ABC-1, 2, 3 & 4

ONLY ONE OPTION CORRECT TYPE

PART-A (Carboxylic acids)
1. MgBr 1. CO2,Et2O Product is –
2. H3O
COOH
(A) (B)
COOH
COOH

(C) COOH (D)

1. CO2, Et2O COOH

2. A A is :
2. H3O

(A) (B) MgBr

MgBr
MgBr
(C) (D)
MgBr
K2Cr2O7/H+
3. Ph–CH2–OH Product is -
O
(A) Ph–CH2–COOH (B) Ph–CH–CH3 (C) Ph–COOH (D) Ph–CH2–O–C–CH3
COOH
CH2–OH

K2Cr2O7/H+
4. Find product is –

COOH
COOH
(A) COOH (B) (C) (D)
COOH

OH

+
5. CrO3/H Product is –

CH3
OH
COOH
COOH

(A) (B) (C) (D)

CH3 CH3 COOH COOH

 ABC-1, 2, 3 & 4
O
H2O/H+
6. C2H5–C–OCH3 Product is -
(A) CH3COOH, C2H5OH (B) CH3COOH, C2H5–COOH
(C) C2H5–COOH, CH 3OH (D) CH3OH, C2H5–OH
O
H2O/H+
7. CH3–C–NH–Ph A+B

A and B are -
O O
(A) Ph–NH–C–H + CH 3 –COOH (B) CH3–C–NH2 + Ph–OH
O O
+
(C) CH3–C–NH2 + Ph–COOH (D) CH3–C–OH + Ph–NH 3

O O
H2O/H+
8. C2H5–C–O–C–Ph A+B
Ratio of A and B is –
(A) 1 : 2 (B) 2 : 1 (C) 1 : 1 (D) 2 : 3

CN H2O/H+
9. Product is –
COOH

(A) (B)
COOH
COOH

(C) COOH (D)

Red P Br2
10. CH3CH2CH2COOH   CH –CH –CH–COOH
3 2

Br
This reaction is called -
(A) cannizzaro reaction (B) Aldol reaction (C) HVZ reaction (D) Reimer Tiemann reaction

COOH SOCl2
11. Product is –

O
(A) (B) C
Cl
Cl
O
C
(C) (D) COOH
H
Cl
Cl

COOH 
12. + NH3 Product is-
O O
(A) (B)
C–O–NH2 C–NH2
COOH
NH2
(C) (D)
COOH
NH2
 ABC-1, 2, 3 & 4
(i) Ag2O
13. Ph–CH–CH–COOH (ii) Br2, 
Product is-
CH3 CH3
Br
(A) Ph–CH–CH–CH2–Br (B) Ph–CCH–CH3 (C) Ph–CH–CH–Br (D) Ph–CH–CH2
CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH2–Br

COOH (i) Ag2O

14. Product is-
(ii) Br2, 
Br
Br
COOH Br
(A) (B) COOH (C) (D) C–Br
O

COOH NaOH + CaO

15.  Product is-

COOH

(A) (B) (C) (D)

16. CH3–CH–CH2–SO3H + NaHCO 3 Product is -

CH3

(A) CH3–CH–SO3Na (B) CH3–CH–CH2–SO3Na + CO2

CH3 CH3

SO3Na

(C) CH3–CH–SO3Na (D) CH3–C–CH3

CH2–CH3 CH3

PART-B (Carbonyl compounds)

17. Product of given reaction is
H2 / Pd (BaSO4 )
CH 3–C H2–C– Cl  
O
(A) CH3–CH2 –CH2–OH (B) CH 3–C H2–C– H
O

(C) (D) None of these

18. Predict the reactant

H2 / Pd (BaSO4 )
Reactant   Ph–CH=O
(A) Ph–CH2OH (B) Ph–COCl (C) Ph–COOCH 3 (D) Ph–COCH 3
 ABC-1, 2, 3 & 4

H2
19. X  Y
Pd(BaSO4 )

X is :
(A) (B) (C) (D)

PCC
20. CH3–CH–CH2–OH  X

CH3
O
(A) CH3–CH–COOH (B) CH3–C (C) CH3–CH–CHO (D) CH3–C=O
CH3 CH2–CH3 CH3 CH3
21. Which of the following is product of given reaction
HO OH
PCC
(Pyridinium
Chlorochromate)

CH2OH

O O O O
(A) (B)

CHO COOH
O O
HO OH
(C) (D) None of these

COOH

22.

