13-04-2025

9610ZJA801444240026 JA

PART 1 : PHYSICS

SECTION-II

1) A person of 80 kg mass is standing on the rim of a circular platform of mass 200 kg rotating about
its axis as 5 revolutions per minute (rpm). The person now starts moving towards the centre of the
platform. What will be the rotational speed (in rpm) of the platform when the person reaches its
centre__________.

2) A uniform rod of length 2ℓ rocks to and fro on the top of a rough semicircular cylinder of radius a.

The period of small oscillations is T. The value of is

3) A long container has air enclosed inside at room temperature and atmospheric pressure (105 pa).
It has a volume of 20,000 cc. The area of cross section is 100 cm2 and force constant of spring is
kspring = 1000N/m. We push the right piston isothermally and slowly till it reaches the original
position of the left piston which is movable. What is the final length of air column in cm ? Assume

that spring is initially relaxed.

4) A block of wood is floating in water such that 1/3rd of it is submerged in water. When the same
block is floated in alcohol, 1/2 of its volume is submerged. Now a mixture of water and alcohol is
made taking equal volume of both and block is floated in it. What is the % of its volume that is now
submerged?

5) When a film of soap solution is created inside a loop formed by rectangular wire frame and an in
extensible light thread AB of length ℓ, the thread assumes shape of a semicircle. By pulling the
midpoint of the thread with a force F , the thread can be given shape of two semicircles as shown in

the figure. Surface tension of the soap solution is . Find x.

6) A straight conducting wire MN of length 4m is rotated in a uniform magnetic field Tesla
about point O with angular speed ω = 10 rad/s as shown in the figure. The axis of rotation is
parallel to . Find the potential difference (in volt) between point M and point N.

7) An infinite plane of charge with is tilted at a 37° angle to the vertical direction as
shown below. Find the potential difference, VA–VB in volts, between points A and B at 5 m distance

apart. (where B is vertically above A).

8) A charge q is kept just outside a cube on extension of digonal GA. The magnitude of electric flux

of side ABCD is . Find value of α.

SECTION-I (i)

1)

A particle moves in x-y plane such that the position vector of the particle depends on time t as

where t is in second and r is in meter.

(A)
Average velocity of the particle in time interval t = 0 to t = 2 sec is m/sec
(B) Average acceleration in time interval t = 0 to t = 2 sec is along y-axis
(C) Path followed by particle is parabolic
(D) Path followed by particle is straight line

2) A closed organ pipe of length 28 cm closed at one end is found to be in resonance when a tuning
fork of frequency 850 Hz is sounded near the open end. If velocity of sound in air is 340 m/s, then
the

(A) end correction of the pipe is 1 cm

(B) end correction of the pipe is 2 cm
 air in the pipe is vibrating in fundamental mode
(C)

(D) air in the pipe is vibrating in first overtone

3) Four identical capacitor each of capacitance 5 µF are connected as shown in Figure. They are
attached to the battery of emf E = 9 V. Initially the key K2 is open, and the switch K1 is closed. Then

key K1 is opened and K2 is closed.

(A) The initial potential difference across capacitor 2 is 3 V.

(B) The final potential difference across capacitor 2 is 1.8 V.
(C) The charge flown through the battery after the reversal of switches is 3µC.
(D) The charge flown through the battery after the reversal of switches is zero.

4) In the given diagram choose correct options :-

(A) The value of I is 4A

(B) The current from the cell is 4A.
(C) Voltage drop across AB is 140 V.
(D) The current from the cell is 10A.

