Solutions DPP-05
1. Among the following that forms an ideal solution?
(1) water and methanol
(2) acetone and ethanol
(3) benzene and toluene
(4) water and HCl
2. On mixing 10 mL of acetone with 40 ml of chloroform the total volume of the solution is
(1) < 50 mL
(2) > 50 mL
(3) = 50 mL
(4) cannot be predicted
3. The mixture of n-hexane and n-heptane is an example of
(1) ideal solution
(2) non-ideal solution
(3) dilute solution Mission 720
(4) none
4. An azeotropic solution of two liquids has boiling point lower than either when it
(1) Shows a negative deviation from Raoult's law
(2) Shows no deviation from Raoult's law
(3) Shows positive deviation from Raoult's law
(4) Is saturated
Answer Key
Question 1 2 3 4
Answer 3 1 1 3
Solutions DPP-06
1. The statement “The mass of a gas dissolved in a given mass of a solvent at any temperature is
proportional to the pressure of the gas above the solvent” is
(1) Dalton’s Law of Partial Pressures
(2) Law of Mass Action
(3) Henry’s Law
(4) None of these
2. Which of the gas will not follow Henry's law?
(1) HCl
(2) He
(3) O2
(4) H2
3. If solubility of gas ‘X’ is 0.5 gL–1 at 1 bar then its solubility at 3 bar pressure will be
(1) 0.5 gL–1
(2) 1.5 gL–1
(3) 3.0 gL–1
(4) 2 gL–1
Mission 720
4. Henry's law constant for dissolution of CH4 in benzene at 298 K is 2 × 105 mm of Hg. Then solubility of
CH4 in benzene at 298 K (in terms of mole fraction) under 760 mm of Hg is:
(1) 1.2 × 10–5
(2) 3.8 × 10–3
(3) 4 × 10–7
(4) 1 × 10–2
5. Which of the following gas does not obey Henry's law?
(1) NH3
(2) H2
(3) O2
(4) He
Answer Key
Question 1 2 3 4 5
Answer 3 1 2 2 1
Solutions DPP-07
1. The vapour pressure of benzene at 90o C is 1020 torr. A solution of 5 g of a solute in 58.5 g benzene has
vapour pressure 990 torr. The molecular weight of the solute is?
(1) 280
(2) 220
(3) 270
(4) 320
2. The lowering of vapour pressure of a solvent by addition of a non-volatile solute to it, is directly
proportional to:
(1) Mole fraction of solute
(2) The nature of the solute in the solution
(3) The atmospheric pressure
(4) All
3. The relative lowering of vapour pressure is equal to the mole fraction of the non-volatile solute. This
statement was given by:
(1) Raoult
(2) Henry
(3) Joule
(4) Dalton
Mission 720
4. The vapour pressure of a solution having solid as solute and liquid as solvent is:
(1) Directly proportional to mole fraction of the solvent
(2) Inversely proportional to mole fraction of the solvent
(3) Directly proportional to mole fraction of the solute
(4) Inversely proportional to mole fraction of the solute
5. One mole of non-volatile solute is dissolved in two moles of water. The vapour pressure of the solution
relative to that of water is
2
(1)
3
1
(2)
3
1
(3)
2
3
(4)
2
Answer Key
Question 1 2 3 4 5
Answer 2 1 1 1 1
Solutions DPP-08
1. 0.15 g of a substance dissolved in 15 g of solvent boiled at a temperature higher by 0.216 oC than that of
the pure solvent. What is the molar mass of the substance. [Kb for solvent = 2.16oCm–1]
(1) 125
(2) 80
(3) 100
(4) 120
2. The rise in boiling point of a solution containing 1.8 g glucose in 100 g of a solvent is 0.1 oC. The molal
elevation constant of the liquid is –
(1) 1.8
(2) 1
(3) 1.6
(4) 2.1
3. The molal elevation constant is the ratio of the elevation in B.P. to:
(1) Molarity
(2) Molality
(3) Mole fraction of solute
(4) Mole fraction of solvent
Mission 720
4. If 0.15 g of a solute dissolved in 15 g of solvent is boiled at a temperature higher by 0.216 oC than that of
the pure solvent. The molecular weight of the substance (molal elevation constant for the solvent is
2.16oC) is
(1) 1.01
(2) 10
(3) 10.1
(4) 100
5. Elevation in boiling point was 0.52oC when 6 gm of a compound X was dissolved in 100 gm of water.
Molecular weight of X is (Kb for water is 0.52 per 1000 gm of water)
(1) 120
(2) 60
(3) 180
(4) 600
Answer Key
Question 1 2 3 4 5
Answer 3 2 2 4 2
