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Alodine 1201

The Safety Data Sheet for BONDERITE M-CR 1201 AERO (ALODINE 1201) outlines the product's hazards, including skin and eye irritation, respiratory sensitization, and potential carcinogenic effects. It provides safety precautions for handling, first aid measures, and emergency contact information. The document also details the product's composition, stability, and regulatory information, emphasizing the need for protective measures during use.

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0% found this document useful (0 votes)
46 views6 pages

Alodine 1201

The Safety Data Sheet for BONDERITE M-CR 1201 AERO (ALODINE 1201) outlines the product's hazards, including skin and eye irritation, respiratory sensitization, and potential carcinogenic effects. It provides safety precautions for handling, first aid measures, and emergency contact information. The document also details the product's composition, stability, and regulatory information, emphasizing the need for protective measures during use.

Uploaded by

John
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

Safety Data Sheet

Revision Number: 004.12 Issue date: 10/22/2021

1. PRODUCT AND COMPANY IDENTIFICATION


Product name: BONDERITE M-CR 1201 AERO known IDH number: 594418
as ALODINE 1201
Product type/use: Conversion coating
Restriction of Use: None identified Region: United States
Company address: Contact information:
Henkel Corporation Telephone: +1 (860) 571-5100
One Henkel Way MEDICAL EMERGENCY Phone: Poison Control Center
Rocky Hill, Connecticut 06067 1-877-671-4608 (toll free) or 1-303-592-1711
TRANSPORT EMERGENCY Phone: CHEMTREC
1-800-424-9300 (toll free) or 1-703-527-3887
Internet: www.henkelna.com

2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
DANGER: CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES SERIOUS EYE IRRITATION.
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING
DIFFICULTIES IF INHALED.
MAY CAUSE GENETIC DEFECTS.
MAY CAUSE CANCER.
MAY DAMAGE FERTILITY OR THE UNBORN CHILD.
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED
EXPOSURE.

HAZARD CLASS HAZARD CATEGORY


SKIN IRRITATION 2
EYE IRRITATION 2A
RESPIRATORY SENSITIZATION 1
SKIN SENSITIZATION 1
GERM CELL MUTAGENICITY 1B
CARCINOGENICITY 1A
REPRODUCTIVE TOXICITY 1B
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE 1

PICTOGRAM(S)

Precautionary Statements

Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been
read and understood. Do not breathe vapors, mist, or spray. Wash affected area thoroughly
after handling. Do not eat, drink or smoke when using this product. Contaminated work clothing
should not be allowed out of the workplace. Wear protective gloves, clothing, eye and face
protection. In case of inadequate ventilation wear respiratory protection.
Response: IF ON SKIN: Wash with plenty of water. IF INHALED: If breathing is difficult, remove victim to
fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously
with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing. IF exposed or concerned: Get medical attention. If skin irritation or rash occurs: Get
medical attention. If eye irritation persists: Get medical attention. Take off contaminated
clothing.
Storage: Store locked up.

IDH number: 594418 Product name: BONDERITE M-CR 1201 AERO known as ALODINE 1201
Page 1 of 6
Disposal: Dispose of contents and/or container according to Federal, State/Provincial and local
governmental regulations.

Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the
United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS).

See Section 11 for additional toxicological information.

3. COMPOSITION / INFORMATION ON INGREDIENTS


Hazardous Component(s) CAS Number Percentage*
Chromic acid 7738-94-5 1-5
Ferrocyanide compound Proprietary 0.1 - 1

* Exact percentages may vary or are trade secret. Concentration range is provided to assist users in providing appropriate protections.

4. FIRST AID MEASURES


Inhalation: If mist or vapor of this product is inhaled, remove person immediately to fresh
air. Seek medical attention if symptoms develop or persist. Delayed effects
possible after inhalation. Administer oxygen or artificial respiration as needed.
Do not use mouth-to-mouth method if victim ingested or inhaled the
substance.

Skin contact: Remove contaminated clothing and footwear. For skin contact, flush with large
amounts of water. Seek immediate medical attention. Launder contaminated
clothing before reuse. Discard any shoes or clothing items that cannot be
decontaminated.

Eye contact: Immediately flush affected eye with large amounts of gently flowing water or
0.9% sterile saline solution for at least 15 minutes. Hold eyelid wide open.
Get immediate medical attention. Eye flushing should continue during
transportation to a doctor.

Ingestion: Get immediate medical attention. Do not induce vomiting. If individual is


conscious, wash out mouth with water. Provide a glass of water to dilute the
material in the stomach.

Symptoms: See Section 11.

Notes to physician: Treat symptomatically and supportively.

