MATERIAL SAFETY DATA SHEET

1. Identification
A. Product name

ND-705 ( Rainbow Collor Chromate)

B. Recommended Use and Restriction on Use
General use : Cr_3 Rainbow Collor chromate
Restriction on use : Cr_3 Rainbow Collor chromate
C. Manufacturer / Supplier / distributor information
○ Manufacturer information
Company name : namdongchemical co.,ltd
Address :(1ra 208,shihwa kongdan,jungwang-dong) 131beon-gil 74
okguchon seo-ro shiheung-city,kyunggi-do,south
Dept. : enviromental safety
Telephone number : 031)499-2411~5
Emergency telephone number : 031)499-2411
Fax number : 031)499-2416
E-mail address : ndchemic@[Link]
○ Supplier/Distributer information
Company name : namdongchemical co.,ltd
Address :(1ra 208,shihwa kongdan,jungwang-dong) 131beon-gil 74
okguchon seo-ro shiheung-city,kyunggi-do,south
Dept. : enviromental safety
Telephone number : 031)499-2411~5
Emergency telephone number : 031)499-2411
Fax number : 031)499-2416
E-mail address : ndchemic@[Link]
2. Hazard identification
A. GHS Classification
Carcinogenicity : Category1
Serious eye damage/irritation : Category1
Skin sensitization : Category1
Skin corrosion/irritation : Category2
Respiratory sensitization : Category1
B. GHS label elements
○ Hazard symbols

○ Signal words
Danger
○ Hazard statements
H314 Causes severe skin burns and eye damage
H317 May cause an allergic skin reaction
H318 Causes serious eye damage
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled
H350 May cause cancer
○ Precautionary statements
1) Prevention
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of the workplace.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
 P281 Use personal protective equipment as required.
P285 In case of inadequate ventilation wear respiratory protection.
2) Response
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all
contaminated clothing. Rinse skin with water/shower.
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position
P304+P341 IF INHALED: If breathing is difficult, remove victim to fresh air and keep
at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P310 Immediately call a POISON CENTER or doctor/physician.
P321 Specific treatment
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER or
- P363 Wash contaminated clothing before reuse.
3) Storage
P405 Store locked up.
4) Disposal
P501 Dispose of contents/container in accordance with
C. Other hazards which do not result in classification : (NFPA Classification)
○ NFPA grade (0 ~ 4 level)
- Health : 3, Flammability : 0, Reactivity : 0
3. Composition/information on ingredients
Trade names and
Chemical Name CAS No. Content
Synonyms
Chromium trinitrate 13548-38-4 20.0
Sulfuric acid 7664-93-9 8.0
Cobalt sulfate 10124-43-3 2.0
Other 25.0
Water 7732-18-5 45.0
4. First-aid measures
A. Eye Contact
- Do not rub your eyes.
- Immediately flush eyes with plenty of water for at least 15minutes and call a doctor/physician.
- Get medical attention immediately.
- Remove contact lenses if worn.
B. Skin Contact
- Flush skin with plenty of wter for at least 15 minutes while removing contaminated clothing and
- Laundering enough contaminated clothing before reuse.
- Get medical attention immediately.
- Go to the hospital immediately if symptoms(flare, irritate) occur.
- Prevent the spread of the skin.
- Remove contaminated clothing, shoes and isolate.
- Wash thoroughly after handling.
- Wear gloves when washing the patient, and please avoid contact with contaminated clothing.
C. Inhalation
- When exposed to large amounts of steam and mist, move to fresh air.
- Take specific treatment if needed.
- Get medical attention immediately.
- Go to the hospital immediately if symptoms(flare, irritate) occur.
- If breathing is stopped or irregular, give artificial respiration and supply oxygen.
D. Ingestion
- About whether I should induce vomiting Take the advice of a doctor.
- Rinse your mouth with water immediately.
- Get medical attention immediately.
