18-05-2025

NSPJEEEITSTEST02 JA

PART-A-PHYSICS

SECTION-I(i)

1) If block m remains at rest in the frame of wedge find value of m1. Given that all the surfaces are

smooth and pulley and strings are ideal.

(A)

(B)

(C)

(D) any value of m1

2) A plank is held at an angle α to the horizontal (fig.) on two fixed supports A and B. The plank can
slide against the supports (without friction because of its weight Mg). Acceleration and direction in
which a man of mass m should move so that the plank does not move?

(A) g sin α down the incline

(B) g sin α down the incline

(C) g sin α up the incline

(D) g sin α up the incline

3) For a spherical charge distribution potential varies with radial distance as V = ar2 + b, Where a
and b is positive constants. The charge density of arrangement is
(A) variable with radial distance and negative in nature
(B) constant with radial distance and negative in nature
(C) variable with radial distance and positive in nature
(D) constant with radial distance and positive in nature

4)

A ball is projected up from a point on an inclined plane of inclination 37°. Initial velocity of ball is 20
m/s at 53° from the incline plane. Range of the projectile along the plane is (see figure) :-

(A)

(B) 50 m
(C) Zero
(D) 70 m

5) The x coordinate of an object is given as a function of time by x = 4t2 – 3t3, where x is in meters
and t is in seconds. Its average acceleration over the time interval from t = 0 to t = 2s is

(A) – 4 m/s2
(B) 10 m/s2
(C) – 10 m/s2
(D) – 13 m/s2

6) Velocity and acceleration of a particle at some instant of time are m/s and
m/s . Then, the speed of the particle is .............. at a rate of ............ m/s2. Which of
2

the following sets of information best suits for the blank spaces?

(A) increasing, 2
(B) decreasing, 2
(C) increasing, 4
(D) decreasing, 4

SECTION-I(ii)

1) Two blocks having masses m1 and m2 are connected by a thread and are placed on an inclined
plane with thread loose as shown in figure. Let μ1 & μ2 are friction coefficients between the blocks &
plane respectively. When the blocks are released :
(A) Thread will remain loose if m1 < m2
(B) Thread will remain loose if μ1 = μ2 ≠ 0
(C) Thread will remain loose if μ1 = 0 and μ2 ≠ 0
(D) Thread will remain loose if μ1 ≠ 0 and μ2 = 0

2) Two blocks with masses M1 and M2 of 10kg and 20kg respectively are placed as in figure where μs
= 0.2 between all surfaces, then tension in string and acceleration of M2 block will be :-

(A) 250 N
(B) 3 m/s2
(C) 200 N
(D) 6 m/s2

3) For the system shown in figure, all the pulleys are light and frictionless and strings are ideal.
Initially the system is held at rest by some external means. Now the system is released i.e., external
effect has been removed, but still it has been observed that 10 kg and 5 kg blocks are not moving.

This is possible when for

(A) m1 and m2 are both equal to kg

(B) sum of m1 and m2 is 5 kg

(C) many possible values of m1 and m2

(D) harmonic mean of m1 and m2 is kg

4) A stationary electric dipole = p is situated at origin. A positive charge q, mass m executes

circular motion of radius s at constant speed in the field of the dipole. Characterize the plane of orbit
is :-
 The speed of charge particle is v =
(A)

The speed of charge particle is v =

(B)

Angular momentum of charge is L =

(C)

(D) Angular momentum of charge is L =

5) A non-conducting solid sphere of radius 30 cm and relative permittivity 1 has the volume charge

density , where r (in cm) is the radial distance of any point in the space
from the centre of the sphere. Then choose the correct statement(s):

(A) Density of electric field lines is maximum at r = 25 cm

(B) Density of electric field line is maximum at r = 20 cm
Electrical energy stored in the space r = 30 cm to r → ∞, is same as that of a solid non
(C) conducting sphere carrying charge of 0.0225 μC and radii 30 cm having uniform volume charge
density in the same space r = 30 cm to r → ∞.
Variation of magnitude of electric field due to the sphere with respect to radial distance r is
(D)
rectangular hyperbola in the region r = 30 cm to r → ∞.

