Material Safety Data Sheet

1 . Product and com pany identification

Product code : C70-N501/G280 900
Product nam e : [Link] MULTIGRIP
Material uses : Pri
nting.
Manufacturer/ Distributor : Sun Chemi calCorporati
on
631 CentralAvenue
Carlstadt,NJ07072
In case of em ergency : (800)424-9300 (U.S.)
(703)527-3887 (Internati
onal
)
Regulatory inform ation : Canada: (905)796-2222
US: (201)933-4500
Other inform ation : (513)830-8500
Date of revision : 1/24/2009.

2 . Hazards identification
Physical state : Liquid.
Color : Clear.
OSHA/HCS status Thismateriali
sconsidered hazardousby the OSHA Hazard Communi
cati
on Standard
(29 CFR 1910.1200).
Em ergency overview : W ARNING !
CONTAINS MATERIAL W HICH CAUSES DAMAGE TO THE FOLLOW ING ORGANS:
BLOOD,MUCOUS MEMBRANES,LYMPHATIC SYSTEM,RESPIRATORY TRACT,
SKIN,CENTRAL NERVOUS SYSTEM,EYE,LENS OR CORNEA.
FLAMMABLE LIQUID AND VAPOR.
VAPOR MAY CAUSE FLASH FIRE.
MAY BE HARMFUL IF ABSORBED THROUGH SKIN OR IF SW ALLOW ED.
CONTAINS MATERIAL W HICH MAY CAUSE DAMAGE TO THE FOLLOW ING
ORGANS:KIDNEYS,LIVER.
Do noti ngest. Avoid prolonged contactwi
th eyes,ski
n and clothing. Keep away from
heat,sparksand fl ame. Keep contai nercl
osed. Use only with adequate venti
lati
on.
W ash thoroughly afterhandling.
Routes of entry [Link] ati
on.
Potential acute health effects
Eyes : May cause mil
d eye i
rri
tati
on.
Skin : Harmfuli
n contactwith ski
n.
Inhalation : No known si
gnifi
canteffectsorcri
ti
calhazards.
Ingestion : Harmfuli
fswal
lowed.
Potential chronic health effects
Carcinogenic effects : No known si
gni
fi
canteffectsorcri
ti
calhazards.
Mutagenic effects : No known si
gni
fi
canteffectsorcri
ti
calhazards.
Teratogenicity / : No known si
gni
fi
canteffectsorcri
ti
calhazards.
Reproductive toxicity
Medical conditions : Pre-exi
sting skin and di
gesti
ve di
sordersand di
sordersi
nvolving any othertargetorgans
aggravated by over- mentioned in thi
sMSDS asbei ng atri
skmay be aggravated by over-exposure to thi
s
exposure product.
See toxicological inform ation (section 11)

11-May-2010 en -US Page: 1/7

 C70-N501/G280 900

2 . Hazards identification

3 . Com position/inform ation on ingredients

Hazardous ingredients CAS num ber %
Diacetone Al cohol 123-42-2 40 - 70
Ethylene GlycolMonopropylEther 2807-30-9 10 - 25
2-Butoxyethanol 111-76-2 5 - 10
SuperHi gh Flash Naphtha 64742-95-6 1 - 2.5
1,2,4-Tri
methyl benzene 95-63-6 1 - 2.5