E. Delayed and immediate effects and also chronic effects from short and long term exposure
- Not available
 F. Notes to Physician
- Notify medical personnel of contaminated situations and have them take appropriate protective
- IF exposed or concerned, get medical attention/advice.
- Remove to fresh air and keep at rest in a position comfortable for breathing.
5. Fire-fighting measures
A. Suitable (Unsuitable) extinguishing media
- Avoid use of water jet for extinguishing
B. Specific hazards arising from the chemical
- Not available
C. Special protective actions for fire-fighters
- Move containers from fire area, if you can do without the risk.
- Keep unauthorized personnel out.
- Withdraw immediately in case of rising sound from venting safety devices or discoloration of
- Using a unattended and water devices in case of large fire and leave alone to burn if you do not
- Do not access if the tank on fire.
- Vapor or gas is burned at distant ignition sources can be spread quickly.
6. Accidental release measures
A. Personal Precautions, protective equipment and emergency procedures
- Wear proper personal protective apparatus as indicated in Section 8 and avoid skin contact and
- Must work against the wind, let the upwind people to evacuate.
- Move container to safe area from the leak area.
- Remove all sources of ignition.
- Do not direct water at spill or source of leak.
- Avoid skin contact and inhalation.
- Cleanup and disposal under expert supervision is advised.
- Keep unauthorized people away,isolate hazard area and deny entry.
B. Environmental precautions
- Prevent runoff and contact with waterways, drains or sewers.
- if large amounts have been spilled, inform the relevant authorities.
C. Methods and materials for containment and cleaning up
- Large spill : Stay upwind and keep out of low areas. Dike for later disposal.
- Notification to central government, local government. When emissions at least of the standard
- Dispose of waste in accordance with local regulation.
- Appropriate container for disposal of spilled material collected.
- Small leak: sand or other non-combustible material, please let use absorption.
- Wipe off the solvent.
- Dike for later disposal.
- Spilled material should be treated as a potential risk of waste collected.
7. Handling and storage
A. Precautions for safe handling
- Avoid contact with incompatible materials.
- Dealing only with a well-ventilated place.
- Do not handle until all safety precautions have been read and understood.
- Operators should wear antistatic footwear and clothing.
- Do not inhale the steam prolonged or repeated.
- Contaminated work clothing should not be allowed out of the workplace.
B. Conditions for safe storage, including any incompatibilities
- Save in cool, dry and well ventilated place.
- Save applicable laws and regulations.
- Avoid direct sunlight.
- No open fire.
- Prevent static electricity and keep away from combustible materials or heat sources.
- By specifying a storage area for carcinogenic substances.
- Collected them in sealed containers.
8. Exposure controls/personal protection
A. Exposure Limits
○ ACGIH TLV
- [Nitric acid ; Aqua fortis] : TWA 2 ppm
- [Cobalt sulfate] : TWA 0.02 ㎎/㎥
B. Engineering Controls
 - A system of local and/or general exhaust is recommended to keep employee exposures above
the Exposure Limits. Local exhaust ventilation is generally preferred because it can control the
emissions of the contaminant at its source, preventing dispersion of it into the general work area.
The use of local exhaust ventilation is recommended to control emissions near the source.
C. Personal Protective Equipment
○ Respiratory protection
- Under conditions of frequent use or heavy exposure, Respiratory protection may be
- Respiratory protection is ranked in order from minimum to maximum.
- Consider warning properties before use.
- Any chemical cartridge respirator with organic vapor cartridge(s).
- Any chemical cartridge respirator with a full facepiece and organic vaporcartridge(s).
- Any air-purifying respirator with a full facepiece and an organic vapor canister.
- For Unknown Concentration or Immediately Dangerous to Life or Health : Any supplied-air
respirator with full facepiece and operated in a pressure-demand or other positive-pressure
mode in combination with a separate escape supply. Any self-contained breathing
apparatus with a full facepiece
○ Eye protection
- Wear primary eye protection such as splash resistant safety goggles with a secondary
- Provide an emergency eye wash station and quick drench shower in the immediate work
○ Hand protection
- Wear appropriate glove.
