Chemistry
(Structure of Atom)
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JEE Advanced 2024 Paper 2 Online
1
According to Bohr's model, the highest kinetic energy is
associated with the electron in the
A first orbit of H atom
B first orbit of He+
C second orbit of He+
D second orbit of Li2+
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JEE Advanced 2024 Paper 2 Online
1
According to Bohr's model, the highest kinetic energy is
associated with the electron in the
A first orbit of H atom
B first orbit of He+
C second orbit of He+
D second orbit of Li2+
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JEE Advanced 2019 Paper 2 Offline
2 Consider the Bohr's model of a one-electron atom where the
electron moves around the nucleus. In the following List-I
contains some quantities for the nth orbit of the atom and
List-II contains options showing how they depend on n.
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JEE Advanced 2019 Paper 2 Offline
2
Which of the following options has the correct combination
considering List-I and List-II?
A (III), (P)
B (III), (S)
C (IV), (U)
D (IV), (Q)
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JEE Advanced 2019 Paper 2 Offline
2
Which of the following options has the correct combination
considering List-I and List-II?
A (III), (P)
B (III), (S)
C (IV), (U)
D (IV), (Q)
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JEE Advanced 2019 Paper 2 Offline
3 Consider the Bohr's model of a one-electron atom where the
electron moves around the nucleus. In the following List-I
contains some quantities for the nth orbit of the atom and
List-II contains options showing how they depend on n.
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JEE Advanced 2019 Paper 2 Offline
3
Which of the following options has the correct combination
considering List-I and List-II?
A (II), (R)
B (I), (P)
C (I), (T)
D (II), (Q)
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JEE Advanced 2019 Paper 2 Offline
3
Which of the following options has the correct combination
considering List-I and List-II?
A (II), (R)
B (I), (P)
C (I), (T)
D (II), (Q)
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JEE Advanced 2017 Paper 1 Offline
4 The wave function, ψn,1,m1 is a mathematical function whose
value depends upon spherical polar coordinates (r, θ, φ) of
the electron and characterized by the quantum numbers n, 1
and m1. Here r is distance from nucleus, θ is colatitude and φ
is azimuth. In the mathematical functions given in the table,
Z is atomic number and a0 is Bohr radius.
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JEE Advanced 2017 Paper 1 Offline
4
For He+ ion, the only INCORRECT combination is
A (I) (i) (R)
B (II) (ii) (Q)
C (I) (iii) (R)
D (I) (i) (S)
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JEE Advanced 2017 Paper 1 Offline
4
For He+ ion, the only INCORRECT combination is
A (I) (i) (R)
B (II) (ii) (Q)
C (I) (iii) (R)
D (I) (i) (S)
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JEE Advanced 2017 Paper 1 Offline
5 The wave function, ψn,1,m1 is a mathematical function whose
value depends upon spherical polar coordinates (r, θ, φ) of
the electron and characterized by the quantum numbers n, 1
and m1. Here r is distance from nucleus, θ is colatitude and φ
is azimuth. In the mathematical functions given in the table,
Z is atomic number and a0 is Bohr radius.
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JEE Advanced 2017 Paper 1 Offline
5
For He+ ion, the only CORRECT combination is
A (I) (i) (S)
B (II) (i) (Q)
C (I) (i) (P)
D (I) (iv) (R)
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JEE Advanced 2017 Paper 1 Offline
5
For He+ ion, the only CORRECT combination is
A (I) (i) (S)
B (II) (i) (Q)
C (I) (i) (P)
D (I) (iv) (R)
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JEE Advanced 2024 Paper 1 Online
6
Among the following, the correct statement(s) for electrons
in an atom is(are)
Uncertainty principle rules out the existence of
A
definite paths for electrons.
The energy of an electron in 2s orbital of an atom is
B lower than the energy of an electron that is infinitely
far away from the nucleus.
According to Bohr's model, the most negative energy
C value for an electron is given by n = 1, which
corresponds to the most stable orbit.
According to Bohr's model, the magnitude of velocity
D
of electrons increases with increase in values of n.
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JEE Advanced 2024 Paper 1 Online
6
Among the following, the correct statement(s) for electrons
in an atom is(are)
Uncertainty principle rules out the existence of
A
definite paths for electrons.
The energy of an electron in 2s orbital of an atom is
B lower than the energy of an electron that is infinitely
far away from the nucleus.
According to Bohr's model, the most negative energy
C value for an electron is given by n = 1, which
corresponds to the most stable orbit.
According to Bohr's model, the magnitude of velocity
D
of electrons increases with increase in values of n.
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JEE Advanced 2022 Paper 1 Online
7
For diatomic molecules, the correct statement(s) about the
molecular orbitals formed by the overlap of two 2pz orbitals
is(are)
A σ orbital has a total of two nodal planes.
σ* orbital has one node in the xz-plane containing the
B
molecular axis.
π orbital has one node in the plane which is
C perpendicular to the molecular axis and goes through
the center of the molecule.
