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SDS Glycerol

The document is a Safety Data Sheet for Glycerol, detailing its identification, uses, hazards, and safety measures. Glycerol is classified as a hazardous chemical with specific risks including skin and eye irritation, and respiratory issues. The document outlines emergency procedures, handling, storage, and personal protective equipment recommendations.

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samia
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0% found this document useful (0 votes)
44 views9 pages

SDS Glycerol

The document is a Safety Data Sheet for Glycerol, detailing its identification, uses, hazards, and safety measures. Glycerol is classified as a hazardous chemical with specific risks including skin and eye irritation, and respiratory issues. The document outlines emergency procedures, handling, storage, and personal protective equipment recommendations.

Uploaded by

samia
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

GLYCEROL

ALPHA CHEMICALS PTY LTD Chemwatch Hazard Alert Code: 2


Chemwatch: 1987-5 Issue Date: 23/12/2022
Version No: 13.1 Print Date: 19/01/2024
Safety Data Sheet according to WHS Regulations (Hazardous Chemicals) Amendment 2020 and ADG requirements S.GHS.AUS.EN

SECTION 1 Identification of the substance / mixture and of the company / undertaking

Product Identifier
Product name GLYCEROL
Chemical Name Not Available
C3-H8-O3; C3-H5-(OH)3; propanetriol; glycerin; glycerine; 1,2,3-trihydroxypropane; E 422; Emery 916; Emery 917; G 101; GL 300; Glyceol
Synonyms Opthalgan; Glycerin DG; Glyrol; Glysanin; IFP; Mackstat H 66; NSC 9230; Osmoglyn; Pricerine 9088 9091; 101467: GOLD CROSS GLYCEROL
BP 100ML; glycerol; Pricerine 9075 - Nitration Grade; Salim Refined glycerine; glycerine technical
Chemical formula C3H8O3
Other means of identification Not Available
CAS number 56-81-5

Relevant identified uses of the substance or mixture and uses advised against
As solvent, humectant, plasticiser, emollient, sweetener; in the manufacture of nitroglycerol (explosive), cosmetics, liquid soaps, liqueurs,
confectioneries, blacking, printing and copying inks and lubricants. It is also used in the manufacture of elastic glues, lead oxide cements; to keep
Relevant identified uses
fabrics pliable; to preserve printing on cotton; for printing rollers; to keep frost from windshields; as antifreeze in automobiles, gas meters and
hydraulic jacks, in shock absorber fluids. In fermentation nutrients in production of antibiotics.

Details of the manufacturer or supplier of the safety data sheet


Registered company name ALPHA CHEMICALS PTY LTD
Address 4 ALLEN PLACE WETHERILL PARK NSW 2164 Australia
Telephone 61 (0)2 9982 4622
Fax Not Available
Website ~
Email [email protected]

Emergency telephone number


Association / Organisation ALPHA CHEMICALS PTY LTD CHEMWATCH EMERGENCY RESPONSE (24/7)
Emergency telephone
61 (0)418 237 771 +61 1800 951 288
numbers
Other emergency telephone
Not Available +61 3 9573 3188
numbers

Once connected and if the message is not in your preferred language then please dial 01

SECTION 2 Hazards identification

Classification of the substance or mixture

HAZARDOUS CHEMICAL. NON-DANGEROUS GOODS. According to the WHS Regulations and the ADG Code.

Chemwatch Hazard Ratings


Min Max
Flammability 1
Toxicity 0 0 = Minimum
Body Contact 2 1 = Low
Reactivity 1 2 = Moderate
3 = High
Chronic 0 4 = Extreme

Poisons Schedule Not Applicable


Skin Corrosion/Irritation Category 2, Serious Eye Damage/Eye Irritation Category 2A, Specific Target Organ Toxicity - Single Exposure
Classification [1]
(Respiratory Tract Irritation) Category 3
Legend: 1. Classified by Chemwatch; 2. Classification drawn from HCIS; 3. Classification drawn from Regulation (EU) No 1272/2008 - Annex VI

Page 1 continued...
Chemwatch: 1987-5 Page 2 of 9 Issue Date: 23/12/2022
Version No: 13.1 Print Date: 19/01/2024
GLYCEROL

Label elements

Hazard pictogram(s)

Signal word Warning

Hazard statement(s)
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.

