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TN SET 2025 Chemistry

1. Which of the following reaction is a redox reaction?

(a) [Fe(CN)6]4- + [Mo(CN)8]3- → [Fe(CN)6]3- + [Mo(CN)8]4-
(b) HNO3 + 2H2SO4 → 2HSO4- + NO2+ + H3O+
(c) SO3 +H2SO4 → H2S2O7
-
(d) SbF5 + 2HF → H2F+ + SbF6

2. Match the following:

Reaction Organometallic catalyst
1. CH2=CH2 + ½ O2 → CH3CHO (i) (Ph3P)3RhCl
2. CH3OH + CO → CH3COOH (ii) Co2(CO)8
3. CH2=CH2 + 2CO + 2H2O → CH3CH2CHO (iii) [Rh(CO)2I2]
4. CH2=CH2 + H2 → CH3-CH3 (iv) [PdCl4]2-

(a) 1-iv, 2-iii, 3-ii, 4 - i (b) 1-iii, 2-iv, 3-i, 4 - ii

(c) 1-ii, 2-iii, 3-i, 4 - iv (d) 1-iv, 2-i, 3-ii, 4 - iii

3. The 19F NMR spectrum of SF4 consists of:

(a) One 1:2 triplets of different intensity (b) Two [Link] doublets of equal intensity
(c) Two [Link] triplets of equal intensity (d) Three [Link] triplets of unequal intensity

4. ESR spectrum of the complex ion [Mn(CN)8]3- in solution consists of one line. If the sample enriched
with 13C nine line(s) are observed. This shows I for 13C is:
(a) 1/2 (b) 3/2 (c) 1 (d) 2

5. In Diborane, the B…H…B bonds are:

(a) 3c-2e bonds (b) 2c-3e bonds (c) 2c-2e bonds (d) 3c-3e bonds

6. The increasing order of d orbitals of Fe in Ferrocene

(a) dx2-y2 = dxy < dz2 < dxz = dyz (b) dz2 < dxz = dyz < dx2-y2 = dxy
2 2 2
(c) dz < dxy = dyz < dx -y = dxz (d) dxz = dyz < dz2 < dx2-y2 = dxy

7. Which of the following metal carbonyl has three bridged >C=O groups?
(a) Fe2(CO)9 (b) Mn2(CO)10 (c) Fe3(CO)12 (d) Te2(CO)10

8. Predict the incorrect statement about the electronic absorption of [Mn(H2O)6]2+

(a) All the transitions are Laporte forbidden and spin forbidden
(b) Absorption associated with Laporte and spin forbidden are very weak
(c) [Mn(H2O)6]2+ ion is strongly colored even in dilute solution
(d) [Mn(H2O)6]2+ is, d5 system

9. [Ni(CN)4]2- is
(a)Thermodynamically stable and kinetically labile
(b)Thermodynamically labile and kinetically stable
(c) Thermodynamically stable and kinetically inert
(d) Thermodynamically labile and kinetically labile

10. The correct statement for alkali metal is

(a) Reducing power increases from top to bottom
(b) Oxidizing power increases from top to bottom
(c) Reducing power does not change from top to bottom
(d) Oxidizing power decreases from top to bottom
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11. Which of the following statement is correct regarding the higher ionization energy of Phosphorus than
Sulphur?
(a) Phosphorus is larger than Sulphur (b) Half-filled p-orbitals of Phosphorus is stable
(c) Completely filled p-orbitals of Phosphorus (d) The charge on sulphur is more

12. Number of electrons (x) involved in the following reaction is:

N≡N + 8H+ + x → 2NH3 + H2
(a) 8 (b) 6 (c) 4 (d) 10

13. Which of following pairs of iron complexes will show quadrupole interaction in its Mossbauer
spectra?
(a) Fe(CO)5 and [Fe(CN)5NH3]3- (b) K4[Fe(CN)6] and K3[Fe(CN)6]
(c) [Fe(H2O)6]Cl3 and [Fe(H2O)6]Cl2 (d) [Fe(CO)5] and K3[Fe(CN)6]

14. [Co(NH3)5NO2]2+ and [Co(NH3)5ONO]2+ are :

(a) Coordination isomers (b) Linkage isomers
(c) Ionization isomers (d) Ligand isomers

15. The plot between potential (V) and pH for different species of a metal is called as:
(a) Ellingham diagram (b) Pourbaix diagram
(c) Orgel diagram (d) Walsh diagram

16. __________ nitrides are termed by transition + inner transition metals.

