NEET AITS 11 CHEMISTRY

Q1. Alkanes mainly undergoes reactions having:

A. Free radical reaction
B. Ionic elimination
C. Electrophilic addition
D. Heat/photochemical substitution
Q2. The reagent used for the following conversion:

a. LiAlH4
b. Amalgamated zinc and concentrated HCl
c. Red phosphorous and concentrated HI
d. Soda lime
Q3. Which of the following is used for the conversion of 2-hexyne into trans-hexene?
A. H2/Pd/BaSO4
B. H2, PtO2
C. NaBH4
D. Li-NH3/C2H5OH

Q4. Here the product is:

Q5. Isopropyl bromide on Wurtz reaction gives:

A. Hexane
B. Propane
C. 2,3-dimethyl butane
D. Neo-hexane
Q6. The number of possible enantiomeric pairs that can be produced during monochlorination of
2-methyl butane are:
A. 2 B. 3 C. 4 D. 1
Q7. The intermediate product formed during the addition of HCl to propene in presence of
peroxide is:

Q8. Which will have smallest heat of hydrogenation per mole?

A. Cis-2-butene
B. Trans-2-butene
 C. 1,3-butadiene
D. 1-butene
Q9. The treatment of benzene with isobutene in the presence of sulphuric acid gives:
A. Isobutyl benzene
B. n-butyl benzene
C. Tert-butyl benzene
D. Cumene
Q10. Which of the following is a free radical substitution reaction?

Q11. The reaction conditions leading to provide the best yield of C2H5Cl are:

Q12. The highest boiling point is expected for:

A. Iso-octane
B. n-octane
C. 2,2,3,3-tetramethyl butane
D. n-butane
Q13. Acidic hydrogen is present in:
A. Ethyne
B. Ethene
C. Benzene
D. Ethane
Q14. Which is not product when is treated with HIO4?
A. HCCOH
B. H 2O
C. HCHO
D. CO2
Q15. Which is an incorrect statement regarding oxymercuration-demercuration?
A. Here rearrangement takes place
B. In the second step demercuration occurs that is, NaBH4 reduces – HgOAc2 group of
hydrogen
C. The net reaction is addition of water according to Markovnikov’s rule
D. In the first step oxymercuration occurs, that is water and Hg(OAc)2 add to double bond

Q16. Compound A is:

A. 2-propanal
B. Propane
C. Propene
D. 2-propanone
Q17. Which of the following gives propyne on hydrolysis?
A. Al4C3 B. Mg2C3 C. B4C D. La4C3
Q18. Which has the maximum boiling point as well as melting point out of the following:

A. 1 in both cases
B. 1, 2
C. 1, 3
D. 2, 1
Q19. In the given reaction [A] will be:

A. Meso-2, 3-dibromobutane
B. Racemic mixture of 2, 3-dibromobutane
C. Meso as well as racemic mixture
D. Reaction is not possible
Q20. In the reaction given below A will be:
 A. t-BuOK
B. Alcoholic KOH
C. Et3N
D. Conc. H2SO4
Q21. The relative rates of hydrogenation is in the order of:
A. 𝑅2 𝐶 = 𝐶𝐻𝑅 > 𝑅𝐶𝐻 = 𝐶𝐻𝑅 > 𝑅𝐶𝐻 = 𝐶𝐻2 > 𝐶𝐻2 = 𝐶𝐻2
B. 𝐶𝐻2 = 𝐶𝐻2 > 𝑅𝐶𝐻 = 𝐶𝐻2 > 𝑅𝐶𝐻 = 𝐶𝐻𝑅 > 𝑅2 𝐶 = 𝐶𝐻𝑅
C. 𝑅𝐶𝐻 = 𝐶𝐻𝑅 > 𝑅2 𝐶 = 𝐶𝐻𝑅 > 𝑅𝐶𝐻 = 𝐶𝐻2 > 𝐶𝐻2 = 𝐶𝐻2
D. 𝑅2 𝐶 = 𝐶𝐻𝑅 > 𝐶𝐻2 = 𝐶𝐻2 > 𝑅𝐶𝐻 = 𝐶𝐻𝑅 > 𝑅𝐶𝐻 = 𝐶𝐻2
Q22. Benzene reacts with CH3COCl in the presence of anhydrous AlCl3 to give:
A. C6H5CH3
B. C6H5Cl
C. C6H5O2Cl
D. C6H5COCH3
Q23. What will be the product in the following reactions?

Q24. Which is most easily dehydrohalogenated?

A. 1 B. 2 C. 3 D. Cannot be determined

Q25.
Q26. CH3 − CH = CH2 + NOCl → P. Identify P.

Q27. Which of the following are aromatic here?

A. 3 only B. 1, 3 C. 3, 4 D. 1, 3, 2
Q28. Consider the following reaction:

Identify the structure of the major product X:

Q29.