Precautionary statement(s) Prevention


P271 Use only outdoors or in a well-ventilated area.
P261 Avoid breathing mist/vapours/spray.
P280 Wear protective gloves, protective clothing, eye protection and face protection.
P264 Wash all exposed external body areas thoroughly after handling.

Precautionary statement(s) Response


P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312 Call a POISON CENTER/doctor/physician/first aider/if you feel unwell.
P337+P313 If eye irritation persists: Get medical advice/attention.
P302+P352 IF ON SKIN: Wash with plenty of water.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P332+P313 If skin irritation occurs: Get medical advice/attention.
P362+P364 Take off contaminated clothing and wash it before reuse.

Precautionary statement(s) Storage


P405 Store locked up.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.

Precautionary statement(s) Disposal


P501 Dispose of contents/container to authorised hazardous or special waste collection point in accordance with any local regulation.

SECTION 3 Composition / information on ingredients

Substances
CAS No %[weight] Name
56-81-5 >=96 Glycerol
Legend: 1. Classified by Chemwatch; 2. Classification drawn from HCIS; 3. Classification drawn from Regulation (EU) No 1272/2008 - Annex VI; 4. Classification drawn from C&L;
* EU IOELVs available

Mixtures
See section above for composition of Substances

SECTION 4 First aid measures

Description of first aid measures


If this product comes in contact with the eyes:
Wash out immediately with fresh running water.
Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper
Eye Contact
and lower lids.
Seek medical attention without delay; if pain persists or recurs seek medical attention.
Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
If skin contact occurs:
Immediately remove all contaminated clothing, including footwear.
Skin Contact
Flush skin and hair with running water (and soap if available).
Seek medical attention in event of irritation.
If fumes or combustion products are inhaled remove from contaminated area.
Lay patient down. Keep warm and rested.
Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures.
Inhalation
Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained.
Perform CPR if necessary.
Transport to hospital, or doctor, without delay.

Continued...
Chemwatch: 1987-5 Page 3 of 9 Issue Date: 23/12/2022
Version No: 13.1 Print Date: 19/01/2024
GLYCEROL

Immediately give a glass of water.


Ingestion
First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.

Indication of any immediate medical attention and special treatment needed


Treat symptomatically.

SECTION 5 Firefighting measures

Extinguishing media
Water spray or fog.
Foam.
Dry chemical powder.
BCF (where regulations permit).
Carbon dioxide.

Special hazards arising from the substrate or mixture


Fire Incompatibility Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result

Advice for firefighters


Alert Fire Brigade and tell them location and nature of hazard.
Wear full body protective clothing with breathing apparatus.
Prevent, by any means available, spillage from entering drains or water course.
Use water delivered as a fine spray to control fire and cool adjacent area.
Fire Fighting
Avoid spraying water onto liquid pools.
DO NOT approach containers suspected to be hot.
Cool fire exposed containers with water spray from a protected location.
If safe to do so, remove containers from path of fire.
Combustible.
Slight fire hazard when exposed to heat or flame.
Heating may cause expansion or decomposition leading to violent rupture of containers.
On combustion, may emit toxic fumes of carbon monoxide (CO).
May emit acrid smoke.
Mists containing combustible materials may be explosive.
Fire/Explosion Hazard
Combustion products include:
carbon dioxide (CO2)
acrolein
other pyrolysis products typical of burning organic material.
May emit poisonous fumes.
May emit corrosive fumes.
HAZCHEM Not Applicable

SECTION 6 Accidental release measures

Personal precautions, protective equipment and emergency procedures


See section 8

Environmental precautions
See section 12

Methods and material for containment and cleaning up


Slippery when spilt.
Remove all ignition sources.
Clean up all spills immediately.
Avoid breathing vapours and contact with skin and eyes.
Minor Spills
Control personal contact with the substance, by using protective equipment.
Contain and absorb spill with sand, earth, inert material or vermiculite.
Wipe up.
Place in a suitable, labelled container for waste disposal.
Slippery when spilt.
Moderate hazard.
Clear area of personnel and move upwind.
Alert Fire Brigade and tell them location and nature of hazard.
Major Spills Wear breathing apparatus plus protective gloves.
Prevent, by any means available, spillage from entering drains or water course.
No smoking, naked lights or ignition sources.
Increase ventilation.
Stop leak if safe to do so.

