26-05-2025

4602CJA101031250002 JA

PART-A-PHYSICS

SECTION-I(i)

1) α and β are the angle made by a vector from positive x & positive y -axes respectively. Which set
of α and β is not possible:

(A) 45o, 60o

(B) 30o, 60o
(C) 60o,60o
(D) 30o, 45o

2) If x1 = 4sinθ and x2 = 3cosθ then maximum value of x1 + x2 is :

(A) 7
(B) 5
(C) 4
(D) 1

3) A car starting from rest is accelerated at constant rate until it attains a speed of 16 m/s. It moves
with the constant speed 16 m/s for some time and then it is retarded at other constant rate until it
comes to rest. Considering that the car moves with constant speed for half of the time of total
journey, what will be the average speed of the car for the whole journey (in m/s) ?

(A) 18
(B) 12
(C) 9
(D) 15

4) A projectile is fired at an angle θ with the horizontal. Find the condition under which it lands

perpendicular on an inclined plane inclination α as shown in figure.

(A) sin α = cos (θ – α)

(B) cos α = sin (θ – α)
(C) tanθ = cot (θ – α)
(D) cot(θ – α) = 2tanα

5) A particle is projected from a point O on the horizontal surface OA with speed u and angle of
projection θ. It just grazes the plane BC which makes an angle α with the horizontal. The time taken
by the projectile to reach P from the instant of projection is, if θ = 2α

(A)

(B)

(C)

(D)

6)

A stone is dropped into a quiet lake and waves move in circles at the speed of 5 cm/s. At the instant
when the radius of the circular wave is 8 cm, how fast is the enclosed area increasing ?

(A) 80 π cm2/s
(B) 90 π cm2/s
(C) 85 π cm2/s
(D) 89 π cm2/s

SECTION-I(ii)

1) If then select the correct alternative (s) :

(A) is perpendicular to
(B) is parallel to

(C) Component of along = –component of along

(D)

2) A particle is in motion on the x-axis. The variation of its velocity with position is as shown. The
graph is circle and its equation is x2 + v2 = 1, where x is in m and v in m/s. The CORRECT
statement(s) is/are
(A) When x is positive, acceleration is negative.
(B) When x is negative, acceleration is positive.

(C) At Q, acceleration has magnitude m/s2

(D) At R, acceleration is infinite.

3) Choose the correct alternative (s) :

If the greatest height to which a man can throw a stone is h, then the greatest horizontal
(A)
distance upto which he can throw the stone is 2h.
The angle of projection for a projectile motion whose range R is n times the maximum height is
(B)
tan–1 (4/n)
The time of flight T and the horizontal range R of a projectile are connected by the equation gT2
(C)
= 2Rtanθ where θ is the angle of projection.
A ball is thrown vertically up. Another ball is thrown at an angle θ with the vertical. Both of
(D) them remain in air for the same period of time. Then the ratio of maximum heights attained by
the two balls 1 : 1.

4)

The motion of a body is given by the equation = 6.0 –3v, where v is speed in m s–1 and t is in
second. If body was at rest at t = 0, then

(A) the speed varies with the time as v = 2(1 – e–2t) m s–1
(B) the terminal speed is 1.0 m s–1
(C) the magnitude of the initial acceleration is 2.0 m s–2
(D) the speed is 1 m s–1 when the acceleration is half the initial value.

5) A projectile is projected at an angle of elevation α. After t seconds, it appears to have an angle of

elevation β as seen from the point of projection. Which of the following are correct?

(A) the y-coordinate of the position of the projectile at time t is , where v is the
velocity of projection
the x-coordinate of the position of projectile at time t is , where v is the velocity of
(B)
projection

(C)
tan β = tan α – , where v is the velocity of projection
(D)
velocity of projection is

6) Two cities A and B are connected by a regular bus service with buses plying in either direction
every T seconds. The speed of each bus is uniform and equal to Vb. A cyclist cycles from A to B with a
uniform speed of Vc. A bus goes past the cyclist in T1 second in the direction A to B and every T2
second in the direction B to A. Then :-

(A)

(B)

(C)

(D)

SECTION-III

1) In the graph shown between a2 vs v where a is the acceleration v is the velocity of particle. If rate

of charge of acceleration wrt time is when velocity of particle will be 5 m/s. Find x.

2) If . Find .