X is :

(A) (B)

(C) (D)
 ABC-1, 2, 3 & 4
(i) SnCl2 / HCl
23. CH3–CN    X + NH4Cl
(i )i H2O

Identify ‘X’ :
(A) CH3–CH=O (B) CH3–CH2–CH=O (C) CH3CH2OH (D) CH3CH(OH)CH 3

O
C–H
(i) SnCl2 / HCl
24. R 

(i )i H2O

Identify ‘R’ :
CN CH2–OH NH2 CH3
(A) (B) (C) (D)

O
Ph–C–O Dry distillation
25. Ca   Product
Ph–C–O
O
O O O OH
(A) Ph–C–H (B) Ph–C–Ph (C) Ph–C–C–Ph (D) Ph–C–C–Ph
O O H
O
Ph–C–O Dry distillation
26. Ca   Product
H–C–O
O
O O
(A) Ph–C–H (B) Ph–C–Ph (C) H–C–H (D) Ph–C–C–H
O O O


27. Ca-Salt of Carboxylic acid 

X and Y
(A) (H–COO) 2Ca + (CH3–COO) 2 Ca (B) (HCOO) 2Ca + (CH3–CH2–COO)2Ca
(C) (CH3COO)2Ca + (CH3CH2–COO)2Ca (D) None of these
28. Benzaldehyde, when heated with conc. KOH solution, gives
(A) C6H5CH2OH only
(B) C6H5COOH only
(C) C6H5COOK only
(D) a mixture of C 6H5COOK and C 6H5CH2OH
29. The Cannizzaro’s reaction is not given by :
(A) C6H5CHO (B) HCHO (C) CH3CHO (D) (CH 3)3C–CHO
NaOH
30. In the reaction, (CH3)3CCHO + HCHO 

 A+B
heat
the products (A) and (B) are respectively :
(A) (CH3)3CCH2OH and HCOO – Na+. (B) (CH3)3CCOONa and CH 3OH.
(C) (CH3)3CCH2OH and CH 3OH. (D) (CH3)3COONa and HCOO – Na+.
 ABC-1, 2, 3 & 4

31. SnCl2
( X)  
 HO
 
HCl
  C6H5COO  C6H5CH2 – OH

(A) (B) (C) (D) C6H5–CN

32. Which of the products is formed when acetone is reacted with dil. NaOH solution after heating?
O CH3 O
||
(A) CH3–C–CH=C–CH 3 (B) CH3 – C – CH – CH – CH3
| |
CH3 OH
O OH OH
| |
(C) CH3–C–CH2–C=CH 2 (D) CH3 – C — C – CH3
| |
CH3 CH3 CH3

33. Product is :

(A) (B) (C) (D)

(i) dil. NaOH

34. Reactant   CH3–CH=CH–C–H
(i )i 
O
Reactant is :
O O O O
(A) CH3–CH3 (B) H–C–C–H (C) CH3–C–CH3 (D) CH3–C–H


35.

(A) H–CN (B) CH3–CN (C) CH3–CH2–CN (D) CH3–COCl

36. The structure of the compound when acetaldehyde reacts with NH 2–OH is
(A) CH3CH=NCONHNH 2 (B) CH3CH=NNHCONH 2
(C) CH3CH=NOH (D) CH3CH=NNH2


CH3 OH
37. (X) + (Y)  C=N
– H2O H
idenitfy (X) and (Y)
CH3 CH3
(A) X  C=O ; y = NH2CONHNH 2 (B) X  C=O ; y = NH2–NH2
H H
CH CH
(C) X  3 C=O ; y = NH2–OH (D) X  3 C=O ; y = NH2–NH–Ph
H H
 ABC-1, 2, 3 & 4

38. BaSO4
H2
Identify (X) and (Y).

(A) (B)

(C) (D)

39. Benzaldehyde and acetone can be distinguished by

(A) Mulliken Baker test (B) Fehling solution
(C) Iodoform test (D) Ninhydrin test

40. Acetaldehyde and benzaldehyde can be distinguished by

(A) Tollen's test (B) Fehling solution
(C) FeCl3 test (D) NaHCO 3 test

41. Propanal and propanone can not be distinguished by

(A) Iodoform test (B) Fehling solution
(C) Tollen's test (D) 2,4- DNP test

42. Which of the following compound will not react with I 2 /OH–.

(A) (B) (C) (D) CH 3 – CHO

43. 2-Pentanone can be distinguished from 3- Pentanone by which reagent ?

(A) 2, 4- Dinitrophenyl hydrazine (B) Tollen's reagent
(C) I2 and dilute NaOH (D) Fehling solution

44. Tollen’s reagent (AgNO 3 + NH4OH) can be used to distinguish between.

(A) and (B) and

(C) and (D) and

 ABC-1, 2, 3 & 4

1. (C) 2. (B) 3. (C) 4. (D) 5. (A)

6. (C) 7. (D) 8. (C) 9. (C) 10. (C)

11. (B) 12. (B) 13. (C) 14. (C) 15. (B)

16. (B) 17. (B) 18. (B) 19. (C) 20. (C)

21. (A) 22. (C) 23. (A) 24. (A) 25. (B)

26. (A) 27. (A) 28. (D) 29. (C) 30. (A)

31. (D) 32. (A) 33. (B) 34. (D) 35. (B)

36. (C) 37. (C) 38. (A) 39. (C) 40. (B)

41. (D) 42. (C) 43. (C) 44. (C)