Hour
Sl.No Day Date Theory / Lab Topic of Delivery
alloted
1 Friday 29-Apr-22 Theory 6 Hard Water
2 Saturday 30-Apr-22
3 Sunday 1-May-22
4 Theory 1 Hard Water
Monday 2-May-22
Practise 4 hardness Calculation
5 Tuesday 3-May-22
6 Wednesday 4-May-22 Theory 2 Boiler feed water
7 Thursday 5-May-22 Theory 3 Boiler troubles
8 Friday 6-May-22 Theory 6 Boiler troubles
9 Saturday 7-May-22
10 Sunday 8-May-22
11 Monday 9-May-22 Practise 4 advanced purification methods
12 Therory 3 Water softening methods
Tuesday 10-May-22 Lab 4,5 Experiment-1
13 Wednesday 11-May-22
14 Thursday 12-May-22 Theory 3 Water softening methods
15 Friday 13-May-22 Theory 6 Corrosion
16 Saturday 14-May-22
17 Sunday 15-May-22
18 Monday 16-May-22
19 Theory 3 Types of corrosion
Tuesday 17-May-22 Lab 4,5 Experiment-2
20 Wednesday 18-May-22
21 Thursday 19-May-22 Theory 3 Factors for Corrosion
22 Friday 20-May-22 Theory 6 Semiconductors
23 Saturday 21-May-22
24 Sunday 22-May-22 PUBLIC HOL
25 Monday 23-May-22 Practise 4 Corrosion
26 Tuesday 24-May-22 Theory 3 Non-Elemental Semiconductor
Lab 4,5 Experiment-3
27 Wednesday 25-May-22
28 Thursday 26-May-22 Theory 3 Preparation of semiconductors
29 Friday 27-May-22 Theory 6 Applications
30 Saturday 28-May-22
31 Sunday 29-May-22
32 Monday 30-May-22
33 Tuesday 31-May-22 Theory 3 Magnetic materials
Lab 4,5 Experiment-4
34 Wednesday 1-Jun-22
35 Thursday 2-Jun-22 Theory 3 Magnetic materials
36 Friday 3-Jun-22 Theory 6 Insulators
37 Saturday 4-Jun-22
38 Sunday 5-Jun-22
39 Monday 6-Jun-22 Practise 4 Insulators
Introduction
40 Tuesday 7-Jun-22 Theory 3
Lab 4,5 Experiment-5
41 Wednesday 8-Jun-22
42 Thursday 9-Jun-22 Theory 3 Absorption Spectroscopy
43 Friday 10-Jun-22 Theory 6 Absorption Spectroscopy
44 Saturday 11-Jun-22
45 Sunday 12-Jun-22
46 Monday 13-Jun-22 Practise 4 Absorption Spectroscopy
47 Theory 3 IR spectroscopy
Tuesday 14-Jun-22
Lab 4,5 Experiment-6
48 Wednesday 15-Jun-22
49 Thursday 16-Jun-22 Theory 3 IR spectroscopy
50 Friday 17-Jun-22 Theory 6 NMR spectroscopy
51 Saturday 18-Jun-22
52 Sunday 19-Jun-22
53 Monday 20-Jun-22 Lab 4,5 Experiment-7
54 Tuesday 21-Jun-22
55 Wednesday 22-Jun-22
56 Thursday 23-Jun-22
57 Friday 24-Jun-22
58 Saturday 25-Jun-22
59 Sunday 26-Jun-22
60 Theory 3 Introduction
Monday 27-Jun-22
lab 4,5 Experiment-8
61 Tuesday 28-Jun-22
62 Wednesday 29-Jun-22 Theory 3 Plastics
63 Tliursday 30-Jun-22
64 Friday 1-Jul-22 Theory 6 Polymers preparation
65 Saturday 2-Jul-22
66 Sunday 3-Jul-22
67 Theory 3 Examples of polymers
Monday 4-Jul-22
Lab 4,5 Experiment-9
68 Tuesday 5-Jul-22 Practise 4 Polymers
69 Wednesday 6-Jul-22 Theory 5 Examples of polymers
70 Thursday 7-Jul-22
71 Friday 8-Jul-22 Theory 3 Types of polymers
72 Saturday 9-Jul-22
73 Sunday 10-Jul-22
74 Theory 3 Types of polymers
Monday 11-Jul-22
Lab 4,5 Experiment-10
75 Tuesday 12-Jul-22
76 Wednesday 13-Jul-22 Theory 5 Introduction
77 Thursday 14-Jul-22
78 Friday 15-Jul-22 Theory 3 Internal energy and enthalpy
79 Saturday 16-Jul-22
80 Sunday 17-Jul-22
81 Theory 3 Derivation
Monday 18-Jul-22
Lab 4,5 Experiment-11
82 Tuesday 19-Jul-22 Practise 4 Submit a report
83 Wednesday 20-Jul-22 theory 5 Second law of thermodynamics