3) If the shaded area is then x is :

4) A particle A is thrown with initial velocity 5 m/s along a frictionless inclined plane of inclination β.
Another particle B is thrown with initial velocity 10 m/s at an angle α with the horizontal at the same
moment when A is thrown and from same position as that of A. Both the particle meet again on the

inclined plane. The value of is :-

5) If and then, The unit vector in the direction of is

. The value of x is

PART-B-CHEMISTRY

SECTION-I(i)

1) 5 moles of AB2 weigh 125 × 10–3 kg and 10 moles of A2B2 weigh 300 × 10–3 kg. The molar mass of
A(MA) and molar mass of B(MB) in kg mol–1 are :

–3 –3
(A) MA = 50 × 10 and MB = 25 × 10
–3 –3
(B) MA = 25 × 10 and MB = 50 × 10
–3 –3
(C) MA = 5 × 10 and MB = 10 × 10
–3 –3
(D) MA = 10 × 10 and MB = 5 × 10

2) If the mass of 1022 molecules of a hydrocarbon is about 1.2g. Then Gram molecular mass of
hydrocarbon is (Take NA = 6 × 1023) :

(A) 36 g mol–1
(B) 72 g mol–1
(C) 54 g mol–1
(D) 90 g mol–1

3) x mol of FeC2O4. Fe2(C2O4)3 .2H2O requires 500 ml 0.4M Al2(Cr2O7)3 solution then select the correct
statement(s) :-

(A) n-factor of Al2(Cr2O7)3 is 6

(B) n-factor of Al2(Cr2O7)3 is 12
(C) Moles of oxalate which react with Al2(Cr2O7)3 is 0.4
(D) Moles of oxalate which react with Al2(Cr2O7)3 is 0.65
4) For the balance reaction

which of the following is correct :-

(A)

(B)

(C)

(D)

5) If in Bohr's model, for unielectronic atom, time period of revolution is represented as Tn,z where n
represents shell no. and z represents atomic number then the value of T1,2 : T2,1 will be :-

(A) 8 : 1
(B) 1 : 8
(C) 1 : 1
(D) None of these

6) The ionziation enthalpy of hydrogen atom is 1.312 x 106 J mol–1. The energy required to excite the
electron in the atom from n =1 to n =2 is :-

(A) 8.51 x 105 J mol–1

(B) 6.56 x 105 J mol–1
(C) 7.56 x 105 J mol–1
(D) 9.84 x 105 J mol–1

SECTION-I(ii)

1)

Choose the correct relation on the basis of Bohr's theory :-

(A)
velocity of electron ∝

(B)
frequency of revolution ∝
(C) radius of orbit ∝ n2Z

(D)
force on electron ∝

2) If the wave number of 1st line of Balmer series of H-atom is ‘x’ then :
 wave number of 1st line of lyman series of the He+ ion will be
(A)

wave number of 1st line of lyman series of the He+ ion will be
(B)

(C)
the wave length of 2nd line of lyman series of H-atom is

(D)
the wave length of 2nd line of lyman series of H-atom is

3) A sample of oxygen contains O16 & O18 isotopes only with percentage abundance respectively as
90% & 10%.
Identify the correct option(s) :

(A) Average atomic mass of sample is 16.2.

(B) Average number of protons per atom is 8.
(C) Average number of neutrons per atom is 8.2.
(D) Molecular mass of oxygen gas which can be formed from the sample can vary from 32 to 36.

4) Two flask of equal capacity contain NH3 & SO2 gases respectively, are kept under similar
conditions of temperature & pressure. Select the correct option on the basis of above information:

(A) More moles are present in flask contain NH3

(B) Flask of SO2 has more mass
(C) Flask of NH3 has more number of atoms.
(D) Both flask contain same number of molecules of NH3 & SO2 respectively

5) Which of the following samples of reducing agents is /are chemically equivalent to 25 ml of 0.2 N
KMnO4 to be reduced to Mn2+ and water ?

3+
(A) 25 ml of 0.2 M FeSO4 to be oxidized to Fe
(B) 50 ml of 0.1 M H3AsO3 to be oxidized to H3AsO4.
+
(C) 25 ml of 0.1 M H2O2 to be oxidized to H and O2.
4+
(D) 25 ml of 0.1 M SnCl2 to be oxidized to Sn .

6) The correct statement(s) is/are :-

The n–factor of HNO3 in the following reaction is

(A)

(B) The reaction is a intramolecular redox reaction.