4 . First aid m easures

Eye contact : Immedi atel
y fl
ush eyeswi th plenty ofwaterforatl east15 mi nutes,occasi onal l
ylifting
the upperand l owereyel ids. Checkforand remove any contactl enses. Getmedi cal
attenti
on.
Skin contact : Flush contami nated skin wi th plenty ofwater. Remove contami nated clothing and
shoes. W ash contami nated cl othi ng thoroughly with waterbefore removi ng it,orwear
gloves. Conti nue to rinse foratl east10 mi nutes. Getmedi calattention. W ash cl othi ng
before reuse. Cl ean shoesthoroughl y before reuse.
Inhalation : Move exposed person to fresh ai r. Keep person warm and atrest. Ifnotbreathi ng,i f
breathing isirregul arori frespi ratory arrestoccurs,provi de arti
fi
cialrespi rati
on oroxygen
by trai
ned personnel . Itmay be dangerousto the person provi ding aid to give mouth-to-
mouth resusci tati
on. Getmedi calattenti on. Ifunconsci ous,pl ace in recovery posi tion
and getmedi calattenti on immedi atel
y. Mai ntain an open airway. Loosen ti ghtclothi ng
such asa col l
ar,tie,bel torwai stband.
Ingestion : W ash outmouth wi th water. Remove denturesi fany. Move exposed person to fresh
air. Keep person warm and atrest. Ifmateri alhasbeen swal lowed and the exposed
person isconsci ous,gi ve smallquantiti
esofwaterto dri nk. Stop i fthe exposed person
feelssickasvomi ti
ng may be dangerous. Do noti nduce vomi ti
ng unlessdirected to do
so by medi calpersonnel . Ifvomiti
ng occurs,the head shoul d be keptlow so thatvomi t
doesnotenterthe l ungs. Getmedi calattenti
on. Nevergi ve anythi ng by mouth to an
unconsci ousperson. Ifunconsci ous,pl ace in recovery positi
on and getmedi cal
attenti
on immedi ately. Mai ntai
n an open airway. Loosen ti ghtcl othing such asa collar,
ti
e,bel torwai stband.
Protection of first-aiders : No acti
on shallbe taken invol
ving any personalri skorwi thoutsuitabl
e training. Itmay
be dangerousto the person providing aid to gi
ve mouth-to-mouth resusci tati
on. W ash
contaminated cl
othing thoroughly with waterbefore removi ng i
t,orweargl oves.

5 . Fire-fighting m easures
Flam m ability of the product : Flammabl eliquid. In a fi
re ori
fheated,a pressure i
ncrease wil
loccurand the container
may burst,with the ri
skofa subsequentexpl osi
on. Runoffto sewermay create fire or
explosi
on hazard.
Products of com bustion : Decomposi ti
on productsmay i ncl
ude the fol
lowi
ng material
s:
carbon oxi
des
Extinguishing m edia
Suitable : Use dry chemi cal ,CO2,waterspray (fog)orfoam.
Not suitable : Do notuse waterj et.
Special exposure hazards : Promptl yisolate the scene by removing allpersonsfrom the vici
nity ofthe i
ncidentif
there i
sa fire. No acti on shal
lbe taken i
nvol vi
ng any personalri
skorwi thoutsuitabl
e
trai
ning. Move contai nersfrom fi
re area i
fthiscan be done withoutri sk. Use water
spray to keep fi
re-exposed contai nerscool .

11-May-2010 en -US Page: 2/7

 C70-N501/G280 900

5 . Fire-fighting m easures
Special protective equipm ent : Fi re-fi
ghtersshoul
d wearappropri ate protecti
ve equipmentand sel f-contai
ned breathi
ng
for fire-fighters apparatus(SCBA)wi th a ful
lface-piece operated in posi
tive pressure mode.
Flam m ability (OSHA criteria) : II
Flash point : Lowestknown val ue:37.8 to 61°C (100.0 to 141.8°F)(Cl osed cup)

6 . Accidental release m easures

Personal precautions : No action shallbe taken involvi
ng any personalri skorwi thoutsuitable traini
ng.
Evacuate surroundi ng areas. Keep unnecessary and unprotected personnelfrom
enteri
ng. Do nottouch orwal kthrough spi ll
ed material. Shutoffal li
gni ti
on sources. No
fl
ares,smoki ng orflamesi n hazard area. Avoi d breathi
ng vaporormi st. Provi
de
adequate ventilati
on. W earappropri ate respiratorwhen ventilati
on isinadequate. Put
on appropriate personalprotective equi pment(see secti on 8).
Environm ental precautions : Avoi d dispersalofspi ll
ed materi aland runoffand contactwi th soil
,waterways,drai ns
and sewers. Inform the rel evantauthori ti
esi
fthe producthascaused envi ronmental
pol l
ution (sewers,waterways,soi lorai r).
Methods for cleaning up : Stop l eaki fwi thoutrisk. Move contai nersfrom spi l
larea. Approach rel ease from
upwi nd. Prevententry i nto sewers,watercourses,basementsorconfi ned areas. W ash
spillagesi nto an effluenttreatmentpl antorproceed asfol l
ows. Contai n and col l
ect
spillage wi th non-combusti ble,absorbentmateri [Link],earth,vermi culi
te or
diatomaceousearth and pl ace in containerfordi
sposalaccordi ng to l
ocalregul ati
ons
(see secti on 13). Use spark-prooftool sand explosion-proofequi pment. Di spose ofvi a
al i
censed waste di sposalcontractor. Contami nated absorbentmateri almay pose the
same hazard asthe spi lled product. Note:see section 1 foremergency contact
informati on and secti on 13 forwaste di sposal.