84 Thursday 21-Jul-22
85 Friday 22-Jul-22 theory 3 Derivation
86 Saturday 23-Jul-22
87 Sunday 24-Jul-22
88 Theory 3 Joule-Thomson Effect
Monday 25-Jul-22
Lab 4,5 Experiment-12
89 Tuesday 26-Jul-22
90 Wednesday 27-Jul-22 Theory 5 Derivation
91 Thursday 28-Jul-22
92 Friday 29-Jul-22 Theory 3 Van’t Hoff equations
93 Saturday 30-Jul-22
94 Sunday 31-Jul-22
95 Theory 3 Maxwell relations
Monday 1-Aug-22
Lab 4,5 Experiment-13
96 Tuesday 2-Aug-22 Practise 4 Applications
97 Wednesday 3-Aug-22 Theory 5 Liquid Crystals
98 Thursday 4-Aug-22
99 Friday 5-Aug-22 Theory 3 Liquid Crystals
100 Saturday 6-Aug-22
101 Sunday 7-Aug-22
102 Monday 8-Aug-22
103 Theory 3 Liquid Crystals
Tuesday 9-Aug-22
Lab 4,5 Experiment-14
104 Wednesday 10-Aug-22
105 Thursday 11-Aug-22 Theory 3 Nano Materials
106 Friday 12-Aug-22 Theory 6 Nano Materials
107 Saturday 13-Aug-22
108 Sunday 14-Aug-22
109 Monday 15-Aug-22
110 Theory 3 Nano Materials
Tuesday 16-Aug-22
Lab 4,5 Practise
Non-Conventional Energy
111 Wednesday 17-Aug-22 Theory 5
Sources
112 Thursday 18-Aug-22
Non-Conventional Energy
113 Friday 19-Aug-22 Theory 6
Sources
Non-Conventional Energy
114 Saturday 20-Aug-22 Theory 1
Sources
115 Sunday 21-Aug-22
116 Monday 22-Aug-22 Theory 3 Revision
117 Theory 3 Revision
Tuesday 23-Aug-22
Lab 4,5 Examination
118 Wednesday 24-Aug-22 IIMID EXAMINATIONS
119 Thursday 25-Aug-22 II MID EXAMINATIONS
120 Friday 26-Aug-22 II MID EXAMINATIONS
121 Saturday 27-Aug-22 II MID EXAMINATIONS
122 Sunday 28-Aug-22
123 Monday 29-Aug-22 II MID EXAMINATIONS
124 Tuesday 30-Aug-22 II MID EXAMINATIONS
125 Wednesday 31-Aug-22 VINYAKACHAVITHI
126 Thursday 1-Sep-22 END SEMESTER THEORY EXAMINAT
127 Friday 2-Sep-22 END SEMESTER THEORY EXAMINAT
128 Saturday 3-Sep-22 END SEMESTER THEORY EXAMINAT
129 Sunday 4-Sep-22
130 Monday 5-Sep-22 END SEMESTER THEORY EXAMINAT
131 Tuesday 6-Sep-22 END SEMESTER THEORY EXAMINAT
132 Wednesday 7-Sep-22 END SEMESTER THEORY EXAMINAT
133 Thursday 8-Sep-22 END SEMESTER THEORY EXAMINAT
134 Friday 9-Sep-22 END SEMESTER THEORY EXAMINAT
135 Saturday 10-Sep-22 END SEMESTER THEORY EXAMINAT
136 Sunday 11-Sep-22 PUBLIC HOLIDAY
137 Monday 12-Sep-22 END SEMESTER THEORY EXAMINAT
138 Tuesday 13-Sep-22 END SEMESTER THEORY EXAMINAT
139 Wednesday 14-Sep-22 END SEMESTER THEORY EXAMINAT
Instructional Methods /
Sub Topics
Activities
Sources of water, Types of hard water, Hardness units. Delivery
PUBLIC HOLIDAY
CaCO3 Equivalents, problems on hardness Delivery
Calculation of hardness of different samples of water
Introduction to boiler troubles Practise
Scale & Sludge- formation, Disadvantages Delivery
Priming & foaming, Caustic Embrittlement, Boiler Corrosion-formation, Delivery
Disadvantages
PUBLIC HOLIDAY
student need to visit one water plant & need to submit the report
Zeolite process- advantages, limitations Delivery
Determination of alkalinity in water sample Demonstration/Practise
Ion-exchange process, advantages, limitations Delivery
Introduction, Classification of corrosion, cause & effect of corrosion. Delivery/Practise
PUBLIC HOLIDAY
Dry corrosion, wet corrosion with examples & mechanism