(C)
The equivalent mass of (NH4)2Cr2O7 in option (B) is if M is molecular mass of (NH4)2Cr2O7.
(D) In the reaction H2 acts as oxidising agent.
 SECTION-III

1) 3.8 gm of a tribasic carboxylic acid derivative of a saturated hydrocarbon required 100 ml of 0.6M
NaOH solution to reach equivalence point. Calculate molar mass of tribasic carboxylic acid
derivative of saturated hydrocarbon. Fill your answer as sum of digits (excluding decimal
places) till you get the single digit answer.

2) Consider titration of NaOH solution versus 1.25M oxalic acid solution. At the end point following
burette readings were obtained.
(i) 4.5 mL (ii) 4.5 mL (iii) 4.4 mL (iv) 4.4 mL (v) 4.4 mL
If the volume of oxalic acid taken was 10.0 mL then the molarity of the NaOH solution is _______M.
(Rounded-off to the nearest integer)

3) 90 g of a silver coin was dissolved in strong nitric acid, and excess of sodium chloride solution was
added. The silver chloride precipitate was dried and weighed 71.75 g. Calculate the percentage of
silver in the coin (Atomic mass of Ag = 108, Na = 23, Cl = 35.5)
Ag + 2HNO3 → AgNO3 + NO2 + H2O
AgNO3 + NaCl → AgCl + NaNO3
Fill your answer as sum of digits (excluding decimal places) till you get the single digit
answer.

4) How many moles of –ve charge is present in the mixture containing

[(62 g NO3–) + (2.4092 × 1024 ion of S2–)]

5) In collection of H-atoms, all electron jump from 5th excited state to ground level finally, without
emitting any line in infrared region. Total number of possible different radiations are -

PART-C-MATHEMATICS

SECTION-I(i)

1) If , then sum of digits of x is

(A) 3
(B) 6
(C) 9
(D) 18

2) The value of expression is equal to

(A) 0
(B) 2
(C) 3
(D) 5

3) If then which of the following is correct

(A) Number of values of x is 3

(B) Number of values of x is 4
(C) Sum of values of x is 14
(D) Sum of values of x is 19

4) The sum of the infinite series is

(A)

(B)

(C)

(D)

5) If roots of x3 – 5x2 + kx – 27 = 0 are in G.P. then value of k is equal to

(A) 6
(B) 9
(C) 15
(D) no real value of k

6) Range of values of x for which the sum has finite value is

(A)

(B)

(C)

(D)

SECTION-I(ii)

1) Let a1, a2, a3,........ and b1, b2, b3,........ be arithmetic progression such that a1 = 25, b1 = 75 and a100
+ b100 = 100, then
 The common difference in progression 'ai' is equal in magnitude but opposite in sign to the
(A)
common difference in progression 'bj'.
(B) an + bn = 100 for any n.
(C) (a1 + b1), (a2 + b2), (a3 + b3), ....... are in A.P.

(D)

2) If 10 harmonic means H1, H2, H3 ......... H10 are inserted between 7 and – , then

(A) H1 = –7
H2 =
(B)

(C)
H1 = –
H10 =
(D)

3) Indicate the correct alternative(s), for if and

, then

(A) xyz = xz + y
(B) xyz = xy + z
(C) xyz = x + y + z
(D) xyz = yz + x

4) The sum of the first two terms of a geometric progression is 15. The first term exceeds the

common ratio of the progression by . The fourth term of the progression is

(A)

(B)

(C)

(D)

5) If 3x = 4x–1, then x =
(A)

(B)

(C)

(D)

6) Consider the equation . Then

(A) Sum of the solution = 24

(B) Sum of the solution = 30
(C) Absolute difference of root is 20
(D) Product of roots = 44

SECTION-III

1) If number of solutions of the equation |x – 1| + |x – 2| + |x – 3| + |x – 4| = 3 is same as the number

of solutions of the equation |2x + 3| + |2x – 3| = px, then the number of possible positive integral
values of p is

2) If , then the number of integers satisfying above

equation will be equal to

3) If the value of
is l, then l2 is equal to ________.

4) If the sum to first n terms of a series, the rth term of which is given by (2r + 1)2r can be expressed
as
R(n · 2n) + S · 2n + T, then find the value of (R + S + T).