6) Three concentric conducting spherical shells have radii r, 2r and 3r and charge q1, q2 and q3

respectively as shown in the figure. Select the correct alternatives

(A)

(B)

(C)

(D)

SECTION-III
1) In the given figure a half ring with variable charge density in y – z plane is shown. At point A, a
small dipole (P = dipole moment) is rotated from + x direction to +z direction. The work done is
. Find x.

2) Figure shows a cylindrical conducting rod of diameter d and length ℓ >> d is uniformly charged
in vacuum such that electric field near its surface and far from its ends is E0. Electric field at r >> ℓ
on the axis of the cylinder is . Then find the value of N.

3) A board is being moved with a constant velocity v0 on a smooth horizontal plane. A small block is
projected on the rough boards. Coefficient of friction between board and block is μ = 0.3. Block is
projected with velocity v1 = 25 m/s at an angle of θ = 37° relative to ground. What is the velocity of

block (in m/s) relative to ground after time t = 10 sec.

4) The velocity of a particle traveling in a straight line is given by v(t) = 5 – 6e–t/2 m/s, where time t is
in seconds and t ≥ 0. If the particle is observed at x = 7m at the instant t = 0, its position x is

expressed as function of time Find numerical value of .

5) A retarding force is applied to a body moving in a straight line so that during an interval of its

motion, its speed v decreases with increased coordinate s according to the relation , where k
is a constant. If the body has a forward speed of 2 m/sec and its coordinate is 9 m at time t = 0,

determine the speed v at . Fill 2v in OMR sheet.

PART-B-CHEMISTRY

SECTION-I(i)
1) The compound A decomposed (A → product) by first order kinetics. If the concentration of A
dropped from 0.1 M to 0.05 M in 30 minutes, find the rate of reaction after 60 minutes, from start, in
M min–1

(A)

(B)

(C)

(D)

2) The reaction Cis-X trans-X is 1st order in both direction. At 25ºC the equlibrium
constant is 0.10 and the rate constant Kf = 3 × 10–4 sec–1. In an experiment starting with the pure cis
form, how long would it take for half of the equilibrium amount of the trans isomer to be formed -

(A) 150 sec.

(B) 200 sec.
(C) 240 sec.
(D) 210 sec.

3) A saturated solution of sparingly soluble salt MCl2 has vapour pressure of 29.97 torr while pure
water has a vapour pressure of 30 torr at the same temperature. If the solubility product of salt MCl2
is 2.54 × 10–x then value of x is-

[Given : = 6.35 × 10–6, density of solution = 1gm/ml]

(A) 4
(B) 5
(C) 2
(D) 6

4)

Match the List :

List - I List - II

(P) (1) Enantiomers

(Q) (2) Diastereomers

(R) (3) Identical

(S) (4) Geometrical isomer

(A) P-1 Q-2,3 R-4 S-2

(B) P-2 Q-1 R-2,3 S-4
(C) P-3 Q-1 R-2 S-1
(D) P-2 Q-1 R-1,4 S-3

5)

Identify Z in the following series of chemical reactions.

(A) C2H5I
(B) CH3I
(C) CHI3
(D) CH3CHO

6) ; The product A is -

(A)

(B)

(C) Me COOH + MeCOOH

(D) None

SECTION-I(ii)

1) According to the Arrhenius equation:

In Arrhenius equation, factor e–Ea/RT corresponds to fraction of reactant molecules that have
(A)
kinetic energy equal to activation energy.
Rate constant increases with increases in temperature. This is mainly due to a greater number
(B)
of collisions whose energy exceeds the activation energy.
Higher the magnitude of activation energy of a reaction, stronger is the temperature
(C)
dependence of its rate constant.
 The pre–exponential factor depends on the frequency at which collisions between reactant
(D)
molecules per unit volume per unit time occur, irrespective of their energy.