Determination of total, temporary& permanent hardness of water by EDTA methDemonstration/Practise
Factors effecting rate of corrosion, Types of corrosion Delivery/Practise
Introduction, Band theory of solids, Classification based on mechanism of
Delivery/Practise
working
PUBLIC HOLIDAY
student need to explain on corrosion influencing factors Delivery/Practise
Classification, Models with examples Delivery/Practise
Estimation of copper content of the given solution by EDTA method Demonstration/Practise
Distillation, Zone refining, Single Crystal and doping techniques Delivery
p-n juntion diode as rectifier, p-n-p and n-p-n transisters Delivery/Practise
PUBLIC HOLIDAY
Intoduction, types- ferro, ferri magnetic materials Delivery
Determination of DO content of water sample winkler's method Demonstration/Practise
Hall effect and its applications Delivery
Classification, properties and applications Delivery
PUBLIC HOLIDAY
student need to explain an application of insulators in their daily life Delivery/Practise
Electromagnetic radiation, terminology of wave, Introduction-basic terms in
spectroscopy
Conductometric Titration of strong acid vs Strong base Demonstration/Practise
Principle, Energy transitions, Selection rules Delivery
Instrumentation, applications Delivery
PUBLIC HOLIDAY
Instrumentation and Working of daily practice of UV-Vis light is explained Delivery/Practise
Principle, Fundamental mode of vibrations Delivery/Practise
Estimation of Vitamin-C Demonstration/Practise
Instrumentation, Applications-Determination of functional groups Delivery
Principle, NMR time scale, Instrumentation, applications-MRI scan, CT Scan Delivery/Practise
PUBLIC HOLIDAY
Preparation of Polymer/drug Demonstration/Practise
I MID EXAMINATIONS
I MID EXAMINATIONS
I MID EXAMINATIONS
I MID EXAMINATIONS
I MID EXAMINATIONS
PUBLIC HOLIDAY
Degree of polymerization, Functionality, Classification of polymers with
Delivery
examples
Determination of strength of given hydrochloric acid using pH meter Demonstration/Practise
Thermoplastic & Thermosetting polymers, Fabrication of plastics Delivery/Practise
Various methods of Fabrication of plastic material Delivery/Practise
PUBLIC HOLIDAY
Preparation, properties and uses of Nylon 6,6 Delivery/Practise
Potentiometric-determination of redox potential Demonstration/Practise
students need to identify the various conducting polymers used in daily life Delivery/Practise
Preparation, properties and uses of PVC and Thiokol Delivery/Practise
Conducting polymers-Introduction, Types, Applications Delivery/Practise
PUBLIC HOLIDAY
Biomedical Polymers, FRP Delivery
Saponification value of an oil Demonstration/Practise
Thermodynamics - Terminology, Zero and First Law of Thermodynamics Delivery
Work done in an ideal gas, Enthalpy-Importance, Derivation Delivery
PUBLIC HOLIDAY
Reversible isothermal expansion of ideal gas- Joule Thomson effect and its
coefficient Delivery/Practise
determination of the rate constant of reaction Demonstration/Practise
measurement of electrode potential Practise
Statement, significance and Limitations, Delivery
Gibbs Helmholtz equation, Applications, Nernst equation- calculation of emf of
