Creute Toul Comp-er

Jupid
J
St
I,
CN) Ru Ru (N)

Àattracum tms n Prame

mutal
mtal

alenC
eietam houns
in Sph

Oynth e s i s

tNA),Ru +R (N
A
m 492»m
Pyraain qandL
to Ru
4t
onenALondlio.

easts
C
R (NEs]
CN) Ru-
ine in pHs neR
alled
543nm Aasei
LTTComptn)
2
NH)Ru-N o +Ht.
acid

Lotme «Can ler

UV w i ble ueplaced
o 442 nm uy abtrr
JUan
u/ R
shD s t A Nanalue at 142mm ComplUK.
wic doneapes n ámenai
Am 54} nm
Cinterai, )
SUAR
2 LN).Ru-ÁOu(N),1cest
potentio c

TKuo otendiomubuy.
trouckuat
xRD.
ykal
dtemi nd. y sir
SRLG Cm4r maii m JPLmd upn
-ecut paed
Ruu Neuwnts

is N-Ru s appnozimakuy 45'a

Cmt oi ni h
Ru 1 um Ahe pAAn
dwiates
dh ryaRene ufaand u 2 dy 04 94

mùid haheR Compl

Absosm spoteum

LNB ty .
Amar 54 nm.
Specda ot 47 nm

MLET O b s o p h m
5

wiei ble Kegim) Xmar 5c Snm.

th
aklui uut ed Ao
muta do i g a
eaa an Juand

IR
158nm mdanaltwe
A 15o (n

cctli luted o
h i in trna lenn

Chabe htns

Ru tomn
S+

h
N R A - P - Ru (NHS)
 MO Deseotpu ok Ru py- Ru
igad ohmactor)
ABMO

gd
(MLCT
t2g x* [5%nm)
NgMO
metr matal chmnelir
MMCT) dua Kaleuct chmge
ABM 0 botr
bCmutal charmcir)
Am1578m
/4
dun dtloalirolüm

Spotial ontalap
Autwee Ru (4d) --n*

m Ru
LLugad prcsend
( t dep endls Ane digand pHe Sinkun Ru
N
Nt Omothe waand
d u Nh qeLo-tup is seLplaced l y
T
inanalencL Chase
(cPYbiPY)
th Ahe
wwAnttuyn
beurst ecCuS a t lolr

Aitid un o
nkaaalence dLand
he

Samt Oxidaln
equnalent cnk9
(us th in

dcreasts C NH is suplactd Ly o m o e
iuondin iqand
Jack Ji noAmulit t
uck met

[Ru[by).").cPY)
mo
únbayatue
t Channtr
a n d ie olsomesd

un he dleloais alim

ohRut) eluetumg du
lpy gand
lit mo duack duo ndi ng laands un The
Cmmqlor
Ceordinaiim cphne twn Pu odm

E EJeck trens Jut t h hun u aLsms Gcun

houg hi pyra in Cigawd

-

Vas kas Complux

as nkoral al
dhlor de
Ond hars PPh3
a n d t0 and
stut wrally wdLndihed
t L a u Vaska .

-Ir Pphg
PP homoeneeus CAtalysIS
bin did, uus Al bly

Applilalums

m o t n u A ltalyAis

oO tris Compli
e v i b
diindrg H rIULA inoling
mimicking
Atudied o
Soluent Jsthe

Sote o CO
CO
S nhe Risb:)
pMF
P PPhg
I h0
+
Phg
Solven
N atimephit
P-0
aLiganc Ar atmesph

6eS tem,coornalnel Comp

Squa
mutualy Tang PPM
0A JigansA
 O r i d a t i n

HAim
d d i h

Vaslkas mpl<A.

0A PPhg t
-PPha H

PhP

C o

Ph3

2 0 p A n kintis
duplnds m u eme.
ML
and
nasakas
tmpln

Vaskas
heus-h nthopy hang LeLEuneen

O.A
Audies
no
Ahos
aus actin
RX
umir
Fom
ano Ptu eally
compiuX
Waldin inversim
ún tat
adienl
acclovaated y uenzeyl proxdde
ASets
mecnanism
tooaads Haoi t a r
Snagsine

TLfco)i +R RIL,(co)
.Rx
L R)[t)
R
Heactin Leut een Me, uunty halide ma
Vaska's comple l o h t edeo pliluie

Pokh
Can dnidid dnt iuo clas&tS
() nuo philie (non adi
tal)
w) aadital michanism
hindired u a t i ma
Steri aaliy
adicaR pathway,
Juth SMal
undeagoes aimpl oA
V b kas CompUn
woluel (h2,30 HX, d9
 (1950 m m Vaskas tompl¢r i n ugano Co
l-C stretthirg ueaueny
oxidatim s i t i dr
charaelenstie ' t dhi

M C=0

m C=o
c o halion

T - eack bondng {m M ta L

has
AT D-A Ts(I)>I (Il),(0)
dho
uoer d-es Lack duonding
o n d r 0nd
Thus weakens the ML
Jon hu,
Smultanisusly stoung thens C0
Mesult i n úncYeastd