5) If the arithmetic mean of a1, a2.......a48 is and the arithmetic mean of b1, b2, ...... b48 is λ such that

ai + bi = 1 ∀ i = 1,2,.......48, then the value of – 4λ is equal to

 ANSWER KEYS

PART-A-PHYSICS

SECTION-I(i)

Q. 1 2 3 4 5 6
A. D B B D C A

SECTION-I(ii)

Q. 7 8 9 10 11 12
A. A,C,D A,B,C A,B,C,D A,D A,B,C,D C,D

SECTION-III

Q. 13 14 15 16 17
A. 8 2 4 3 4

PART-B-CHEMISTRY

SECTION-I(i)

Q. 18 19 20 21 22 23
A. C B C A D D

SECTION-I(ii)

Q. 24 25 26 27 28 29
A. A,B,D A,C A,B,C,D B,C,D A,C,D A,B,C,D

SECTION-III

Q. 30 31 32 33 34
A. 1 6 6 9 3

PART-C-MATHEMATICS

SECTION-I(i)

Q. 35 36 37 38 39 40
A. C C A A C A

SECTION-I(ii)

Q. 41 42 43 44 45 46
A. A,B,C,D A,D B,C A,B A,B,C A
 SECTION-III

Q. 47 48 49 50 51
A. 3 6 3 4 6
 SOLUTIONS

PART-A-PHYSICS

2) y = x1 + x2
y = a sin θ + b cos θ

= a cos θ – b sin θ = 0

tan θ =

ymax = a ×

3)

If the constant speed attained = v m/s.

t1 = t3 =

S2 = v(t1 + t3) =
avg. speed

=
v = 16 m/s, average speed = 12 m/s
4) Vx = Vcos (θ – α) –g sin αt
as it collider surface normally,

vx = 0 for (t = T)

⇒ T=

Also time of flight is T =

∴
∵ cot (θ – α) = 2 tan α.

5)
u cos θ · sin α = (u sin θ – gt ) cos α

(θ = 2α)

7) is perpendicular to .

8)
9) (A) ∴ A is correct.

(B)

∴ B is correct

(C)

⇒ gT2 = 2R tanθ ∴ C is correct

(D)
hmax ∝ T2

T1 = T2, hmax(1) = hmax(2) ∴ D is correct

10)

V = 2(1 – e–3t)

3 = 6e–3t

11) y-coordinate is

y = v sin α t [Therefore A is correct]

x –coordinate is
x = v cos α t [Therefore B is correct]
Equation of trajectory is

⇒ [C is correct]

Rearrenging

⇒ [∴ D is correct]

12) The distance between the bus remains same, either it is observed by cyclist stationary

observer.
For bus moving A to B
VbT = (Vb – Vc) T1 ....(1)
For bus moving B to A
VbT = (Vb + Vc) T2 ....(2)
On solving equation (1) and (2), we get

13)

14)

∴
= 12 + 4 – 14 = 2

15) Area =
 16)
uB cos(α + β) = uA

cos(α + β) =

α+β=

17)

x=4

PART-B-CHEMISTRY

18)

A + 2B =
Molar mass of AB2

A = 5 × 10–3
B = 10 × 10–3

19) Mass of 1022 molecule = 1.2g

mass of 1 molecule =

mass of NA molecule =

20)
ev. of oxalate = Eqv. of Al2 (C2O7)3
moles × Hf = 0.4 × 18 ×

21)

22)

Frequency =

Frequency = T∝ = ⇒

23)

Ist excitation energy =

24)

(A) v = 2.18 × 106 × ⇒v∝ or v ∝

(B) f = or f = ∝ f∝

(C) r ∝ n2 / Z [T ∝ ] F=

F∝ F∝
So ans (A,B,D)

25)

Use

26)

Avg. atomic mass =

 Atomic no. same for both so, Avg. protons per atom is 8.
Avg. no. of neutrons = Avg. atomic mass – Z = 8.2

27)

P, V, T same.
∴ Moles same & molecules same.
∴ NH3 will have more number of atoms.

28) Milli eq. of KMnO4 = 6.2 × 25 = 5.0

(A) [Link]. = 25 × 0.2 × 1 (nf) = 5.0
(B) [Link]. = 5.0×0.1 × 2 (nf) = 10.0
(C) [Link]. = 2.5×0.1 × 2 (nf) = 5.0
(D) [Link]. = 2.5×0.1 × 2 (nf) = 5.0
So as = A,C,D.

29) (A) B.R will be 2Zn + 5HNO3 → 2Zn(NO3)2 +

Electrons exchanged = 5

∴ n.f. =
(B) O.N. of N decreases & Cr increases.
∴ Intramolecular redox.
(C) Balance reaction (NH4)2Cr2O7 → N2 + Cr2O3 + 4H2O
Electron exchange = 6
​∴ n.f. = 6.
(D) O.N. of Na increases.
∴ H2 is oxidising agent.