a cell Delivery/Practise
PUBLIC HOLIDAY
Joule-Thomson effect and its derivation Delivery/Practise
Introduction to thin layer chromatograpy Demonstration/Practise
Derivation of Clausius Clapeyron equation, Application, Determination of
Latent heat Delivery/Practise
Van’t Hoff isotherm, Van’t Hoff isochore Delivery/Practise
PUBLIC HOLIDAY
Maxwell Differential Equations Delivery/Practise
Introduction to Chemdraw software (Virtual laboratory). Demonstration/Practise
Problems on various derivations Practise
Introduction, Classification Delivery
Thermotropic and Lyotropic LCs- Properties, types Delivery/Assignment
PUBLIC HOLIDAY
Applications of Liquid crystals Delivery/Assignment
Introduction to UV and IR experiments (Virtual laboratory). Demonstration/Practise
Introduction, Types of nanoparticles, General Properties Delivery
Fullerenes: Introduction, Preparation, Properties and Uses Delivery
PUBLIC HOLIDAY
CNT: Introduction, Preparation, Properties and Applications Delivery
Practise of all experiments in AC lab Syllabus Practise
Solar Energy: Photovoltaic Cell- Design, working, Advantages Delivery/Assignment
Geothermal Energy: Design, working, Advantages Delivery/Assignment
Hydrothermal Energy: Design, working, Advantages Delivery/Assignment
PUBLIC HOLIDAY
Revision of Unit 1-3
Revision of Unit 4-6
Lab Internal Examinations
IIMID EXAMINATIONS
II MID EXAMINATIONS
II MID EXAMINATIONS
II MID EXAMINATIONS
PUBLIC HOLIDAY
II MID EXAMINATIONS
II MID EXAMINATIONS
VINYAKACHAVITHI
ND SEMESTER THEORY EXAMINATIONS
ND SEMESTER THEORY EXAMINATIONS
ND SEMESTER THEORY EXAMINATIONS
PUBLIC HOLIDAY
ND SEMESTER THEORY EXAMINATIONS
ND SEMESTER THEORY EXAMINATIONS
ND SEMESTER THEORY EXAMINATIONS
ND SEMESTER THEORY EXAMINATIONS
ND SEMESTER THEORY EXAMINATIONS
ND SEMESTER THEORY EXAMINATIONS
PUBLIC HOLIDAY
ND SEMESTER THEORY EXAMINATIONS
ND SEMESTER THEORY EXAMINATIONS
ND SEMESTER THEORY EXAMINATIONS
Assessment Method for TLO
MCQ
Problem solving /Assignment
Problem solving /Assignment
MCQ/Assignment
MCQ/Assignment
MCQ/Assignment
student need to visit one water plant & need to
submit the report
MCQ
MCQ
MCQ/Assignment
MCQ/Assignment
MCQ
Assignment
MCQ/Assignment
MCQ/Assignment
student need to submit a applications in their daily life
student need to submit a applications in their daily life
student need to submit a applications in their daily life
MCQ/Assignment
student need to submit a applications in their daily life
MCQ/Assignment
MCQ/Assignment
MCQ/Assignment
MCQ/Assignment
MCQ/Assignment
MCQ/Assignment
MCQ/Assignment
MCQ/Assignment
Student need to differentiate various plastics
Student need to differentiate various plastic quality
Practice
Assignment
MCQ/Assignment
MCQ/Assignment
MCQ/Assignment
MCQ
practice /Assignment
practice /Assignment
Submit a report
practice /Assignment
MCQ/Assignment
Practice/Assignment
Practice/Assignment
Practice/Assignment
Practice/Assignment
Practice/Assignment
MCQ
MCQ/Assignment
project/ assignment
project/ assignment
MCQ/Assignment
MCQ/Assignment
project/ assignment
project/ assignment
project/ assignment
project/ assignment
Sl# S# L# Topics
Unit-1
Water Technology-(9Lectures )
