01-06-2025

7501CJA101001250029 JA

PHYSICS

Section-I(i)

1) x–t graph for a uniformly accelerated motion is as shown in the figure. Then find the average

velocity between points J and K

(A) 3m/s
(B) 2m/s
(C) 4 m/s
(D) 1.5 m/s

2) A particle is acted upon by force F = F0cos(ωt) along X-axis. The amplitude of its velocity is given

by . Choose the correct condition for resonance. (At the time of resonance
velocity of particle is maximum) & X, Y, Z are constant :-

(A) Y2 = XZ
(B) Z2 = XY
(C) Y2 = 4XZ
(D) X2 = YZ

3) Having gone through a plank of thickness h, a bullet changed its velocity from v0 to v. Find the
time of motion of the bullet in the plank, assuming the resistance force to be proportional to the
square of the velocity.

(A)

(B)

(C)

(D)
4) For shown graph magnitude of acceleration of particle at point P is

(A) units

(B)
units
(C) units
(D) can't determined

Section-I(ii)

1) The velocity-time graph of a particle in one-dimensional motion is shown in figure. Which of the
following formulae is/are correct for describing the motion of the particle over the time-interval t1 to

t2, where x & a denotes position and acceleration of particle:-

(A)
x(t2) = x(t1) + v(t1)(t2 – t1) + a(t2 – t1)2
(B) v(t2) = v(t1) + a(t2 – t1)

(C)

(D)

2) The navigator of a ship can determine his position relative to a fixed point, such as a lighthouse.
Figure shows the (straight) track of a ship passing by a lighthouse. At the point P, the navigator
measures the angle a between the line of sight to the lighthouse and the direction of motion of ship.
He then measures how far the ship has advanced through the water until the angle between the line
of sight and the direction of motion is twice as large as it was initially.

Relative to another fixed lighthouse the displacement vector is same as the displacement vector
(A)
relative to first lighthouse
Relative to another fixed lighthouse the magnitude of displacement vector is two times the
(B)
magnitude of displacement vector relative to first lighthouse
The magnitude of the displacement vector equals to two times the magnitude of the final
(C)
position vector of the ship relative to the lighthouse.
The magnitude of the displacement vector equals to the magnitude of the final position vector
(D)
of the ship relative to the lighthouse.

3) An experimental rocket starts vertically from rest with a constant upward acceleration during
flight a small piece detaches at 1s from start and rocket engine shuts at 5s from start. The detached
small piece falls to ground 2s after it is separated from rocket. Identify the correct statements :-

(A) Upward acceleration of rocket is 8 m/s2

(B) Height of rocket is 100 m above starting position when rocket engine shuts.
(C) Maximum height reached by rocket is 180 m.
(D) Total time of flight for rocket to fall down is 15 sec.

4) Which of the following statement are true for a moving body?

(A) If its speed changes, its velocity must change and it must have some acceleration.
(B) If its velocity changes, its speed must change and is must have some accelerations.
(C) If its velocity changes, its speed may or may not of change, and it must have some acceleration.
(D) If its speed change but direction of motion does not change, its velocity may remain constant.

Section-I(iii)

1) Velocity-time graph of particle moving along a straight line is shown in figure. Find suitable
match(s) between the two rows.

List I List II
(A) (P)

(B) (Q)

(C) (R)

(D) (S)

(T) Greatest displacement

(A) A → P,Q;B → Q,R;C → R,S;D → S,T
(B) A → P,S;B → P,S;C → R,T;D → S,T
(C) A → P,S;B → P,S;C → P,Q;D → P,T,R
(D) A → P,S;B → Q,R;C → P,S;D → P,T,R

2) Find suitable match between two rows.