○ Skin protection
- Wear appropriate glove.
9. Physical and chemical properties
A. Appearance
Appearance : Liquid
Color : deep violet
O. Partition coefficient of n-octanol/water : N/A
B. Odor : light odor
P. Autoignition Temperature : N/A
C. Odor threshold : N/A
Q. Decomposition Temperature : N/A
D. pH :Acid (1.0 below)
R. Viscosity : N/A
E. Melting point/Freezing point : N/A
S. Molecular weight : N/A
F. Initial Boiling Point/Boiling Ranges : Not available
G. Flash point : Not available
H. Evapourating Rate : N/A
I. Flammability(solid, gas) : N/A
J. Upper/Lower Flammability or explosive limits : N/A
K. Vapour pressure : N/A
L. Solubility : a soluble
M. Vapour density : N/A
N. Specific gravity : 1.06~1.09
10. Stability and reactivity
A. Chemical stability
- This material is stable under recommended storage and handling conditions.
B. Possibility of hazardous reactions
- Hazardous Polymerization will not occur.
C. Conditions to avoid
- Avoid contact with incompatible materials and condition.
D. Incompatible materials
- Not available
E. Hazardous decomposition products
- Not available
11. Toxicological information
A. Information on the likely routes of exposure
○ (Respiratory tracts)
- May cause allergy or asthma symptoms or breathing difficulties if inhaled
○ (Oral)
 - Not available
○ (Eye·Skin)
- Causes serious eye damage
- Causes severe skin burns and eye damage
- May cause an allergic skin reaction
B. Delayed and immediate effects and also chronic effects from short and long term exposure
○ Acute toxicity
* Oral
- [Chromium trinitrate] : LD50 3250 ㎎/㎏ Rat
- [Cobalt sulfate] : LD50 424 ㎎/㎏ Rat
* Dermal
- [Chromium trinitrate] : LD50 3232 ㎎/㎏ Mouse (Subcutaneous)
* Inhalation
- Not available
○ Skin corrosion/irritation
- Causes severe skin burns and eye damage
○ Serious eye damage/irritation
- Causes serious eye damage
○ Respiratory sensitization
- May cause allergy or asthma symptoms or breathing difficulties if inhaled
○ Skin sensitization
- May cause an allergic skin reaction
○ Carcinogenicity
* ISHL(The industrial Safety and Health Law in Korea)
- Not available
* MOL Announcement
- Not available
* IARC
- [Chromium trinitrate] : Group 3 (Chromium [III] compounds )
* OSHA
- Not available
* ACGIH
- [Chromium trinitrate] : A4 (Chromium (III) compounds, inorganic compounds)
* NTP
- Not available
* EU CLP
- Not available
* Other
- [Cobalt sulfate] : group 2B
○ Germ cell mutagenicity
- Not available
○ Reproductive toxicity
- Not available
○ STOT-single exposure
- Not available
○ STOT-repeated exposure
- Not available
○ Aspiration hazard
- Not available
12. Ecological information
A. Ecotoxicity
○ Fish
- [Chromium trinitrate] : LC50 4.4 ㎎/ℓ 96 hr ((Mortality) Rainbow trout, donaldson trout).
