@ An eleckon %q ce fhe ‘finitely deep cubical polentiat. Well of width 4h. Wht ‘ip Ue ground mate: ema and — finat excitation enwngy 2 Po We have the seletion ) ‘in on En= ht cn= 4,2) Sma> 2 The leapt enorgy of the ticle cm be obtained by putting nei The On a ee by he En = b> ma? Gives 5 m= Ott x to? ky a eI = 1m and hz 663 x10. 3-S Bi? = (6:63 x to" SY)” s BX 9M x lon“ BR (Ion) Ee HEC 10 2"* Hoxie : 8 xIL K Io", (on 2?" Ee = 5) Fm (oo aad S : 18, Gg eo ge ae ey 1602 x 10°!9 gas 2: Fos Firat exclation en Eg= 4E, = 4436.6 = 149, oe pascticle tm ome dimendional box 2 ig Deksimine the expectation valye of fooition dioCC 8 iste Ane € 5 a ee Gen function. oF a. posticle "in LD box hy 2 pr ; Yo (2) = fH stn (2 x 4 * Expectation value fa fepition of a particle WS dibmad) a3 ¢- ce A> = CP Ode Hy Od Zee> - 2) 9 @) Sesin® (M2) 2c ove aie = 2s. Loe eich A a Expectation value ef petition ef a posrtide te 4D-m fy Ox. A proton oe a nwwoton in a number can wougnly be Segoxaed as a particle ima ber , the surface cf the nucleua plays the wie of the wall of the box and pravtons mover move ov leph “eely belween there wall > what in the ener velea Sed | whm % pevten maker 4 dsangition m the Finat excited ptate to the ground pale of a box of nuclear size Le, tox lem 7 Any (ives a= 1x (om it and m= mp = 16% x Io ky The energy. af gre and piate wh given bye En = nee h® 2mpar a: dla freith* 2iley Tx (05 x ee) imate aq loadaaeaun. Sibyl oiaay 2 Sed | Ue aeons)F894 inty En COU MTEEE Barth: Sd Bale will be ie Fie ot anh, Teh "i i ee Seti PON OTe 13-2 x16! > f.-€, T1312 % eee gaa ea ®.-E, = 3.9 Rte!8. Tyee 9. g.5 (18 Cav ES ey 16 x07 Ost An cigon (unclear an beter 4 i, pa gfe a Find Corresponding tigen lalue 2 EA = Oliver > ewe Let Serato, Ax a2 lace As a = efx oar? S BG ah ia efx) da ( aH Ay. = id) ax (Pe >) Ay . Biieibie Since S PE x Ay. Bie Sigg) he v Fer Obert Aik ope Os The ware, function ofa postticle to) ths a = Bale mn one dimensional box of length Late given by» [E sim ( (BE Ja . Gleutale tpt ; cf Finding the porrticle with in an hes e at th wntre ef box ef length L= 10ako ne shed 9 Guds Ans: Accading. to quention » Vt 1B sequived that we have fold bec to Glaulate the probability: of Finding the poorttele gerrg t udthin the infowwat of Rot the Gntre of bom eF ase ey ty van frm oust te ssl . me (Here Ab a ey th et Bee ST oe oe ny chove sound ptale i You Natt 2 "tie 4 ps dy dectangulen Probability » P= \vool a sin rast se ince , Ware function fora panticle ‘im 15 gourd eiacin ir a. Yeo = Jz Sin (BBja tals Foo quand pate (n> 4) € p. . } CUE se (Bpae] te EU Ouse earns eae i ( sin’ (Ex dau Eg G6 oS t fi thes eae oss ' Bt (rw )x) ae ons L (oste 4 eas Be, ee ieee eos ene i [8 ouce [5*CE)], au | $ oo Ae yb > 20) o. . ic [ene s sin { 22) oekees sin (2t Jowse ] c Pez (v-t Sm (22 Jo.s5L Ss in (28 ous P= 0198 w 196% Find the porba bility thet @ posrtice tm a bow L wide can be’ found belween azo! are n> bi jonun THEN ty the niMiaptolle 2 4 | Wave -fanction for 4" posrticle ay one dimumpim bor Pos os width OL! 1B given by = \ : O- \gBran ane 2 elit A ie sin (nn) x ee (ven Limit 2¢, <0 doi Bory : Vee, : i a f Fes bor Probability Bet (Hy aay laa a Po GML I sim (nm) a | ae : r i Sin® (NE) ae. 42 i (I- ee 2(AE )ac) dae “In “ Pe _ e- S 5H 2 t Linn (208)+], teem “te fa sing a al ye moving wn o SD Prove thet the eigen functions of a porte "one dimempional bex axe onthegonal @ 1 Eigen unction fF 9 particle an 1D bex | = in (RE Vac Yad) J sin ( fy above eign functions i SPEEA