(a) Salt-like (b) Covalent (c) Diamond like (d) Interstitial

17. Total number of orbitals and maximum number of electrons respectively in a shell whose principal
quantum number n = 3 is:
(a) 9 and 18 (b) 3 and 32 (c) 4 and 18 (d) 16 and 32

18. The correct increasing order of energy of d orbitals in square planar field of coordination complexes
is:
(a) dxy = dyz < dz2 < dxz < dx2-y2 (b) dxz = dyz < dz2 < dxy < dx2-y2
(c) dxz = dyz < dxy < dz2 < dx2-y2 (d) dxy = dyz < dxz < dz2 < dx2-y2

19. The trans effect of the following ligands decreases in the order:
(a) CN- > NO2- > Br- > H- (b) CN- > H- > Br- > NO2-
(c) CN- > H- > NO2- > Br- (d) Br- > NO2- > H- > CN-

20. The correct order of increasing ionic radii of the following ion is:
(a) Co2+ < Ni2+ < Cu2+ < Fe2+ < Mn2+ (b) Ni2+ < Co2+ < Zn2+ < Fe2+ < Mn2+
(c) Fe2+ < Mn2+ < Co2+ < Cu2+ < Ni2+ (d) Co2+ < Fe2+ < Mn2+ < Ni2+ < Cu2+

21. Which of the following chemical reaction is example for Lux-Flood definition?
(a) NH4+ + NH2- → 2NH3 (b) CaO + SiO2 → CaSiO3
(c) 4CO + Ni → Ni(CO)4 (d) 2H2O → H3O+ + OH-
234 234
22. The disintegration product obtained from 90Th is 91Po . The disintegration is accompanied by
emission of -----
(a) neutrino (b) γ rays (c) α particle (d) β particle

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23. Identify the ground terms of 3d5 of Mn2+ ion

(a) 6P (b) 4F (c) 6S (d) 6D

24. Which one of the following compound is analogue of benzene?

(a) Diborane (b) Tetrameric cyclophosphazone
(c) Carborane (d) Trimeric cyclophosphazene

25. The disease caused by excess intake of Cu is

(a) itai-itai (b) Wilson disease (c) Scurvy (d) Pellagra

26. The term symbol for the system having L = 0, S = 0 is __________

(a) 1S0 (b) 3P1 (c) 2D3 (d) 2P2

27. The correct order of energy level for 1, 3 - butadiene is:

(a) E1= α-2β; E2 = α - β; E3 = α + β; E4 = α + 2β
(b) E1= α + 2β ; E2 = α + β; E3 = α - β; E4 = α - 2β
(c) E1 = α - β ; E2 = α - 2β; E3 = α + 2β; E4 = α + β
(d) E1 = α + β ; E2 = α + 2β; E3 = α + 2β; E4 = α - β

28. Which of the following statement is incorrect about vibrational energy of a diatomic molecule?
(a) The energy of the lowest state is called zero point energy
(b) The vibrational energy is zero at the lowest vibrational level
(c) The diatomic molecules vibrate even at the lowest vibrational level
(d) The lowest energy state is given by εo =1/2 ̅o, where ̅o is the wave number in cm-1 units.

29. Which of the following statement is incorrect?

(a) Entropy of a closed system must increase in an irreversible adiabatic process.
(b) Entropy of an isolated system must increase in any irreversible process.
(c) Suniv is zero in an irreversible process.
(d) Suniv = Ssyst + Ssurr is unchanged in a reversible process.