List-I List-II
 (A) (P) Acceleration ∝ v

(B) (Q) Acceleration ∝ t

(C) (R) Acceleration is uniform

(D) (S) Acceleration is non uniform

(A) A → R;B → S;C → P;D → Q

(B) A → R;B → R;C → S;D → P,S
(C) A → P;B → Q;C → R;D → S
(D) A → S;B → R;C → Q;D → P

3) Displacement-time curve of a particle moving along a straight line is shown in figure

List-I List-II

less than instantaneous

(A) Average velocity is (P)
velocity
 (B) Initial velocity is (Q) constant

(C) Acceleration is never (R) less than zero

If AB part is parabolic
(D) then acceleration of particle (S) greater than zero
in this part is
(A) A → P;B → Q,S;C → R;D → Q,S
(B) A → P;B → Q, R;C → S;D → R
(C) A → P,Q;B → R;C → S;D → P
(D) A → R;B → S;C → P;D → Q,S

4) Two teams TOM and JERRY run a relay race along the path ABCDEF. B,C,D and E are check
points where runners of different abilities are stationed. In the relay race when a player reach to the
check point then other player of the same team starts running from that check point to the next

check point. The graphs of

motion between two check points for two teams are shown below :
Then match the enteries of List-I with enteries of List-II
List-I List-II

Path(s) for which both teams will

(A) (P) A B
take same time

Path(s) for which team “TOM” will

(B) (Q) B C
take more time than team “JERRY”

(C) Shortest path(s) (R) C D

Path(s) for which average speed of

(D) team “TOM” is more than team (S) D E
“JERRY”
 (T) E F
(A) A → P;B → Q, R;C → R, S;D → S,T
(B) A → S, T;B → Q,R;C → P,S;D → P, Q
(C) A → S;B → Q, T;C → P, S;D → P, R
(D) A → T;B → Q,S;C → P;D → R

Section-II

1) A helicopter takes off along the vertical with an acceleration of 3 m/sec² & zero initial velocity. In
a certain time, the pilot switches off the engine. At the point of takeoff, the sound dies away in 30
sec. Determine the velocity of the helicopter at the moment when its engine is switched off,
assuming the velocity of sound is 320 m/sec.

2) A particle is moving with uniform acceleration along x-axis with initial velocity along positive x. At

t= s the magnitude of displacement becomes the total distance travelled. By this time the x
coordinate of particle is still positive. The instant (in sec) at which displacement becomes zero is

3) Two trains are moving in opposite direction on same track. When their separation was 600 m
their drivers notice the mistake and start slowing down to avoid collision. Graphs of their velocities
as function of time is as shown. If separation between the drivers when first train stops is x then find

the value of .

4)
Two particles 1 and 2 move along the x axis. The position (x) - time (t) graph for particle 1 and
velocity (v) - time (t) graph for particle 2 has been shown in the figure. Find the time when the two
particles collide. It is given that x0 = ut0, and that the particle 2 was at origin at t = 0 &

5) A car manufacturer usually tells a optimum speed (V0) at which the car should be driven to get
maximum mileage. In order to find the optimum speed (in km/hr.) for a new model, an engineer of
the car company experimented a lot and finally plotted a graph between the extreme time t (defined
as number of hours a tank full of petrol lasts) vs the constant speed V at which car was run.

Calculate the optimum speed V for this new model.

6) A particle moves in a straight line with constant acceleration 'a'. The displacements of particle
from origin in times t1, t2 and t3 are 1m, 2m and 4m respectively. If times are in A.P. with common
difference of 1 sec, find acceleration of particle.

CHEMISTRY

Section-I(i)

1) When electron in a hydrogen atom is excited then which of the following increases ?

(A) Radius of orbit

(B) Time period of revolution
(C) Angular momentum
(D) All of these

2) Assuming Heisenberg Uncertainty Principle to be true what could be the minimum uncertainty in
de-brogile wavelength of a moving electron accelerated by Potential Difference of 6V whose

uncertainty in position is

(A) 6.25 Å
(B) 6 Å
(C) 0.625 Å
(D) 0.3125 Å

3) According to Maxwell's theory of electrodynamics, an electron going in a circle should emit

radiation of frequency equal to its frequency of revolution. What should be the wavelength of the
radiation emitted by a hydrogen atom in the ground state if this rule is followed?

