Test
SOLUTION
Class 12 - Chemistry
Time Allowed: 30 minutes Maximum Marks: 20
1. Which of the following formula represents Raoult's law for a solution containing non-volatile solute? [1]
a) psolute = p
0
solute
⋅x
solute b) p = KH ⋅ x
c) psolute = p
∘
⋅x
solvent d) PTotal = Psolvent
solvent
2. The colligative property used for the determination of molar mass of polymers and proteins is: [1]
a) Elevation is boiling point b) Depression in freezing point
c) Osmotic pressure d) Relative lowering in vapour pressure
3. Which among the following shows a negative deviation from Raoult's law? [1]
a) Acetone and chloroform b) Acetone and benzene
c) Methyl alcohol and water d) Carbon tetrachloride and chloroform
4. A compound CaCl2⋅ 6H2O undergoes complete dissociation in water. The Van't Hoff factor i is: [1]
a) 6 b) 3
c) 4 d) 9
5. The depression in freezing point for 1M urea, 1 M glucose and 1 M NaCl are in the ratio of [1]
a) [Link] b) [Link]
c) [Link] d) [Link]
6. For dissolution of gases in liquids, the concentration of a gas in a liquid is: [1]
a) proportional to the vapour pressure of the b) lower to the pressure of the gas as compared
gas to the liquid
c) proportional to the pressure of the gas over d) equal to the pressure of the gas in relation to
the liquid the liquid
7. A solution showing a large positive deviation from ideal behaviour has [1]
a) ΔHmix is positive b) Lower boiling point than both the
components and ΔHmix is negative
c) Higher boiling point than both the d) ΔHmix is Negative
components
8. Solubility of gas in liquid decreases with increase in [1]
a) Pressure b) Number of solute molecules
c) Volume d) Temperature
9. Colligative properties depend on ________. [1]
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a) the nature of the solute particles dissolved in b) the nature of solvent particles.
solution.
c) the number of solute particles in solution. d) the physical properties of the solute
particles dissolved in solution.
10. A compound undergoes complete dimerization in a given organic solvent. The Van't Hoff factor i is : [1]
a) 1.0 b) 2.0
c) 0.5 d) 0.25
11. Which has highest freezing point at 1 atm? [1]
a) 0.1 molal sugar solution b) 0.1 molal BaCl2 solution
c) 0.1 molal NaCl solution d) 0.1 molal FeCl3 solution
12. An azeotropic solution of two liquids has boiling point higher than either of them when it: [1]
a) is saturated b) shows no deviation from Raoult's law
c) shows negative deviation from Raoult's law d) shows positive deviation from Raoult's law
13. For an electrolyte undergoing association in a solvent, the van't Hoff factor: [1]
a) is always greater than one b) has zero value
c) is always less than one d) has negative value
14. Liquid ammonia bottle is first cooled before opening because [1]
a) Vapour pressure increases on cooling b) Vapour pressure Same on cooling
c) Vapour pressure decreases on cooling d) Vapour pressure of liquid ammonia is very
low at room temperature
15. Which of the following units is useful in relating the concentration of a solution with its vapour pressure? [1]
a) mole fraction b) parts per million
c) mass percentage d) molality
16. Value of Henry’s law constant KH ________. [1]
a) increases with increase in temperature. b) decreases with increase in temperature.
c) first increases then decreases. d) remains constant.
17. A 500 g of tooth paste has 0.2 g of fluoride concentration. Fluorine concentration in terms of ppm is [1]
a) 250 b) 200
c) 1000 d) 400
18. The increase in the temperature of the aqueous solution will result in its: [1]
a) Molarity to decrease b) Mass % to increase
c) Molarity to increase d) Mole fraction to increase
19. A compound undergoes complete dimerization in a given organic solvent. The Van't Hoff factor i is: [1]
a) 0.5 b) 5
c) 1 d) 2
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20. Which will form maximum boiling azeotrope? [1]
a) C2H5OH + H2O b) H3NO2 + H2O
c) HNO3 + H2O d) C6H6 + C6H5CH3
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