Motucule addud Produet|oon")

ILo) CPPha), |16+ tm

Tr [0to)ulprh)20l5th

204 6

2041 um

adauot
-

Reoacts u i h 0,, ieversiby, horms : |

11tf!Co

PPht ,

CL
CD
-
0-0 ond uyth
esmblus nith p o n i l l
1:44 A concludud h a t . adduurt ooopta
3tuctu

Sbomwn u a a s tHangulay
a b s o p l o n
aut B6o
at

IR
T r - p r 0xo tructupe

nitue ano h e
The Adt
add
is ltamag

moment M- 3.9D.
adduet
m - Up
uonaing

dy(t

haisde
Lx=
)LPha)
rCto
)
talihbl dzy phLLi tals
ds
ssth
tainize thi D,-adduet usuting
0-D uond ngtn.
m
erense
anionie tigaund)
I ACoo)[pPh,) (A =ninalent, Leasiei
phepahmal
to t
Aeaclim hall is ds tue
mutal omplir uen
vthe
uneti m h r pyA

o JHAO (iy
Heac au uasiul oh'tompl
i c n opends m the dm
Phope A
 Di niteogn Compltxes tragitímnnctals

NChmically unrt
Ngt 3h 2NH
Halur bosch poLEB
thr modynanmicaly kamomcd NEN
to high
Occur dus .ds m o e i a t i n
A i m d i d nst

entegy
Biolay ialN; iralin
3Ht hoguna 2N+
MO-eLegna NH

NNg+Be+
Mg ADP
G mg Atp
+14HP

Complt
Iranti m mikal- dinitaogtn

poted ditiytn compua uy

Firsb
Sunsk r 1963 NH
,NN 2
LKct,.BHm0 NM4.0,
2
N

diawmagnitic

Mo l IR uand
1-10-2100 cm

attulut ad to

NEN
dnet N,aim: Yamamoto ctal im 1ac
AL(08)E2 Pha
Cofacac)1Na(1atm), NEN
t u tohutnc, Oc

PPh
miltal N,
Caoy p o y onw huoka ansitim
ompluA

-ucdean d n g t m
metal- N, Complexe&
t a l n 196
Tau

R Nt,CU ( Mg), [uNH), H

Ae. Hh04 ' Nlam)

CN Ru-N=N-Ru/N

v HebHollimetallie dindtsuoger duudacd wompalta

Re Mo leoa
gamd rthanae MAdim
Phe N=N
Ph-CNHN-H
ReOcl,CPm),]

dungena
OH, ,Ph

Phe PM,Ph
Ph PMa
TPme,fh
Mady Cth,I ClRe NEN Mo 0Me

ChC PhmyP
2
fMu,?h Re-N
bamd ab 1992 em n
IR
mono nulear tomplut nit to L81btmd
hut vm Jtmk olie comptt
 CAODdnali ovv Chemi
Mmds dinihAm lmpkr e;
(eneaa bindinq

nd 4n Sde-On
N
Mononuclear M NN M-1
N
N
Binuelca M NN- M M1M MNN
MNNM N M
M M N
M M
M
N
M
M M

MNM
Mono nucl eow dintuogth guidging end m
Comptexes Co0udinalid
c i i d n theu dinatsa 9n Compl enA
M-N-N
1G4 ZM-N=N uúdor tha
IGo
Auenage ond oist ante
N =N 19A
tnampl ide 8n bidaed adi nitogn tmplea

phtNi,CN)0.3.
amplas o uloek, dinú 1uogtn Complexu

N
nt as iand
Jt eeak gand i l e s ifs nm p aq

2 g (LU MO)
T uack bev

M
3 >fOMO)
NENO Uclonadm
olonatin
u t uten
A 44
Mdy
A 16
Na(30)
Weaker T do naism
NEN
tO -Qucapto
1

weak leuis uas

L t octn
T Uack diondny Compl ms at
omplxes a
Mdya) N,(?u) Raman actine
wt mot IR acti
Fr due to symmit y
idginq complto ts
Kum a n band duuu suift ed pLsenr m mouculad
2150- 00m-l,
RaAnan band (N=N)
Un tnd Compltx es
Skts om 230 m
2950-1800 m
huni cal Attinali on 2 dt
pendi na 4n 7 back dwnd
Reactii o ornátjuog Complex
Qlon ati m N-N
Coord nadi m i t h M dLaodss
Ond du to e do nation c m M to N. antibond

LUMO
(W Put nali m dinítog o mplexes
Mo del Lonplexs uotuig nvoluu Me W
 Coo nated d a hsphin igand
NEN
PMe Ph
PhMP
MO +H304
PmePh eeess
PhMe,P

