(D)

SECTION-I(ii)

1) If p, ρ, g and h denote pressure, density, acceleration due to gravity and height, respectively. In

the case of flow of fluid, , where v denotes velocity. Mark the correct option(s)

(A) the equation is dimensionally correct

(B) if dimensions of u0 are [M°LT°], the equation is dimensionally correct

(C)
dimensions of are same as that of
(D) None of the above

2)

Consider East as +ve x-axis, North as +ve y-axis. A girl walks 10 m East first time then 10 m in a
direction 30° West of North for the 2nd time & then third time in unknown direction and magnitude,
so as to return to her initial position. What is her third displacement vector :-

(A)

(B)

(C)
(D) she cannot return

3)

Vectors , and represents three sides of a quadrilateral in

cyclic order :-

(A) The fourth side has a length equal to in magnitude

(B) Vector representing fourth side is
(C) Vector representing fourth side is
(D) Resultant of vectors and is perpendicular to the vector representing fourth side

4) A bird starts from (1, 0, 0) in the direction with a speed 21 m/s for 5 sec, then along

the direction with a speed for 5 sec. Find the final displacement of the bird so
that it reaches the origin?

(A)
(B)
(C)
(D)

5) The resultant of two forces 3p and 2p is R. If the first force is doubled keeping same direction,
then the resultant is also doubled. Find the angle between two forces.

(A) 60°
(B) 120°
(C) 150°
(D) 90°

6) If and , then find a vector whose magnitude is equal to component of

A along B and direction is along .

(A)

(B)

(C)

(D)

SECTION-II

1)

In the given figure if the angle between and is 5α°. Find the value of α.
2) The magnitude of resultant of two vectors acting at an angle of 60° to each other is units.
The first vector has a magnitude of 4 units. The magnitude of second vector is _______ units.

3) A string is pulled with a force F = 130 N as shown. The force vector comes out to be

Write in OMR sheet.

4) If mass is expressed as vx dy az where v is velocity; d is density and a is acceleration then the value
of x + y + z is

5) In a new system of unit, 1 unit of mass 10 kg, 1 unit of length is 10 m & 1 unit of time 10 sec. If 1
unit of power in this unit is equal to x watt find x.

6) The time period of oscillation of a body is given by

T=
K : Represents the kinetic energy, m mass, g acceleration due to gravity and A is unknown quantity.
If [A] = Mx Ly Tz , then what is the value of x + y + z.

PART-2 : CHEMISTRY

SECTION-I(i)

1) Which one represents an impossible arrangement?

n m s

(A) 3 2 –2 1/2

(B) 4 0 0 1/2
 (C) 3 2 –3 1/2

(D) 5 3 0 1/2
(A) A
(B) B
(C) C
(D) D

2) Which element have the same number of s-electrons as the d-electrons in Fe2+ :

(A) Li
(B) Na
(C) N
(D) P

3) Maximum number of electrons with s = in [Cr] will be :

(A) 15
(B) 14
(C) 18
(D) 24

4) Zeff value of Be+3 ion is :

(A) 1.95
(B) 2.05
(C) 4
(D) 2.4

5) Which of the isoelectronic ions K+, Ca2+, Cl– and S2– has largest ionic radius?

(A) K+
(B) Ca2+
(C) Cl–
(D) S2–

6) Atomic radii of flourine and neon in Å units are respectively given by

(A) 0.72, 1.60

(B) 1.60, 1.60
(C) 0.72, 0.72
(D) 1.60, 0.72

SECTION-I(ii)
1) Which of the following orders of atomic / Ionic radius is correct ?

(A) B < Al ≈ Ga
(B) Sc > Cu < Zn
(C) C < O < N
(D) Al+3 < Al+2 < Al+

2) An element 'X' having atomic number '25' on removal of two electrons, changes into its dipositive
cation 'Y'. Which of the following statement/s is/are INCORRECT regarding 'X' and 'Y'.

(A) spin only magnetic moment : X > Y

(B) effective nuclear charge on outermost electron : X > Y
(C) Total number of d-electrons : X = Y
(D) Radius : X < Y

3) The ionic radii depends upon in the following factors :

(A) Charge on cation

(B) Charge on anion
(C) Shell number of valence shell electron(s) of the ion.
(D) Effective nuclear charge

4)

Which of the following sets contain only isoelectric species ?