5. FIRE FIGHTING MEASURES


Extinguishing media: Use media appropriate for surrounding material.

Special firefighting procedures: Wear full protective clothing. Wear self-contained breathing apparatus.

Unusual fire or explosion hazards: Formation of toxic gases is possible during heating or in fires.

Hazardous combustion products: Upon decomposition, this product may yield gaseous nitrogen oxides, carbon
monoxide, carbon dioxide and/or low molecular weight hydrocarbons.
Chromium oxide.

6. ACCIDENTAL RELEASE MEASURES


Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and
unprotected personnel.

Environmental precautions: Prevent further leakage or spillage if safe to do so. Wear appropriate
protective equipment and clothing during clean-up.

Clean-up methods: Absorb spill with inert material. Shovel material into appropriate container for
disposal. Dispose of according to Federal, State and local governmental
regulations.

IDH number: 594418 Product name: BONDERITE M-CR 1201 AERO known as ALODINE 1201
Page 2 of 6
7. HANDLING AND STORAGE
Handling: Avoid contact with eyes, skin and clothing. Wash thoroughly after handling.
Avoid breathing vapors or mists of this product. Use only with adequate
ventilation. Launder work clothes frequently. Do not store or consume food,
drink, or tobacco products in areas where they may become contaminated
with this material. Do not take internally. Clothing or other material wet with
this product and allowed to dry may become flammable. For industrial use
only.

Storage: For safe storage, store at or above 40 °F (4.4 °C)


Keep container tightly closed and in a cool, well-ventilated place away from
incompatible materials.

For information on product shelf life, please review labels on container or check the Technical Data Sheet.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION


Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper
exposure controls and protective equipment for each task performed.

Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER


0.0005 mg/m3 STEL
(as Cr(VI)) Inhalable
fraction.
0.0002 mg/m3 TWA
(as Cr(VI)) Inhalable
0.005 mg/m3 TWA
fraction.
0.0025 mg/m3
0.0005 mg/m3 STEL
Chromic acid OSHA_ACT None None
(as Cr(VI)) Inhalable
fraction.
0.1 mg/m3 Ceiling
(SKIN) (as Cr(VI))
Inhalable fraction.
(Dermal sensitization)
(Respiratory
sensitization)
Ferrocyanide compound None None None None

Engineering controls: Provide local and general exhaust ventilation to effectively remove and
prevent buildup of any vapors or mists generated from the handling of this
product.

Respiratory protection: If ventilation is not sufficient to effectively prevent buildup of aerosols, mists or
vapors, appropriate NIOSH/MSHA respiratory protection must be provided.

Eye/face protection: Wear safety glasses; chemical goggles (if splashing is possible).

Skin protection: Wear impervious gloves for prolonged contact. Gloves should be tested to
determine suitability for prolonged contact. Use of impervious boots is
recommended.

9. PHYSICAL AND CHEMICAL PROPERTIES


Physical state: Liquid
Color: Orange
Odor: None
Odor threshold: Not available.
pH: <2
Vapor pressure: Not applicableNot applicable
Boiling point/range: > 100 °C (> 212°F)
Melting point/ range: 0 °C (32°F) calculated
Specific gravity: 1.00 - 1.02 at 60 °F (15.56 °C)
Vapor density: Not applicable
Flash point: > 100 °C (> 212°F) ; Aqueous solution
Flammable/Explosive limits - lower: Not applicable
Flammable/Explosive limits - upper: Not applicable
Autoignition temperature: Not applicable
Flammability: Not applicable
Evaporation rate: Not applicable
Solubility in water: Complete
Partition coefficient (n-octanol/water): Not determined
IDH number: 594418 Product name: BONDERITE M-CR 1201 AERO known as ALODINE 1201
Page 3 of 6
VOC content: Not applicable
Viscosity: Not available.
Decomposition temperature: Not available.

10. STABILITY AND REACTIVITY


Stability: Stable at normal conditions.

Hazardous reactions: None under normal processing.

Hazardous decomposition Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low
products: molecular weight hydrocarbons. Chromium oxide.

Incompatible materials: This product may react with strong reducing agents. Avoid contact with organic materials, oils,
greases, and any oxidizable materials. Strong bases. Metals.

Reactivity: Not available.

Conditions to avoid: Store away from incompatible materials.