AAHHSEGOGSESSSECSSSS | P of Complex Conjugate wn w= Fe se (38% ! Fos ‘inten ™ Yn por JB sin( | Foro orthogonal Condition 5 Hp BD Yin 09 d=? a Hone » ¢ ¥ Wn (x) dn = (4) Se eee ‘a [cos [(n-m) x x[o}- 8 [¢ntm) rata} dn yrrijean |Se ee, hey y A ’ n(%) and Yn (a Wu Orthogonal te each other — a long chain, Molecule of length SA elect Tae 08 fre to move along he lng th “Guin ne pate: energy , the ener O% belween thy ® energy “stats af thy elechon and alpo Wave | 5 : thin pent aaa Time arising oom ize 20° pio energy ey= ht 2mat E,= (3:14) x (10°34)? pa eS eae 2X 91x fon 3x 25 elo e Zhe. lop es tea ev The fisst two ensgy. Blls WU4 giv by ned) n= Eeeatahe ie) eee amar 2mqr Energy pep between Fiant tur enwrgy Bt Td Ey Ey = Sth? 2ma> E,-E,= 3x 21-9 x10" Toule = 5:1 K 1072? Tole fo-E,= 3x 136 = 4-06 Wavelength cf absorption line Gn be given a hee 627k a he Apa ene Bx E We penton ante 65" K [on 7° a= 3.04% o> ™ 0 Sones os Pe 4 e Th siz one aN inpide Zoo (he The The fw G ne alii eT EEwe? A past = Hele ° e ea acres moving “in one: dimennional pstewtiod «be Ymbatil a mM) oF width 25K Calautale Ae " A Finding tha poseficle within am intexvad SA ot the contesr gf the bok Whin HK MH VAS Bhale of leant energy ? Ue wae Famction cP a particle enclosed with an mAimite potemtiol welt in given bY YOs) = Se sin (Rye Whim the particle “ie tn te least ensrgy Otte hone mM hin Gur - wed = f2'sin BE @ AY the connor of thay bo 365 9lz) aes Re of Finding ha forcticle fn tha anit alow ot the Compan of bo ® nits que b | Bal? =) [yz freee) 2 spi = 2 a ear aa Sl poo the probebility in athe growed Bx % guien by = | ¥@)) ax 2 be tivim: = 268 = 25¥ 100M, ard: Adem SA = sxioPm es oso ae adi asx (ole Ov. Delermine the expectation Value of the momentum of 6 particle reaped m4 one - dimensional box 2 Ant Exhectation volua of momurcm of porrtide iT SP? = ( (i) fac YG) de The = nowmalized wave function af « poxticle Aaappead in. one -cimempional box tb given by Yr (2% = {2 Sin (ae jx Typ detivetive with pet to xe E,s ilAnd complex ony Does) Mgtte of 4k valid’ “Function ip “JB Sin (OE )a = Y, (0) But Pac = “thd = -menumtom, opetetor 2 ates =f aed (-NL) Pe (aan afar - (9 "> OU( AE sin (gh Ja) CDE (Lf sas] | > ZPn> = _; n bot) zs) {sin (22) s'(nt) nda 2 fa > = -ih Co sin (282 Jan-da éfar> =e Thus , the expectation value of momuntym of pascticle tapped mM one—dimen gional bex in 2¢30 QU Show that Yoo = 2% where cis some finde Gnatent ip acceptable eigen function: Nowmalize 4 ever Fhe segion = 078 NE a! The (riven wave function 16 Head = el! ~ cos cat i sin Cr Tt p deivation 16 given by eS APS. je a mesin rt, eran dx 1) Sma Sm Ca amd OS ca aE, periodic Functiona with maximum value 4 and cin a Finite Constant, Ye) ant Are on Finite for al) values of a - vi) The function 0) Ona eat! axe Single Values a D becouse. (0S CH Gnd sinc ae Smgle Valued constant Foy all valuss of O°Yeny an ee dod all Va ae HO ave alte conatanis For fier ¥O9 ip an acceptable -fasm of thee} 2 » for nowmalization, we write a 2 W (a = NM glee = Buel deterring Ns such thet 3 PO Woe =| Ng ~icae e 9 & |-dn=} “a os +4 ee eel ee aa N® (2a) =4 Nee el Sia Hone , the nosmalized wave function ip Pe) = 21, elex ae & 20 Qv. A particle ip in Gubie ben of length Lin VS gpouna Btate- Find the pebability thet 2 particle will be found ‘mn 4 volume defined by ofeck , ogyig hij mo ezek 2 ae - Ais The wave function for a fasticle im cubic ber oP length ip given’ by - = (7) = CB) sin (HT Jae sin (MEY sin (MEE ET For guound Blade