(A) P3–, S2–, Cl–, K+

(B) Na+, K+, Cl–, F–
(C) Ti4+, Sc3+, Cl–, Ar
(D) O2–, Na2+, FΘ, Ar

5) Spin only magnetic moment of 4.89 B.M. is shown by :

(A) Fe
(B) Fe+3
(C) Cr+2
(D) Mn+3

6) Which rule(s) is/are violated if an element's configuration is written as :

(A) Aufbau rule

(B) Pauli's rule
(C) Hund's rule
(D) No rule is violated
 SECTION-II

1) How many of the following elements have less than 8 electrons in s-subshell.
Fe, Ga, Ca, Cr, Zn, K, Ar, Cu

2) From the following list of orbitals,

s, px, py, pz, dxy, dyz, dxz,

3) The number of p block elements accordingly to following configuration is________.

1s22s22p6, 1s22s2, 1s22s22p63s23p63d104s2, 1s22s22p63s23p1

4) According to slater's rule, how many maximum electrons have same value of Zeff. in Cr atom.

5)

Find the number of chemical species having radius less than Mg+2.
Li+, K+, Mg, Ca+2, Sr+2

6) Out of the following total number of elements which have bigger size as compare to hydrogen
atom –
F, N, P, S, K

PART-3 : MATHEMATICS

SECTION-I(i)

1) The solution set of is

(A)
(B)
(C)
(D)

2) The polynomials P(x) = kx3 + 3x2 – 3 and Q(x) = 2x3 – 5x + k, when divided by (x – 4) leaves the
same remainder. Then the value of k is

(A) 2
(B) 1
(C) 0
(D) –1

3) Let , then the value of x4 + y4 + (x + y)4 is equal to

(A) 527
(B) 1152
(C) 976
(D) 1254

4) Number of non-negative integral values of x satisfying the inequality

is

(A) 4
(B) 3
(C) 5
(D) 7

5) Simplified value of .

(A) x76/15
(B) x78/15
(C) x79/15
(D) x77/15

6) If and where a, b, p, q ∈ N then the value of a + b + p

+ q is

(A) 37
(B) 38
(C) 39
(D) 40

SECTION-I(ii)

1) If complete solution set of the inequality (x2 + x – 2)(x2 + x – 16) + 40 ≥ 0 is x ∈ (–∞, –4] ∪ [a, b] ∪
[c, ∞) then value of a + b + c is equal to

(A) 4
(B) 3
(C) 2
(D) 7
2) Let a, b ∈ ℚ such that = , then which of the following is not true

(A)
is an integer

(B)
is a rational number
(C) is an irrational number
(D) is a rational number

3) If m, and then possible values of ''m + n' can be

(A) 23
(B) 32
(C) 56
(D) 59

4) Let . If the remainder when P(x) is divided

by x2 - 14x + 13 is R(x) = ax + b then

(A) R(2) = –2149

(B) R(2) = –2059
(C) R(3) = –318
(D) R(–3) = –3209

5) Let a > 2, be a constant. If there are just 18 positive integers satisfying the inequality (x -
2
a)(x - 2a)(x - a ) < 0 then which of the option(s) is/are correct?

(A) 'a' is composite

(B) 'a' is odd
(C) 'a' is greater than 8
(D) 'a' lies in the interval (3, 11)

6) if f(x) is a polynomial of degree three with leading coefficient 1 such that f(1) = 1, f(2) = 4, f(3) =
9, then

(A) f(4) = 22

(B)

(C) f(5) = 49
(D) f(5) = 25

SECTION-II
1) If where a and b are natural number find (a + b).

2) Find product of all real values of x satisfying = 10

3) Let P(x) is a polynomial of degree 5 with leading coefficient '1' such that P(1) = 1, P(2) = 4, P(3) =
9, P(4) = 16 and P(5) = 25, then find the value of P(6) ?