5) A coaxial cable consists of a thin inner current carrying wire fixed along the axis of a hollow
current carrying tube. Let B1 and B2 be the magnetic fields in the region between the conductors and

outside the tube, respectively

(A) B1 ≠ 0, B2 ≠ 0, for conductors carrying equal currents in opposite directions

(B) B1 ≠ 0, B2 = 0, for conductors carrying equal currents in opposite directions
(C) B1 ≠ 0, B2 ≠ 0, for conductors carrying equal currents in same directions
(D) B1 ≠ 0, B2 = 0 for conductors carrying equal currents in same directions

6) A light source, which emits two wavelengths λ1 = 400 nm and λ2 = 600 nm, is used in a Young's
double slit experiment. If recorded fringe widths for λ1 and λ2 are β1 and β2 and the number of
fringes for them within a distance y on one side of the central maximum are m1 and m2, respectively,
then

(A) β2 > β1
(B) m1 > m2
(C) From the central maximum, 3 maximum of λ2 overlaps with 5 minimum of λ1
rd th

(D) The angular separation of fringes for λ1 is greater than λ2

SECTION-I (ii)

1) Assuming reference position for gravitational potential is at ∞. Consider the situation of List-I and
match them with the conditions in List-II.

List-I List-II

Gravitational potential at
(P) (1)
position (1) & (2) is same

Gravitational potential at
(Q) (2) position (1) is less than at
position (2)

Magnitude of gravitational field

(R) (3) at position (1) is less than at
position (2)

Magnitude of gravitational field

(S) (4) at position (1) is more than at
position (2)

(5) None
(A) P → 3;Q → 1;R → 2;S → 4
(B) P → 3;Q → 2;R → 4;S → 4
(C) P → 3;Q → 1;R → 4;S → 4
(D) P → 2;Q → 1;R → 3;S → 4

2) One mole of an ideal monoatomic gas is taken round the cyclic process ABCA as shown in figure.

List-I List-II

(P) The work done by the gas during complete cycle (1)

(Q) Heat absorbed by the gas in the path AB (2)

The minimum temperature attained by the

(R) (3) P0V0
gas during the cycle.

The maximum temperature attained by the

(S) (4) 3P0V0
gas during the cycle.

(5) 2P0V0
(A) P → 1;Q → 2;R → 3;S → 4
(B) P → 3;Q → 4;R → 2;S → 1
(C) P → 3;Q → 4;R → 1;S → 2
(D) P → 1;Q → 2;R → 4;S → 3

3) List–I shows the cylindrical region of radius r where a downward magnetic field exists, and is

increasing at the rate of . A rod PQ is placed in different situation as shown. Match the list–I with
the correct statement in List–II regarding the induced e.m.f. in rod.

List-I List-II

Induced e.m.f. in rod PQ is

(P) (1)
 Induced e.m.f. in rod PQ is less
(Q) (2)
than

End P is positive with respect to

(R) (3)
point Q

End Q is positive with respect to

(S) (4)
point P

(5) End P and Q are at same potential

(A) P → 3,4;Q → 5;R → 1,5;S → 1,4
(B) P → 2,3;Q → 4;R → 1,5;S → 2,5
(C) P → 2,4;Q → 1,3;R → 1,4;S → 2,3
(D) P → 2,3;Q → 1,4;R → 1,3;S → 2,4

4) In List-I, we have certain situations where a battery of variable voltage other than zero is
connected in a circuit. List-II has comments on current in element A on variation of voltage:-

Column-I Column-II

On increasing V (from a certain value to another certain value),

(P) (1)
i may/will increase in magnitude

Ammeter is ideal
 On increasing V (from a certain value to another certain value),
(Q) (2)
i may/will decrease in magnitude.

Ammeter is ideal

On increasing V (from a certain value to another certain value),

(R) (3)
i may/will not change at all in magnitude

A → 4Ω resistor

(S) (4) On reversing V (keeping same value), i may/will be zero

A → 4Ω resistor

On reversing V (keeping same value), i may/will increase in

(5)
magnitude
(A) P → 3,4;Q → 3,4;R → 1,2,5;S → 1,4
(B) P → 2,3;Q → 1,4;R → 3,4;S → 4,5
(C) P → 1,2;Q → 2,3;R → 2,4;S → 3,5
(D) P → 4,5;Q → 1,2;R → 4,5;S → 2,4

PART 2 : CHEMISTRY

SECTION-II

1) An octahedral complex of chromium contains NH3 and Cl ligands. The oxidation number of
chromium in the complex is +3. The complex shows one cis and one trans isomer(no fac or mer
isomers). Reaction of the complex with AgNO3 solution forms white precipitate. How much
precipitate in gram will be formed if one mole of the complex reacts with excess of AgNO3 solution?

