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MOLE CONCEPT (Physical Chemistry)

EXERCISE-I
DPP-1
INTRODUCTION OF MOLE
1. 1 a.m.u equals to (a.m.u = atomic mass unit.)
(A) 6.022 × 1023 gm (B) 6.022 × 1023 kg
(C) 1.66 × 10−24 gm (D) 1.66 × 10−24 kg
2. Define relative atomic mass
mass of an atom (in gm)
(A) Relative atomic mass =
1 a⋅m⋅u.
mass of an atom (in gm)
(B) Relative atomic mass = 1
of mass of single atom of C−12 (in gm)
12
mass of an atom (in gm)
(C) Relative atomic mass = 1
th of mass of single atom of C−12 in a mu
12
mass of an atom (in gm)
(D) Relative atomic mass = 6.022×1023
3. Unit of relative atomic mass is
(A) a.m.u (B) gm (C) kg (D) Unit less
4. Mass of an atom is 80 amu, its relative atomic mass will be
80
(A) 80 (B) (C) 80 NA (D) 80 × 1.66 × 10−24
NA

5. If mass of one apple is 50 gm, then mass of 1 mole apple (Given NA = 6 × 1023 )
(A) 3 × 1025 gm (B)1.2 × 1022 gm (C)3 × 1025 amu (D) 50 amu
6. Molar mass of electron is nearly (NA = 6 × 1023)
Given: Mass of 1 electron = 9.1 × 10–31 kg
(A) 9.1 × 10–31 kg mol–1 (B) 9.1 × 10–31 gm mol–1
(C) 54.6 × 10–8 gm mol–1 (D) 54.6 × 10–8 kg mol–1
7. Mass of 1 mol (Molar mass) of Al is (Given; Atomic mass of Al = 27)
27
(A) 27 kg (B)27 amu (C) 27 gm (D) gm
NA

8. Mass of an atom of Sodium (Given atomic mass of Sodium : 23)

(A) 23 gm (B) 23 kg (C) 23 amu (D) 23 × 1.66 × 10–23 amu
9. Mass of 1 molecule of CO2 is
(A) 44 gm (B) 44 amu (C) 44 kg (D) 44 NA gm
10. Find the molar mass of the following molecules:
Given : Atomic mass : O = 16, N = 14, S = 32, C = 12, Cu = 63.5
(i) O2 (ii) N2 (iii) NO2 (iv) H2O
(v) NH3 (vi) N2O4 (vii) SO2 (viii) H2SO4
(ix) CO2 (x) Glucose (C6H12O6)
(xi) Acetic acid (CH3COOH)
(xii) Sucrose (C12H22O11)
(xiii) Blue vitriol (CuSO4.5H2O)
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MOLE CONCEPT (Physical Chemistry)

DPP-2
PROBLEMS RELATED WITH INTERCONVERSION OF MOLE,
MASS AND NUMBER
1. The number of moles of ammonia in 4.25 g of ammonia is :
(A) 0.425 (B) 0.25 (C) 0.236 (D) 0.2125
2. The approximate number of molecules of CO2 present in 44 g of CO2 is :
(A) 6.0 1023 (B) 3 1023 (C) 12 1023 (D) 3 1010
3. The number of carbon atoms present in a signature, if a signature written by carbon pencil by
1.2 × 10–3 gm carbon is
(A) 12.04 × 1020 (B) 6.02 × 1019 (C) 3.01 × 1019 (D) 6.02 × 1020
4. The weight of 1  1022 molecules of CuSO4. 5H2O is :
(A) 41.59 g (B) 415.9 g (C) 4.159 g (D) 2.38 g
5. Find the number of moles of the following :
(i) 28 g of N2 (ii) 28 g of N (iii) 64 g of O2 (iv) 64 g of O
(v) 54 mg of H2O (vi) 48 mg of CH4 (vii) 23 mg of NO2 (viii) 15 mg of CH3COOH
6. Find the following for 180 gm of Urea:
Given: Urea (NH2CONH2)
Atomic weight :( C = 12, H = 1, O = 16, N=14)
(i) Number of moles of Urea (ii) Number of molecules of Urea
(iii) Number of moles of carbon atom (iv) Number of moles of hydrogen atom
(v) Number of moles of oxygen atom (vi) Number of moles of nitrogen atom
(vii) Number of atoms of carbon, hydrogen, nitrogen and oxygen
(viii) Total number of atoms
7. For 49 g of H2SO4, Find the following:
(i) Number of moles of H2SO4
(ii) Number of moles of hydrogen, sulphur and oxygen atom
(iii) Number of molecules of H2SO4
(iv) Number of atoms of hydrogen, sulphur and oxygen
(v) Total number of atoms
8. Find:
(ii) Mass of 200 atoms of 16
8 O in amu
(ii) Mass of 100 atoms of 14
7 N in gm.
9. Find:
(i) No. of moles of Cu atom in 1020 atoms of Cu.
(ii) No. of molecules and atoms in 54 gm H2O.
(iii) No. of atoms in 88 gm CO2.
10. Calculate the number of electrons, protons and neutrons in 1 mole of 16O–2 ions.