- [Cobalt sulfate] : LC50 3.46 ㎎/ℓ 96 hr Pimephales promelas
○ Crustaceans
- [Chromium trinitrate] : (50000ug / l 6.5hr LT50 (mortality), mussels)
- [Cobalt sulfate] : EC50 0.397 ㎎/ℓ 48 hr (Species Daphnia pulicaria)
- [2-Hydroxypropanoic acid monosodium salt ; Sodium lactate] : EC50 > 2050 ㎎/ℓ 48 hr
○ Algae
- [Cobalt sulfate] : EC50 10.2 ㎎/ℓ 96 hr (Species Phaeodactylum tricornutum)
 B. Persistence and degradability
○ Persistence
- [Chromium trinitrate] : (Not applicable)
- [Cobalt sulfate] : log Kow not available
- [2-Hydroxypropanoic acid monosodium salt ; Sodium lactate] : log Kow -4.77
○ Degradability
- Not available
C. Bioaccumulative potential
○ Bioaccumulative potential
- [Cobalt sulfate] : BCF 200 ~ 1000
○ Biodegration
- Not available
D. Mobility in soil
- Not available
E. Other adverse effects
- Not available
13. Disposal considerations
A. Disposal methods
- Since more than two kinds of designaed waste is mixed, it is difficult to treat seperatly, then can
be reduction or stabilization by incineration or similar process.
- if water separation is possible, pre-process with Water separation process.
- Dispose by incineration.
B. Special precautions for disposal
- The user of this product must disposal by oneself or entrust to waste disposer or person who
other’s waste recycle and dispose, person who establish and operate waste disposal facilities.
- Dispose of waste in accordance with all applicable laws and regulations.
14. Transport information
A. UN number
3082
B. Proper shipping name
Environmentally hazardous substances, liquid, n.o.s.(Nitric acid)
C. Hazard class : 9
D. Packing group : Ⅲ
E. Marine pollutant
- Not applicable
F. Special precautions for user related to transport or transportation measures
- Local transport follows in accordance with Dangerous goods Safety Management Law.
- Package and transport follow in accordance with Department of Transportation (DOT) and other
regulatory agency requirements.
- EmS FIRE SCHEDULE : F-A (General fire schedule)
- EmS SPILLAGE SCHEDULE : S-F (Water-soluble marine pollutants)
15. Regulatory information
A. National and/or international regulatory information
○ POPs Management Law
- Not applicable
○ Information of EU Classification
* Classification
- [Nitric acid ; Aqua fortis] : O; R8 C; R35
- [Cobalt sulfate] : Carc. Cat. 2; R49/ Muta. Cat. 3; R68, Repr. Cat. 2; R60, Xn;
* Risk Phrases
- [Nitric acid ; Aqua fortis] : R8, R35
- [Cobalt sulfate] : R49, R22, R42/43, R50/53, R60, R68
* Safety Phrase
- [Nitric acid ; Aqua fortis] : S1/2, S23, S26, S36, S45
- [Cobalt sulfate] : S53, S45, S60, S61
○ U.S. Federal regulations
* OSHA PROCESS SAFETY (29CFR1910.119)
- [Nitric acid ; Aqua fortis] : 226.7995 kg 500 lb
* CERCLA Section 103 (40CFR302.4)
- [Nitric acid ; Aqua fortis] : 453.599 kg 1000 lb
 * EPCRA Section 302 (40CFR355.30)
- [Nitric acid ; Aqua fortis] : 453.599 kg 1000 lb
* EPCRA Section 304 (40CFR355.40)
- [Nitric acid ; Aqua fortis] : 453.599 kg 1000 lb
* EPCRA Section 313 (40CFR372.65)
- [Nitric acid ; Aqua fortis] : Applicable
○ Rotterdam Convention listed ingredients
- Not applicable
○ Stockholm Convention listed ingredients
- Not applicable
○ Montreal Protocol listed ingredients
- Not applicable
16. Other information
A. Reference
- The information contained herein is believed to be accurate. It is provided independently of any
sale of the product for purpose of hazard communication. It is not intended to constitute
performance information concerning the product. No express warranty, or implied warranty of
merchantability or fitness for a particular purpose is made with respect to the product or the
information contained herein
- 1. KOSHA
- 2. NITE
- 3. ESIS
- 4. NLM
- 5. SIDS
- 6. IPCS
B. Issue date
- 2012-10-25
C. Revision number and Last date revised
D. Other