SDS Glycerol
SDS Glycerol
Product Identifier
Product name GLYCEROL
Chemical Name Not Available
C3-H8-O3; C3-H5-(OH)3; propanetriol; glycerin; glycerine; 1,2,3-trihydroxypropane; E 422; Emery 916; Emery 917; G 101; GL 300; Glyceol
Synonyms Opthalgan; Glycerin DG; Glyrol; Glysanin; IFP; Mackstat H 66; NSC 9230; Osmoglyn; Pricerine 9088 9091; 101467: GOLD CROSS GLYCEROL
BP 100ML; glycerol; Pricerine 9075 - Nitration Grade; Salim Refined glycerine; glycerine technical
Chemical formula C3H8O3
Other means of identification Not Available
CAS number 56-81-5
Relevant identified uses of the substance or mixture and uses advised against
As solvent, humectant, plasticiser, emollient, sweetener; in the manufacture of nitroglycerol (explosive), cosmetics, liquid soaps, liqueurs,
confectioneries, blacking, printing and copying inks and lubricants. It is also used in the manufacture of elastic glues, lead oxide cements; to keep
Relevant identified uses
fabrics pliable; to preserve printing on cotton; for printing rollers; to keep frost from windshields; as antifreeze in automobiles, gas meters and
hydraulic jacks, in shock absorber fluids. In fermentation nutrients in production of antibiotics.
Once connected and if the message is not in your preferred language then please dial 01
HAZARDOUS CHEMICAL. NON-DANGEROUS GOODS. According to the WHS Regulations and the ADG Code.
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Label elements
Hazard pictogram(s)
Hazard statement(s)
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
Substances
CAS No %[weight] Name
56-81-5 >=96 Glycerol
Legend: 1. Classified by Chemwatch; 2. Classification drawn from HCIS; 3. Classification drawn from Regulation (EU) No 1272/2008 - Annex VI; 4. Classification drawn from C&L;
* EU IOELVs available
Mixtures
See section above for composition of Substances
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Extinguishing media
Water spray or fog.
Foam.
Dry chemical powder.
BCF (where regulations permit).
Carbon dioxide.
Environmental precautions
See section 12
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Control parameters
Emergency Limits
Ingredient TEEL-1 TEEL-2 TEEL-3
Glycerol 45 mg/m3 180 mg/m3 1,100 mg/m3
Exposure controls
Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls can
be highly effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection.
The basic types of engineering controls are:
Process controls which involve changing the way a job activity or process is done to reduce the risk.
Appropriate engineering Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation that strategically
controls "adds" and "removes" air in the work environment. Ventilation can remove or dilute an air contaminant if designed properly. The design of a
ventilation system must match the particular process and chemical or contaminant in use.
Employers may need to use multiple types of controls to prevent employee overexposure.
Individual protection
measures, such as personal
protective equipment
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NATURAL+NEOPRENE A A-PAPR-AUS /
up to 10 x ES A-AUS P2 -
Class 1 P2
NITRILE A
A-AUS / Class 1
up to 50 x ES - -
* CPI - Chemwatch Performance Index P2
A: Best Selection up to 100 x ES - A-2 P2 A-PAPR-2 P2 ^
B: Satisfactory; may degrade after 4 hours continuous immersion
C: Poor to Dangerous Choice for other than short term immersion ^ - Full-face
NOTE: As a series of factors will influence the actual performance of the glove, a final A(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 = Acid gas or
selection must be based on detailed observation. - hydrogen cyanide(HCN), B3 = Acid gas or hydrogen cyanide(HCN), E = Sulfur
* Where the glove is to be used on a short term, casual or infrequent basis, factors such dioxide(SO2), G = Agricultural chemicals, K = Ammonia(NH3), Hg = Mercury, NO =
as "feel" or convenience (e.g. disposability), may dictate a choice of gloves which might Oxides of nitrogen, MB = Methyl bromide, AX = Low boiling point organic
otherwise be unsuitable following long-term or frequent use. A qualified practitioner compounds(below 65 degC)
should be consulted.
Cartridge respirators should never be used for emergency ingress or in areas of
Ansell Glove Selection unknown vapour concentrations or oxygen content.