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MOLE CONCEPT (Physical Chemistry)

DPP-3
PROBLEMS RELATED WITH
INTERCONVERSION OF MOLE, MASS AND NUMBER
1. Ethanol, C2H5OH, is the substance commonly called alcohol. The density of liquid alcohol is
0.8 g/ml at 293 K. If 1.2 mole of ethanol are needed for a particular experiment, what volume of
ethanol should be measured out?
(A) 55 ml (B) 58 ml (C) 69 ml (D) 79 ml
2. Which of the following has the Maximum mass ?
1
(A) 1 g-atom of Carbon (B) mole of CH4
2
(C) 10 mL of water (D) 3.011 × 1023 atoms of oxygen
3. Which of the following contain largest number of carbon atoms?
(A) 15 gm ethane, C2H6 (B) 40.2 gm sodium oxalate, Na2C2O4
(C) 72 gm glucose, C6H12O6 (D) 35 gm pentene, C5H10
4. A sample of aluminium has a mass of 54.0 g. What is the mass of the same number of
magnesium atoms? (At. wt. Al = 27, Mg = 24)
(A) 12 g (B) 24 g (C) 48 g (D) 96 g.
5. A gaseous mixture contains CO2 (g) and N2O (g) in a ratio of 2 : 5 by mass. The ratio of the
number of molecules of CO2 (g) and N2O (g) is
(A) 5 : 2 (B) 2 : 5 (C) 1 : 2 (D) 5 : 4
6. What is the mass of one billion 12C atom in gram?
7. Calculate the weight of 12.046 × 1023 atoms of carbon.
8. Calculate mass of O atoms in 6 gm CH3COOH?
9. Calculate mass of water present in 499 gm CuSO4.5H2O?
(Atomic mass – Cu = 63.5, S = 32, O = 16, H = 1)
10. What mass of Na2SO4.7H2O contains exactly 6.023 × 1022 atoms of oxygen?

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MOLE CONCEPT (Physical Chemistry)

DPP-4
PROBLEMS RELATED WITH PV= nRT
1. How many moles are there in 0.821 L of any gas at 50 atm and 200 K.
(A) 2 moles (B) 4 moles
(C) 1.25 × 10–3 moles (D) 1.25 × 103 mole
2. How many moles are there in 2.24 m3 of any gas at 190 torr and 273 ºC.
(A) 1.25 moles (B) 12.5 moles
(C) 1.25 × 10–3 moles (D) 1.25 × 103 mole
3. If V ml of the vapours of substance at 1 atm and 273 K weighs W gm. Then molar mass of
substance is:
V
(A) (W/V) × 22400 (B) × 22.4
W
W 1
(C) (W – V) × 22400 (D)
V  22400
4. 80 gm of SOx gas occupies 15 lit at 2 atm and 300 K . The value of x is -
(Given : R = 0.08 L-atm/K-Mole)
(A) 3 (B) 2 (C) 1 (D) None
5. While resting, an average 70 kg human male consumes 16.628 L of oxygen per hour at 27 °C
and 100 kPa. How many moles of oxygen are consumed by the 70 kg man while resting for 1
hour?
(A) 0.67 (B) 66.7 (C) 666.7 (D) 67.5
6. At same temperature and pressure, two gases have the same number of molecules. They must
(A) have same mass (B) have equal volumes
(C) have a volume of 22.7 dm3 each (D) have an equal number of atoms
7. Four 1-1 litre flasks are separately filled with the gases H2, He, O2 and O3 at the same
temperature and pressure. The ratio of total number of atoms of these gases present in
different flask would be :
(A) 1 : 2 :3 : 4 (B) 2 : 1 :2 : 4 (C) 2 : 1 :2 : 3 (D) 2 : 1 :2 : 3
8. For the ideal gas, find the number of moles:
(i) P = 0.8314 Pa V = 6000 m3 T = 300 K
(ii) P = 5 atm V = 8.21 L T = 200 K
(iii) P = 831.4 Pa V = 5000 L T = 250 K
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MOLE CONCEPT (Physical Chemistry)