(A) 4500 nm
(B) 450 nm
(C) 45 nm
(D) 4.5 nm

4) Pure FeS2 is burnt with air in which O2 is 60% by volume is more as that of required. What is the
percentage of N2, by volume, in the gaseous mixture after the reaction? Air contains 20% O2 and
80% N2 by volume.
(Given: FeS2 + O2 → Fe2O3 + SO2(g))

(A) 60.9
(B) 82.8
(C) 70.4
(D) 50.3

Section-I(ii)

1)

An elements has three isotopes X20 , X21 and X22. Percentage abundance (mole %) of X20 is 90 and
average atomic mass of X is 20.18. Select correct option(s) -

(A) Percent abudance of X21 = 8%

(B) Percent abudance of X21 = 2%
(C) Percent abudance of X22 = 8%
(D) Percent abudance of X22 = 2%

2) When photons of energy 4.25 eV strike the surface of a metal 'A', the ejected photo electrons if
maximum kinetic energy have wavelength λA. The maximum kinetic energy of photoelectrons
liberated from another metal 'B' by photons of energy 4.7 eV is 1.5 eV less than that of photo
electrons of metal A. If wavelength of photo electrons of metal B is twice than that of photoelectron
of 'A' then

(A) Work function of A = 2.25 eV

(B) Work function of B = 4.2 eV
(C) Maximum (K.E.) of photoelectrons of 'A' = 2 eV
(D) Maximum (K.E.) of photoelectrons of 'B' = 3.5 eV

3) 1st excitation potential for the H-like (hypothetical) sample is 24 V. Then :

(A) Ionisation energy of the sample is 36 eV

(B) Ionisation energy of the sample is 32 eV
(C) Binding energy of 3rd excited state is 2 eV

(D)
2nd excitation potential of the sample is V

4) An α-particle having kinetic energy 4.0 MeV is projected towards tin nucleus (Z = 50). Select the
correct information(s) regarding the α-particle.

(A) Its distance of closest approach towards the nucleus is 3.6 × 10−14 m.
(B) Its potential energy at a distance of 9.0 × 10−14 m from the nucleus is 1.6 MeV.
(C) Its kinetic energy at a distance of 4.5 × 10−14 m from the nucleus is 0.8 MeV.
(D) At a moment, the distance between α-particle and the nucleus becomes 2.0 × 10−16 m.

Section-I(iii)

1)

In a mixture, 50 ml, 0.12 M Fe(NO3)3, 100 ml, 0.1 M FeCl3 and 100 ml, 0.26 M Mg(NO3)2 are mixed.
For this solution find correct match.

List-I List-II
(Ion) (Molarity)

(P) [Fe+3] (1) 0.104

(Q) [Mg+2] (2) 0.12

(R) [Cl–] (3) 0.064

(S) [NO3–] (4) 0.28

The correct option is
(A) P → 3;Q → 1;R → 2;S → 4
(B) P → 1;Q → 2;R → 3;S → 4
(C) P → 3;Q → 4;R → 2;S → 1
(D) P → 2;Q → 4;R → 1;S → 3

2) Match the entries in Column I with entries in Column II and then pick out correct options.