2)

More acidic compound than benzoic acid is/are

(A)

(B)

(C)

(D)

3)

Correct order of acidic strength

(A) III > I

(B) I > IV
(C) IV > III
(D) II > I

4)

Which of the following reactions will not undergo in forward direction ?

(A) HC≡CH + NaOH

(B)

(C)

(D)

5)

Methane will be produced in which of the following reaction :

(A)

(B)

(C)

(D)

6)

(A)

(B)

(C)

(D)

SECTION-III

1) Elevation in boiling point of 0.25M aq. solution of weak acid HX is 0.14. What is molarity of H+ ion
in solution.
HXaq.
Given : Kb(H2O) = 0.5
Molality = Molarity
[Give answers as [H+] × 100]
2) In the saturated aqueous solution of PbCl2 the freezing point decreases by °C then ‘D’ is
(Given Ksp of PbCl2 = 4 × 10–6, Kf, water = 2K-kg/mole.

3)

How many of the following are more acidic than CH3 – CH2 – OH

4)

The maximum number of stereoisomer that could exist for the compound below ?

5)

How many compounds can show geometrical as well as optical isomerism :

PART-C-MATHEMATICS

SECTION-I(i)

1) Let 2p + 3q + 4r = 15 and if the expression p3q5r7 takes the maximum value, then p : q : r is equal
to (where p, q, r R+) -

(A) 18 : 20 : 21
(B) 3 : 5 : 7
(C) 2 : 3 : 4
(D) 6 : 15 : 28
2)

The value of is-

(A) 1

(B)

(C)

(D) 2

3)

Match List-I with List-II and select the correct answer using the code given below the list.

List-I List-II

(P) Largest integral value of 'x' satisfying < 0 is (1) 0

(Q) Greatest value of the expression ,x R is (2) 4

Number of integral value(s) of 'a' for which 2 lies between the roots
(R) (3) 3
of equation (2a – 1)x2 + x – 1 = 0, is
If sin x, cos y and sin z are in G.P and x + z = , then the value of
(S) (4) 2
, wherever exists is

(A) P-4 Q-4 R-1 S-4

(B) P-4 Q-1 R-4 S-4
(C) P-3 Q-4 R-2 S-3
(D) P-2 Q-3 R-3 S-4

4) If a is even natural number, b is odd natural number and

(where [x] represents greatest integer function of x), then k1 + k2 equals

(A) 2
(B) 3
(C) 4
(D) 5

5) If domain of is , then the value of a + b is

(A) 15
(B) 16
(C) 4
(D) 05

6) Let f : → be defined by f(x) = ln (x + ), then number of solutions of |f–1(x)| = e–|x| is :-

(A) 1
(B) 2
(C) 3
(D) Infinite

SECTION-I(ii)

1)

If a, b, c, d are distinct positive numbers in H.P., then

(A)

(B) abc + bcd = abd + acd

(C)

(D)

2) If p,α,β,q, are in A.P. with common difference 'd' and p,γ,δ,q are in G.P. (p, q are different positive
numbers), then

(A) αβ > γδ
(B) αβ < γδ
(C) αβ = q2 – 3qd + 2d2
(D) γδ = q2 – 3qd

3)

If a,b,c are positive real numbers such that ,

then which of the following statement(s) is/are true ?

(A)

(B)

(C)

(D)
4) If N = 34x35y is a 6 digit number, such that N is divisible by 99, then the value of 2x + 3y is equal
to

(A) 7
(B) 6
(C) 5
(D) 8

5) Let ƒ : R → R and g : R → R be mappings such that ƒ(g(x)) is an injective mapping then which of the
following statement(s) is(are) true ?

(A) ƒ(x) may be many-one mapping

(B) g(x) must be injective mapping
(C) If g(x) is surjective then ƒ(x) must be injective
(D) If g(x) is into mapping then ƒ(x) must be many-one mapping.