7 . Handling and storage

Handling : Puton appropri ate personalprotecti ve equi pment(see secti on 8). Eating,dri nking and
smoki ng shoul d be prohi bited i
n areaswhere thi smateri ali
shandl ed,stored and
processed. W orkersshoul d wash handsand face before eati ng,drinking and smoki ng.
Do notgeti n eyesoron ski n orcl othing. Do notbreathe vaporormi st. Do noti ngest.
Use onl y with adequate venti l
ation. W earappropri ate respiratorwhen venti l
ation is
inadequate. Do notenterstorage areasand confi ned spacesunl essadequatel y
ventil
ated. Keep i n the originalcontai neroran approved al ternati ve made from a
compati ble materi al,keptti ghtl
y closed when noti n use. Store and use away from heat,
sparks,open fl ame orany otheri gniti
on source. Use expl osi on-proofel ectri
cal
(venti
lating,lighting and materi alhandl ing)equipment. Use non-sparki ng tools. Take
precautionary measuresagai nstel ectrostati
cdischarges. To avoi d fi
re orexpl osion,
dissi
pate staticel ectrici
ty during transferby groundi ng and bondi ng contai nersand
equipmentbefore transferri ng materi al. Empty containersretai n productresi due and
can be hazardous. Do notreuse contai ner.
Storage : Store i
n accordance wi th l
ocalregulations. Store i
n a segregated and approved area.
Store i
n ori
gi nalcontai
nerprotected from di rectsunli
ghtin a dry,cooland wel l
-ventil
ated
area,away from i ncompati bl
e materials(see section 10)and food and drink. Eli
minate
alli
gniti
on sources. Separate from oxi dizi
ng materials. Keep containerti
ghtly cl
osed
and sealed untilready foruse. Contai nersthathave been opened mustbe careful l
y
resealed and keptuprightto preventl eakage. Do notstore in unlabeled containers. Use
appropriate containmentto avoid environmentalcontami nati
on.

8 . Exposure controls/personal protection

Product nam e Exposure lim its
Diacetone Al
cohol ACGIH TLV (United States,1/2007).
TW A:238 mg/m³8 hour(s).
TW A:50 ppm 8 hour(s).
2-Butoxyethanol ACGIH TLV (United States,1/2007).
TW A:20 ppm 8 hour(s).
1,2,4-Tri
methyl
benzene ACGIH TLV (United States,1/2007).
TW A:123 mg/m³8 hour(s).
TW A:25 ppm 8 hour(s).
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 C70-N501/G280 900

8 . Exposure controls/personal protection

Consult local authorities for acceptable exposure lim its.

Engineering m easures : Use onl

y with adequate venti
lation. Use processencl osures,localexhaustventi l
ati
on or
otherengi
neeri ng control
sto keep workerexposure to airborne contami nantsbelow any
recommended orstatutory limits. The engineeri
ng controlsalso need to keep gas,vapor
ordustconcentrationsbel ow any lowerexpl osi
ve l
imits. Use explosi
on-proofventi l
ati
on
equipment.
Personal protection
Eyes : Safety eyewearcompl ying with an approved standard shoul d be used when a risk
assessmenti ndi catesthi sisnecessary to avoi d exposure to l
iquid splashes,mi sts,
gasesordusts.
Skin : Personalprotecti ve equipmentforthe body shoul d be sel
ected based on the taskbei ng
performed and the ri sksi nvolved and shoul d be approved by a speci ali
stbefore handli
ng
thi
sproduct.
Respiratory : Use a properl y fi
tted,air-puri
fying orair-fed respiratorcompl ying with an approved
standard ifa riskassessmenti ndicatesthi si snecessary. Respi ratorsel ecti
on mustbe
based on known oranti cipated exposure l evels,the hazardsofthe productand the safe
working li
mitsofthe sel ected respirator.
Hands : Chemi cal-resistant,impervi ousgl ovescompl ying with an approved standard shoul d be
worn atal lti
meswhen handl i
ng chemi calproductsi fa riskassessmenti ndicatesthi
sis
necessary.
Hygiene m easures : W ash hands,forearmsand face thoroughl y afterhandl ing chemi calproducts,before
eating,smoki ng and using the lavatory and atthe end ofthe worki ng period. Appropri
ate
techniquesshoul d be used to remove potenti ally contami nated clothi
ng. W ash
contaminated cl othing before reusing. Ensure thateyewash stati onsand safety showers
are cl
ose to the workstation location.

