SCHOOL OF EXCELLENCE SECONDARY SCHOOL 2017 A.
Y 2nd SEMISTER TEST-
1. CHEM. GRADE-11
I. write true if the statment is correct and write false if the statment is not correct
1. sp hybrid orbitals are orbitals that are formed by intermixing of one-s orbital and one p orbital and
form linear arrangement.
2. Paramagnetic properties are properties of molecules that can be exist if moleculehas unpaired
electrons.
3. The bond order of molecule that consists of three bonding pair (triple bond) is three.
4. The energy of anti bonding molecular orbital is lower than the energy of bonding molecular orbital.
II. Choose the best answer from the given alternatives
5. Which of the following is the strongest intermolecular force?
a. London force b. dispersion force c. hydrogen bonding force d. dipole-dipole force
6. The structure of BF3 is:
a. trigonal planar b. square pyramid c. trigonal bipyramid d. octahedral
7. How many sigma and pi bond are present in naphthalene?
a. 11 and 5 b. 6 and 3 c. 10 and 3 d. 3 and 2
8. The paramagnetic property of oxygen is well explained on the basis of:
a. VSEPR theory b. VB theory c. MO theory d. Lewis structure
9. The bond order of N2 according to MO theory is: a. 2 b. 3 c. 0 d. 1
10. In sp2 hybridization, the orbitals are oriented at an angles of:
a. 109.5o b. 180o c. 90o d.120o
11.When one s and two p orbitals hybridized the type of hybrid orbitals are
a. sp hybrid orbitals b. sp2 hybrid orbitals c. sp3 hybrid orbitals d. sp3d hybrid orbitals
12. The carbon atom in ethane, ethene and ethyne provides three common type of hybrid orbitals
respectively;
a. sp,sp2, sp3 b. sp3, sp2, sp c. sp,sp3d, sp3d2 d. sp2, sp2d, spd3
13. Which of the following is network covalent crystal?
a. silicates b. NaCl (table salt ) c. gold d. suger (table suger)
14. Which one of the following is correct about π bond? a. it is formedby end to end interaction
c. it is formed by side to side interaction b. it can be formed by s and s orbitals interactions
d. it can be formed by s and p orbitals interactions
15. What type of molecular orbital results from the adition of two atomic orbitals?
a. Bonding molecular orbitais c. Anti-bonding molecular orbital
b. Ionic orbital d. Covalent orbital
16. Which of the following is not property of metals?
a. They are shiny c. They are malleable and ductile
b. They have high electrical and thermal conductivity d. they are brittle
17.Which of the following species is paramagnetic?
a. O-2 b. CN- C.NO+ d. CO
18. Which of the following molecule has a regular octahedral geometry?
a. NH3 b.CO2 c. C2H4 D. SF6
19. The percentage of s and p characters in sp3 hybrid orbitals is:
a. 25% s and & 75% p c. 50% s and 50% p
b. 66.67% p and 33.33% p d. 70% s and 30% p
20. Which of the following is the correct electron configration of a peroxide ion, O2-2?
a. (σ1s)2 (σ*1s)2 (σ2s)2 (σ*2s)2 (σ2px)2 (π2py2= π2pz2) (π*2py2= π*2pz2) (σ*2px)2
b. (σ1s)2 (σ*1s)2 (σ2s)2 (σ*2s)2 (σ2px)2 (π2py2= π2pz2) (π*2py2= π*2pz2)
c. (σ1s)2 (σ*1s)2 (σ2s)2 (σ*2s)2 (σ2px)2 (π2py2= π2pz2) (σ*2px)2
d. (σ1s)2 (σ*1s)2 (σ2s)2 (σ*2s)2 (σ2px)2 (π2py2= π2pz2)
III. Work out; Give clear answer for the following quesion
21. For N2+ ;
a. Write molecular orbital electron configuration
b. Draw the energy diagram to show how the atomic orbitals of two nitrogen combine to form
molecular orbital of N2
c. How many unpaired electrons are/is present in N2?
d. What is the bond order in N2?
e. Is N2 paramagnetic or diamagnetic?