Column I Column II

(P) (1) Moles of gas = 2.4

(Q) (2) Volume of gas at NTP = 53.76 L

(R) (3) Moles of reactant (left) = 1.8 mol

(S) (4) Moles of solid product = 1.8 mol

(A) P → 1;Q → 4;R → 2;S → 3;T → 2;U → 3;V → 1;W → 2;X → 3

(B) P → 3;Q → 4;R → 3;S → 4;T → 2;U → 4;V → 1;W → 2
(C) P → 1;Q → 2;R → 3;S → 4;T → 1;U → 2;V → 1;W → 2;X → 1;Y → 2
(D) P → 1;Q → 2;R → 4;S → 1;T → 2;U → 3;V → 2;W → 1;X → 2;Y → 3

3)

Given x = % increase in volume due to reaction at constant pressure & temperature

M1 = Theoretical molar mass before reaction starts
M2 = Observed molar mass of gaseous mixture after complete reaction
D1 = Theoretical vapour density before reaction starts
D2 = Observed vapour density of gaseous mixture after complete reaction

List-I
List-II
(Extent of reaction = 100%)

(P) (1) x = 25%

NH3(g) —→ N2(g) + H2(g)

(Q) (2) x = 100%

SO3(g) —→ SO2(g) + O2(g)

(R) PCl5(g) —→ PCl3(g) + Cl2(g) (3) x = 50%

(S) (4) M1 > M2

HCl(g) —→ H2(g) + Cl2(g)

(5) D1 = D2

Considering list-I and list-II select CORRECT combination

(A) P → 1;Q → 2;R → 5;S → 4
(B) P → 2;Q → 3;R → 4;S → 5
(C) P → 3;Q → 1;R → 2;S → 4
(D) P → 2;Q → 1;R → 2;S → 3

4) If longest wavelength of Balmer series of hydrogen atom is x nm, then :

List-I List-II

Approximate energy difference of 3rd and Ist

(I) (P)
orbit of H-atom

Wavelength of first line of Paschen series of H-

(II) (Q)
atom

Approximate energy difference of 4th and 2nd

(III) (R)
orbit of H-atom

Wavelength of series limit of Lyman series of H-

(IV) (S)
atom
(A) I → Q;II → P;III → S;IV → R
(B) I → S;II → R;III → Q;IV → P
(C) I → R;II → P;III → S;IV → Q
(D) I → Q;II → R;III → S;IV → P

Section-II

1) The formula of the magnesium salt of a monobasic acid is MgA2.nH2O (HA is the formula of the
acid). 1 gram of the salt on strong heating leaves behind 0.2 gram of MgO. Given that the molecular
mass of the acid is 62. What is the value of (10 × n) ?
2) An amount of 5 moles of A, 6 moles of B and excess amount of C are mixed to produce a final
product D, according to the following reactions. A + 2B → I
I+C→B+D
What is the maximum moles of D, which can be produced assuming that the products formed can
also be reused in the reactions?

3) A metal oxide has a formula X2O3. It can be reduced by hydrogen to give free metal and water.
0.1596 g of metal oxide requires 6 mg of H2 for complete reduction. The atomic mass of metal is x

amu find the value of :

4) A metal surface is exposed to 500 nm radiation. The threshold frequency of the metal for
photoelectric current is 4.4 × 1014 Hz. The velocity of ejected electron is ________× 105 ms–1 (Nearest
integer)
[Use : h = 6.63 × 10–34 Js, me = 9.0 × 10–31 kg]

5) Light from a discharge tube containing H-atoms is some excited state, falls on the surface of
sodium metal. The kinetic energy of the fastest photoelectron was found to be 10.93 eV. If He+ ions
were present in the same excited state, the kinetic energy of the fastest photoelectron would have
been 49.18 eV. If the excited state orbit number (n) and work function of Na (in eV) is (m) then find
500(n+m)

6) The circumference of third orbit of a single electron species is 3 nm. What may be the
approximate wavelength (in nm) of the photon required to just ionize electron from this orbit.
(Given:- hc = 1240 eV.nm, Bohr radius for H atom = 0.53 Å)

MATHEMATICS

Section-I(i)

1) The set of values of ‘a’ for which f(x) = ax2 + 2x(1 – a) – 4 is negative for exactly three integral
values of x, is

(A) (0, 2)
(B) (0, 1]
(C) [1,2)
(D) [2, ∞)