11. TOXICOLOGICAL INFORMATION


Relevant routes of exposure: Skin, Inhalation, Eyes, Ingestion

Potential Health Effects/Symptoms

Inhalation: May be harmful or fatal if inhaled. Nasal itch and soreness, perforation of the nasal septum,
dental erosion, and chronic asthmatic bronchitis may result from repeated exposure. Mists or
vapors may be irritating to the respiratory tract. May cause sensitization by inhalation.
Skin contact: A component in this product may be harmful or fatal if absorbed through the skin, especially if
skin is damaged. Mists, vapors or liquid may cause severe irritation or burns. Product contains
chromium, which may cause an allergic skin sensitization reaction. Contact with broken skin
may lead to formation of firmly marginated "chrome sores".
Eye contact: This product is severely irritating to the eyes and may cause irreversible damage including
burns and blindness.
Ingestion: Harmful or fatal if swallowed. May cause burns of the mouth, throat and stomach. May also
cause gastrointestinal disturbances such as nausea, vomiting, abdominal pain, and diarrhea.
Ingestion of this product may cause nausea, vomiting and diarrhea.

Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects
Allergen, Blood, Carcinogen, Central nervous
system, Corrosive, Developmental, Eyes,
Chromic acid None
Gastrointestinal, Irritant, Kidney, Liver,
Mutagen, Reproductive, Respiratory
Ferrocyanide compound None Cellular

OSHA Carcinogen
Hazardous Component(s) NTP Carcinogen IARC Carcinogen
(Specifically Regulated)
Known To Be Human
Chromic acid Group 1 Yes
Carcinogen.
Ferrocyanide compound No No No

12. ECOLOGICAL INFORMATION


Ecological information: Do not empty into drains / surface water / ground water.

IDH number: 594418 Product name: BONDERITE M-CR 1201 AERO known as ALODINE 1201
Page 4 of 6
13. DISPOSAL CONSIDERATIONS
Information provided is for unused product only.

Recommended method of disposal: Follow all local, state, federal and provincial regulations for disposal.

14. TRANSPORT INFORMATION


The transport information provided in this section only applies to the material/formulation itself, and is not specific to any
package/configuration.

U.S. Department of Transportation Ground (49 CFR)


Proper shipping name: RQ, Environmentally hazardous substance, liquid, n.o.s.
Hazard class or division: 9
Identification number: UN 3082
Packing group: III
DOT Hazardous Substance(s): Chromic acid

International Air Transportation (ICAO/IATA)


Proper shipping name: RQ, Environmentally hazardous substance, liquid, n.o.s.
Hazard class or division: 9
Identification number: UN 3082
Packing group: III

Water Transportation (IMO/IMDG)


Proper shipping name: RQ, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Hazard class or division: 9
Identification number: UN 3082
Packing group: III

15. REGULATORY INFORMATION


United States Regulatory Information

TSCA 8 (b) Inventory Status: All components are listed as active or are exempt from listing on the Toxic Substances
Control Act (TSCA) inventory.

TSCA 12 (b) Export Notification: Chromic acid (CAS# 7738-94-5).

CERCLA/SARA Section 302 EHS: None above reporting de minimis.


CERCLA/SARA Section 311/312: Immediate Health, Delayed Health
CERCLA/SARA Section 313: This product contains the following toxic chemicals subject to the reporting requirements of
section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40
CFR 372). Chromic acid (CAS# 7738-94-5).
CERCLA Reportable quantity: Chromic acid (CAS# 7738-94-5) 10 lbs. (4.54 kg)

California Proposition 65: This product contains a chemical known in the State of California to cause cancer. This
product contains a chemical known to the State of California to cause birth defects or other
reproductive harm.

Canada Regulatory Information

CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic
Substances List.

16. OTHER INFORMATION


This safety data sheet contains changes from the previous version in sections: New Safety Data Sheet format.

Prepared by: Regulatory Affairs

Issue date: 10/22/2021

IDH number: 594418 Product name: BONDERITE M-CR 1201 AERO known as ALODINE 1201
Page 5 of 6
DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel
Corporation and its affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methods
Henkel has no control. It is the user’s responsibility to determine the suitability of Henkel’s products or any production methods
mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and
persons against any hazards that may be involved in the handling and use of any Henkel’s products. In light of the foregoing,
Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular
purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental damages
of any kind, including lost profits.

This Safety Data Sheet has been generated based on OSHA Hazard Communication Standard (29 CFR 1910.1200) and provides
information in accordance with U.S. federal law only. No warranty or representation of any kind is given with respect to the
substantive or export laws of any other jurisdiction or country. Please confirm that the information provided herein conforms to the
substantive export or other law of any other jurisdiction prior to export. Please contact Henkel Product Safety and Regulatory
Affairs for additional assistance.

IDH number: 594418 Product name: BONDERITE M-CR 1201 AERO known as ALODINE 1201
Page 6 of 6

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