9 . Physical and chem ical properties

Physical state : Liquid.
Color : Clear.
Boiling/condensation point : Lowestknown val ue:149°C (301°F)
Melting/freezing point : May startto sol i
dify atthe fol
lowing temperature:-42.77°C (-45°F)Thisisbased on data
forthe fol
lowing ingredi ent:Diacetone Alcohol.W eighted average:-48.37°C (-55.1°F)
Flash point : Lowestknown val ue:37.8 to 61°C (100.0 to 141.8°F)(Closed cup)
VOC : 65.19%
Auto-ignition tem perature : Lowestknown val ue:244°C (471.2°F)(2-Butoxyethanol ).
Density : 1.0043 g/cm 3 (8.3815 lbs/gal)
Vapor density : Highestknown val ue:>1 (Ai r= 1) (Diacetone Alcohol). W ei
ghted average:1.1 (Ai r=
1)
Evaporation rate : Highestknown val ue:<1 (Di acetone Alcohol) W ei
ghted average:0.9compared wi th
butylacetate
Critical tem perature : Lowestknown val ue:333.9°C (633°F)(Di acetone Alcohol).

10 .Stability and reactivity

Stability and reactivity : The producti
sstabl
e.
Hazardous decom position : Under normalcondi
ti
onsofstorage and use,hazardousdecomposi
ti
on productsshoul
d
products notbe produced.
Reactivity - Light : Notappl
icabl
e.

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 C70-N501/G280 900

11 .Toxicological inform ation

Acute toxicity
Product/ingredient nam e Result Species Dose Exposure
Diacetone Alcohol LD50 Dermal Rabbi t 13500 mg/kg -
LD50 Oral Rat 2520 mg/kg -
LD50 Oral Rat 4000 mg/kg -
LDLo Intravenous Rat 3024 mg/kg -
1,2,4-Tri
methyl benzene LD50 Oral Rat 5 g/kg -
LDLo Rat 1752 mg/kg -
Intraperitoneal
SuperHi gh Flash Naphtha LD50 Oral Rat 8400 mg/kg -
2-Butoxyethanol LD50 Rat 220 mg/kg -
Intraperitoneal
LD50 Oral Rat 917 mg/kg -
LD50 Unreported Rat 917 mg/kg -
LDLo Oral Rat 1500 mg/kg -
TDLo Oral Rat 500 mg/kg -
TDLo Unreported Rat 250 mg/kg -
Ethylene Gl ycolMonopropylEther LD50 Dermal Rabbi t 960 uL/kg -
LD50 Oral Rat 3090 mg/kg -
LD50 Oral Rat 3089 mg/kg -
Conclusion/Sum m ary : No known si
gnificanteffectsorcri
ti
calhazards.
Chronic toxicity
Conclusion/Sum m ary : No known si
gnificanteffectsorcri
ti
calhazards.
Carcinogenicity
Conclusion/Sum m ary : No known si
gnificanteffectsorcri
ti
calhazards.
Classification
Product/ingredient nam e ACGIH IARC EPA NIOSH NTP OSHA
2-Butoxyethanol A3 3 - - - -
Mutagenicity
Conclusion/Sum m ary : No known si
gni
fi
canteffectsorcri
ti
calhazards.
Teratogenicity
Conclusion/Sum m ary : No known si
gni
fi
canteffectsorcri
ti
calhazards.
Reproductive toxicity
Conclusion/Sum m ary : No known si
gni
fi
canteffectsorcri
ti
calhazards.

12 .Ecological inform ation

Environm ental effects : No known si
gni
fi
canteffectsorcri
ti
calhazards.
Aquatic ecotoxicity
Conclusion/Sum m ary : Notavai
labl
e.
Biodegradability
Conclusion/Sum m ary : Notavail
able.
Other adverse effects : No known si
gnifi
canteffectsorcri
ti
calhazards.