2) HA is a weak acid and NaA is it’s salt. An aqueous solution contains HA and NaA in the molar
ratio of 10 :1 respectively. The pH of this aqueous solution is 5.38. What is the pKa of the acid HA?

3) CaCO3(s) CaO(s) + CO(g)

If above reaction takes place in a 100 L container at 1000 K, 100 moles of CO2 is produced at
equilibrium. What is the equilibrium constant KP of the reaction in atm unit ?

4) The polymerization of the ethylene to linear polyethylene is represented by the reaction

n(H2C=CH2)→(CH2–CH2)n
Where n has a large integral value. Given that the average enthalpies of bond dissociation for C = C
and C – C at 298 K are +590 kJ/mol & +331 kJ/mol respectively. Calculate the magnitude of enthalpy
of polymerization in kJ per mole of ethylene at 298 K?

5) The sum of reaction number for which the major product is/are correctly mentioned is :

6) For the given sequence of reaction

How many products are obtained finally ?

7) Degree of unsaturation in the major product is

X then (X–2)
8) Consider the following complex compounds.
[CoCl2Br2]2⊝ , [Ni(en)3]2⊕ , [Ti(H2O)6]3⊕ , [Fe(NH3)6]2⊕ , [Co(H2O)3F3] , K3[Fe(CN)6]

If number of low spin complexes is "X" and number of high spin complexes is "Y" then is

SECTION-I (i)

1) 30 mL of CH3OH(d = 0.8 g/cc) is mixed with 60 mL of C2H5OH (d = 0.92 g/cc) at 25oC to form a
solution of density 0.88 g/cc.
Choose the correct statement(s) from the following.

(A) Molarity of the solution and percentage change in volume are 13.59 and zero respectively.
(B) The mole fraction of solute and molality are 0.385 and 13.59 respectively.
(C) The mole fraction of solvent and molality are 0.615 and 13.59 respectively.
(D) Molarity and molality of resulting solution are 6.33 and 13.59 respectively.

2) Which of the following statement(s) is/are correct for Na3[Co(ONO)6]?

(A) It’s aqueous solution is slightly basic in nature.

(B) It’s IUPAC name is sodium hexanitritocobaltate(III)
(C) It is called sodium cobaltinitrite
(D) One molecule of it forms three ions in water.

3) The total vapour pressure of a binary solution is given by

P = (80 XA + 240 XB) mm Hg
Where XA and XB are the mole fractions of components A and B. Choose the correct statement(s)
from the following:

(A) vapour pressure of solution is less than that of the pure B component.
(B) vapour pressure of solution is more than that of pure A component.
(C) vapour pressure of pure A is 80 mm of Hg and that of pure B is 240 mm Hg.
(D) the vapour pressure of pure A and B are 240 and 80 mm Hg respectively.

4) Which of the following cations will turn a borax bead blue in an oxidizing flame?

(A) Fe3+
(B) Fe2+
(C) Co2+
(D) Cu2+
5)

(A)

(B)

(C)

(D)

6)
Identify correct statement for (A) and (B) products.

(A)
(B)

(C)

(D)

SECTION-I (ii)

1)

List-II
List-I
Graph (A - Reactant in reaction,
(Order)
B - Product in reaction)

(P) Zero order (1)

(Q) First order (2)

 (R) Second order (3)

(S) Third order (4)

(5)

Select correct option :

(A) P → 5;Q → 2;R → 4;S → 1
(B) P → 1;Q → 2;R → 3;S → 5
(C) P → 1;Q → 5;R → 3;S → 1
(D) P → 5;Q → 2;R → 3;S → 1

2)

List-I List-II
(Orbitals) (Nodal graphs)

(P) 3s (1)

(Q) 4p (2)
 (R) 4d (3)

(S) 2s (4)

(5)