9. For the ideal gas, find pressure:

(iv) V = 8.21 L T = 500 K n = 10
(v) V = 100 m3 T = 300 K n=3
(viii) V = 45.4 m3 T = 2730 K n=5
10. For the ideal gas, find the missing parameter in each part among P, V, T and n:
(vi) P = 831.4 Pa V = 1000 L n = 0.1
(vii) P = 22.4 atm T = 273 K n=2
11. Find the volume of ideal gas at STP:
(i) 2 moles of PCl5 (ii) 0.25 moles of NH3
(iii) 0.5 moles of NO2 (iv) 4 moles of N2
12. Find the moles of ideal gas at STP:
(i) 22.7 L of O2 (ii) 45.4 L of N2 (iii) 45.4 mL of NO2 (iv) 11.35 mL of NH3
(v) 2.27 dm3 of SO3 (vi) 113.5 m3 of CO2

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MOLE CONCEPT (Physical Chemistry)

DPP-5
BALANCING OF CHEMICAL REACTIONS
1. C + O2 ⎯→ CO
2. H2 + O2 ⎯→ H2O
3. P + O2 ⎯→ P2O5
4. S8 + O2 ⎯→ SO3
5. C3H8 + O2 ⎯→ CO2 + H2O
6. C2H6 + O2 ⎯→ CO2 + H2O
7. CxHy + O2 ⎯→ CO2 + H2O
8. PCl5 + H2O ⎯→ H3PO4 + HCl
9. NaHCO3(s) → Na2CO3(s) + CO2(g) + H2O(l)
10. KOH + H2CO3 ⎯→ K2CO3 + H2O
11. Ba(OH)2 + H3PO4 ⎯→ Ba3(PO4)2 + H2O
12. Pb(OH)4 + Cu2O ⎯→ PbO2 + CuOH
13. ZnS + AlP ⎯→ Zn3P2 + Al2S3
14. CaSiO3 + HF ⎯→ SiF4 + CaF2 + H2O
15. Ca(ClO3)2 + Na2SO4 ⎯→ CaSO4 + NaClO3
16. FeS2 + O2 → Fe2O3 + SO2
17. P4S3 + O2 ⎯→ P4O10 + SO2
18. BCl3 + P4 + H2 ⎯→ BP + HCl
19. Cl2 + Ca(OH)2 ⎯→ Ca(ClO3)2 + CaCl2 + H2O
20. KMnO4 + HCl ⎯→ KCl + MnCl2 + H2O + Cl2

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MOLE CONCEPT (Physical Chemistry)

DPP-6
PROBLEMS RELATED WITH LIMITING REACTANT
1. For the reaction 2P + Q → R, 8 mol of P and excess of Q will produce :
(A) 8 mol of R (B) 5 mol of R (C) 4 mol of R (D) 13 mol of R
2. If 1.5 moles of oxygen combine with Al to form Al2O3, the weight of Al used in the reaction is:
(A) 27 g (B) 40.5 g (C) 54g (D) 81 g
3. The mass of Mg3N2 produced if 48 gm of Mg metal is mixed with 34 gm NH3 gas is
Mg + NH3 ⎯→ Mg3N2 + H2

(A) 200 gm (B) 100 gm (C) 400 gm (D) 150 gm

3 3 3 3

4. The mass of P4O10 produced if 440 gm of P4S3 is mixed with 384 gm of O2 is

P4S3 + O2 ⎯→ P4O10 + SO2
(A) 568 gm (B) 426 gm (C) 284 gm (D) 396 gm
5. Mass of sucrose C12H22O11 produced by mixing 84 gm of carbon, 12 gm of hydrogen and 56 lit.
O2 at 1 atm & 273 K according to given reaction, is
C(s) + H2(g) + O2 (g) ⎯→ C12H22O11(s)
(A) 138.5 (B) 155.5 (C) 172.5 (D) 199.5
6. Calculate the volume of O2 needed for combustion of 1.2 kg of carbon at STP.

Reaction: C + O2 ⎯⎯ → CO2.
7. Methyl-t-butyl ether, C5H12O, is added to gasoline to promote cleaner burning. How many
moles of oxygen gas, O2 are required to burn 1.0 mol of this compound completely to form
carbon dioxide and water?
8. Aluminum carbide (Al4C3) liberates methane on treatment with water:
Al4C4 + 12H2O ⎯⎯
→ 3CH4 + 4Al(OH)3.
Find mass of aluminum carbide required to produce 11.35 L of methane under STP conditions.
9. Reaction 4A + 2B + 3C ⎯⎯
→ A4B2C3, is started from 2 moles of A, 1.2 moles of
B & 1.44 moles of C. find number of moles of product formed.
10. Carbon reacts with chlorine to form CCl4. 36 gm of carbon was mixed with 142 g of Cl2.
Calculate mass of CCl4 produced and the remaining mass of reactant.