Introduction to Applied Chemistry -Scope, CO, COC's
1
Discussion
2 S1 L1 Sources of water, Types of hard water, Hardness units.
3 S2 L2 CaCO3 Equivalents, problems on hardness
4 S3 L3 Introduction to boiler troubles, Scale & Sludge
5 S4 L4 Priming & foaming, Caustic embrittlement, Boiler corrosion
6 S5 L5 Zeolite process, advantages, limitations
7 S6 L6 Ion-exchange process, advantages, limitations
8 S7 L7 Introduction, Classification of corrosion, effect of corrosion.
9 S8 L8 Dry corrosion, wet corrosion with examples & mechanism
10 S9 L9 Factors influnceing the rate of corossion
Unit-2 Material Chemistry (7-Lectures)
11 S10 L10 Introduction, Band theory of solids
12 S11 L11 Semiconductor Classification, with suitable examples
13 S12 L12 Distillation, Zone refining, Single Crystal and doping techniques
14 S13 L13 p-n juntion diode as rectifier, p-n-p and n-p-n transisters, Amplifier
15 S14 L14 Intoduction, types- ferro, ferri magnetic materials
16 S15 L15 Hall effect and its applications
17 S16 L16 Classification, properties and applications of Insulators
Unit-3 Spectroscopic Techniques and Applications(6 Lectures)
18 S17 L17 Introduction-Electromagnetic radiation, terminology of wave,
Principle, Energy transitions, Selection rules, Instrumentation,
19 S18 L18
applications
20 S19 L19 Principle, Fundamental mode of vibrations
21 S20 L20 Instrumentation, Applications-Determination of functional groups
22 S21 L21 Principle, Coupling constant, Spin-Spin coupling
23 S22 L22 Instrumentation, applications-MRI scan, CT Scan
Unit-4 Polymer Chemistry(6 Lectures)
24 S23 L23 Degree of polymerization, Functionality, Classification
25 S24 L24 Thermoplastic & Thermosetting polymers, Fabrication of plastics
26 S25 L25 Physical and mechanical properties of polymers
27 S26 L26 Preparation, properties and uses of Nylon 6,6, PVC and Thiokol
28 S27 L27 JConducting polymers-Introduction, Types.
29 S28 L28 Biomedical
o Polymers, FRP
u
Unit-5 lUse of Free energy in Chemical Equilbria(9 Lectures)
e
30 S29 L29 Terminology,
- Zero and First Law of Thermodynamics
31 S30 L30 Work
T done in an ideal gas, Enthalpy-Importance, Derivation
31 S31 L31 hSecond law of thermodynamics, Entropy, Gibbs-Free energy
32 S32 L32 oGibbs Helmholtz equation, Applications, Nernst equation
m
33 S33 L33 Joule-Thomson effect and its derivation
s
35 S34 L34 Clausius
o Clapeyron equation, Application
36 S35 L35 nVan’t Hoff isotherm, Van’t Hoff isochore
E
f
f
e
37 S36 L36 Maxwell Differential Equations
38 S37 L37 Problems on various derivations
UNIT-6 Advanced Topics in Chemistry(8 Lectures)
39 S38 L38 Introduction, Classification
40 S39 L39 Thermotropic and Lyotropic LCs- Properties, types
41 S40 L40 Applications of Liquid crystals-LCD
42 S41 L41 Introduction, Types of nanoparticles, General Properties
43 S42 L42 Fullerenes: Introduction, Preparation, Properties and Uses
44 S43 L43 CNT: Introduction, Preparation, Properties and Applications
45 S44 L44 Solar Energy: Photovoltaic Cell- Design, working, Advantages
46 S45 L45 Hydro Energy, Geothermal Energy: Design, working, Advantages
Topic Out Come
To Know various resources of water, Reasons for hardness and Its measurement
To estimate the hardness and other water quality perameters
To know Industrial disadvantages of hard water
To understand the Other types boiler troubles
Able to learn purification methods
Able to learn advanced purification methods
Industrial disadvantage of corrosion
To understand the mechanisams of corrosion
How various factors influnceing the corossion
Able to differntiate semiconductors
Understand various types of non metalic semiconductors
To know the various satges in semiconductor preparation
To Understand the applications of semiconductors
understand the origin of magnestisam
To understand applications of hall effect
Role of insulators in various sectors
To undersatnd the splitting of EMR
knowledge on beers -lamberts law -to identify the unsaturation by using UV
microscopic undestanding of vibrations between atoms to identify functional groups
important in structure elucidation
medical applications of NMR
To understand the basic concepts of polymers
to identify the suitable polymers
to identify the suitable polymers
students able to know the synthestic processes
get knowledge on advance materials