6) Let functions f, g : R → R defined by f(x) = 3x – 1 + |2x + 1|, g(x) = (3x + 5 – |2x + 5|). Then
which relation between f and g is/are true

(A) gof = fog

(B) (fog)–1 = gof
(C) (fof) = gog
(D) (fof)–1 = gog

SECTION-III

1)

If then value of is

2) Let a1, a2, a3, ........., an be the sequence, satisfying ∀ n ≥ 1, n N. If L =

ar, then sum of the digits of L is

3) Let α, β, γ are real roots of x3 – 7x2 + ax + 50 = 0 and |α|, |β|, |γ| are roots of x3 – bx2 + cx – d = 0.
If minimum integral value of (b + d) is k, then unit digit of k is

4) Let ƒ : [1, ∞) ~ {2} → B, is an onto function then sum of all integers in set
B, is
5) If [x] + [2x] + [3x] + ... + [2020x] = 1009ℓ, where , then sum of digits of ℓ, is
(Where [.] denotes greatest integer function)
 ANSWER KEYS

PART-A-PHYSICS

SECTION-I(i)

Q. 1 2 3 4 5 6
A. B B B C C B

SECTION-I(ii)

Q. 7 8 9 10 11 12
A. B,D A,B A,B,C,D B,D B,C A,B,C

SECTION-III

Q. 13 14 15 16 17
A. 4 6 8 0 3

PART-B-CHEMISTRY

SECTION-I(i)

Q. 18 19 20 21 22 23
A. A D B C C C

SECTION-I(ii)

Q. 24 25 26 27 28 29
A. B,C,D A,C,D B,C,D A,C,D A,C,D A,D

SECTION-III

Q. 30 31 32 33 34
A. 3 6 4 8 4

PART-C-MATHEMATICS

SECTION-I(i)

Q. 35 36 37 38 39 40
A. A B A B A B

SECTION-I(ii)

Q. 41 42 43 44 45 46
A. A,B,D A,C,D A,B,C,D D A,B,C A,B,D
 SECTION-III

Q. 47 48 49 50 51
A. 7 6 2 6 2
 SOLUTIONS

PART-A-PHYSICS

1)
a = g tan θ

N=
T – N sin θ = 3 ma
T = 4 ma

m1g – 2ma = m1a

m1 = = 2m

m1 =

2)

3)
4)

5)

v= = 8t – 9t2
∴ Δv = (16 – 36) – (0) = – 20

∴ aavg =

6)

Speed changes due to tangential acceleration. Tangential acceleration is the component of

acceleration along velocity vector

Therefore speed decreases at 2m/s2.

7) When the blocks are released, the thread will remain loose if acceleration of the lower block
m1 is less than or equal to the acceleration of the upper block m2. It will happen only when the
coefficient of the friction for m2 is less than or equal to that for m1. Hence, if m2 is smooth and
m1 is rough then thread will remain loose and m2 will collide with m1. If both the blocks are
equally rough or both are smooth then the separation between the two blocks will remain
constant because two blocks will move identically. Hence the thread will remain loose.
Acceleration of a block does not depend on its mass. It depends on inclination of the plane (θ)
and coefficient of friction (μ) only.

8)
9)

For 10 kg block remain stationary

T1 = 10 g and for 5 kg to remain stationary T2 = 5g

For pulley P2, T2 = 2T3 T3 = 2.5 g

Let m1 and m2 are moving with acceleration a w.r.t. pulley P2

Then
10)

11)

12)

Potential on innermost shell is zero

⇒ 6q1 + 3q2 + 2q3 = 0 .......(1)

Potential on outermost shell is zero

..... (2)
13)

14)

15)

a = –3

at t = so it will stop relative motion before 10 sec. So it will have same velocity as
plank.