y= ny= Naat cuilie ly yoo?) = (2) sin (Za sin(E) 4. Sin(B)* x ma teoF Final ie gen vf SSS ¥ CO padl® dodge Here; -the pobapit Wp thawed rhe fastele yn a dette W of 9 porrticle that will be found defined by ; Case Se o€y ob and oc ze Lk wp sven dy | = Po pe ee ay ; = PLAT] C2)" sn je. sin so()e[otoan ds as Pe (2)* (shes [2-cs(anyar}. Afi cos(28) y]-4 [1 o@E)2], Sy i tii. a eda P=(4)° fa- sin (2m yal) [ik sin (Qe) a], [2b snare) aE as oe : P= 1 2 Olas € Foe nay Qs A Free poorticle if tenfined tr a Cubicok box af side o- 7 wie te eigen value and eigen functions fos an | Onuygy Bhake se presented by Nat nyt he What ip the ovder of degenesacy “in this tox 9 Ang The energy. levds ofa posrticle im Abree ~dimenpional Bye ‘ por of sides % band c ip given by ug 22h Rn nea Eqninyine = ZR [nf antares | and tu wave function For that peaciclag 4 i ( Ret\ ov sin (ee ye eon nT \ 2. Ur ees gin (DE) 0 in ( Fi ) ( z- ) For a Cubical box a=b=C fh Emm snynn 2h (ng tet ne ) » ama> m eely bs Yroinyne = [ f2] sn (nam sin (ABE) 12S (oat Jz Pe we Ratm tna =4, there ave three Bets of AR? sole Ce OB C2511 5 Cary) and Cty 2) o Thug’ the Fegwene wey vs the fold becouse there ave dhtee eigen functions Cantespondng to energy. 02: E= 1 Gatay) = wk gary = eke ch ae sees -E casey = a (4tttO= 6Th re) Zmar Ge “Tr above quastion » what Shall happen te degeneracies fox ny tng tne =4 Vf dhe box ip Net (ubioL bat ectangulay pavallel opie? with pidea Oy band Such Ape thet a=bec? D OF 4 SOS When a=b¢c, the energieh cosrenpending. te three Matte C2atst) 9 C2. and (13 bhalt Steppectively be 2 > 45.0 cal PahY weve aye eens oh (rb) Se (84) e 2M ar E(u) = Oh (4. 4 dee Veo hea & 4h an Wonke aa Cogs ye Se ace * eons Tek +4). eh cons BE(arg RE a) 1 : “Thug, the enengy a (4 +i)i6 doubly dagenem de Cossesponding te eigen functions Yay ond Yar whereas enegy 1h (2 atin non ~ degenesate 2r a> £ ©. Show that the dle~ Broglie wwanelength appodated with ZA an electron & energy V election Nols \é abpreexim ortel 4, : 12.24 Y=}. mm Wehave 4° See W Ags We have TES Subptituting the values & bo m and @ one obtain ie Gon [ee pied Janis Vion 91 4 18 Rb xoHes\ oso hn eae eat Lg (2.29 Ny WW As. Tame tert the uncerteinty. tn position ef « hyatmgen ree MARK abot 2% oT ky ib of tee order Nee % ae in RemeEnStint> about 6m. Determine Ae uncertdialy A The uncertainty “i momentum ib given by Dfy & b. > Los nto yy Neos x (ort kg misec 17? On The average period that elapee belween the excitation Pian atom and He time it emiks Sadiation ib 158 Second, Find the Uncesfainty Tn the energy emia and fhe, uncestainly ta tre Foequenyy of AGMT emitied. hive gh= Losy alo 2 Js awinh= 66axts “Ise ANS: The uncestainty Tr the enesigy ih given by 2 posyxls 8) ia uncertsinty In’ the Feequemuy of light emitted 1h Given dy Re 3 a pve) BES a 1 OSH eit 82 (59 x10 ate h 6.63 xo" enuigy. ef an election contined . Find lourpt ‘ (u18 Find the [ot ead irene Ce Cae ero MONS ashe ength 1A ‘ one e yee 2 et Bie. dares 2ma> eh aves Foe, 6 = qx (\-054 x1? by jd 2x OL 4 oo 2! x Cle eelES of the Thaleus ‘te [cm Teealing 4 on 4 } Weve eee box haw why election does ‘Net exinte nuclens 2 Arg. Zero port emoigy & = noe ama? = S44 x (one (n= 4.054 x 40°34 55 m= 9d xfo3 kg) a= jo" m) The culombic attraction energy on the ether hand yh Me e298 ee The = coulombic adiraction energy ip doo weals for fe Ruclenp to hold an election . Qx. Caleulafe the length of a ons dimensional box Fas ushich the difference belween tr lout emengy levels cha molecule beomes