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MOLE CONCEPT (Physical Chemistry)

DPP-7
PROBLEMS RELATED WITH MIXTURE, % YIELD
1. A mixture containing 3 moles each of C4H8 and C6H6 undergoes complete combustion with O2
to form CO2 and H2O. Calculate total mass of CO2 produced
(A) 1320 gm (B) 610 gm (C) 528 gm (D) 792 gm
2. 12.46g of a mixture of MgO and MgCO3 on strong heating lost 4.4g in weight what is the % MgO
in the initial mixture.
(A) 32.58 (B) 64.42 (C) 17.79 (D) 82.21
3. Aluminium reacts with sulphur to form aluminium sulphide. If 5.4 gm of Aluminium reacts
with 12.8gm sulphur gives 12gm of aluminium sulphide, then the percent yield of the reaction
is-
2Al + 3S ⎯⎯→ Al2S3
(A) 100 % (B) 95 % (C) 80 % (D) 75 %
4. Two successive reactions, A → B and B → C, have yields of 90% and 80%, respectively. What is
the overall percentage yield for conversion of A to C?
(A) 90% (B) 80% (C) 72% (D) 85%
5. Hydrazine N2H4 (used as a fuel in rocket system) can be produced according to the following
reaction.
CINH2 + 2NH3 → N2H4 + NH4Cl
When 1.0 kg CINH; is reacted with excess of NH3, 473 g of N2H4 is produced. What is the
percentage yield?
(A) 76.12 (B) 67.21 (C) 26.17 (D) 16.72
6. When 4 gm of a mixture of NaHCO3 and NaCl is heated, 0.66 gm CO2 gas is evolved. Determine
the percentage composition (by mass) of the original mixture.
7. One gram of an alloy of aluminium and magnesium when heated with excess of dil. HCl forms
magnesium chloride, aluminium chloride and hydrogen. The evolved hydrogen collected at 0°C
has a volume of 1.12 litres at 1 atm pressure. Calculate the composition of (% by mass) of the
alloy.
8. Cyclohexanol is dehydrated to cyclohexene on heating with conc. H2SO4. Find %yield of this
reaction, if 61.5 gm cyclohexene is obtained from 100 g of cyclohexanol?
C6H12O ⎯⎯⎯⎯⎯
con.H2SO4
→ C6H10 + H2O

9. 200 g impure CaCO3 on heating gives 11.35 L CO2 gas at STP. Find the percentage of calcium in
the lime stone sample.

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MOLE CONCEPT (Physical Chemistry)

DPP-8
PROBLEMS RELATED WITH
SEQUENTIAL AND PARALLEL REACTION
1. The following process has been used to obtain iodine from oil-field brines in California.
NaI + AgNO3 ⎯⎯
→ AgI + NaNO3 ;
2AgI + Fe ⎯⎯
→ Fel2 + 2Ag
2FeI2 + 3Cl2 ⎯⎯
→ 2FeCl3 + 2I2
How many grams of AgNO3 are required in the first step for every 254 kg 2 produced in the
third step?
(A) 340 kg (B) 85 kg (C) 68 kg (D) 380 kg
2. 10 g of a sample of a mixture of CaCl2 and NaCl is treated to precipitate all the calcium as
CaCO3. This CaCO3 is heated to convert all the Ca to CaO and the final mass of CaO is 1.62 g . The
percent by mass of CaCl2 in the original mixture is:
(A) 32.1 % (B) 16.2 % (C) 21.8 % (D) 11.0 %
3. Consider the following reaction
2Na + 2NH3 ⎯→ 2NaNH2 + H2(g)
2NaNH2 + C ⎯→ Na2CN2 + 2H2 (g)
Na2CN2 + C ⎯→ 2NaCN
51 gm dry ammonia gas is passed over excess heated sodium to form sodamide (NaNH 2) which
is further reacted with carbon (excess) to finally form NaCN. Find the total volume of H 2(g)
evolved at 0.5 atm, 273K
(A) 201.6 L (B) 100.8 L (C) 403.2 L (D) 50.4 L
4. 25.4 g of iodine and 14.2g of chlorine are made to react completely to yield a mixture of Cl and
Cl3. Calculate the number of moles of Cl and Cl3 formed.
(A) 0.1 mole, 0.1 mole (B) 0.1 mole, 0.2 mole
(C) 0.5 mole, 0.5 mole (D) 0.2 mole, 0.2 mole
5. Sulphur trioxide may be prepared by the following two reactions :
S8 + 8O2(g) → 8SO2(g)
2SO2(g) + O2(g) → 2SO3(g)
How many grams of SO3 will be produced from 1 mol of S8?
6. 2PbS + 3O2 → 2PbO + 2SO2
3SO2 + 2HNO3 + 2H2O → 3H2SO4 + 2NO
According to the above sequence of reactions, how much H2SO4 will 1075.5 gm of PbS produce?