Personal Protective Equipment advice is contained in Section 8 of the SDS.

SECTION 7 Handling and storage

Precautions for safe handling


DO NOT allow clothing wet with material to stay in contact with skin
Avoid all personal contact, including inhalation.
Safe handling Wear protective clothing when risk of exposure occurs.
Use in a well-ventilated area.

Continued...
Chemwatch: 1987-5 Page 4 of 9 Issue Date: 23/12/2022
Version No: 13.1 Print Date: 19/01/2024
GLYCEROL

Prevent concentration in hollows and sumps.


DO NOT enter confined spaces until atmosphere has been checked.
Avoid smoking, naked lights or ignition sources.
Avoid contact with incompatible materials.
When handling, DO NOT eat, drink or smoke.
Store in original containers.
Keep containers securely sealed.
No smoking, naked lights or ignition sources.
Other information Store in a cool, dry, well-ventilated area.
Store away from incompatible materials and foodstuff containers.
Protect containers against physical damage and check regularly for leaks.
Observe manufacturer's storage and handling recommendations contained within this SDS.

Conditions for safe storage, including any incompatibilities


Metal can or drum
Suitable container Packaging as recommended by manufacturer.
Check all containers are clearly labelled and free from leaks.
Glycerol:
reacts violently with strong oxidisers, acetic anhydride, alkali metal hydrides, calcium hypochlorite, calcium oxychloride, chlorine, chromic
anhydride, chromium oxides, ethylene oxide, hydrogen peroxide, phosphorous triiodide, potassium chlorate, potassium permanganate,
Storage incompatibility potassium peroxide, silver perchlorate, sodium hydride, sodium peroxide, sodium triiodide, sodium tetrahydroborate,is incompatible with
strong acids, caustics, aliphatic amines, isocyanates, uranium fluoride
is able to polymerise above 145 C
Avoid reaction with oxidising agents

SECTION 8 Exposure controls / personal protection

Control parameters

Occupational Exposure Limits (OEL)


INGREDIENT DATA
Material
Source Ingredient TWA STEL Peak Notes
name
10 Not Not (a) This value is for inhalable dust containing no asbestos and <
Australia Exposure Standards Glycerol Glycerin mist
mg/m3 Available Available 1% crystalline silica.

Emergency Limits
Ingredient TEEL-1 TEEL-2 TEEL-3
Glycerol 45 mg/m3 180 mg/m3 1,100 mg/m3

Ingredient Original IDLH Revised IDLH


Glycerol Not Available Not Available

Exposure controls
Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls can
be highly effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection.
The basic types of engineering controls are:
Process controls which involve changing the way a job activity or process is done to reduce the risk.
Appropriate engineering Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation that strategically
controls "adds" and "removes" air in the work environment. Ventilation can remove or dilute an air contaminant if designed properly. The design of a
ventilation system must match the particular process and chemical or contaminant in use.
Employers may need to use multiple types of controls to prevent employee overexposure.

General exhaust is adequate under normal operating conditions.

Individual protection
measures, such as personal
protective equipment

Safety glasses with side shields.


