Chem 5 (Analytical Chemistry): Learning Exercise No.
2
Errors in Chemical Analyses
Answer the following as required:
1. Explain the difference between: (10pts)
a) Accuracy and precision
b) Systematic and random error
c) Absolute and relative error
d) Mean and median
e) Constant and proportional error
2. A batch of nuclear fuel pellets was weighed to determine if they fell
within control guidelines. The weights were 127.2, 128.4, 127.1, 129.0,
and 128.1 g. Calculate: (10pts)
a) the mean,
b) the median, and
c) the range
3. The results of an analysis are 36.97 g, compared with the accepted
value of 37.06 g. What is the relative error in parts per thousand? (5pts)
4. The following is a list of common errors encountered in research
laboratories. Categorize each as a determinate or an indeterminate
error, and further categorize determinate errors as instrumental,
operative/personal, or methodological: (10pts)
a) An unknown being weighed is hygroscopic.
b) One component of a mixture being determined quantitatively by
gas chromatography reacts with the column packing.
c) A radioactive sample being counted repeatedly without any
change in conditions yields a slightly different count at each trial.
d) The tip of the pipet used in the analysis is broken