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MOLE CONCEPT (Physical Chemistry)

7. Moles of ABC3 produced in the following set of reaction when 180 gm of A, 180gm of B and 200
gm of C are mixed in a container (given molar masses of A, B, C are 20, 30 & 10 respectively.
2A + 3B + 5C ⎯⎯→ A2BC2 + B2C3
B2C3 + 3C ⎯⎯→ 2BC3
BC3 + A ⎯⎯→ ABC3
8. Total weights (in gm) of P4O6 and P4O10 will be produced by the combustion of 31g of P4 in 32g
of oxygen leaving no P4 and O2.

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MOLE CONCEPT (Physical Chemistry)

DPP-9
PROBLEMS RELATED WITH
% by MOLE, % by MASS and Mavg
1. Average mol. wt. of a gaseous mixture which contains 80% by mole N2 & rest O2 gas is-
(A) 28 (B) 30.6 (C) 28.8 (D) 29.2
2. The percentage by mole of NO2 in a mixture of NO2(g) and NO(g) having average molecular
mass 34 is :
(A) 25% (B) 20% (C) 40% (D) 75%
3. The vapour density of a sample of SO3 gas is 28. Its degree of dissociation into SO2 and O2 is
(a) 1/7 (B) 1/6 (C) 6/7 (D) 2/5
4. An organic compound contains 40% carbon and 6.67% hydrogen by mass. Which of the
following represents the empirical formula of the compound?
(A) CH2 (B) CH2O (C) C2H4O (D) CH3O
5. A quantity of 1.4 g of a hydrocarbon gives 1.8 g water on complete combustion. The empirical
formula of hydrocarbon is
(A) CH (B) CH2 (C) CH3 (D) CH4
6. Calculate the atomic mass (average) of chlorine using the following data:
Isotope % Natural Abundance Molar Mass
35Cl 75.77 34.9689
37Cl 24.23 36.9659
7. Average atomic mass of Magnesium is 24.31 amu. This magnesium is composed of 79 mole
% of 24Mg and remaining 21 mole % of 25Mg and 26Mg. Calculate mole % of 26Mg.
8. An organic compound contains carbon, hydrogen and nitrogen. If weight ratio of C, H, N (in
same order) is 9 : 1 : 3.5 and molar mass of compound is 216 gm/mole and number of atoms
x
present in 1 molecule of compound are x then calculate value of .
4
9. A compound has carbon, hydrogen and oxygen in 3 : 3 : 1 atomic ratio. If the number of moles
in 1 g of the compound is 6.06 × 10–3, then the molecular formula of the compound will be
10. A 60 gm sample of organic compound having empirical formula CxHyO on complete combustion
gives 88 gm of CO2 & 36 gm of H2O. The value of (x + y) is.

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MOLE CONCEPT (Physical Chemistry)

DPP-10
MISCELLANEOUS PROBLEM
1. If the mass of neutron is double and that of proton is halved, the molecular mass of H 2O
containing only H1 and O16 atoms will
(A) increase by about 25%
(B) decrease by about 25%
(C) increase by about 16.67%
(D) decrease by about 16.67%
2. The mass of CO2 produced from 620 gm mixture of C2H4O2 & O2, prepared to produce
maximum energy is (Combustion reaction is exothermic)
(A) 413.33 gm (B) 593.04 gm (C) 440 gm (D) 320 gm
3. X gm A atoms on combining with Y atoms of B form 5 molecules of a compound containing A &
B. Find the molecular weight of compound formed. (Atomic weight of B = M)
 X + MYNA 
(A) ( A
XN + MY )
(B) X + M (C) X + MY (D)  
5 5 5  5 

4. The minimum mass of mixture of A2 and B4 required to produce at least 1 kg of each product is:
(Given At. mass of 'A' = 10 ; At. mass of 'B' = 120)
5A2 + 2B4 ⎯⎯→ 2AB2 + 4A2B
(A) 2120 gm (B) 1060 gm (C) 560 gm (D) 1660 gm
5. In the quantitative determination of nitrogen, N2 gas liberated from 0.42 gm of a sample of

organic compound was collected over water. If the volume of N2 gas collected was 100 mL at
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total pressure 860 mm Hg at 250 K, % by mass of nitrogen in the organic compound is

[Aq. tension at 250 K is 24 mm Hg and R = 0.08 L atm mol–1 K–1]