π* orbital has one node in the xy-plane containing the
D
molecular axis.
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JEE Advanced 2022 Paper 1 Online
7
For diatomic molecules, the correct statement(s) about the
molecular orbitals formed by the overlap of two 2pz orbitals
is(are)
A σ orbital has a total of two nodal planes.
σ* orbital has one node in the xz-plane containing the
B
molecular axis.
π orbital has one node in the plane which is
C perpendicular to the molecular axis and goes through
the center of the molecule.
π* orbital has one node in the xy-plane containing the
D
molecular axis.
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JEE Advanced 2019 Paper 2 Offline
8 The ground state energy of hydrogen atom is –13.6 eV. Consider
an electronic state ψ of He+ whose energy, azimuthal quantum
number and magnetic quantum number are –3.4 eV, 2 and 0,
respectively.
Which of the following statement(s) is(are) true for the state ψ?
A It is a 4d state
The nuclear charge experienced by the electron in this
B state is less than 2e, where e is the magnitude of the
electronic charge
C It has 2 angular nodes D It has 3 radial nodes
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JEE Advanced 2019 Paper 2 Offline
8 The ground state energy of hydrogen atom is –13.6 eV. Consider
an electronic state ψ of He+ whose energy, azimuthal quantum
number and magnetic quantum number are –3.4 eV, 2 and 0,
respectively.
Which of the following statement(s) is(are) true for the state ψ?
A It is a 4d state
The nuclear charge experienced by the electron in this
B state is less than 2e, where e is the magnitude of the
electronic charge
C It has 2 angular nodes D It has 3 radial nodes
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JEE Advanced 2023 Paper 2 Online
9 For He+, a transition takes place from the orbit of radius
105.8pm to the orbit of radius 26.45pm. The wavelength (in
nm) of the emitted photon during the transition is ______.
[Use:
Bohr radius, a = 52.9pm
Rydberg constant, RH = 2.2 × 10-18 J
Planck's constant, h = 6.6 × 10-34 Js
Speed of light, c = 3 × 108 ms–1 ]
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JEE Advanced 2023 Paper 2 Online
9 For He+, a transition takes place from the orbit of radius
105.8pm to the orbit of radius 26.45pm. The wavelength (in
nm) of the emitted photon during the transition is ______.
[Use:
Bohr radius, a = 52.9pm
Rydberg constant, RH = 2.2 × 10-18 J
Planck's constant, h = 6.6 × 10-34 Js
Speed of light, c = 3 × 108 ms–1 ]
Correct answer:- 30
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JEE Advanced 2021 Paper 2 Online
10 Consider a helium (He) atom that absorbs a photon of
wavelength 330 nm. The change in the velocity (in cm s–1) of He
atom after the photon absorption is __________.
(Assume : Momentum is conserved when photon is absorbed.
Use : Planck constant = 6.6 × 10–34 J s, Avogadro number = 6 ×
1023 mol–1, Molar mass of He = 4 g mol–1)
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JEE Advanced 2021 Paper 2 Online
10 Consider a helium (He) atom that absorbs a photon of
wavelength 330 nm. The change in the velocity (in cm s–1) of He
atom after the photon absorption is __________.
(Assume : Momentum is conserved when photon is absorbed.
Use : Planck constant = 6.6 × 10–34 J s, Avogadro number = 6 ×
1023 mol–1, Molar mass of He = 4 g mol–1)
Correct answer:- 30
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JEE Advanced 2020 Paper 2 Offline
11 The figure below is the plot of potential energy versus
internuclear distance (d) of H2 molecule in the electronic
ground state. What is the value of the net potential energy E0
(as indicated in the figure) in kJ mol-1, for d = d0 at which the
electron-electron repulsion and the nucleus-nucleus
repulsion energies are absent? As reference, the potential
energy of H atom is taken as zero when its electron and the
nucleus are infinitely far apart.
Use Avogadro constant as 6.023 × 1023 mol-1.
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JEE Advanced 2020 Paper 2 Offline
11 The figure below is the plot of potential energy versus
internuclear distance (d) of H2 molecule in the electronic
ground state. What is the value of the net potential energy E0
(as indicated in the figure) in kJ mol-1, for d = d0 at which the
electron-electron repulsion and the nucleus-nucleus
repulsion energies are absent? As reference, the potential
energy of H atom is taken as zero when its electron and the
nucleus are infinitely far apart.
Use Avogadro constant as 6.023 × 1023 mol-1.
Correct answer:- –5242.41
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JEE Advanced 2015 Paper 1 Offline
12
Not considering the electronic spin, the degeneracy of the
second excited state( n = 3) of H atom is 9, while the
degeneracy of the second excited state of H– is _________.
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JEE Advanced 2015 Paper 1 Offline
12
Not considering the electronic spin, the degeneracy of the
second excited state( n = 3) of H atom is 9, while the
degeneracy of the second excited state of H– is _________.
Correct answer:- 3
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