13 .Disposal considerations
W aste disposal : The generation ofwaste shoul d be avoided orminimized whereverpossi bl
e. Di spose of
surplusand non-recyclable productsvi aal i
censed waste disposalcontractor. Di sposal
ofthisproduct,soluti
onsand any by-productsshoul d atallti
mescompl y with the
requirementsofenvi ronmentalprotecti on and waste di
sposall egi
slati
on and any regional
localauthori
ty requi
rements. Avoi d dispersalofspil
led materialand runoffand contact
with soi
l,waterways,drainsand sewers.
Referto protecti
ve measuresl
isted i
n secti
ons7 and 8.
Empty containersorlinersmay retai
n some productresi
dues.

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 C70-N501/G280 900

14 .Transport inform ation

Regulatory UN num ber Proper shipping Class PG* Label Additional
inform ation nam e inform ation
DOT Classification UN1210 PRINTING INK 3 III -

PG* :Packi
ng group

15 .Regulatory inform ation

HCS Classification : Combustiblel i
quid
Targetorgan effects
TSCA 8(b)inventory : Li
sted
[Link] regulations : TSCA 4(a)di oxins/furanestesti ng:No productswere found.
TSCA 4(a)finaltesting order:No productswere found.
TSCA 4(a)finaltestrul es:Pol ytetrafluoroethyl
ene;Di
acetone Alcohol
TSCA 4(a)ITC pri ority li
st:No productswere found.
TSCA 4(a)proposed testrul es:No productswere found.
TSCA 5(a)2 fi
nalsi gni fi
cantrul es:No productswere found.
AZ TSCA 5(a)2 proposed si gnifi
cantrul es:No productswere found.
TSCA 5(e)substance consentorder:No productswere found.
TSCA 6 finalri
skmanagement:No productswere found.
TSCA 6 proposed ri skmanagement:No productswere found.
TSCA 8(a)CAIR:No productswere found.
TSCA 8(a)chemi calri skrul es:No productswere found.
TSCA 8(a)di oxin/furan precursor:No productswere found.
TSCA 8(a)IUR:No productswere found.
TSCA 8(a)PAIR:Di methyl polysi l
oxane;Di acetone Alcohol
TSCA 8(c)cal l
sforrecord ofSAR:No productswere found.
TSCA 8(d)H and S data reporti ng:No productswere found.
TSCA 12(b)annualexportnoti ficati
on:No productswere found.
TSCA 12(b)one-ti me export:Di acetone Alcohol
TSCA precursorchemi callist:No productswere found.
TSCA commerce controll i
st:No productswere found.
SARA 302/304/311/312 extrem ely hazardous substances:No productswere found.
SARA 302/304 em ergency planning and notification:No productswere found.
SARA 302/304/311/312 hazardous chem icals:[Link] gmentBl ack7;Di acetone
Alcohol;2-Butoxyethanol ;1,2,4-Tri methylbenzene
SARA 311/312 MSDS distribution -chem ical inventory -hazard identification:C.I.
PigmentBl ack7:Immedi ate (acute)heal th hazard,Del ayed (chroni c)health hazard;
Diacetone Alcohol :Fire hazard,Immedi ate (acute)heal th hazard;2-Butoxyethanol :Fire
hazard,Immedi ate (acute)heal th hazard,Del ayed (chroni c)health hazard;1,2,4-
Trimethyl
benzene:Fi re hazard,Del ayed (chronic)heal th hazard
Clean W ater Act (CW A)307:EthylBenzene
Clean W ater Act (CW A)311:Xylene;EthylBenzene
Clean Air Act (CAA)112 accidental release prevention:No productswere found.
Clean Air Act (CAA)112 regulated flam m able substances:No productswere found.
Clean Air Act (CAA)112 regulated toxic substances:No productswere found.
SARA 313

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 C70-N501/G280 900

15 .Regulatory inform ation

Product nam e CAS num ber Concentration
Form R -Reporting : GlycolEthers 2807-30-9 12.15
requirem ents GlycolEthers 111-76-2 7.695

SARA 313 notifi

cationsmustnotbe detached from the MSDS and any copyi ng and redistri
bution ofthe MSDS shal
lincl
ude
copyi
ng and redistri
buti
on ofthe noti
ce attached to copi
esofthe MSDS subsequently redistri
buted.
CONEG : In compl i
ance.