30)

(MF = C7H10O6 , M = 190)

31) VNaOH = 4.4 ml

eq. of NaOH = eq. of H2C2O4
or, M × 4.4 × 1 = 1.25 × 10 × 2
or, M = 5.68 M
∴ Nearest integer answer is 6.

32) POAC on Ag
1 × nAg = nAgCl × 1

= = 0.5
wAg = 0.5 × 108 = 54 gm
 % Ag = × 100 = 60 %

33) Moles of NO3– =

Moles of S2– =
Total moles of charge = (1 + 4 × 2) = 9

34) Since, Paschen, Bracket, Pfund are not observed, hence possible lines are.

PART-C-MATHEMATICS

35)
⇒ 4 + log3(x) = 23 = 8
⇒ log3(x) = 4 ⇒x = 34 = 81
sum of digits of = 8 + 1 = 9

36) The value of expression

=2+3–2=3

38)

....(1)

(2)
subtract (1) – (2)

39) be the root product of roots = = 27

⇒ a=3
This is also root of given equation
∴ put in main equation
33 – 5.9 + 3K – 27 = 0
K = 15

40)
⇒ 2x2 + 17x + 21 > 0
& 2x2 – 17x + 21 > 0
(2x + 3)(x + 7) > 0 & (2x – 3)(x – 7) > 0

x ∈ (–∞,7) &

41)

a100 + b100 = 100

25 + 99d1 + 75 + 99d2 = 100
99d1 + 99d2 = 0
d1 + d2 = 0
d1 = –d2
(A) Correct
(B) an + bn = a1 + (n – 1)d1 + b1 + (n – 1)d2
= a1 + b1 = 100 (Correct)
(C) Correct (as sum of corresponding terms of two AP's also form an AP)
(D) (a1 + b1) + (a2 + b2) + ..... + (a100 + b100)
= 100 × 100 = 104

42)

Now + 11d = –3, 11d =

⇒ d=

Now = = H1 = –7

, H2 =

43)

x = 1 + cos2 ϕ + cos4 ϕ .... = = cosec2 ϕ

y = 1 + sin2 ϕ + sin4 ϕ .... = = sec2 ϕ

z = 1 + sin2 ϕ cos2 ϕ + sin4 ϕ cos4 ϕ .... =

Now z = ⇒ =z
⇒ xy = xyz – z

also =1
⇒ x + y = xy
Hence xyz = xy + z = x + y + z

44) a + ar = 15 ....(1)

a–r= ....(2)

a = 9,

45) 3x = 4x – 1
x· log3 = (x – 1)log 4
log 4 = x (log4 – log3)

⇒x= =

46) Equation valid when 2x – 4 > 0 ⇒ x ≥ 2

& 3x + 4 ≥ 0 ⇒
Squaring 3x + 4 = 4 + 2x – 4 +
⇒
x2 – 24x + 80 = 0
⇒ x = 4, 20

47) As, minimum value of |x – 1| + |x – 2| + |x – 3| + |x – 4| will be 4 ∀ x ∈ [2, 3]. So, number of

solutions of the equation |x – 1| + |x – 2| + |x – 3| + |x – 4| = 3 will be zero.
 Graph of y =| 2x – 3 | + | 2x + 3 | (Even function) ∴ y = px (p >
0) will not cut the graph if p ∈ (0, 4) ⇒ pintegral = 1, 2, 3.

48) Put
∴ given equation becomes
|t – 2| + |t – 3| = 1
⇒ 2≤t≤3
⇒ 5 ≤ x ≤ 10

49)

– – – –
________________________

Now

2
⇒ =3

50)

Tn = (2n + 1) . 2r

Sn = = 3.2 + 5.22 + 7.23 + ... + (2n – 1) . 2n–1 + (2n + 1) . 2n

2Sn = 3.22 + 5.23 + ... + (2n – 3) . 2n–1 + (2n – 1) . 2n + (2n + 1) . 2n+1
Sn – 2Sn = 3.2 + 2.22 + 2.23 + ... + 2.2n – (2n + 1)2n+1
–Sn = 2 + 2[2 + 22 + 23 + ... + 2n] – (2n + 1) . 2n+1
–Sn = 2 + 2.2(2n – 1) – (2n + 1) + 2n+1
–Sn = 2.2n+1 – 2 – (2n + 1) . 2n+1
Sn = (2n + 1 – 2) . 2n+1 + 2
Sn = (2n – 1) . 2n+1 + 2 = 4(n + 2n) – 2 . (2n) + 2
R+S+T=4–2+2=4

51)

then