2) Let f(x) = x2 + px + q and g(x) = x2 + rx + s where real roots of f(x) = 0 are α, β and real roots of

g(x) = 0 are α + δ, β + δ such that minimum value of f(x) be and least value of g(x) occurs at

then correct option is –

(A)
Least value of g(x) is

(B)
Least value of g(x) is
(C) Roots of the equation g(x) = 0 are 3, 4
Roots of the equation g(x) = 0 are
(D)

3) Number of integral values of x satisfying the inequality

(A) 2
(B) 4
(C) 6
(D) 8

4) If complete solution of the inequality ≥ 0 is [a,b)∪[c,d] then a+b+c+d =

(A) –2
(B) 2
(C) 4
(D) None of these

Section-I(ii)

1) If x2 + 3x + 5 is the greatest common divisor of (x3 + ax2 + bx + 1) and (2x3 + 7x2 + 13x + 5)
(where a,b ), then the value of (a + b) is greater than or equal to-

(A) 7
(B) 8
(C) 9
(D) 10

2) If a, b, c are rational numbers ( a > b > c > 0) and quadratic equation (a + b – 2c) x2 + (b + c –
2a) x + (c + a – 2b) = 0 has a root in the interval (-1,0) then which of the following statement (s)
is/are correct ?

(A) a + c < 2b
(B) both roots are rational
(C) ax2 + 2bx + c = 0 have both roots negative
(D) cx2 + 2bx + a = 0 have both roots negative
3) Let α, β (α > β) be the roots of equation , define . Which of
the following holds?

(A)
(B)

(C)

(D)

4) Let . If α and β are roots of equation f(x) = 0,

then the value of is equal to

(A) 0
(B)
(C)

(D)

Section-I(iii)

1) Let P(x) = x5 + x2 + 1 has zeros α1,α2,α3,α4,α5 and Q(x) = x2 – 2, then match List-I with List-II :

List-I List-II

(I) (P) 20

(II) (Q) –23

(III) (R) 40

(IV) (S) –10

(T) 15
(A) I → Q;II → S;III → R;IV → P
(B) I → T;II → Q;III → R;IV → P
(C) I → R;II → P;III → T;IV → Q
(D) I → Q;II → S;III → P;IV → T

2) Consider the equation (k + 2)x4 – (k – 1)x2 + (k – 1) = 0 (where k ∈ R) Match List-I with List-II and
select the correct answer using the code given below the list.
 List-I List-II
(I) has no solution if (P)
(II) has one solution if (Q) k=1
(III) has two solutions if (R)
(IV) has four solutions if (S)
(A) I → P;II → Q;III → S;IV → R
(B) I → R;II → Q;III → S;IV → P
(C) I → R;II → Q;III → P;IV → S
(D) I → S;II → R;III → Q;IV → P

3)

Column - I Column - II

(A) (P)
Set of all values of x satisfying the inequation is

Set of all values of x satisfying the inequation

(B) (Q)
is

(C) (R)
Set of all values of x satisfying the inequation is

(D) (S)
Set of all values of x satisfying the inequation is

(T)
(A) A → R;B → T;C → Q;D → P
(B) A → P;B → Q;C → R;D → S
(C) A → Q;B → P;C → R;D → S
(D) A → S;B → R;C → P;D → Q

4)
Consider the function

Column - I Column - II

(A) If has no solution, then (P) (2, 4)

(B) If has one solution, then (Q) (–∞, –2) ∪ (4, ∞)

(C) If has two solution, then (R) (–2, 2) ∪ {4}

(D) If has more then two solution, then (S) {–2, 2}

(A) A → P;B → Q;C → R;D → S

(B) A → Q;B → R;C → P;D → S
(C) A → R;B → S;C → Q;D → P
(D) A → S;B → R;C → P;D → Q
 Section-II

1) If 2n(A\B) = n(B\A) and 5n(A ∩ B) = n(A) + 3n(B), where P\Q = P∩Qc.