(A) P → 4;Q → 1;R → 3;S → 2

(B) P → 2;Q → 3;R → 2;S → 5
(C) P → 2;Q → 1;R → 3;S → 5
(D) P → 1;Q → 3;R → 4;S → 3

3)

Column-I Column-II

(P) Acetone + CHCl3 (A) ΔSmix > 0

(Q) Ethanol + Water (B) ΔVmix > 0

(R) C2H5Br + C2H5I (C) ΔHmix > 0

(S) Acetone + benzene (D) Maximum boiling point azeotrope

(E) Minimum boiling point azeotrone

(A) P → A,D;Q → A,B,C,E;R → A;S → A,B,E
(B) P → A,D;Q → A,B,C,E;R → A;S → A,B,C,E
(C) P → A,B;Q → A,B,C,E;R → A,B,E;S → A
(D) P → A,C;Q → A;R → B,C;S → A,B

4) Match each species in List-I with List-II and choose correct option :

List-I List-II
 (P) A carbohydrate which yields only glucose on hydrolysis (1) Sucrose

(Q) A carbohydrate which yields glucose and fructose on hydrolysis (2) Lactose

(R) A carbohydrate which yields glucose and galactose on hydrolysis (3) Amylose

(S) A carbohydrate which can reduce Fehling solution (4) Mannose

(5) Cellulose
(A) P → 3,5;Q → 2;R → 1;S → 2,4
(B) P → 5;Q → 1;R → 2;S → 2,3
(C) P → 3;Q → 1;R → 2;S → 2,5
(D) P → 3,5;Q → 1;R → 2;S → 2,4

PART 3 : MATHEMATICS

SECTION-II

1) Let the function, f : [–7, 0] → R be continuous on [–7, 0] and differentiable on (−7, 0). If f(–7)= −3
and ฀′(฀) ≤ 2, for all ฀ ∈ (−7, 0), then for all such functions f(x), the maximum value of ฀(−1) + ฀(0)
is :

2) The area of the region given by and is equal to (in square units)

where a, b, c are integers & a & b are co-prime, then equals

3) Let f(x) be a differentiable function such that f(f(x)) = x, where x∈(0, 1], also f(0) = 1, then if the

value of is I then is

4) In a tetrahedron OABC, the edges are of

lengths, |OB|=|AC|=b, |OC|=|AB|=c, Let G1 and G2 be the centroids of the triangle ABC and AOC

such that then the value of is

5) If then find the value of cos–1(cos(p – 1))

[Use : π = 3.14]

6) The number of solutions of the equation sin⁡(πx)=|ln|x|| is

7) is equal to :

8)

The greatest integer less than or equal to

SECTION-I (i)

1) Let f(x) = cos2x (etan x) then

(A)
f ′(x) has a point of local minima at

(B)
f ′(x) has a point of local maxima in interval

(C)
f ′(x) has exactly two point of extrema in

(D)
f ′′(x) has no root in

2) If 1, z1, z2, z3,......zn–1 are 'n' nth roots of unity, then the value of

is equal to

(A)

(B)

(C)

(D)

3) Solution(s) of the differential equation (y2dx – 2xy dy) = x3y3 dy + x2y4 dx can be :
where c : constant of integration.

(A)

(B)
(C)

(D)

4) System of equation x + y + az = b, 2x + 3y = 2a & 3x + 4y + a2z = ab + 2 has

(A) unique solution when a ≠ 0, b ∈ R

(B) no solution when a = 0, b = 1
(C) infinite solution when a = 0, b = 2
(D) infinite solution when a = 1, b ∈ R

5) Let A,B be two events such that and . Then

(A)

(B)

(C)

(D)

6) Consider the following frequency distribution of 44 students

xi 3 9 17 23 27

fi 8 10 12 9 5
Which of the following is/are CORRECT ?
(A) Mean of the given distribution is 15
(B) Median of the given distribution is 17

(C)
Mean deviation about mean of the given distribution is

(D)
Mean deviation about median of the given distribution is

SECTION-I (ii)

1) Match List-I with List-II and select the correct answer using the code given below the list.