(A) 10 % (B) 5 % (C) 20 % (D) 100 %

3 3 3 3

6. 40 gm of a carbonate of an alkali metal or alkaline earth metal containing some inert impurities
was made to react with excess HCl solution. The liberated CO2 occupied 12.315 lit. at 1 atm &
300 K. The correct option is
(A) Mass of impurity is 1 gm and metal is Be
(B) Mass of impurity is 3 gm and metal is Li
(C) Mass of impurity is 5 gm and metal is Be
(D) Mass of impurity is 2 gm and metal is Mg

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MOLE CONCEPT (Physical Chemistry)

7. Industrially TNT (C7H5N3O6, explosive material) is synthesized by reacting toluene

(C7H8) with nitric acid in presence of sulphuric acid. Calculate the maximum weight of
C7H5N3O6 which can be produced by 140.5 gm of a mixture of C7H8 and HNO3.
C7H8 + 3HNO3 ⎯→ C7H5N3O6 + 3H2O

(A) 140.5 (B) 113.5 (C) 140.5 (D) 140.5 – (3 × 18)

2

8. One gram of the silver salt of an organic dibasic acid yield, on strong heating, 0.5934 g of silver.
If the weight percentage of carbon in it 8 times the weight percentage of hydrogen and one-half
the weight percentage of oxygen, determine the molecular formula of the acid.
[Atomic weight of Ag = 108]
(A) C4H6O4 (B) C4H6O6 (C) C2H6O2 (D) C5H10O5

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MOLE CONCEPT (Physical Chemistry)

EXERCISE-II
MORE THAN ONE OPTION MAY CORRECT
1. In 2.6 kg of FeSO4. 6H2O (Atomic weight of Fe = 56)
(A) No. of atom of O are 100 × NA
(B) Moles of H atoms are 120 × NA
(C) Molecules of water are 6 × NA
2−
(D) Moles of e– present in SO 4 are 500

2. Select the correct statement(s) for (NH4)3PO4.

(A) Ratio of number of oxygen atom to number of hydrogen atom is 1 : 3
(B) Ratio of number of cation to number of anion is 3 : 1
(C) Ratio of number of gm-atom of nitrogen to gm-atoms of oxygen is 3 : 2
(D) Total number of atoms in one mole of (NH4)3PO4 is 20.
3. Which of the following statements regarding stoichiometry of a reaction is(are) correct.
(A) In a chemical reaction, number of atoms of each element is equal in reactants and products.
(B) In a chemical reaction, reactants combine in a fixed mass ratio.
(C) In a chemical reaction, maximum mass of products result from stoichiometric amounts of
reactants for a fixed mass of reactants.
(D) Limiting reagent will be left at the end of reaction.
4. 50 gm of CaCO3 is allowed to react with 68.6 gm of H3PO4 then select the correct option(s)-
3CaCO3 + 2H3PO4 ⎯→ Ca3(PO4)2 + 3H2O + 3CO2
(A) 51.67 gm salt is formed
(B) Amount of unreacted reagent = 35.93 gm
(C) nCO2 = 0.5 moles
(D) 0.7 mole CO2 is evolved
5. 'A' reacts by following two parallel reaction to give B & C If half of 'A' goes into reaction I and
other half goes to reaction-II. Then, select the correct statement(s)
A+N ⎯⎯
I
→ B+L
1
A+N ⎯⎯
II
→ B+ 1 C+L
2 2

(A) Mass of B will be always greater than C

(B) If 2 mole of C are formed then total 2 mole of B are also formed
(C) If 2 mole of C are formed then total 4 mole of B are also formed
(D) If 2 mole of C are formed then total 6 mole of B are also formed

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MOLE CONCEPT (Physical Chemistry)

6. Silver metal in ore is dissolved by potassium cyanide solution in the presence of air by the
reaction
4 Ag + 8 KCN + O2 + 2H2O ⎯→ 4 K[Ag (CN)2] + 4 KOH
(A) The amount of KCN required to dissolve 100 g of pure Ag is 120 g.
(B) The amount of oxygen used in this process is 0.742 g (for 100 g pure Ag)
(C) The amount of oxygen used in this process is 7.40 g (for 100 g pure Ag)
(D) The volume of oxygen used at STP is 5.20 litres.
7. Given following series of reactions:
(I) NH3 + O2 ⎯→ NO + H2O
(II) NO + O2 ⎯→ NO2
(III) NO2 + H2O ⎯→ HNO3 + HNO2
(IV) HNO2 ⎯→ HNO3 + NO + H2O
Select the correct option(s):
(A) Moles of HNO3 obtained is half of moles of Ammonia used if HNO2 is not used to produce
HNO3 by reaction (IV)

(B) 100 % more HNO3 will be produced if HNO2 is used to produce HNO3 by reaction (IV) than if
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HNO2 is not used to produce HNO3 by reaction (IV)

(C) If HNO2 is used to produce HNO3 then 1 th of total HNO3 is produced by reaction (IV)
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(D) Moles of NO produced in reaction (IV) is 50% of moles of total HNO3 produced.