16)

V(t) = 5 – 6e–t/2
x(t) = kt + ℓe–t/2 + m
at t = 0
x (0) = 7
7=0+ℓ+m ......(i)

v(t) = k – ⇐
 k=5

⇐
Putting Value of ℓ in eqn (i)
m = –5

17)
At t = 0, v = 2 & s = 9

∴
k = 36

= 6t +c
BC (at t = 0 s = 9)

= 6(0) + C; C = 18

= 6t + 18 ....(i)
∵ Put t = 37/9 in equation (i)

s3/2 = 37 + 27
s =[64]2/3

s= 16 at

2v = 3

PART-B-CHEMISTRY

18)

First order reaction

 t1/2 =

k= min–1
rate of reaction after 60 min.
r = k[A]t

r=

r=

19)

Kf + Kb =

t= ln
t = 210 sec.

20) = 10–3
As MCl2 gives 3 mole particles

molarity =

molality KSP = 4s3 = 4 × = 2.54 × 10–5

x=5

21)

(P) and (3)

Compound cantain two chiral center, configuration around C7 and C3 is R in both compounds so
identical (Q) There is no plane of symmetry and the molecule cannot show GI also so there are
enantiomer
(1)
(R)
Diastereomers (2)

(S) and ≡ (1)

Mirror image of each other so enantiomer
Correct Answer (C) → P – 3, Q – 1, R – 2, S – 1

24)

(B) Rate constant increases with increases in temperature. This is due to a greater number of
collisions whose energy exceeds the activation energy.
(C) Higher the magnitude of activation energy, stronger is the temperature dependence of the
rate constant.
(D) The pre–exponential factor is a measure of the rate at which collisions occur, irrespective
of their energy.

27)

28)

30) ΔTb = i kb m
0.14 = (1 + α) × 0.5 × 0.25
α = 0.12
[H+] = 0.03 M

31)

PbCl2 ⇌ Pb2+ + 2Cl–

Ksp = 4s3 = 4 × 10–6
s = 10–2 M
 ΔTf = ikf.m
i = 3, kf = 2 K. kg/mol

ΔTf = 3 × 2 × 10–2 = 6 × 10–2 =

D=6

34)
These four compounds can show geometrical as well as optical isomerism

PART-C-MATHEMATICS

35)

36)
37)

38) Given series

have (b – 1) terms

First term + last term =

=
=a–1
Similarly
second term + second last term

=
=a–1

So required sum =
⇒ k1 + k2 = 3

39)

f(X) = where { } fractional part function.

To define f(x)
(OR)
Clearly from the graph
(OR)
To find ;

Domain of -
a + b = 15

40)

f(x) = y = ln(x + )
y –y
⇒e = ;e =

f–1(x) =

No. of solutions = 2
41)

42)

43)

44) N must be divisible by 11 and 9, (8 + x) – (y + 7) is divisible by 11

⇒ x + 1 – y is multiple of 11
x + 1 – y = 0 or ±11
y = x + 1, y is even
sum of digits = x + y + 15
x + y = 3 or 12 or 21
x = 1, y = 2 ⇒ 2x + 3y = 8

45) For option (A) :

g is one-one & ƒ is many-one
but ƒ(g(x)) is one-one

For option (B) :

If g(x) is many one then one-one
g is many-one & ƒ is one-one then ƒ(g(x)) is not one-one.

For option (C) :

g is on to and ƒ is many one
⇒ ƒ{g(x)} in not one-one

For option (D) :

g, ƒ both are one-one but ƒ{g(x)} is one-one

46) g(x) =
After calculation
f(g(x)) = x = gf(x)
⇒ f = g–1 and g = f–1
Hence (fof)–1 = (g–1 og–1)–1 = gog
And (fog)–1 = gof.
47)

48)

49)
∴ d = |α||β||γ| = 50
& b = β + γ – α = 7 – 2α
use AM > GM on β, γ
we get minimum integral value of b is 12 at α =

50)

if x ∈ [1, 2), then y ∈ (2, 4]

if x ∈ [2, ∞), then y ∈ (–2, 0)
sum = 3 + 4 – 1 = 6 Ans.

51) 1009 ℓ =

Also [nx] + [1010 – nx] = 1010 + [nx] + [–nx]

= 1009 (nx ≠ Ι)

(2 × 1009)ℓ = ⇒ ℓ = 1010