4) If the sum is equal

to then the value of a + b is (a, b ∈ )

5) If then (x·y·z)2 is equal to

6) The number of all real solution of the equation

 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I(i)

Q. 1 2 3 4 5 6
A. B A C C A C

SECTION-I(ii)

Q. 7 8 9 10 11 12
A. B,C A A,B C B D

SECTION-II

Q. 13 14 15 16 17 18
A. 3.00 1.00 5.00 4.00 1.00 3.00

PART-2 : CHEMISTRY

SECTION-I(i)

Q. 19 20 21 22 23 24
A. C D A C D A

SECTION-I(ii)

Q. 25 26 27 28 29 30
A. A,B,D A,B,D A,B,C,D A,C A,C,D A,B,C

SECTION-II

Q. 31 32 33 34 35 36
A. 4.00 1.00 2 8.00 0.00 5.00

PART-3 : MATHEMATICS

SECTION-I(i)

Q. 37 38 39 40 41 42
A. A B B B D C

SECTION-I(ii)

Q. 43 44 45 46 47 48
A. C A,B,D B,C A,D B,D A,B,C
 SECTION-II

Q. 49 50 51 52 53 54
A. 8.00 8.00 156.00 8.00 1296.00 5.00
 SOLUTIONS

PART-1 : PHYSICS

1) In new system,

Force unit = 50 kgm/s2 = 50 N

2)
[y] = [v] = [LT–1]

3) [β] = [T–1], α = P × β = [ML2T–4]

4)

5) [P] = [V]x [A]y[F]z

⇒ [ML–1T–2] = [LT–1]x [LT–2]y [MLT–2]z
⇒ [ML–1T–2] = [L]x + y + z [T]–x – 2y – 2z [M]z
Comparing exponents :
z=1
x + y + z = –1 ⇒ x + y = –2 .... (i)
and –x – 2y – 2z
⇒ –x – 2y – 2 = –2 .... (i)
⇒ x + 2y = 0 .... (ii)
Solving (i) and (ii)
x = –4 and y = 2
∴ [P] = [FA2V–4]

6)

7) and h all have dimensions of length equation will be dimensionally correct only if
u0 has dimensions of length.

8)

9) ⇒ fourth side

10)

11)

R2 = 9p2 + 4p2 + 12p2 cos θ ... (i)

4R2 = 36p2 + 4p2 + 24 p2 cos θ ... (ii)
from equation (i) & (ii) equating value of R2
13p2 + 12p2 cos θ = 10p2 + 6p2 cos θ
3p2 = – 6p2 cos θ

cos θ =
θ = 120°

12)

required vector =
 (θ = angle b/w A & B)

13)
5α = 15
α=3

14)

R2 = a2 + b2 + 2ab cos θ
21 = 42 + b2 + 8b cos 60
b2 + 4 b – 5 = 0
b2 + 5b – b – 5
b(b + 5) – 1 (b + 5) = 0
b=1

15)
A(5, 0, 6) B(2, 12, 2)

16) m = R vx dy az (where k is dimensionless)

[M] = [LT–1]x [ML–3]y [LT–2]z
Solve for x, y and z.

17)

1 kg m2s–3 = x[(10 kg) (10m)2.(10s)–3]

18)
 [T] = = =
0 2
⇒ [A] = M L T
x = 0, y = 1, Z = 2

x+y+z=3

PART-2 : CHEMISTRY

19) l = 0 to (n – 1)
m = – l to + l

20) No. of 'd' e– in Fe2+ = 6

No. of 's' e– in
Li = 3 N=4
Na = 5 P = 6

21) 1s2 2s2 2p6 3s2 3p6 4s1 3d5

1+ 1+ 3+ 1+ 3+ 1+ 5

22)
So for single species
Zeff = Z = 4

23) Explanation : Ionic size order is asked

Concept : +ve charge ; –ve charge ∝ size

Solution/Explanation/Calculation :

More –ve charge, more size

Hence, the correct answer is option (4).

24)

Radius order F < Ne

( noble gas having highest radius in period)
so (A) 0.72, 1.60

25) Atomic radius → decreases on going from left to right.

(A)
(B) Sc > Cu < Zn
(D)

26) Atomic number of X = 25 [Mn]

'X' 'Y'
Mn Mn2+
Electronic [Ar]3d54s2 [Ar]3d5
configuration
µ =
Zeff = X < Y
d-electrons 5 5
Radius X > Y

27)

(A) Charge on cation Zeff IE

(B) Charge on anion Zeff IE
(C) Shell number IE
(D) Zeff ∝ IE

28)

(1) P3–, S2–, Cl–, K+ have 18 electron each.

(2) Na+, F– have 10e each
K+, Cl– have 18e each
(3) Ti4+, Sc3+, Cl–, Ar have 18e each
(4) Na+, F–, O2– have 10e each
Ar have 18e

29) 4.89 = = : four unpaired electrons are present in Fe, Cr+2 and Mn+3.