List-I List-II

If the equation sin4x – (k + 2)sin2x – (k +

(P) 3) = 0 has a solution then possible value (1) –2
of k can be
 (Q) If the expression , (2) –1
then possible value of y can be

If both roots of the quadratic equation x2

(R) + 2(k + 1)x + k + 5 = 0 are positive then (3) 2
possible values of k can be

If (sinx + sin2x + sin3x)2 + (cosx + cos2x

(S) + cos3x)2 = 1 then cosx can have the (4) –3
value equal to

(5) 4
(A) P → 4;Q → 3;R → 2;S → 1
(B) P → 1;Q → 2;R → 4;S → 3
(C) P → 2;Q → 4;R → 1;S → 3
(D) P → 3;Q → 1;R → 4;S → 2

2) Given a,b,c,d are distinct real numbers

Match List-I with List-II and select the correct answer using the code given below the list.

List-I List-II

(P) if a,b,c,d are in A.P., then (where a,b,c,d > 0) (1) bc > ad

(Q) if a,b,c,d are in G.P., then (where a,b,c,d > 0) (2) bc < ad

(R) if a,b,c,d are in H.P., then (where a,b,c,d > 0) (3) b + c > a + d

(S) if a,b,c,d are in A.P., then (where a,b,c,d < 0) (4) b + c < a + d

(5) b2 + c2 < a2 + d2
(A) P → 1,5;Q → 4,5;R → 2,4,5;S → 1,5
(B) P → 1;Q → 2,4;R → 1,3;S → 1,4
(C) P → 1;Q → 2,3;R → 2,4;S → 3
(D) P → 1;Q → 1,3;R → 2,4;S → 5

3) Match List-I with List-II and select the correct answer using the code given below the list.

List-I List-II

(I) (P) 1
If , then the value of a is equal to

ƒ:(0, ∞) → R such that ƒ(x) = (a – 7) log3x + (b–2)ex + sinx, ƒ(x) is

(II) (Q) 2
bounded function, then a + b – 7 is

Let ƒ(x) = x2 + px + 10 and ƒ(x) is an even function ∀ x ∈ R. If

(III) (R) 5
is , where m & n are relatively prime, find
(m + n)

The sum of all values of x for which the

(IV) (S) 9
function is continuous but not differentiable is
 (T) 11
(A) I → P;II → S;III → Q;IV → R
(B) I → S;II → R;III → P;IV → Q
(C) I → P;II → Q;III → S;IV → R
(D) I → P;II → R;III → S;IV → Q

4) Match List-I with List-II and select the correct answer using the code given below the list.

List-I List-II

If the line x – y –2 = 0 is rotated through

an angle in the clockwise direction

(P) about point P(5,3) and equation of line in (1) Rational
new position is , then k is

The point R lying on x-axis such

that PR + QR is minimum, if P and Q are
(Q) (2) Irrational
(1,1) and (3,2) respectively, then value
of (a + b + c) is [where a and b are
coprime]

Let A(3,4), B(0,0) and C(3,0) be vertices

of ΔABC. If P(α,β) is a point inside the
(R) (3) Even integer
ΔABC equidistant from sides of triangle,
then (α + β) is

Real value of x satisfying x4 – 2x3 – x2 –

(S) (4) Odd integer
2x + 1 = 0 is

(5) Prime number

(A) P → 1;Q → 1,3;R → 2,4;S → 1
(B) P → 2;Q → 1,3;R → 1,3,5;S → 2
(C) P → 2;Q → 3;R → 1,4;S → 1
(D) P → 3;Q → 2;R → 1,3,4;S → 2
 ANSWER KEYS

PART 1 : PHYSICS

SECTION-II

Q. 1 2 3 4 5 6 7 8
A. 9.00 6.28 100.00 40.00 2.00 4.80 3.00 7.00

SECTION-I (i)

Q. 9 10 11 12 13 14
A. A,B,C B,D A,D A,B,C B,C A,B,C

SECTION-I (ii)