PASSAGE BASED QUESTIONS

COMPREHENSION 8 TO 9
Preparation of cobalt Metaborate involves the following steps of reactions:
(i) Ca2B6O11 + Na2CO3 (aq) ⎯→CaCO3 (insoluble) + Na2B4O7 + 2NaBO2
(ii) Na2B4O7 ⎯→NaBO2 + B2O3
(iii) CoO + B2O3 ⎯→Co(BO2)2.
(Atomic weight : B = 11, Co = 59)
8. Mass of Ca2B6O11 in kg required to produce 14.5 kg of Co(BO2)2, assuming 100% yield of each
reaction is
(A) 32.2 (B) 40 (C) 28.2 (D) 30

9. If the yield of reaction (i), (ii) & (iii) is 60%, 200 % & 32.2 % respectively, then mass of Ca2B6O11
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in kg required to produce 14.5 kg of Co(BO2)2 is

(A) 250 (B) 200 (C) 190 (D) 150

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MOLE CONCEPT (Physical Chemistry)

COMPREHENSION 10 TO 12
Water is added to 3.52 grams of UF6. The products are 3.08 grams of a solid [containing only U,
O & F] and 0.8 gram of a gas only. The gas [containing fluorine and hydrogen only], contains 95
% by mass fluorine.
[Assume that the empirical formula is same as molecular formula.]
10. The empirical formula of the gas is
(A) HF2 (B) H2F (C) HF (D) HF3
11. The empirical formula of the solid product is
(A) UF2O2 (B) UFO2 (C) UF2O (D) UFO
12. The percentage of fluorine of the original compound which is converted into gaseous
compound is
(A) 66.66 % (B) 33.33 % (C) 50 % (D) 89.9 %

MATCHING LIST/MATCH THE COLUMN

13. Column-I Column-II
(Amount of substance) (No. of moles of particular atoms in
the given substance)
(P) 6.022 × 1024 molecules of Al2(SO4)3.3H2O (A) 15 mole O-atoms
(Q) 90 gm C6H12O6 (B) 3 mole O-atoms
(R) 112 litre SO3(g) at 1 atm and 0°C. (C) 2.5 mole O-atoms
(S) 54 gram N2O5 (g) (D) 150 mole O-atoms
Code : (P) (Q) (R) (S)
(A) 4 2 1 3
(B) 4 2 3 1
(C) 4 1 2 3
(D) 2 1 4 3

14. Matching list type :

Column-I Column-II
(mass of product)
(P) 2H2 + O2 → 2H2O (1) 1.028 g
1g 1g
(Q) 3H2 + N2 → 2NH3 (2) 1.333 g
1g 1g
(R) H2 + Cl2 → 2HCl (3) 1.125 g
1g 1g
(S) 2H2 + C → CH4 (4) 1.214 g
1g 1g
P Q R S
(A) 3 4 1 2
(B) 2 4 1 3
(C) 4 3 1 2
(D) 2 3 1 4
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MOLE CONCEPT (Physical Chemistry)

15. Column - I Column - II

(A) 1 mole N–3 (Nitride ion) (P) 10 mole electrons
(B) 1 mole O–2 (Oxide ion) (Q) 8 mole protons
(C) 1 mole CH4 (R) 6.023 × 1023 molecules
(D) 1 mole H2O (S) 10 mole protons
(T) 5 mole atoms

ASSERTION REASON
The following questions consist of two statements. Mark the answer as follows.
(A) If both statements are CORRECT, and Statement II is the CORRECT explanation of
Statement I.
(B) If both statements are CORRECT, and Statement II is CORRECT the CORRECT explanation of
Statement I.
(C) If Statement I is CORRECT, but Statement II is INCORRECT.
(D) If Statement I is INCORRECT, but Statement II is CORRECT.

16. Statement I: During a chemical reaction, the total moles remain constant.
Statement II: During a chemical reaction, the total mass remains constant.
17. Statement I: For the reaction:
2A(g) + 3B(g) → 4C(g) + D(g),
the vapour density remains constant throughout the progress of reaction.
Statement II: In all the gaseous chemical reactions, the vapour density remains constant.
18. Statement I: The number of atoms in a given mass of dioxygen (oxygen) and trioxygen (ozone)
gases is same.
Statement II: The number of atoms in a given mass of an element does not depends on
molecular formula.