30. In the hydrogen spectrum, the transition of an electron from higher level to n = 4 level arises in the
______ series and __________ region respectively.

(a) Brackett, IR (b) Paschen, IR (c) Balmer, UV (d) Pfund, visible

31. ∇2 is called:
(a) Position operator (b) Hamiltonian operator (c) Laplacian operator (d) Momentum operator

32. Which of the following pair is an acceptable wave function in the range 0 to 2π:
(a) sin x and tan x (b) sin x and cosec x (c) sin x and (cos x + sin x) (d) tan x and cosec x

33. Arrhenius plot of ln k against 1/T for the decomposition of Acetaldehyde is given in the figure. The
slope is equal to:

(a) Ea /R (b) Ea (c) R (d) –Ea /R

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34. In the character table given below:

Td E 8C3 3C2 6S4 6σd

A1 1 1 1 1 1
A2 1 1 1 -1 -1
E 2 -1 2 0 0
T1 3 0 -1 1 -1
T2 3 0 -1 -1 1
The order of the point group is:
(a) 5 (b) 12 (c) 6 (d) 24
35. Match the correct pair of the following:
Molecules Types
(i) CH3F (A) Oblate symmetric top
(ii) H2O (B) Spherical top
(iii) SF6 (C) Asymmetric top
(iv) BCl3 (D) Prolate symmetric top

(a) (i)-(D), (ii)-(B), (iii)-(C), (iv)-(A) (b) (i)-(A), (ii)-(B), (iii)-(C), (iv)-(D)
(c) (i)-(A), (ii)-(C), (iii)-(B), (iv)-(D) (d) (i)-(D), (ii)-(C), (iii)-(B), (iv)-(A)

36. The Huckel secular equation for cyclobutadiene is:

(a) | |=0 (b) | | =0 (c) | | =0 (d) | | =0

37. Which is not true about bonding molecular orbital?

(a) It is formed by the addition overlap of atomic orbitals
(b) The wave function of a bonding molecular orbitals is given by ΨMO = ΨA-ΨB
(c) The lobes of atomic orbitals should have the same signs
(d) Every electron in bonding molecular orbital contributes towards the attractive forces.

38. The Miller indices of the crystal plane which cut through the crystal axes at (2a, -3b, -3c) is:
(a) ( ) (b) ( ) (c) (3 2 2) (d) ( )

39. Which of the following is a n-type semiconductor?

(a) Silicon doped with Aluminium (b) Silicon doped with Boron
(c) ZnO with Zinc atoms as impurities (d) Cu2O with Cu2+ ions as impurities

40. The mark-Houwink-Sakurada equation for the determination of molecular weight of a polymer is:
(a) [η].α = K. v (b) [η] = K. ̅ (c) [η] = ̅ (d) [η] . K=

41. If the substituent groups in a polymer lie alternatively above and below the plane, the configuration is
called.
(a) Atactic (b) Syndiotactic (c) Zig-zag (d) Isotactic

42. In polymerization, the kinetic chain length (𝒱) is given by which of the following expressions.
Assume, rate of initiation is Ri; rate of propagation is RP; rate of Termination in Rt
(a) η = (b) η = (c) η = (d) η =

43. The number of significant figures in = 0.131 is

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(a) 2 (b) 3 (c) 4 (d) 1

44. In the phase diagram of a one component system for a two-phase equilibrium, the Clapeyron equation
gives the slope of:
(a) (b) (c) (d)

45. The molar partition Function of the system is:

(a) Q = *∑ ( )+ (b) Q = *∑ ( )+

(c) Q = *∑ ( )+ (d) Q = *∑ ( )+

46. The ionic strength of 0.15 KCl solution is:

(a) 1.5 (b) 0.015 (c) 0.15 (d) 0.12

47. Debye - Huckel limiting law is:

(a) log ± = -0.509| | (b) log ± = -0.509| |
(c) log ± 0.509| | (d) log ± = -0.509| |