Chemical goggles. [AS/NZS 1337.1, EN166 or national equivalent]
Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing
the wearing of lenses or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption
Eye and face protection
and adsorption for the class of chemicals in use and an account of injury experience. Medical and first-aid personnel should be trained in
their removal and suitable equipment should be readily available. In the event of chemical exposure, begin eye irrigation immediately and
remove contact lens as soon as practicable. Lens should be removed at the first signs of eye redness or irritation - lens should be removed in
a clean environment only after workers have washed hands thoroughly.
Skin protection See Hand protection below
Wear chemical protective gloves, e.g. PVC.
Wear safety footwear or safety gumboots, e.g. Rubber
The selection of suitable gloves does not only depend on the material, but also on further marks of quality which vary from manufacturer to
manufacturer. Where the chemical is a preparation of several substances, the resistance of the glove material can not be calculated in advance
Hands/feet protection and has therefore to be checked prior to the application.
The exact break through time for substances has to be obtained from the manufacturer of the protective gloves and has to be observed when
making a final choice.
Personal hygiene is a key element of effective hand care. Gloves must only be worn on clean hands. After using gloves, hands should be
washed and dried thoroughly. Application of a non-perfumed moisturiser is recommended.

Continued...
Chemwatch: 1987-5 Page 5 of 9 Issue Date: 23/12/2022
Version No: 13.1 Print Date: 19/01/2024
GLYCEROL

Suitability and durability of glove type is dependent on usage.


Body protection See Other protection below
Overalls.
P.V.C apron.
Other protection Barrier cream.
Skin cleansing cream.
Eye wash unit.

Recommended material(s) Respiratory protection


GLOVE SELECTION INDEX Type A-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001,
Glove selection is based on a modified presentation of the: ANSI Z88 or national equivalent)
"Forsberg Clothing Performance Index". Where the concentration of gas/particulates in the breathing zone, approaches or
The effect(s) of the following substance(s) are taken into account in the computer- exceeds the "Exposure Standard" (or ES), respiratory protection is required.
generated selection: Degree of protection varies with both face-piece and Class of filter; the nature of
GLYCEROL protection varies with Type of filter.

Material CPI Required Minimum Half-Face Full-Face Powered Air


NATURAL RUBBER A Protection Factor Respirator Respirator Respirator

NATURAL+NEOPRENE A A-PAPR-AUS /
up to 10 x ES A-AUS P2 -
Class 1 P2
NITRILE A
A-AUS / Class 1
up to 50 x ES - -
* CPI - Chemwatch Performance Index P2
A: Best Selection up to 100 x ES - A-2 P2 A-PAPR-2 P2 ^
B: Satisfactory; may degrade after 4 hours continuous immersion
C: Poor to Dangerous Choice for other than short term immersion ^ - Full-face
NOTE: As a series of factors will influence the actual performance of the glove, a final A(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 = Acid gas or
selection must be based on detailed observation. - hydrogen cyanide(HCN), B3 = Acid gas or hydrogen cyanide(HCN), E = Sulfur
* Where the glove is to be used on a short term, casual or infrequent basis, factors such dioxide(SO2), G = Agricultural chemicals, K = Ammonia(NH3), Hg = Mercury, NO =
as "feel" or convenience (e.g. disposability), may dictate a choice of gloves which might Oxides of nitrogen, MB = Methyl bromide, AX = Low boiling point organic
otherwise be unsuitable following long-term or frequent use. A qualified practitioner compounds(below 65 degC)
should be consulted.
Cartridge respirators should never be used for emergency ingress or in areas of
Ansell Glove Selection unknown vapour concentrations or oxygen content.
The wearer must be warned to leave the contaminated area immediately on
Glove — In order of recommendation detecting any odours through the respirator. The odour may indicate that the mask is
not functioning properly, that the vapour concentration is too high, or that the mask is
AlphaTec 02-100 not properly fitted. Because of these limitations, only restricted use of cartridge
AlphaTec® 15-554 respirators is considered appropriate.
Cartridge performance is affected by humidity. Cartridges should be changed after 2
AlphaTec® Solvex® 37-185 hr of continuous use unless it is determined that the humidity is less than 75%, in
AlphaTec® 38-612 which case, cartridges can be used for 4 hr. Used cartridges should be discarded
daily, regardless of the length of time used
AlphaTec® 53-001 76a-p()
AlphaTec® 58-005
AlphaTec® 58-008
AlphaTec® 58-530B
AlphaTec® 58-530W
AlphaTec® 58-735

The suggested gloves for use should be confirmed with the glove supplier.