Q. 15 16 17 18
A. C B C A

PART 2 : CHEMISTRY

SECTION-II

Q. 19 20 21 22 23 24 25 26
A. 143.50 6.38 82.10 72.00 6.00 11.00 9.00 0.33

SECTION-I (i)

Q. 27 28 29 30 31 32
A. B,C A,B,C A,B,C C,D C,D A,D

SECTION-I (ii)

Q. 33 34 35 36
A. D C B D

PART 3 : MATHEMATICS

SECTION-II

Q. 37 38 39 40 41 42 43 44
A. 20.00 85.00 2021.00 3.00 2.14 6.00 15.00 197.00

SECTION-I (i)

Q. 45 46 47 48 49 50
A. A,B,C B,C A,B B,C,D A,C A,B,C
 SECTION-I (ii)

Q. 51 52 53 54
A. A A C A
 SOLUTIONS

PART 1 : PHYSICS

1) Li = Lf

180ω0 = 100ω1
ω1 = 1.8ω0 = 1.8 × 5
= 9 rpm

2) θ is small

3)
P2V2 = P1V1
V1 = 20000cc.
P1 = 105 Pa
V2 = Ax

0
P2 = P +

⇒ 105 × 20000 × 10–6 = 10– 4 × 100x

⇒ 2000 = 1000 [x (1 + x)]
x2 + x – 2 = 0

x= =1m
x = 100 cm.

4) .....(i)

.....(ii)

From equation (i) & (ii) ;

5)
In equilibrium condition, lateral pull of the soap film on the thread due to surface tension must
everywhere be normal to the thread.

6)

7) N/C ∴

8)

ϕnet = 0

ϕDCGH = ϕEFGH = ϕBCGF =

ϕABCD = ϕADHE = ϕABFE =

9)

t=0⇒
t=2⇒
∴

∴< >=

∴< >=

10)
28 + e = 30

λ=
850 + y = 0.4
λ = 40 cm

11)
Since, all capacitor are same,
∴ V2 = 3V
After K, is opened battery is out of circuit
∴ no charge can flow through it.

12)

By KCL, 6 + I = 10 ⇒ I = 4A
By KVL, 200 – 25 i – 100 = 0
i = 4A

VAB = 10 × 14 = 140 V
13)
By ampere's law

14)

(A)

no. of fringes m =
3rd maxima in case of λ2

(B)
5 minima incase of λ1
th

y1 = y2 so (C)

15) gravitational potential is α so any position far away has more potential.
Gravitational field inside a uniform hollow sphere is zero due to its own mass, but it is non-zero
due to other masses present near by.

0 0 0 0
16) For (P) : W = (2P )(V ) = P V

0 0
For (Q) : QAB = nCV (TB–TA) = 1 × R = 3P V

For (R) : TA = , TB = = 3TA, TC = = 2TA

⇒ Minimum temperature : Tmin =

(OR Temperature will be minimum for a point which is nearest to origin)
Maximum temperature will be either on end points or in process BC.
 For (S) : As for process BC :

= ⇒ P = 5P0 –

0 0
⇒ PV = 5P V – V2 But PV = RT. So RT = 5P V – V2

0
⇒ = 5P0 – (2V) = 0 ⇒ V = V

0
⇒ RTmax = 5P ⇒ Tmax =

17)

18) For D :

Similar for C
A, B are wheatstone so no change.

PART 2 : CHEMISTRY

19)

[Cr(NH3)4Cl2]Cl + AgNO3 → AgCl + [Cr(NH3)4Cl2]NO3

1 1
∴ Mole of AgCl formed = 1
Mass of AgCl = 143.50 g

20) pH = pKa + log

or, 5.38 = pKa + log

∴ pKa = 5.38 + 1 = 6.38

21)

Kp = 82.1

22)
n double bonds dissociate to form 2n single bond.
ΔH for polymerization of 1 mol of ethylene

=+590 – 2 × 331 = –72 kJ mol–1 = –72.00 kJ mol–1

23)

24)
25)

26) X = K3[Fe(CN)6] Y = [CoCl2Br2]2⊝ , [Fe(NH3)6]2⊕ , [Co(H2O)3F3]