If n(A ∪ B) = 10, then the value of is

(where n(X) denotes the cardinal number of set X)

2) If both roots of the equation are smaller than 5, then the largest
integral value of k is

3) Let P(x) = a0 + a1x + ...anxn be a polynomial with integer coefficients and ai ∈ {0,1} for all i = 0,
1,2,...n

Given , then the value of P(1) is :

4) Let be roots of x2 − 6(5t2 − 3t + 7)x − 2 = 0 with

then the minimum value of is λ then 10λ is equal to

5) If x1 is the integral solution of the equation then the value of x12 is

6) The sum of all the elements in the set | H.C.F. of n and 2040 is 1} is equal
to _______.
 ANSWER KEYS

PHYSICS

Section-I(i)

Q. 1 2 3 4
A. B C C A

Section-I(ii)

Q. 5 6 7 8
A. C,D A,D A,B,C,D A,C

Section-I(iii)

Q. 9 10 11 12
A. C B A C

Section-II

Q. 13 14 15 16 17 18
A. 80 12 7 1 80 1

CHEMISTRY

Section-I(i)

Q. 19 20 21 22
A. D C C B

Section-I(ii)

Q. 23 24 25 26
A. B,C A,B,C B,C,D A,B,C

Section-I(iii)

Q. 27 28 29 30
A. A C B A

Section-II

Q. 31 32 33 34 35 36
A. 30 5 10 5 2910 821

MATHEMATICS
 Section-I(i)

Q. 37 38 39 40
A. C C D A

Section-I(ii)

Q. 41 42 43 44
A. A,B A,B,C,D A,B,C A,B,D

Section-I(iii)

Q. 45 46 47 48
A. A C A B

Section-II

Q. 49 50 51 52 53 54
A. 7 3 6 393 4 1251
 SOLUTIONS

PHYSICS

1)

2) At resonance v will be maximum, tending to infinity. So term in the denominator i.e.

will tend to zero (minimum).

3) F = kv2
4) From graph slope =

so At point P,

Acceleration a =

5) is NOT constant
(A) & (B) are valid only for constant acceleration

6)

7)
at t1 = 1 sec
v1 = 0 + a(1)

h1 = 0 +
small piece that detaches has initial speed = v1 = (a)
and acc. = –g

also, its displacement to ground is –h1 = v1(2)

⇒ a = 8 m/s2
at t2 = 5 sec
v2 = 0 + a(5) = 40 m/s

& h2 = 0 +
so, displacement to fall down will be – 100 m also, + 40 m/s will become initial velocity and
acceleration = –g

– 100 = (+40)(t) –
⇒ t = 10 sec
hence, total time of flight = 15 sec.
Now for maximum height, v = 0
from t2 = 5 sec
acceleration = –g
02 = (40)2 – 2gh
h = 80 m above h2
⇒ hmax = 180 m

8)

In case of uniform circular motion speed constant but velocity changes.

9) (A) → (P,S) ; (B) → (P,S) ; (C)→ (P,Q) ; (D)→ (P,T,R)

10) For (A), v2 ∝ x ⇒ Acceleration = constant,

For (B), v ∝ t ⇒ = constant

For (C), v ∝ t2 ⇒ ∝ t,

For (D), v ∝ x ∝v

11)

Average velocity = slope of Secant

12) AB→

BC→
CD→

DE→

EF→

13)

Lets say at height engine was switched off.

so 30 sec = t1 + t2
t1 → for reaching helicopter to height h
t2 → Last sound emitted by engine to reach ground.

So for velocity when engine was switched off.

v2 = u2 + 2as

14)

(distance) = displacement

so answer is 2t1 = 12
15)

d2 = 288 (t = 0 – t = 8)
=200

16)

x co-ordinate of particle 1 at time 't' is

......(i)
[This is the equation of the straight line given in the question]
For particle 2.