The wearer must be warned to leave the contaminated area immediately on
Glove — In order of recommendation detecting any odours through the respirator. The odour may indicate that the mask is
not functioning properly, that the vapour concentration is too high, or that the mask is
AlphaTec 02-100 not properly fitted. Because of these limitations, only restricted use of cartridge
AlphaTec® 15-554 respirators is considered appropriate.
Cartridge performance is affected by humidity. Cartridges should be changed after 2
AlphaTec® Solvex® 37-185 hr of continuous use unless it is determined that the humidity is less than 75%, in
AlphaTec® 38-612 which case, cartridges can be used for 4 hr. Used cartridges should be discarded
daily, regardless of the length of time used
AlphaTec® 53-001 76a-p()
AlphaTec® 58-005
AlphaTec® 58-008
AlphaTec® 58-530B
AlphaTec® 58-530W
AlphaTec® 58-735
The suggested gloves for use should be confirmed with the glove supplier.
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TOXICITY IRRITATION
Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2. Value obtained from manufacturer's SDS. Unless otherwise
specified data extracted from RTECS - Register of Toxic Effect of chemical Substances
Asthma-like symptoms may continue for months or even years after exposure to the material ends. This may be due to a non-allergic condition
known as reactive airways dysfunction syndrome (RADS) which can occur after exposure to high levels of highly irritating compound. Main
criteria for diagnosing RADS include the absence of previous airways disease in a non-atopic individual, with sudden onset of persistent
asthma-like symptoms within minutes to hours of a documented exposure to the irritant. Other criteria for diagnosis of RADS include a reversible
airflow pattern on lung function tests, moderate to severe bronchial hyperreactivity on methacholine challenge testing, and the lack of minimal
GLYCEROL lymphocytic inflammation, without eosinophilia. RADS (or asthma) following an irritating inhalation is an infrequent disorder with rates related to
the concentration of and duration of exposure to the irritating substance. On the other hand, industrial bronchitis is a disorder that occurs as a
result of exposure due to high concentrations of irritating substance (often particles) and is completely reversible after exposure ceases. The
disorder is characterized by difficulty breathing, cough and mucus production.
At very high concentrations, evidence predicts that glycerol may cause tremor, irritation of the skin, eyes, digestive tract and airway. Otherwise it
is of low toxicity. There is no significant evidence to suggest that it causes cancer, genetic, reproductive or developmental toxicity.
Toxicity
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Legend: Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity 4. US EPA,
Ecotox database - Aquatic Toxicity Data 5. ECETOC Aquatic Hazard Assessment Data 6. NITE (Japan) - Bioconcentration Data 7. METI (Japan)
- Bioconcentration Data 8. Vendor Data
For Glycerol: Log Kow: -2.66 to -2.47, Atmospheric Fate: Glycerol is broken down in the air by hydroxyl radicals the half-life for this process is 6.8 hours. However, only a negligible
amount of the substance will move to the atmospheric compartment. Terrestrial Fate: Only a negligible amount of glycerol will move into the soil compartment, if released into the
environment. Aquatic Fate: Glycerol is considered to be readily biodegradable in the aquatic environment. Pre-adapted microorganisms can break glycerol down rapidly in
oxygenated/low oxygen waters. The substance is not expected to react with water. When released to water, 100% of the substance will remain in the water compartment - only
negligible amounts will be distributed to sediment.
DO NOT discharge into sewer or waterways.
Bioaccumulative potential
Ingredient Bioaccumulation
Glycerol LOW (LogKOW = -1.76)
Mobility in soil
Ingredient Mobility
Glycerol HIGH (KOC = 1)
Labels Required
Marine Pollutant NO
HAZCHEM Not Applicable
Air transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
14.7.1. Transport in bulk according to Annex II of MARPOL and the IBC code
Not Applicable
14.7.2. Transport in bulk in accordance with MARPOL Annex V and the IMSBC Code
Product name Group
Glycerol Not Available
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Safety, health and environmental regulations / legislation specific for the substance or mixture
Other information
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification
committee using available literature references.
The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or
other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered.
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end of SDS