SECTION 9 Physical and chemical properties

Information on basic physical and chemical properties


Oily, colourless, odourless liquid, with syrupy, sweet taste. Miscible with water and alcohol. Insoluble in benzene, ether, chloroform, fixed and
Appearance
volatile oils. Absorbs water from the air. Also absorbs hydrogen sulfide, hydrogen cyanide and sulfur dioxide.

Physical state Liquid Relative density (Water = 1) 1.2-1.3 @ 20 C


Partition coefficient n-octanol
Odour Not Available Not Available
/ water
Odour threshold Not Available Auto-ignition temperature (°C) 370
Decomposition
pH (as supplied) Not Applicable >280
temperature (°C)
Melting point / freezing point
18 Viscosity (cSt) Not Available
(°C)
Initial boiling point and boiling
290 Molecular weight (g/mol) 92.1
range (°C)
Flash point (°C) 160 Taste Not Available
Evaporation rate Non Volatile Explosive properties Not Available
Flammability Not Applicable Oxidising properties Not Available
Surface Tension (dyn/cm or
Upper Explosive Limit (%) 19 Not Available
mN/m)
Lower Explosive Limit (%) 3 Volatile Component (%vol) Nil @ 38 C.
Vapour pressure (kPa) 0.003 @ 50 C Gas group Not Available

Continued...
Chemwatch: 1987-5 Page 6 of 9 Issue Date: 23/12/2022
Version No: 13.1 Print Date: 19/01/2024
GLYCEROL

Solubility in water Miscible pH as a solution (1%) 7 approx.


Vapour density (Air = 1) 3.17 VOC g/L Not Available

SECTION 10 Stability and reactivity

Reactivity See section 7


Unstable in the presence of incompatible materials.
Chemical stability Product is considered stable.
Hazardous polymerisation will not occur.
Possibility of hazardous
See section 7
reactions
Conditions to avoid See section 7
Incompatible materials See section 7
Hazardous decomposition
See section 5
products

SECTION 11 Toxicological information

Information on toxicological effects


The material can cause respiratory irritation in some persons. The body's response to such irritation can cause further lung damage.
Inhaled
Not normally a hazard due to non-volatile nature of product
Ingestion of large quantities may cause nausea, diarrhoea and vomiting. Biokinetic studies indicate that a 70 kg adult should be able to
metabolise and excrete over 2 grams of glycerol in an 8-hour workday.
Ingestion
Although ingestion is not thought to produce harmful effects (as classified under EC Directives), the material may still be damaging to the health
of the individual, following ingestion, especially where pre-existing organ (e.g. liver, kidney) damage is evident.
The material may accentuate any pre-existing dermatitis condition
Skin contact is not thought to have harmful health effects (as classified under EC Directives); the material may still produce health damage
following entry through wounds, lesions or abrasions.
Open cuts, abraded or irritated skin should not be exposed to this material
Skin Contact
Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects. Examine the skin
prior to the use of the material and ensure that any external damage is suitably protected.
The material may cause mild but significant inflammation of the skin either following direct contact or after a delay of some time. Repeated
exposure can cause contact dermatitis which is characterised by redness, swelling and blistering.
Evidence exists, or practical experience predicts, that the material may cause eye irritation in a substantial number of individuals. Prolonged eye
Eye
contact may cause inflammation characterised by a temporary redness of the conjunctiva (similar to windburn).
Long-term exposure to respiratory irritants may result in airways disease, involving difficulty breathing and related whole-body problems.
Chronic
Substance accumulation, in the human body, may occur and may cause some concern following repeated or long-term occupational exposure.

TOXICITY IRRITATION

dermal (guinea pig) LD50: 58500 mg/kg[1] Not Available


Glycerol
Inhalation(Rat) LC50: >5.85 mg/L4h[1]

Oral (Mouse) LD50; 4090 mg/kg[2]

Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2. Value obtained from manufacturer's SDS. Unless otherwise
specified data extracted from RTECS - Register of Toxic Effect of chemical Substances