Acceleration =
x co-ordinate at time 't' is

....(ii)
Since t cannot be larger than t0

17)

Equation of the line given in graph is

....(1)
When car moves at constant speed V for time t, it will cover a distance

. ...(2)
Graph of X vs V is parabolic as shown
X is maximum for V = 80 km/hr–1 [∵ parabola is symmetric curve and vertex will lie midway
between
V = 10 and V = 150
For V = 80, value of X is

18)

Velocity-time graph of the particle is as shown below :

Area under v - t graph gives the displacement hence

S2 - S1 = area BCNM

BENM ....(1)
s3 - s2 = area CDPN

...(2)
(1) - (2) gives :
2s2 - s1 - s3 = -y.d
or
 or

or slope of line AD
=acceleration

∴ acceleration of particle

CHEMISTRY

19)

An excitation,
(A)
∴

(B)

(C) Angular momentum

20) .... (i)

.... (ii)

.... (iii)

= 0.625 Å

21)

Frequency of EMR = Frequency of revolution

22)

4FeS2 + 11O2 → 2Fe2O3 + 8SO2(g)

4 mole (say) 11 mole 8 mole
Final composition of gases:

O2 = 11 × = 6.6 mole

N2 = (11 + 6.6) × = 70.4 mole

SO2 = 8.0 mole
∴ Total moles of gases = 6.6 + 70.4 + 8.0 = 85

∴ Volume per cent of N2 = × 100 = 82.82%

23)

X20 = 90%

X21 = x%
X22 = (10 – x)%

x = 2%
X21 % = 2 %
X22 % = 8%

24) ....... (i)

....... (ii)
....... (iii)
....... (iv)

....... (v)

KEA = 2eV
∴

25)

1st excitation potential = 10.2 Z2 = 24 V

∴ Z2 = 24/10.2

∴ IE = 13.6 Z2 = = 32 eV.

Binding energy of 3rd excited state = 0.85 Z2 = = 2eV.

2nd excitation potential of sample = 12.09 Z2 = = V.

26)

(a) (K.E.)initial = (P.E.)at distance of closest approach

or 4.0 MeV = K.

or, 4 × 106 × 1.6 × 10–19

= 9 × 109 ×

∴ Distance of closest approach, r = 3.6 × 10–14 m

(b) P.E. = K.

= 9 × 109 ×

= 1025 × (1.6 × 10–19)2 J

= = 1.6 MeV

(c) P.E. = K .

=
= 3.2 MeV

∴ K.E. of α-particle at this distance

= 4.0 –3.2 = 0.8 MeV

27)
28)

29)

(I)
initially 1

Finally 0

x= × 100 = 100%

M2 = Mavg = = = 8.5
M1 = 17

(II) SO3(g) → SO2(g) +

initially 1 mole

Finally 0 1
M2 = Mavg =
M1 = 80

(III) PCl5(g) → PCl3(g) + Cl2(g)

t=0 1 mole
t=t 0 1 mole 1 mole

M2 = Mavg =
M1 = 208.5

(IV) HCl(g) → +
t=0 1 mole

t=t 0 mole mole

M2 = Mavg =
M1 = 36.5

30)

(P)

(Q)

(R)

(S)

31) Mg(OH)2 + 2HA → MgA2.nH2O MgO

1g 0.2g
Apply POAC on Mg
n=3

32)

A + 2B → I
I+C→B+D
A+B+C→D
5 6 excess x

x = 5 mol.

33) X2O3 + 3H2 → 2x + 3H2O

1 mol 3 mol
(2a + 48g) 6g
0.006 g H2 is required by 0.1596g oxide 6gH2 will be required by 159.6g oxide
2a + 48 = 159.6
a = 55.8

34)

υ : speed of electron having max. K.E.

⇒ from Einstein equation : E = ϕ + K.E.max

35)

where x is work function.