30)

Concept : Aufbau rule : According to this rule, the available atomic orbitals with the lowest
energy levels are occupied before those with higher energy levels.

Hund’s rule : The electrons are filled in different orbitals of a subshell so that the value of spin
multiplicity is maximum

pauli’s rule : In an atom, no. two electrons can have the same four electronic quantum
numbers.

(A) Aufbav rule violated because 3s is not completely filled

(B) Pauli’s violated because in 2s orbital both the electron have same spin quantum no.

(C) Hund’s rule violated because value of spin multiplicity for 3p is not maximum.
 31)

Ans : (4)

No. of e–s in s-subshell

26Fe – 1s2 2s2 2p6 3s2 3p6 4s2 3d6 8

31Ga – 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p1 8

20Ca – 1s2 2s2 2p6 3s2 3p6 4s2 8

21Cr – 1s2 2s2 2p6 3s2 3p6 4s1 3d5 7

30Zn – 1s2 2s2 2p6 3s2 3p6 4s2 3d10 8

18Ar – 1s2 2s2 2p6 3s2 3p6 6

29Cu – 1s2 2s2 2p6 3s2 3p6 4s1 3d10 7

No of elements = 3

32)

Ans : (1)
px, py dxy ⇒ fully lobes are present on xy–plane
pz, dyz, dxz ⇒ whole nodal plane is xy–plane

33)

Ans : (2)
The number of p-block elements = 2
(1s2 2s2 2p6, 1s2 2s2 2p6 3s2 3p1)

34)

Cr (Z = 24)
Accoording to slater's rule :-
(1s2), (2s2, 2p6), (3s2, 3p6), (3d5), (4s1)
(2s2, 2p6) → same group → same zeff.
maximum electrons in same group = 8.

35)

None of the species has radius less than Mg+2

36)

All are bigger than Hydrogen, Hydrogen is the smallest element in periodic table.
PART-3 : MATHEMATICS

38)

P (4) = 64k + 48 – 3 = 64k + 45

Q (4) = 128 – 20 + k = k + 108
given P (4) = Q (4)
∴ 64k + 45 = k + 108
⇒ 63k = 63 ⇒ k = 1

39)

x+y=5
x2 + y2 = 23
x4 + y4 = 527
(x + y)4 = 625

40)

, x ≠ –1 ⇒

x ∈ (–∞, –1) ∪ (–1, 2]

required value of x = {0, 1, 2}.

41)

42) 4 = 3 + 1

3+1=

So,
a = 3, b = 1
p = 27, q = 8
a + b + p + q = 39

43)

Let x2 + x – 2 = t
t2 – 14t + 40 ≥ 0
(t – 4)(t – 10) ≥ 0
t≤4 or t ≥ 10
2
x +x–2≤4 x2 + x – 2 ≥ 10
x2 + x – 6 ≤ 0 x2 + x – 12 ≥ 0
(x + 3)(x – 2) ≤ 0 (x + 4)(x – 3) ≥ 0
x ∈ [–3, 2] x ∈ (–∞, –4] ∪ [3, ∞)
x ∈ (–∞, –4] ∪ [–3, 2] ∪ [3, ∞)

44) × =

= a= ,b=

(A) ∉I

(B) ∉Q

(C) ∉Q

(D) ∉Q
Hence (A), (B), (D) are not true

45)
So, n = 27 or 3
m = 29

46) R(x) = 212x – 2573

R(2) = –2149
R(-3) = –3209

47)
x < a or 2a < x < a2
Total integers,
a – 1 + a2 – 2a – 1 = 18

48) f(x) = (x – 1)(x – 2)(x – 3) + x3

f(4) = 22

f(5) = 49

49)

=
=1+

=
=

50)

⇒ = 10 ⇒ t2 – 10t + 1 = 0

t= ⇒ = or

⇒ x2 – 3 = 1 or x2 – 3 = –1

⇒ x = 2 or –2 or or
Product 8

52) Rationalize each term

53) xy + zx = 29
yz + xy = 26
xz + yz = 51
⇒ 2[xy + yz + zx] = 106
⇒ xy + yz + zx = 53
Now, xy = 2, zx = 27; yz = 24
⇒ x2y2z2 = 24 × 2 × 27 = 1296

54) Consider cases,