48. The unit of spectral density is:

(a) energy x (volume)-1 x (frequency)-1 (b) energy x volume x (frequency)-1
(c) (energy)-1 x (volume)-1 x frequency (d) (energy) x (volume)-1 x frequency

49. Which of the following statements related to Hermitian Operator are correct?
(i) The Eigen values of a Hermitian operators are real.
(ii) Two Eigen functions of a Hermitian operator that corresponds to different values are orthogonal.
(iii) The Eigen values of a Hermitian operator and not real.
(iv) Two Eigen functions of a Hermitian operator that corresponds to different values are orthonormal.
(v) If two Hermitian Operator commute, their product is also a Hermitian operator

(a) (i), (ii), (iii) (b) (ii), (iii), (iv) (c) (i), (ii), (v) (d) (iii), (iv), (v)

50. Write the cell diagram for the reaction below: Cu(s) + Cl2(g) → Cu2+(aq) + 2Cl-(g)
(a) Cu(s) Cu2+(s)║Cl2(g), Cl-(aq)│C(s) (b) Cu(s)Cu2+(aq)║ Cl-(aq)│Cl2(g), C(s)
(c) Cu(s) Cu (aq)║Cl2(g)│ Cl (aq)│C(s)
2+ -
(d) C(s) Cl2(g), Cl-(g) ║ Cu2+(aq) C(s)

51. The correct R, S configuration of the given molecules is:

(a) 1S,2R (b) 1R,2S (c) 1S,2S (d) 1R,2R

52. Predict the major product in Elimination reaction given below:

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(a) (b) (c) (d)

53. Find the correct increasing order of stability of the following Carbocations:

(I) Ph2CH+ (II) (CH3)2CH+ (III) (IV)

(a) (III) < (I) < (II) < (IV) (b) (I) < (III) < (IV) < (II)
(c) (II) < (I) < (IV) < (III) (d) (IV) < (III) < (II) < (I)

54. Find out the suitable products in the following Grignard reaction:

(a) A = B = CH3Br (b) A = B=

(c) A = B = (CH3)2CHOH (d) A = B=

55. Predict the product in the following rearrangement:

(a) (b) (c) (d)

56. Predict the incorrect statement about free radicals:
(a) A free radical is sp2 hybridised or sp3 hybridized
(b) Thermolysis of benzoylperoxide at 70 oC generates C6H5 radicals

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(c) free radical is more stable than

. . .
(d)The stability order of Benzene substituted free radicals follows the order Ph3C < Ph2CH <PhCH2

57. What will be the product in the following reaction?

(a) (b)

(c) (d)
58. What is the major product in the following reaction?

(a) (b) (c) (d)

59. The product formed in the following reaction is

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(a) + (b) + CH3COOH

(c) + (d) +

60. Which of the following compounds will NOT undergo Mc Lafferty rearrangement?

(a) (b) (c) (d)

61. Choose the correct IUPAC name of the compound given below:

(a) 2-Chlorospiro[4.5]decane (b) 3-Chlorospiro[4.5]decane

(c) 2-Chlorospiro[5.4]decane (d) 3-Chlorospiro[5.4]decane

62. Cis-1,3-Dimethyl cyclohexane is:

(a) (b) (c) (d)

63. Molecules belonging to which of the following set of point groups are chiral?

(a) C1, Cn and Dn (b) Cnv, Cnh and Dnd (c) Dnh, Dnd and Cnh (d) Td, Oh and C3v

64. When cis-2-Butene reacts with singlet and triplet carbenes, it produces there 1,2-Dimethyl
cyclopropanes.
(a) Both give cis isomers only
(b) Singlet carbene gives Cis isomer whereas Triplet carbenes gives cis and trans isomer.
(c) Singlet carbine gives trans isomer whereas triplet carbine gives Cis isomer
(d) Singlet carbine gives Cis and trans isomer whereas triplet carbene gives trans isomer only
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65. Arrange the following compounds in the order of increasing SN1 reactivity:

I. II. III.
(a) III < II < I (b) II < I < III (c) I < II < III (d) I < III < II

66. Predict the product of the following reaction:

(a) (b) (c) (d)

67. Predict the product of the reaction given below

(a) (b) (c) (d)

68. What is the major product in the following reaction?

(a) (b) (c) (d)

69. Common amine protecting groups in the following:

(i) Carbonates (ii) N-Substituents like benzyl
(iii) Amides and imides (iv) Acetals

(a) (i), (ii), (iii) and (iv) (b) (i), (ii) and (iii) only
(c) (i) and (iii) only (d) (i) and (ii) only
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70. In the reaction of achiral 2-pentanene to the chiral 4-methyl-3-heptanone, the role of

is
(a) Active reagent (b) Reducing agent (c) Chiral auxiliary (d) Oxidising agent

71. Find out the suitable product in the following reaction

(a) (b) (c) (d)

72. In the reaction [A] and [B] respectively are:

(a) (b)

(c) (d)

73. Predict the product in the following Photo Fries reaction?

(a) and (b) and

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(c) and (d) only

74. The shape of the Cyclooctatetraene is:
(a) Tub - Shaped (b) Octahedral (c) Hexagonal (d) Octagonal planar

75. Specific rotation [α] for pure compounds __________ .

(a) (b) (c) (d)

where a is the observed rotation, l is the cell length in decimeters, c is the concentration in grams per
milliliter, and d is the density in the same units

76. Predict the correct increasing order of cavity size the given crown ethers:
(a) [12] Crown-4 < [15] Crown-5 < [18] Crown-6
(b) [18] Crown-6 < [15] Crown-5 < [12] Crown-4
(c) [15] Crown-5 < [18] Crown-6 < [12] Crown-4
(d) [18] Crown-6 < [12] Crown-4 < [15] Crown-5

77. Acid rain is caused due to the emission of:

(a) Oxides of Sulphur and Oxides of Nitrogen (b) CO2 and Methane
(c) Particulate matter and Ozone (d) volatile organic compounds

78. The various devices and methods employed for the collection of particulates air pollutants are:
(a) Cold trapping and Absorption (b) Adsorption and filtration
(c) Gravity separation and precipitation (d) Adsorption and Absorption

79. Given below are two statements:

Statement I: Enzymes are supramolecules when it binds the substrate at the active site via non-
covalent bonding
Statement II: During catalysis enzymes can act as acids and bases
Choose the correct answer from the following options:
(a) Both statement I and statement II are true (b) Both statement I and statement II are false
(c) Statement I is true and statement II is false (d) Statement I is false and statement II is true

80. Which is not a preferable characteristic of water to be used as green solvent?

(a) Cheap and economical (b) It is safe solvent
(c) It has larger heat capacity (d) It has lowest heat capacity

81. Which of the following reaction involves the principle of green chemistry?

(a)

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(b)

(c)

(d)

82. Based on the crystalline grain and shape, quantum dots are:
(a) Zero dimension (b) One dimension (c) Two dimension (d) Three dimension

83. The correct diagram which represents the variation of band gap with diameter of a semiconducting
chiral CNT is:

(a) (b)

(c) (d)

84. The study of interaction of drugs with the target molecule through binding interaction is called:
(a) Pharmacology (b) Pharmacokinetics (c) Pharmacodynamics (d) Pharmacophore

85. Which one is cryptand?

(a) (b)

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(c) (d)

86. Drugs that increase the rate of urine formation are:

(a) Diuretics (b) Anthelmintic (c) Antiseptics (d) Uricosuric agents

87. The change of atmospheric air temperature with altitude is __________.

(a) Adiabatic rate (b) Lapse rate (c) Isothermal rate (d) Global rate

88. Which one of the following intermediates can be trapped through Diels - Alder reaction?
(a) Carbonium ion (b) Benzyne (c) Nitrene (d) Carbene