comparable to ils erode Kinetic Onengy at a given temperature 2 Aye Ena En =Cnt) OR eg amqr where Kg ib Boltzmanrta Constennt ae [ canto on | m ke/T On Fosa pogticle in the atefey nad)? amd 3 of an one yr alimenpionag box ef length L, find the parbability that the pasttice 6 mw the Ryn ORK bot Phe Bie 2ma> Ut 4 five: mh = deh ATO RE Pi Geo. JO ah OSH wo Weed su xo 1s 2Ey = 2. x 1p 2! ‘ = 3:28 x yet! ev 1.6 X jol9 : RC aU 4 y 2%. Mibat ode the permittee Valuaun of of an i rained in ona dimensional box width am -3 : 2 (Re=to™ 5,5) D> The permitted value of encsigy. of an © in one dimensional box NS En= tre 2ma? biven = 4 - 1.054 x1o34 ‘ ag ses eee eee ay TAM = Ty 8 eae En=n* (rosy x) x (a14)2 2X94 «103! x (1018)? = Des (ccoleptona al o =16 = W 2018 X10 DPV) 16x jo = (Aen) brew E, = 3-464 keV , Er = IS 044 kev Ex = 33-849 key i ii ticle im @ bor Gan be 25 Find the probability, thet 9 pax : @ found bejween aa a Sf 0559 where a in the width ef the box, when the particle Is in the fixnt excited fiate 9Are Bs eS (0.28- ZF width a can be found The way, le ‘ Maje oe eo ef a particle im the finat excited SF one dimumsionat box ef width 9 ip alae oe sm 27% 9 Probability p= ri byl? mM ay +2 _ Pod ( sit one can Dy Q eS a {4 [4- os dne] dn % a fina ou 2 fe a sim ane) Now, N=-o.550 gg y= 04S F P= [Coss - 04s) - 4 Crean oe Tt = flow 16 singe! - 0:588 oT 6-28, = 0.0064 = 0-64 % ‘ dite ae Qu roant? | CRs of Fina the probebility. \ hom eee, oKea Hee awa Balad i Te. wave Function of a posrticle im the nt etade Te ake box ff width “a! 4K py, = V2 sin fi) se fsobe bili ty of @ paseticle that Con be neo BS m=4[n, Ih I fi 4 | Y\ ean Chien Fond baw 2 q sin 0n £ [1 ten (20m) 3a, sin (2589) le ° }-an fx Ose ete i ae ae fF choim moleade of lergth SA Os fe Anes a8 Fre to move alone She length. Colasiate Speen, Ge crude > The eneigy gab bedween die So emedy ataks of the electors and algo ¢ ahsorption fine ariping. rom thin Transition 7 The emerge. of eleckonn in nth pale ip given by En= nh? ¥ Imaz The 2eve pont emuigy 16 gluen by. Ey = ch 2ma> Whete , h = 4.054 rlon tt Jag > me 9.4 x (07! kg 5 9= Sh = Sx pom E, = (314)? x (1054 x10 8%)” DiGi eters kot DB = 24x10"? = 2M x [o 16 xJor!® = dip S dev. Enurgy cf electron m the Second ptate Ey = 46, = WKS sees, 5eo DOO: Oop ae [ee 6-45 4. Soey The Cow brgth ef absorbtion d “on line he DE — ~~ = 6.62 x10 4, pales Ee WSK IG wed ” Mai bsaitor tei > = 2360 J > 3 * » O28 A powticle of mags m= lo *? kg ip Confined to move Bee vm a bor F length of where erdy ame at 4 D=0 and nerh.. whet is the Prebobilidy ef find the particle betwen 4.6000 A ond d-sool A fw ny and n=2 2 > = r60et _ Ans. oe Sin 20M dy , : ! y arg00d a * & [x-fa( sh 20nts) § [ann | A.600e Fos n=4 . 4 Pa (fc eee Gag SGA oo ng) fe 27 j P= 3.45 x10 ° ‘ Foy n=, one obtain P= 905 X10 ' lero confined R lowert ener of an el O2 @ Clulate the ar eae pee ih — Simi loxly i Ww oa bial 4 id Oe dita opible enws gies 3 ste eS eee oer ges by | : eq art cot ange ee oeay ‘ : beeFox the lotvent oe Wencane Tey ee 2 eS STeh= 10)? aa oe Er x (16") 2K IU xI67 x Corte) * 5 SECS Ca eae 2x QUI ry = 1803x108 5 ~ 108 ey Z ® Fina te keoperaluste gt which the awerage envy Che thee clecutl fs perfect gap would be 7 equal ty the — lowent envigy of the electron 7 Ke = 4:38 x 10°23 3lk 2 | eee he gequived tempewrture , tun | ae Keil, = SDS 416 og eye 2ma™ Te 2 Veesix One es anos hae * ae? Note=- The above model in ne aceptable for H atom = B the experimental value of grand Brae emwigy, Eine - 186 ae