NUMERICAL VALUE TYPE QUESTION

19. P4S3 + 8O2 ⎯→ P4O10 + 3SO2
Calculate minimum mass of P4S3 is required to produce at least 1 gm of each product.
20. Determine the percentage composition (by mass) of a mixture of anhydrous sodium carbonate
and sodium bicarbonate from the following data:
wt. of the mixture taken = 2g
Loss in weight on heating = 0.11 gm.

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MOLE CONCEPT (Physical Chemistry)

21. Nitrogen (N), phosphorus (P), and potassium (K) are the main nutrients in plant fertilizers.
According to an industry convention, the numbers on the label refer to the mass % of N, P 2O5,
and K2O, in that order. Calculate the N : P : K ratio of a 30 : 10 : 10 fertilizer in terms of moles of
each element, and express it as x : y : 1.0. Find y.
22. A quantity of 1 g dry green algae absorbs 5.0×10–3 moles of CO2 per hour by photosynthesis. If
the carbon atoms were all stored after photosynthesis as starch (C6H10O5)n, how long (in
hours) would it take for algae to increase its own weight by 81%, assuming photosynthesis
taking place at a constant rate?
23. A 1.174 g sample of special grade steel was treated appropriately with Chugaev's reagent by
which nickel was precipitated as nickel dimethylglyoxime, NiC8H14O4N4. The dried precipitate
weighed 0.2887 g. The percentage of nickel in the steel being analysed is (Ni = 58.7)
24. In a determination of P an aqueous solution of NaH2PO4 is treated with a mixture of ammonium
and magnesium ions to precipitate magnesium ammonium phosphate Mg(NH4)PO4. 6H2O. This
is heated and decomposed to magnesium pyrophosphate, Mg2P2O7 which is weighed. A
solution of NaH2PO4 yielded 1.054 g of Mg2P2O7. What weight of NaH2PO4 was present
originally?
25. Sodium chlorate, NaClO3, can be prepared by the following series of reactions:
2KMnO4 + 16 HCl → 2 KCl + 2 MnCl2 + 8H2O + 5 Cl2
6Cl2 + 6 Ca(OH)2 → Ca(ClO3)2 + 5 CaCl2 + 6H2O
Ca(ClO3)2 + Na2SO4 → CaSO4 + 2 NaClO3
What mass of NaClO3 can be prepared from 100 ml of concentrated HCl (density 1.18 gm/ml
and 36% by mass)? Assume all other substances are present in excess amounts.
26. Recent controversial efforts to generate energy via 'cold fusion' of deuterium atoms have
centred on the remarkable ability of palladium metal to absorb as much as 1120 times its own
volume of deuterium gas at 1 atm and 0°C. The number of deuterium atoms per 10 atoms of Pd
in a piece of fully saturated Pd metal is (Density of Pd = 11.8 g/ml and atomic mass of Pd =
106.2)
27. 5.33 mg of salt [Cr(H2O)5Cl].Cl2. H2O is treated with excess of AgNO3(aq.) then mass of AgCl
precipitate obtained will be : Given : [Cr = 52, Cl = 35.5]
28. To find formula of compound composed of A & B which is given by AxBy, it is strongly heated in
oxygen as per reaction-
AxBy + O2 → AO + Oxide of B
If 2.5gm of AxBy on oxidation gives 3gm oxide of A, Find (x + y)
[Take atomic mass of A = 24 & B = 14]

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MOLE CONCEPT (Physical Chemistry)

29. In one process for waterproofing, a fabric is exposed to (CH3 )2 SiCl2 vapour. The vapour reacts
with hydroxyl groups on the surface of the fabric or with traces of water to form the
waterproofing film [(CH3)2 SiO]n, by the reaction
n(CH3 )2 SiCl2 + 2nOH − ⟶ 2nCl− + nH2 O + [(CH3 )2 SiO]n
where n stands for a large integer. The waterproofing film is deposited on the fabric layer upon
layer. Each layer is 6.0"Å thick [ the thickness of the (CH3 )2 SiO group]. How much (CH3)2SiCl2 is
needed to waterproof one side of a piece of fabric, 1.00" " m by 3.00" " m, with a film 300 layers
thick? The density of the film is 1.0 g/cm3.
First multiply your answer with 100. Then fill your answer as sum of digits (excluding
decimal places) till you get the single digit answer.
30. The molecular mass of an organic acid was determined by the study of its barium salt. The
barium salt contains two moles of water of hydration per Ba2+ ion. 2.562gm of this salt reacts
completely with 30ml of 0.2MH2 SO4 to produce BaSO4 and the acid. The acid is monobasic.
What is the molecular wt. of anhydrous acid? (Atomic wt. of Ba = 137)

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