2NH
2NH + MoCtv) - tomplec

NN
F H e ANH
NH
N
P

P
Mo

.
Chail Yle

NEN

N P
Mo H,e
L
NNH

NH P
Mo

N
N
He
Mo Mo
P p
Nh

nonucleo oinutaogn Cmpltn "T

ther mo
m
V, Cr, Fe Nh And hydaPe
2
PLoto nai m

P Fe-NEN HOT N +N,t4 t Felt)

oTHE Compl
tounríeld
P

N,HA m a pdk A

WhtHeOt ed uuth acid

CR 2r N=N-r NH4+ 2N2

-30'c t 2 [p*ar

wht C
 lkyiu
lkxu
dinútuogen uidacd
dtuidgcd C mp
Cleauaye d

Ngllak

Mo- N 35'c
N N
AT
Mo-N=N-Mo (t ArB
BuhrN
A
30 C

Mo
N N
N
 AinstuoCompl tnes hrunuitn mials
Enuimment

usloial uystuw e tmie, mtaluo entym

t a t d l y t aystem un audoe i dati n pusuin

e ducti m O

6u
GHOUnd Alat

w wnpoud es
n 21

aiy tuo
wnpaid es

shuy i a 94-2
1594 kmal
tuput s 02 uides wwputtny aluous he
iniic u a i e t a tntis
uut oidatim0 9 . mouls s

phot thmkal atudin

nadi toa
u teocum uith uu
juuit hanuum mtd M highr Ipu
Meutin
Oxi Coupung
6t u c w a C l a e im
asud n bhu dwt honie
Voska's d a i u t i
m
Meaoá i

ComplR a didel u ghops

A
St
HuLgueySupur
upirot» (o1b) pueo(Ia, lb~IGO
1 5 ( 0 - 0 dtistancs v 13A (O-odishanc 49 A)
 Stucw disignatin Nask a's
Claihsím

0-0
-du4 Typ aG)O
M

D m-oowA TyLLa (ph Pko

M CN )
:pT
(Supao o

Type Tb
)Coloylo
(N
-dioxy

M- ML
-dio
6 y g n di ndi rq

n tmpl tnes aue u n Dmety n tontrast

t'dintuook Compltnes
0-0

094is dereasd
 w n t ot t y

0- 0 -

(4) (
ulun ikal
b A u duulaps
09titad

d 0sli tals
and n

pasr modu Co ddorygun complRAL

Stombin1 a l tau puDnthomatu
-u) x00s ppOA uuy

untaonal
Praddal
Coodinatim
Oond C.
G al sugastid Juondi
u t o e e n mata- accpiir diluial
AHhanmunt
m e a 0-atam
Ound s hyuid pair
itsperpomdiclm to MO2
2n A 0 u i ta
ptan Comple
M
0 ) 9Compl4

Secondmy -mttractims

2
S- itnactím » aLomd
 M
d 4

4
M-0-0
non bondu

oliox4gun Compluces innusus

enealy adhasis
dous Valint,
mtal Complen es
D.A O 2 in
CO

PPhg 0 h, 30,sla PPha

Senite C

Octs Qs an
Mernylunt blul
Formatin o meno
rale dudyg Cmplexs2 Con e
CoDMG. D2 Paidng
2 Co(DM),rid)
Co3-Busaltn-Pidiha CoBtu

-Formatim t
dinnidem dio a tompl eu
2 RhPPha), tl + 20, TRh(Ppha)0.)«

2Co (hisiditOg > Co,lhistidkne)J)

o(rye)f +
2Cocl,+2 pyolien + 4NaI CtoH
bhidgire
 bu Oidisiny igand
isplacemnt

.CPPhe) +20 L 0 Pph:),t2 PhPo

Reactiuly o4 omplxes

ehintkogen do mtal uass thnstr

Buriry dioaugi,
Htrage unig t
electsn mdioxuyse
reoluctim
mo. 5wnpoured
y spin Pai

nueles phili
doygn gand a 4 n s
ebu

ohamacktr.

Reacti d5 7eeptexes cuoH2n Cmplexes

tuu
Aaptex d berwnen
dimiri2ati MOOM

mioyge Copltxs to orm

Comple
Col) +0a n-CoO

-Co0g+Co(1) : 7 Coo,Co
atlack dioxgen igand
mueleo philie
Mo ds n phesenc
eaols uuih
- ToCN);0 Co-0-0-MO cmpte
pLodue
exees
ere N
KaCDporphyin)
ComplexesC om
-:
-FeOa
bast tomple
-
Co-Scnkh

R
 R -0-CeCn)
-0-tol)

Keadins 2 Complex es.

noto natim veactim

M t2HX M
eactim betuoeen -PPha)MLO2 MPA, P) e
diuaste acid pAoduces kt Chtlatid tompa
agtn uiberatirg h02
Nueleophtie atkock m the polon bond

St A
M A x M 0
X
M + M

CPhP,Pt + PhttH Br
fh
CH
CPha) P
unvension of
Conkigeratim.
n eatom suat
SNmuchanism
(PhaPt0, + (Ct,).C=o
Pt
o(),
Cyeie talLA

d i o l o m i t a k a i s n

Compten.
 (PhP)Pt D,
+ Cop P
pph

Pe?
Oxidatim S l u b r i

M
ML, O+ So, -
Ehlatra Sulphlz

M- Pt, Pd C o m p l e x

L LM (NOG)
+NO

MLOn
Ni
M= Pd, P4,