31072024 Class Practice Test # 02 Foundation Batch

ORGANIC CHEMISTRY
(Topic : ISOMERISM)
(for JEE-Mains & Advanced 2026)
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01. Which of the following compounds will show geometrical isomerism :
(a) Cholorocylopropane (b) 1, 1, 2 –Trichlorocycloprapane
(c) Hexachlorocyclopropane *(d) 1,2-Dichlorocyclopropane
02. Geometrical isomerism is possible in :

(a) (b) (c) *(d)

03. Which of the following can show geometrical isomerism :

*(a) (b) (c) (d)

04. and are :

(a) Enantiomers *(b) Geometrical isomers (c) conformers (d) Homologs

05. Which will not show geometrical isomerism :

(a) (b) (c) *(d)

06. Which of the following compounds will exhibit geometrical isomerism :

*(a) 1-Phenyl-2-butene (b) 3-Phenyl-1-butene
(c) 2-Phenyl-1-butene (d) 1, 1-Diphenyl-1-propene
07. Which of the following is correct :
[a] A meso isomer contains at least two chiral carbon and can rotate the plane of
plane polarized light (PPL).
[b] A racemic mixture is equimolar mixture of diastereomers and the mixture can
not rotate the plane of PPL.
[c] A meso isomer cannot rotate the plane of PPL due to absence of chiral centres.
*[d] A meso isomer is achiral due to plane of symmetry or centre of symmetry or both.

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08. Which of the following will not show geometrical isomerism :

(a) (b) (c) *(d)

09. Write correct relation between following molecules :

CH2COOH
(A) (B)
CH2COOH
(a) Position isomers (b) Chain isomers
(c) Homologus *(d) Geometrical isomers
10. Consider the following four statements
S1 : Geometrical isomers are not mirror image isomer.
S2 : A compound having double bond (restricted bond) always show geometrical
isomerism.
S3 : Acyclic compound having single bond does not show geometrical isomerism.
S4 : Cyclodecene can exist in cis & trans form.
(A) T F F T (B) T T F T (C) F F F T *(D) T F T T
11. Which of the following is Incorrect :
Me Me
H OH H F H OH
H OH
(a) HO H is chiral (b) C=C is NOTchiral (c) HO H
is chiral
Cl Br
Me Et

*(d) Me (CHOH)7 Me contains only real chiral carbons but not psuedo chiral carbon
12. Which of the following is optically active :

(a) (b) *(c) (d)

13. Which of the following compound posses plane of symmetry ?

(a) (b) *(c) (d)

Me
Me
14. H Incorrect statement about this compound is :
H
(a) it shows geometrical isomerism *(b) it posses centre of symmetry
(c) it posses plane of symmetry (d) it shows optical isomerism
15. Cis-trans isomerism is shown by :

(a) (b) (c) *(d)

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16. Examine the relation between the following pairs of compounds :
Cl
Cl HO OH
Cl
(I) and (II) OH and
Cl OH
COOH
COOH
(III) and
HOOC COOH
(a) All I, II, III are identical (b) All I, II, III are isomers
*(c) I, II are identical, III is isomer (d) I is identical and II, III are isomer
17. Column – I Column – II
F Br

(A) (P) Cis

CH3O F
F Br

(B) (Q) Trans

F OCH3
H

(C) (R) E
OCH 3
OCH3

(D) (S) Z
OCH3
(a) (A  P,R), (B  R,S), (C  Q,S), (D  P,S)
(b) (A  Q,S), (B  R,S), (C  P,R), (D  P,S)
*(c) (A  Q,S), (B  P,R), (C  P,R), (D  P,S)
(d) (A  P,S), (B  P,R), (C  Q,S), (D  P,Q)
18. The no. of optically active isomers of

and are :
Cl Br Cl Cl
(a) 4, 3 (b) 2, 2 (c) 2, 0 *(d) 4, 2
19. Which of the following have same configuration :

(I) (II) (III)

*(a) I & II (b) II & III (c) I & III (d) all
20. In the following structure, the double bonds are marked as I II, III and IV

Geometrical isomerism is not possible at site (s) :

*(a) I (b) III (c) I and III (d) I and IV
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Integer Type #
21. Chiral centres present in the given structure (Tetracycline) will be :

Ans : 4

22. Calculate the number of chiral centre in the molecule Ethyl 2,2-dibromo-4-ethyl-6-
methoxy cyclohexane carboxylate. Ans : 2
23. The number of isomers for the compound with molecular formula C2BrClFI is.
Ans : 6
24. How many structural isomers of C5H10 will show geometrical isomerism : Ans : 2
25. Number of the following compounds which can show geometrical isomerism is:

(i) (ii) (iii)

(iv) (v) (vi)

(vii)

Ans : 4
26. How many geometrical isomers are possible for the given compound ?
Ph – CH = CH – CH = CH – COOH
Ans : 4
27. How many geometrical isomers of CH3 CH = CH – CH = NOH exist ?

Ans : 4
28. Find out the total number of stereocentres in the given compound.

Ans : 4

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