Asthma-like symptoms may continue for months or even years after exposure to the material ends. This may be due to a non-allergic condition
known as reactive airways dysfunction syndrome (RADS) which can occur after exposure to high levels of highly irritating compound. Main
criteria for diagnosing RADS include the absence of previous airways disease in a non-atopic individual, with sudden onset of persistent
asthma-like symptoms within minutes to hours of a documented exposure to the irritant. Other criteria for diagnosis of RADS include a reversible
airflow pattern on lung function tests, moderate to severe bronchial hyperreactivity on methacholine challenge testing, and the lack of minimal
GLYCEROL lymphocytic inflammation, without eosinophilia. RADS (or asthma) following an irritating inhalation is an infrequent disorder with rates related to
the concentration of and duration of exposure to the irritating substance. On the other hand, industrial bronchitis is a disorder that occurs as a
result of exposure due to high concentrations of irritating substance (often particles) and is completely reversible after exposure ceases. The
disorder is characterized by difficulty breathing, cough and mucus production.
At very high concentrations, evidence predicts that glycerol may cause tremor, irritation of the skin, eyes, digestive tract and airway. Otherwise it
is of low toxicity. There is no significant evidence to suggest that it causes cancer, genetic, reproductive or developmental toxicity.

Acute Toxicity Carcinogenicity


Skin Irritation/Corrosion Reproductivity
Serious Eye Damage/Irritation STOT - Single Exposure
Respiratory or Skin
STOT - Repeated Exposure
sensitisation
Mutagenicity Aspiration Hazard
Legend: – Data either not available or does not fill the criteria for classification
– Data available to make classification

SECTION 12 Ecological information

Toxicity

Glycerol Endpoint Test Duration (hr) Species Value Source

Continued...
Chemwatch: 1987-5 Page 7 of 9 Issue Date: 23/12/2022
Version No: 13.1 Print Date: 19/01/2024
GLYCEROL

LC50 96h Fish >11mg/L 2


EC0(ECx) 24h Crustacea >500mg/l 1

Legend: Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity 4. US EPA,
Ecotox database - Aquatic Toxicity Data 5. ECETOC Aquatic Hazard Assessment Data 6. NITE (Japan) - Bioconcentration Data 7. METI (Japan)
- Bioconcentration Data 8. Vendor Data

For Glycerol: Log Kow: -2.66 to -2.47, Atmospheric Fate: Glycerol is broken down in the air by hydroxyl radicals the half-life for this process is 6.8 hours. However, only a negligible
amount of the substance will move to the atmospheric compartment. Terrestrial Fate: Only a negligible amount of glycerol will move into the soil compartment, if released into the
environment. Aquatic Fate: Glycerol is considered to be readily biodegradable in the aquatic environment. Pre-adapted microorganisms can break glycerol down rapidly in
oxygenated/low oxygen waters. The substance is not expected to react with water. When released to water, 100% of the substance will remain in the water compartment - only
negligible amounts will be distributed to sediment.
DO NOT discharge into sewer or waterways.

Persistence and degradability


Ingredient Persistence: Water/Soil Persistence: Air
Glycerol LOW LOW

Bioaccumulative potential
Ingredient Bioaccumulation
Glycerol LOW (LogKOW = -1.76)

Mobility in soil
Ingredient Mobility
Glycerol HIGH (KOC = 1)

SECTION 13 Disposal considerations

Waste treatment methods


Legislation addressing waste disposal requirements may differ by country, state and/ or territory. Each user must refer to laws operating in their
area. In some areas, certain wastes must be tracked.
A Hierarchy of Controls seems to be common - the user should investigate:
Reduction
Reuse
Recycling
Disposal (if all else fails)
This material may be recycled if unused, or if it has not been contaminated so as to make it unsuitable for its intended use. If it has been
contaminated, it may be possible to reclaim the product by filtration, distillation or some other means. Shelf life considerations should also be
Product / Packaging disposal applied in making decisions of this type. Note that properties of a material may change in use, and recycling or reuse may not always be
appropriate.
DO NOT allow wash water from cleaning or process equipment to enter drains.
It may be necessary to collect all wash water for treatment before disposal.
In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first.
Where in doubt contact the responsible authority.
Recycle wherever possible or consult manufacturer for recycling options.
Consult State Land Waste Authority for disposal.
Bury or incinerate residue at an approved site.
Recycle containers if possible, or dispose of in an authorised landfill.