16 .Other inform ation

Label requirem ents : FLAMMABLE LIQUID AND VAPOR. COMBUSTIBLE. MAY BE HARMFUL IF
ABSORBED THROUGH SKIN OR IF SW ALLOW ED. CONTAINS MATERIAL THAT
CAN CAUSE TARGET ORGAN DAMAGE.
Hazardous Material : Health * 2
Inform ation System (U.S.A.)
Fire hazard 2
Reactivity 0
Personal protection
Version : 1
Notice to reader
To the best of our knowledge,the inform ation contained herein is [Link],neither the above-nam ed
supplier,nor any of its subsidiaries,assum es any liability whatsoever for the accuracy or com pleteness of the
inform ation contained herein.
Final determ ination of suitability of any m aterial is the sole responsibility of the [Link] m aterials m ay present
unknown hazards and should be used with [Link] certain hazards are described herein,we cannot
guarantee that these are the only hazards that exist.

11-May-2010 en -US Page: 7/7

 C70-N501/G280 900

VOLATILE COMPONENT INFORMATION

US EPA
Desi
gnate
[Link] ty:
1.) 1.0043 g/cm 3 (8.3815 l
bs/gal
) =(Dc)s

[Link]
ati
le Content:
1.) 34.81 W ei
ghtpercentofnonvol atil
esin product =(W n)s
2.) 28.9 Volume percentofnonvol ati
lesi
n product =(Vn)s
3.) 10.09 Density,l
b nonvol
ati
les/galnonvol ati
les =(Dn)s

[Link]
ati
les:
1.) 65.19 W ei
ghtpercentoftotalvolati
lesin product =(W v)s
2.) 7.68 Density,l
b vol
ati
les/galvol
atil
es =(Dv)s

D.W aterContent:
1.) 0 W ei
ghtpercentofwaterin product =(W w)s
2.) 0 Volume percentofwateri
n product =(Vw)s

[Link]
ati
le OrganicCompounds,(VOCs):
1.) 65.19 W ei
ghtpercentoforganicvol atil
esin product =(W o)s
2.) 71.1 Volume percentoforganicvol ati
lesin product =(Vo)s
3.) 7.68 Density,l
b organi
cvolati
les/galorgani cvolati
les =(Do)s
4.) 100 W eightpercentofVOCsi n totalvolati
les =(W o)v
5.) 100 Vol ume percentofVOCsi n totalvol
atil
es =(Vo)v

[Link] Contentin ProductExpressed i n OtherTerms:

1.)a.) 5.46 lb VOC / galProduct
1.)b.) 654.72 gramsVOC / l i
terProduct
2.)a.) 5.46 lb VOC / galProductl esswater& exemptsol
vent
2.)b.) 654.72 gramsVOC / l i
terProductlesswater& exemptsol
vent
3.) 18.9 lb VOC / galtotalnonvolati
les

5/11/2010. 1/2
 C70-N501/G280 900
[Link] ati
les
Ingredi
ent CAS number % by wei
ghtDensi
ty (l
b/gal
)

HazardousAi rPoll
utantsVOCs(HAPs) 12.3
Cumene 98-82-8 0.07 7.19
Xylene 1330-20-7 0.07 7.17
EthylBenzene 100-41-4 0.01 7.2
GlycolEthers Notappl i
cabl
e. 12.15 7.6
OtherVOCs(Non-HAPs)
Diacetone Al cohol 123-42-2 40.89 7.83
2-Butoxyethanol 111-76-2 7.7 7.53
SuperHi gh Flash Naphtha 64742-95-6 2.21 6.51
1,2,4-Tri
methyl benzene 95-63-6 2.09 7.34
W ater 7732-18-5 0
Ammoni a. 7664-41-7 0
NOTE:The term Vol ati
le Organi
c Com pounds (VOC)refers onl y to vol
atil
e organi
c m aterials as
defi
ned by the US EPA and does noti nclude water,am m onia,acetone orotherexem ptsol vents.
Unlessotherwise stated,the VOC val
uesreported above are based on materi
alsofconstructi
on.

5/11/2010. 2/2