89. Match the following

Enzyme Non-polar cofactor or Coenzyme
I. Carbonic anhydrase A. Cu2+
II. Cytochrome Oxidase B. Fe2+/Fe3+
III. Peroxidase C. Mg2+
IV. Hexokinase D. Zn2+

Choose the correct answer

(a) IA, IID, IIIB, IVC (b) IC, IIB, IIID, IVA
(c) IB, IIA, IIIC, IVD (d) ID, IIA, IIIB, IVC

90. Find out the percentage economy of N-methyl propamide in the following reaction

CH3CH2-CO-OC2H5 + CH3NH2 → CH3CH2-CO-NHCH3 + CH3CH2OH

Molecular mass of CH3CH2-CO-OC2H5 = 102 g mol-1

Molecular mass of CH3NH2 = 32 g mol-1
Molecular mass of CH3CH2-CO-NHCH3 = 87 g mol-1
Molecular mass of CH3CH2OH = 146 g mol-1
(a) 65% (b) 45% (c) 70% (d) 35%

91. The total amount of Oxygen required to breakdown the organic matter by chemical oxidation is -----
(a) Biological oxygen demand (b) Chemical oxygen demand
(c) Dissolved oxygen (d) Total organic carbon

92. Two molecular components are not bonded to each other by any valance forces but are interlinked are
called:
(a) Catenane (b) Cryptand (c) Calixarenes (d) Cyclodextrin

93. Given below are two statements:

Statement I: Crown ethers are two dimensional while Cryptands are three dimensional.
Statement II: [2, 2, 2] Cryptand binds with K+ ion more strongly than [18] crown-6 crown ether due to
its 3 dimensional structure.
Choose the correct answer from the following options:
(a) Both statement I and statement II are true (b) Both statement I and statement II are false
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(c) Statement I is true and statement II is false (d) Statement I is false and statement II is true

94. For a green synthesis strategy choose the one which is not applicable
(a) Atom economy (b) Lower energy management
(c) Uses of benign solvent (d) Use of halogenated solvent

95. Carbon Nano Tubes are ------ times stronger than steel.
(a) 10 (b) 20 (c) 100 (d) 50

96. The majority structures are CNT is:

(a) Chiral and Zigzag (b) Chiral, Zigzag and SWCNT
(c) Chiral and arm chair (d) Chiral, Zigzag and arm chair

97. The technique that is used to determine the binding affinity of drug and enthalpy change is:
(a) Surface Plasmon resonance (b) Scintillation Proximity Assay
(c) Isothermal titration colorimetry (d) Scanning electron microscopy

98. Which one of the following drug is used in the treatment of Lymphocytic Leukemia?
(a) Chlorambucil (b) Atenol (c) Sorbitrate (d) Chloral

99. In Particle beam lithography, the resolution depends on

(a) Mass and velocity of nano particles (b) and velocity of nano particles
(c) Mass and (d) and

100. The phase not involved in drug action is:

(a) Pharmaceutical phase (b) Pharmacokinetic phase
(c) Pharmacodynamics phase (d) Pharmacological phase

TN SET 2025 Answer Key

1 a 16 d 31 c 46 c 61 a 76 a 91 b
2 a 17 a 32 c 47 d 62 a 77 a 92 a
3 c 18 b 33 d 48 a 63 a 78 c 93 a
4 a 19 c 34 d 49 c 64 b 79 a 94 d
5 a 20 b 35 d 50 c 65 c 80 d 95 c
6 a 21 b 36 c 51 d 66 a 81 d 96 d
7 a 22 d 37 b 52 a 67 a 82 a 97 c
8 c 23 c 38 d 53 c 68 c 83 a 98 a
9 a 24 d 39 c 54 d 69 b 84 c 99 a
10 a 25 b 40 b 55 d 70 c 85 c 100 d
11 b 26 a 41 b 56 d 71 b 86 a
12 a 27 b 42 d 57 a 72 c 87 b
13 ad 28 b 43 a 58 a 73 b 88 b
14 b 29 c 44 a 59 c 74 a 89 d
15 b 30 a 45 c 60 d 75 b 90 a

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