IITJEE (Advanced & Main)/NEET/Board
9899818241/Sec-45, Gurgaon
Redox
Class-1
Bighnaraj Mishra
i
) C
, 2422011
-
I 2N t
(22×1) t (-2×11)=0
U = 0
(Vii) Na
25208
(2×1) t 2N + (-2×8)=0
n =
+7 X It is not possible
became its is
group no .
6 .
Structure
"
*
Another method
atoms
Here two
types of oxygen
are present having
two types of oxidation
Number .
Let ie of peroxide oxygen
'
number
and I D oxide are
oxygen
- n u
present .
Nard 208
(2×1) t
2g
t
¢ -
DN t C 2) (
-
s -
}
n = O
U -16 the +2 0
2g
-
=
y =
MII
U Even and have 2 4,6 values
may
= no . ,
when U -16
2
y
= =
,
and
Thus ,
there are 2 peroxide oxygen
6 oxide oxygen .
(Viii) Hz Sos → Cero 's acid
(2×1) t
y
t (-2×5) = 0
y
= -18 X
structure -2
- o
-9
Hee I ti
Ii
'
,
-
O -
O -
H
- I
0
00
°
Another method
→ = peroxide O✗
ygen
oxide 0✗
5- N =
ygen
I .
2 t C -
I xn ) t
(5-a) C -
2) +
y
= 0
8 where
y
= -
N u =
2,4
putting ,
re =z
y
= +6
CX) HCN
+3
l - 3
1- I
-
H - C EN
'
± , Ia Is
HD H NC
* when coordinate bond is from move
atom
-
re atom to lens -
re
,
the
charge
is o for both the atoms .
* when coordinate bond is from less
-
re atom to move -
ve atom ,
then
donor atom acquires +2 and receiver
atom acquires -2 .
Move - ve hers - ve
:b
1%
"
a-
bond
Tf
/
O O
1- l
l coordinate
with:#
-
H -
N Edc
-2 -12
¥ ± * '
.
+ I
HN
*
Oz
- - Z
t ' Ii go
H -
o -
o
f -
2
1- 5
Lxii) Cao !
2t C 2)
-
+ 2N = o
n -
- O
④
si
Stucke U it '
-
yo
-
+ ,
+4 -
⑧ -
i - i
r
Redox Reaction
-
oxidatiounltakfreectioon-CO.HR)
* Gain of oxygen
lows of
hydrogen
*
* loss
of electrons
Rednetionthtakfree.ch#CRHR)
* Gain of hydrogen
* lots of oxygen
* Gain of electrons
oxidisingagent-co.AT → oxidises other
but itself is reduced .
Reducing agent CR A)
- → reduces other
-
but itself is oxidised .
Types of Redox reactions
( i) Combination Reaction -
Qe
+4 2
d
o -
Ex -
s +
Oz →
coz
CRAY
E. AS
o p +2 -
3
3mg Ns
Mgs Nz
t →
(R A)
.
(0 A).
Ci)
Decomposition -
TED
Ext 2K 05-0 , act 't 30oz
-
(oxidn)
(iii) Reaction
Displacement
-
-
(a) Metal displacement reen )
#§xiI
Ex ciisoy In
-
i ztnsoytcn + →
co .at#@nn
* more reactive metal can
replace the
hers reactive metal from its salt
solvation in the reactive series .
(b) Non metal displacement
#ydn)
-
Ext
2HzEt2Fz→ 4 HE't Iz
t icon
(R A)
-
Cox id )
Cib
Disproportionation Reaction
T oxins
Poy BH, +3 HIKE
-
Ex -13 OH # 3h20 →
-
(Red]
Same element oxidation and
undergo
reduction .
Coxidn)
O -I +5 -
Broj
'
Ex
-
Brzt OH -7 Br t
-
-
(Red )
n
of
Balancing Redox reaction
> Ion - Electron method
> oxidation Number method
Ion -
Electron method
Rules -
(1) Write the unbalanced egestion and
find the
oxidising agent and
reducing
agent . Divide the entire equation into
2 halves -
(a) Oxidation Half Reaction .
(b) Reduction Half Reaction .
yup
③ Balance each half reaction as
follows -
(a) Balance all atoms other than
O and H .
(b) Add H2O to the side deficient in
oxygen
.
(C) Add Ht to the side deficient in
hydrogen
(d) Add electrons ( e s) to
-
balance
the
charge
-
③ Add the 2 half reactions in such
a manner so that e- s
get
cancelled out .
for this
multiply
each half reaction with suitable
integer .
④ Recheck the egestion for charge
balance as well as mars balance .