Hydrogenation of the above compounds in the presence of poisoned palladium catalyst gives:
A. Optically active compound
B. An optically inactive compound
C. A racemic mixture
D. A diastereomeric mixture
Q30. Ethene and ethyne can be distinguished by:
 A. Br2 water
B. KMnO4 solution
C. Cuprous chloride solution
D. Any of the above
Q31. Which of the following sequence of reagents can be used for the conversion of C6H5CH2CH3
into C6 H5 CH = CH2 ?
A. SOCl2; H2O B. SO2Cl2; alc. KOH C. Cl2/hv; H2O D. SOCl2; alc. KOH
Q32. Cold and dil. KMnO4 combines with but-2-yne to form:
A. Butane-1, 3-diol
B. Butane-2, 3-diol
C. Butane-2, 3-dione
D. Butan-2-one
Q33. The most reactive species among the following towards sulphonation is:
A. Toluene
B. Nitrobenzene
C. 1, 3-dimethyl benzene
D. Chlorobenzene
Q34. Cyclooctatetraene is not aromatic. The most important reason for this is that:
A. It is a planar molecule
B. It has eight 𝜋 −electrons
C. Its structure cannot be described by more than the canonical forms
D. Its structure is not that of regular octagon
Q35. Which one of the following is aromatic in nature?

Q36. Which of the following reactions will yield 2, 2-dibromopropane?

A. CH3 CH = CHBr + HBr →
B. HC ≡ CH + 2HBr →
C. CH3 CH = CH2 + HBr →
D. CH2 C ≡ CH + 2HBr →
Q37. In the following sequence of reactions, what is D?

A. Primary amine
B. An amide
C. Phenyl isocyanatc
D. A chain lengthened hydrocarbon
Q38. Among the following reaction:
Which of the following sets of reagents can be used for step 1 and step 2?
STEP 1 STEP 2
1. HBr HBr and peroxide
2. HBr and peroxide HBr
3. Br2 HBr
4. Br2 HBr and peroxide
Select the correct answer using the codes given below:
A. 1 alone B. 1 and 2 C. 1, 2 and 3 D. 1, 2 and 4
Q39. In the following sequence of reactions, the end product P is:

Q40. Consider the following alkenes:

1. 𝐻2 𝐶 = 𝐶(𝐶𝐻2 𝐶𝐻3 )𝐶𝐻(𝐶𝐻3 )2
2. (𝐶𝐻3 )2 = 𝐶(𝐶𝐻3 )𝐶𝐻2 𝐶𝐻3
3. 𝐶𝐻3 𝐶𝐻 = 𝐶(𝐶𝐻3 )𝐶𝐻(𝐶𝐻3 )2
The correct sequence of increasing order of stability of these alkenes is:
A. 3,2,1 B. 1,3,2 C. 1,2,3 D. 2,1,3
Q41. Match the following
The correct matching is:
1 2 3 4
A. (4) (3) (2) (1)
B. (2) (1) (4) (5)
C. (2) (1) (3) (5)
D. (2) (3) (1) (4)
Q42. Place the following compounds in the decreasing order of their relative reactivity with
electrophile (E+).
1. p-nitro chlorobenzene
2. 2, 4-dinitrochlorobenzene
3. Chlorobenzene
A. 3>1>2 B. 1 > 2 > 3 C. 2 > 1 > 3 D. 3 > 2 > 1

Q43.
Here the compound formed is?

Q44. The major product obtained on the monobromination (with Br2/FeBr3) of the following
compound A is:
Q45. The addition of Br2 to Z-2 butene gives:
A. (R, R)-2,3-dibromobutane only
B. (S, S)-2, 3-dibromobutane only
C. (R, S)-2, 3-dibromobutane only
D. A mixture of (R, R) and (S, S)-2, 3-dibromobutanes (50%: 50%)
E. (R, S)-1, 2-dibromobutane
Q46. The treatment of CH3MgX with CH3 C ≡ C − H produces:
A. 𝐶𝐻3 − 𝐶𝐻 = 𝐶𝐻2
B. 𝐶𝐻3 𝐶 ≡ 𝐶 − 𝐶𝐻3
C. 𝐶𝐻4

Q47. The hydrocarbon which can react with sodium in liquid ammonia is:
A. 𝐶𝐻3 𝐶𝐻2 𝐶𝐻2 𝐶 ≡ 𝐶𝐶𝐻2 𝐶𝐻2 𝐶𝐻3
B. 𝐶𝐻3 𝐶𝐻2 𝐶 ≡ 𝐶𝐻
C. 𝐶𝐻3 𝐶𝐻 = 𝐶𝐻𝐶𝐻3
D. 𝐶𝐻3 𝐶𝐻2 𝐶 ≡ 𝐶𝐶𝐻2 𝐶𝐻3
Q48. The correct decreasing order towards reaction with HBr for the given all kones is given as:

A. 3 > 1 > 2 > 4 B. 3 > 2 > 1 > 4 C. 2 > 3 > 1 > 4 D. 4 > 2 > 1 > 3
Q49. Which of these are aromatic here?
 A. 1, 2 B. 1, 3 C. 2, 3 D. 1, 4
Q50. Hexa 2, 4 di-one on ozonolysis by using O3/CCl4 following by H2O/Zn gives:
A. Acetaldehyde
B. Glyoxal
C. Formaldehyde
D. Both A and B