27) = 30 mL = 60 mL
d = 0.8 g/cc d = 0.92 g/cc
W = 0.8 × 30= 24 g W = 60 x 0.92 = 55.2 g

n= = 0.75
Total moles = 0.75 +1.2 = 1.95 Solute = CH3OH, Solvent = C2H5OH
Molarity = 0.75 ×

Molality = 0.75 × =

Mole fraction of solute (CH3OH) =

Mole fraction of solvent (C2H5OH) = 1 –0.385 = 0.615

28)

Na3 [Co(ONO)6] 3Na+ + [Co(ONO)6]3–

[Co(ONO)6]3– + H2O H[Co(ONO)6]2– + OH–
The IUPAC name of the ligand is nitrito.

29)

For option (A)

P = 80XA + 240 XB
= 80 XA + 240 (1 – XA)
= 80 XA + 240 – 240 XA
= 240 + XA(80 – 240)
= 240 – 160 XA
∴ V.P of solution is less than 240 mm Hg which is V.P of pure(B)
For option (B)
P = 80XA + 240 XB
= 80(1 – XB) + 240 XB
= 80 – 80 XB + 240 XB
= 80 + (240 – 80)XB = 80 + 160 XB
∴ V.P of solution is more than 80 mm Hg which is the V.P of pure(A)
For option (C)
P = 80XA + 240XB
For pure (A), XA = 1 and XB = 0
V.P of pure (A) = 80 mm Hg
Similarly
∴ V.P of pure (B) = 240 mm Hg.

30)

Co(BO2)2 and Cu(BO2)2 are blue substances.

31)
32)

33)

(P) For zero order

[Ao] – [At] = Kt
[At] = [Ao] – Kt
(Q) For first order
ln[Ao] – ln[At] = Kt
ln[At] = ln[Ao] – Kt

(R) For second order

ln t1/2 = –ln [Ao] –lnK

(S) For third order

34)

List-II (nodal graphs

(1) n – ℓ – 1 = 2
n–ℓ=3
Possible orbitals : 3s(n = 3, ℓ = 0)
4p (n = 4, ℓ = 1)
(2) n – ℓ – 1 = 2 (ℓ = 0)
n = 3 i.e. = 3s
(3) n – ℓ – 1 = 1 (ℓ ≠ 0)
n–ℓ=2
Possible orbitals
ℓ = 1; n = 3 → 3p
ℓ = 2; n = 4 → 4d
(4) n – ℓ – 1 = 2 (ℓ ≠ 0)
n–ℓ=3
Possible orbitals
ℓ – 1; n = 4 → 4p
ℓ = 2; n = 5 → 5d
(5) n – ℓ – 1 = 1 (ℓ = 0)
n = 2 → 2s

35)

(P)
⇒ More interaction in mixture.
⇒ Negative deviation from Roult’s law.
⇒
⇒ Maximum boiling point azeotrope
[P → A, D]

(Q)
⇒ A–A & B–B interaction > A–B interaction
⇒ Positive deviation from Roult’s law.
⇒ ΔSmix > 0 ; ΔVmix > 0 : ΔHmix > 0
⇒ Minimum boiling point azeotrope
⇒ [Q → A, B, C, E]

(R)
⇒ A–A & B–B interaction A–B interaction
⇒ shows ideal behaviour
⇒ ΔSmix > 0 ; ΔVmix = 0 ; ΔHmix = 0
[R → A]

(S)
⇒ Less interaction in mixture.
⇒ Positive deviation from Roult’s law.
⇒ ΔSmix > 0 ; ΔVmix > 0 ; ΔHmix > 0
⇒ Minimum boiling point azeotrope.
[S → A, B, C, E]

36) Sucrose
α-D-glucose + β-D-fructose
Lactose
β-D-glucose + β-D-galactose
Amylose
α-D-glucose + α-D-glucose + ...
 Mannose cannot be hydrolysed.
Lactose and mannose can reduce Fehling’s solution due to presence of hemiacetal and
aldehyde group.