to learn various fabrication methods
basic knowledge on terimnolgy used in thermodynamics
To understand the basic concept of enthalpy
To understand the basic concept of enthalpy& Free energy
applications of free energy
applications of joule thomson effect
applications of integrated form of Clausius clapeyron equation
applications of vanthoff isotherm and isochore
relation between various state functions
to understand basic types
knowledge on LCD and LED
to know the commercial applications
to know the advanced materials
types and synthesis process and their applications
types, methodogy of CNT synthesis
knowledge on alternative and renewable energy resources
knowledge on alternative and renewable energy resources
Assesment
MCQ
Problem solving /Assignment
MCQ/Assignment
MCQ/Assignment
student need to visit one water plant & need to submit the
report
MCQ
MCQ/Assignment
Project
MCQ
MCQ/Assignment
MCQ/Assignment
student need to submit a applications in their daily life
MCQ/Assignment
MCQ/Assignment
MCQ/Assignment
MCQ/Assignment
MCQ/Assignment
MCQ/Assignment
filed vist -submit a report
MCQ/Assignment
Student need to differentiate various plastics
MCQ/Assignment
Practice
students need to collect various conducting polymers
project on fabrication /composites
MCQ
practice /Assignment
Practice/Assignment
Submit a report
MCQ/report submtion
Practice/Assignment
Practice/Assignment
Practice/Assignment
Practice
MCQ
MCQ/Assignment
project/ assignment
project/ assignment
MCQ/Assignment
MCQ/Assignment
project/submit a report
project/submit a report
Time
Mode of delivery BTL
(min)
Black board/ PPT/animated video BT1 60
Hardness is calculated in AC laboratory BT4 60
Black board/ PPT/animated video BT1 60
Working of boiler is explined with domestic examples /Animated video BT4 60
Zeolite process is demonstrated in lab/home BT3 60
Ion-exchange process is demonstrated in field trips BT3 60
Black board/ PPT/animated video BT3 60
Classification of corrosion is demonstrated BT4 60
student can do a project on corrosion influencing factors BT2 60
Black board/ PPT/animated video BT1 60
Black board/ PPT/animated video BT2 60
Black board/ PPT/animated video BT3 60
working of rectifiers
Black board/ and transisters
PPT/animated video is explined in ECE dept labs BT4 60
project on using
Black board/ magnetic force
PPT/animated videoin various fields BT3 60
demonstration on Hall effect applications BT3 60
Insulators working can explained in industries BT4 60
Electromagnetic wave formation can be explined in ECE dept. lab BT4 60
Instrumentation and Working is explained in AC lab BT2 60
demonstration on BEERS law BT2 60
Instrumentation and Working is explained in AC lab BT4 60
BT2 60
MRI and CT scan explained in near diagnostic centre BT4 60
Black board/ PPT/animated video BT2 60
Preparation of polymer is explined in AC lab BT4 60
Black board/ PPT/animated video BT3 60
Nylon and PVC preparation can be demonstrated in field trip BT3 60
students need to identify the various conducting polymers used in daily life BT3 60
project on plastic recycling or reuse BT4 60
laws of thermodynamics can be demontrated in class room BT2 60
Black board BT3 60
Entropy change can be explained in classroom BT3 60
measurement of electrode potential BT3 60
Demonstrated by using working of refrigerator BT3 60
Black board BT3 60
students need to identify free energy changes in their daily life BT3 60
Black board BT3 60
Black board 60
Black board/ PPT/animated video BT2 60
project on liquid crystal preparation BT2 60
LCD screen working is explained in ECE dept. lab BT4 60
demonstration on chemical methods for nano particle preparation BT2 60
Black board/ PPT/animated video BT4 60
Black board/ PPT/animated video BT2 60
working of Solar cell is explined in our college BT3 60
Hydro power generation is explained in field trip, simulation lab BT3 60
Time split in Min
Web Link
practice
Delivery Assesment /Demonstartion
50 10 https://chem.libretexts.org/
20 10 30 https://www.sciencebysimulation.com/chemreax/Analyzer.aspx
50 10
50 10
50 10
50 10
50 10
50 10
60
50 10
40 20
40 20
50 10
50 10
50 10
50 10
50 10
40 20
40 20
50 10
30 10 20
40 20
40 20
40 20
60
50 10
50 10
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50 10
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