SECTION 14 Transport information

Labels Required

Marine Pollutant NO
HAZCHEM Not Applicable

Land transport (ADG): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

Air transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

14.7.1. Transport in bulk according to Annex II of MARPOL and the IBC code
Not Applicable

14.7.2. Transport in bulk in accordance with MARPOL Annex V and the IMSBC Code
Product name Group
Glycerol Not Available

14.7.3. Transport in bulk in accordance with the IGC Code


Product name Ship Type
Glycerol Not Available

Continued...
Chemwatch: 1987-5 Page 8 of 9 Issue Date: 23/12/2022
Version No: 13.1 Print Date: 19/01/2024
GLYCEROL

SECTION 15 Regulatory information

Safety, health and environmental regulations / legislation specific for the substance or mixture

Glycerol is found on the following regulatory lists


Australian Inventory of Industrial Chemicals (AIIC)

Additional Regulatory Information


Not Applicable

National Inventory Status


National Inventory Status
Australia - AIIC / Australia
Yes
Non-Industrial Use
Canada - DSL Yes
Canada - NDSL No (Glycerol)
China - IECSC Yes
Europe - EINEC / ELINCS / NLP Yes
Japan - ENCS Yes
Korea - KECI Yes
New Zealand - NZIoC Yes
Philippines - PICCS Yes
USA - TSCA Yes
Taiwan - TCSI Yes
Mexico - INSQ Yes
Vietnam - NCI Yes
Russia - FBEPH Yes
Yes = All CAS declared ingredients are on the inventory
Legend:
No = One or more of the CAS listed ingredients are not on the inventory. These ingredients may be exempt or will require registration.

SECTION 16 Other information

Revision Date 23/12/2022


Initial Date 12/05/2005

SDS Version Summary


Date of
Version Sections Updated
Update
Identification of the substance / mixture and of the company / undertaking - Supplier Information, Identification of the
12.1 17/03/2018
substance / mixture and of the company / undertaking - Synonyms
13.1 23/12/2022 Classification review due to GHS Revision change.

Other information
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification
committee using available literature references.

The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or
other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered.

Definitions and abbreviations


PC TWA: Permissible Concentration-Time Weighted Average
PC STEL: Permissible Concentration-Short Term Exposure Limit
IARC: International Agency for Research on Cancer
ACGIH: American Conference of Governmental Industrial Hygienists
STEL: Short Term Exposure Limit
TEEL: Temporary Emergency Exposure Limit
IDLH: Immediately Dangerous to Life or Health Concentrations
ES: Exposure Standard
OSF: Odour Safety Factor
NOAEL: No Observed Adverse Effect Level
LOAEL: Lowest Observed Adverse Effect Level
TLV: Threshold Limit Value
LOD: Limit Of Detection
OTV: Odour Threshold Value
BCF: BioConcentration Factors
BEI: Biological Exposure Index
DNEL: Derived No-Effect Level
PNEC: Predicted no-effect concentration

AIIC: Australian Inventory of Industrial Chemicals


DSL: Domestic Substances List
NDSL: Non-Domestic Substances List
IECSC: Inventory of Existing Chemical Substance in China
EINECS: European INventory of Existing Commercial chemical Substances

Continued...
Chemwatch: 1987-5 Page 9 of 9 Issue Date: 23/12/2022
Version No: 13.1 Print Date: 19/01/2024
GLYCEROL

ELINCS: European List of Notified Chemical Substances


NLP: No-Longer Polymers
ENCS: Existing and New Chemical Substances Inventory
KECI: Korea Existing Chemicals Inventory
NZIoC: New Zealand Inventory of Chemicals
PICCS: Philippine Inventory of Chemicals and Chemical Substances
TSCA: Toxic Substances Control Act
TCSI: Taiwan Chemical Substance Inventory
INSQ: Inventario Nacional de Sustancias Químicas
NCI: National Chemical Inventory
FBEPH: Russian Register of Potentially Hazardous Chemical and Biological Substances

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end of SDS

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