PART 3 : MATHEMATICS

37) f(–7) = –3 and f’(x) ≤ 2

Applying LMVT in [–7, 0], we get
(f(–7) – f(0))/–7 = f’(c) ≤ 2
(–3 – f(0))/–7 ≤ 2
f(0) + 3 ≤ 14
f(0) ≤ 11
Applying LMVT in [–7, –1], we get

⇒ f(–1) ≤ 9
Therefore f(–1) + f(0) ≤ 20

38) The required region is shaded below :

x + y = 6 and cut at S(3,3) & P(0,6). cut at R(2, 4).

Required area = Area of curvilinear ΔOMRO + Area of trapezium MNSR – area of curvilinear

ΔONSO (area of square ONSG – area of sector OSGO)

∴ a = 9, b = 4 and c = 6

39)

Given f(f(x)) = x, x ∈ [0, 1]

and f(0) = 1
Let .........(1)
substitute x = f(y) ⇒ dx =f′(y)dy
also f(f(x)) = x ⇒ f(f(0)) = 0
⇒ f(1) = 0

.........(2)
add (1) & (2)

40)

Now,

Putting in the above result, we get

41)
∴p=π
cos–1 (cos(π –1)) = π – 1 = 2.14

42) The graph of and intersect at the 6 points (four positive and two
negative roots) as clear from the following figures:

43)

= 15

44)

an even integer

So f+g must be equal to 1, because this is the only integer

45) f(x) = cos2x etan x

f ′(x) = etan x (1 – sin 2x)
f ′′(x) = etan x (–cos 2x) (2) + (1 – sin 2x) etan x sec2 x

= f(x) (tan x – 1) (tan3x – tan2 x + 3 tan x + 1)

Let g(x) = tan3x – tan2 x + 3 tan x + 1
g ′(x) = (3 tan2 x – 2 tan x + 3) sec2x > 0

so g(x) is increasing in .

Also

g(x) has exactly one root, in

∴ f ′′(x) has exactly 2 roots in

At f ′(x) has local minima

46) zn – 1 = (z – 1) (z – z1) (z – z2).......(z – zn–1) = 0

Replace

47)

⇒
 48)
for a = 0 D = 0, Dx = 0, Dy = 0, Dz = 2 – b
so for a = 0, b = 2 ⇒ Infinite Solutions
for a = 0, b = 1 ⇒ No solution
for a = 1, D = 0, Dx = 0, Dy = 0, Dz = 0
⇒ Infinite solutions
If a ≠ 0 but a = 1 does't have unique solutions.

49)

and

50)

x1 fi fi |xi – Median|

3 8 24 96 2

9 10 90 60 80

17 12 204 24 0

23 9 207 72 54

27 5 135 60 50

Mean = , (2) Median = 17

Mean deviation about mean =

Mean deviation about median =

51) (P)
sin2x = k + 3 ; sin2x ∈ –1
0≤k+3≤1
–3 ≤ k ≤ –2

(Q) ⇒
(R)
(S) Simplyfy to get cosx = 0; cosx = –1

52) If a,b,c,d > 0 are in A.P.

then & ⇒ bc > ad

&
⇒ b2 + c2 < a2 + d2
If a,b,c,d > 0 are in G.P.

then
⇒ b+c<a+d

⇒ b2 + c2 < a2 + d2
similarly remaining results can be established.

53) (I)

(II) ƒ(x) = (a – 7) log3x + (b – 2)ex + sinx for function to be bounded a = 7; b = 2

(III) ƒ(x) = x2 + px + 10; for ƒ(x) to be even p=0

then m + n = 9
(IV) Point is are x = 2, 3

54)

(P)

(Q) asinA sinB + bcos2A =

2R[sin2AsinB + sinBcos2A] =

∴ ∴ ∴ is 3.

(R)

⇒
2sin2θ + 5sin θ – 3 = 0
⇒ (sinθ + 3)(2sinθ – 1) = 0

∴ , in [0, 7π]
No. of values of of q = 4
(S) AM ≥ HM