Solving: n = 4, m = 1.82 eV
∴ 500 (m+n) = 500 (4+1.82) = 2910

36)
 z=1

MATHEMATICS

37)

38) ...(1)

39)

(x –1)(x – 8)

40)

If x + 1 > 0 ⇒ x ∈ (–1, ∞) ....(i)

21 – 4x – x2 ≤ 1 ....(ii)
also 21 – 4x – x2 ≥ 0 ⇒ x2 + 4x – 21 ≤ 0
(x + 7) (x – 3) ≤ 0
x ∈ [–7, 3] ...(iii)
2
x + 4x – 20 ≥ 0
x ∈ (–∞, –2 – )∪
(i) ∩ (ii) ∩ (iii)

x2 + 4x – 20 0
41) 2(x3 + ax2 + bx + 1) – (2x3 + 7x2 + 13x + 5)
= (2a – 7)x2 + (2b – 13)x – 3
Now, (2a – 7)x2 + (2b – 13)x – 3 = 0.
and x2 + 3x + 5 = 0 have both roots
common,

Hence, and
⇒ [a + b] = 8

42)

f(1) = 0 another root is

Which is rational

again
a + c < 2b & b + c < 2a
Let f(x) = ax2 + 2bx + c
f(x) > 0 for all x > 0
f(0) = c >0
f(–1) = a - 2b + c < 0
both roots are negative

43)

Similarly
substracting we have

(so T(n) forms Fibonacci sequence)

44) ......... (i)

......... (ii)
by (i) & (ii)

(A)

(hence A)
(B) (hence B)

(D)

45) α1, α2, α3, α4, & α5 are roots of this equation x5 + x2 + 1 = 0
put y = x2 – 2
x2 = y + 2
Equation becomes
(y + 2)2x + y + 3 = 0
⇒ (y + 2)4(y + 2) = (y + 3)2
⇒ y5 + 5.y4 × 2 + 10 × y3 × 4 + 10 y2 × 8 + 5y × 16 + 32 = y2 + 6y + 9
⇒ y5 + 10y4 + 40y3 + 79y2 + 30y + 23 = 0
has roots α12 – 2, α22 – 2, ..., a52 – 2

Now

2
46) Take x = t
(k + 2)t2 – (k – 1)t + (k – 1) = 0
let roots be α, β
(I) for no solution take D < 0 or

(II) for one solution take α + β < 0 & αβ = 0

(III) for 2 solutions take

(IV) for 4 solutions, take

α ≠ β, but α, β > 0
⇒ D > 0, α + β > 0 and αβ > 0

47)

Conceptual

48)
Graph of

49)
2(n (A) – n(A ∩ B)) = n(B) – n(A ∩ B)
2n(A) – n(B) = n(A ∩ B)
n(A) + 3n(B) = 5n(A ∩ B)
⇒ n(A) + 3n(B) = 10n(A) – 5n(B)
8n(B) = 9n(A)

n(A) = 8k; n(B) = 9k

⇒ n(A ∩ B) = 7k
n(A ∪ B) = 10k = 10
k=1

50) .....(1)
...(2)

...(3)
From 1, 2, 3 k<4

51)

a0 + 2a2 + 22a4 +... = 13 ...(1)

2
a1 + 2a3 + 2 a5 +... = 19 ...(2)
By comparing a0 = 1, a4 = 1, a6 = 1
and a2 = a8 = a10 = 0
a1 + 2a3 + 22a5 + 23a7 + 24a9+... = 19
⇒ a1 = a3 = a9 = 1 and
a5 = a7 = a11 = a13 = 0
P(x) = 1 + x + x3 + x4 + x6 + x9

52)
Put n = 98

Minimum value is λ =

53)
Case I

Not positive
Case 2
x<–1

x2 = 4

54)
n should not be multiple of 2, 3, 5 and 17.
Sum of all n = (1+3+5+....+99)
(3 + 9 + 15 +....+99) (5 + 25 + 35 + .... + 95) (17)
=2500 867 365 17
= 1251.