Test ID : 927

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.UNIT TEST - 7.
Std : TEST SERIES Max. Marks: 180
Test Date : 17.09.2024 CHEMISTRY Time : 1 Hr.
Note :
For every correct answer four marks will be awarded. For every wrong answer one mark
will be reduced. For unanswered questions zero mark.
Choose the correct answer : 45 x 4 = 180
1. During isothermal expansion of an ideal gas,
its
1) internal energy increases

>
>
2) enthalpy decreases
3) enthalpy remains unaffected
4) enthalpy reduces to zero
1) -PV 2) -2PV
2. Which one of the following is correct option
for free expansion of an ideal gas under 3) -1/2PV 4) Zero
adiabatic condition? 6. Enthalpy change for the reaction
4H(g) → 2H2(g) is –869.6 kJ
1) q ≠ 0, ∆T = 0, W = 0
The dissociation energy of H-H bond is
2) q = 0, ∆T = 0, W = 0
1) –869.6 kJ 2) +434.8 kJ
3) q = 0, ∆T < 0, W ≠ 0
3) +217.4 kJ 4) –434.8 kJ
4) q = 0, ∆T ≠ 0, W = 0
7. Bond dissociation enthalpy of H2, Cl2 and HCl
3. An ideal gas expands isothermally from 10–3 are 434, 242 and 431 kJ mol–1 respectively.
m3 to 10–2 m3 at 300K against a constant Enthalpy of formation of HCl is
pressure of 105 Nm–2. The work done on the 1) 93 kJ mol–1 2) –245 kJ mol–1
gas is 3) –93 kJ mol–1 4) 245 kJ mol–1
1) +270 kJ 2) –900 J 8. Given that
3) +900 kJ 4) –900 kJ C(s) + O2(g) → CO2(g) ; ∆H0 = –X kJ
4. Which of the following are not state 2CO(g) + O2(g) → 2CO2(g) ; ∆H0 = -Y kJ
functions? The enthalpy of formation of carbon
I) q + w II) q monoxide will be
III) W IV) H - TS 1) Y – 2X 2) 2X - Y
1) I and IV Y − 2X 2X − Y
3) 4)
2) II, III and IV 2 2
3) I, II and III 9. The correct thermodynamic conditions for the
4) II and III spontaneous reaction at all temperatures is
5. An ideal monoatomic gas is taken round the 1) ∆H > 0 and ∆S < 0
cycle ABCDA as shown in figure. The work 2) ∆H < 0 and ∆S > 0
done during the cycle is 3) ∆H < 0 and ∆S < 0
4) ∆H > 0 and ∆S ≠ 0
 2 Test ID : 927
10. Reversible expansion of an ideal gas under 1) A and C 2) A, B and D
isothermal and adiabatic conditions are as 3) A, C and D 4) C and D
shown in the figure 13. The work done during reversible isothermal
expansion of one mole of hydrogen gas at
25°C from pressure of 20 atmosphere to 10
atmosphere is (Given R = 2.0 cal K–1 mol–1)
1) 0 calorie
2) –413.14 calories
3) 413.14 calories
4) 100 calories
Which of the following option is not correct? 14. For the following reaction at 300K
1) ∆Sisothermal > ∆Sadiabatic A2(g) + 3B2(g) → 2AB3(g)
2) TA = TB The enthalpy change is +15 kJ, then the
3) Wisothermal > Wadiabatic internal change is
4) TC > TA 1) 19988.4 J 2) 200 J
11. Match column I with column II and choose the 3) 1999 J 4) 1.9988 kJ
correct answer. 15. For an endothermic reaction
Column I Column II A) qp is negative
B) ∆rH is positive
(Process) (Conditions)
C) ∆rH is negative
Isothermal No heat
A I D) qp is positive
process exchange
Choose the correct answer from the options
Carried out at given below.
B Isochoric process II
constant T 1) B and D 2) C and D
Carried out at 3) A and B 4) A and C
C Isobaric process III
constant V 16. Choose the correct statement for the
Carried out at workdone in the expansion and heat absorbed
D Adiabatic process IV or released when 5 litres of an ideal gas at 10
constant P
atmospheric pressure isothermally expands
A B C D
into vacuum until volume is 15 litres.
1) IV III II I
1) Both the heat and work done will be greater
2) IV II III I
than zero
3) I II III IV 2) Heat absorbed will be less than zero and
4) II III IV I work done will be positive
12. In which of the following processes entropy 3) Work done will be zero and heat will also be
increases? zero
A) A liquid evaporates to vapour 4) Work done will be greater than zero and
B) Temperature of a crystalline solid lowered heat will remain zero
from 130K to 0K 17. Enthalpy of neutralization of HCl by NaOH is
C) 2NaHCO3(s) → Na2CO3(s) + CO2(g) + H2O(g) –55.84 kJ/mol and by NH4OH is –51.34
D) Cl2(g) → 2Cl(g) kJ/mol, the enthalpy of ionization of NH4OH
Choose the correct answer from the options 1) 107.18 kJ/mol 2) 4.5 kJ/mol
given below. 3) –4.5 kJ/mol 4) –4.5 J/mol
 3 Test ID : 927
18. If enthalpies of formation of C2H4(g), CO2(g) 24. A chemical reaction will be spontaneous if it
and H2O(l) at 25°C and 1 atm pressure are 52, is accompanied by a decrease in
–394 and –286 kJ/mole the enthalpy of 1) Entropy of the system
combustion of ethane is equal to 2) Enthalpy of the system
1) –141.2 kJ/mol 2) –1412 kJ/mol 3) Internal energy of the system
3) +14.2 kJ/mol 4) +1412 kJ/mol 4) Free energy of the system
19. For the reaction ; X2O4(l) → 2XO2(g) 25. Given the following entropy values (in JK–1
∆U = 2.1 k.cal. ∆S = 20 cal. K–1 at 300 K mol–1) at 298K and 1 atm : H2(g) : 130.6,Cl2(g) :
Hence ∆G is 223.0, HCl(g) : 186.7. The entropy change (in
1) 2.7 k.cal 2) –2.7 k.cal JK–1 mol–1) for the reaction.
3) 9.3 k.cal 4) –9.3 k.cal H2(g) + Cl2(g) → 2HCl(g), is

20. The enthalpy of fusion of water is 1.435 1) +540.3 2) +727.0

Kcal/mol. The molar entropy change for the 3) –166.9 4) +19.8
melting of ice at 0°C is 26. Read the following statements regarding
1) 10.52 cal/mol K spontaneity of a process and make the
2) 21.04 cal/mol K appropriate choice.
3) 5.260 cal/mol K i) When enthalpy factor is absent then
4) 0.526 cal/mol K randomness factor decides spontaneity of a
21. Identify the correct statement for change of process
Gibbs free energy for a system (∆Gsys) at ii) When randomness factor is absent then
constant temperature and pressure. enthalpy factor decides spontaneity of a
process
1) If ∆Gsystem > 0, the process is spontaneous
iii) When both the factors take place
2) If ∆Gsystem = 0, the system has attained
simultaneously, the magnitude of both of
equilibrium
factors decide spontaneity of a process
3) If ∆Gsystem = 0, the system is still moving in a
1) Statements (i) and (ii) are correct and (ii) is
particular direction
incorrect
4) If ∆Gsystem < 0, the process is not 2) Statement (iii) is correct, (i) and (ii) are
spontaneous incorrect
22. The values of ∆H and ∆S for the reaction, 3) Statements (i), (ii) and (iii) are correct
Cgraphite + CO2(g) → 2CO(g) are 4) Statements (i), (ii) and (iii) are incorrect
170 kJ and 170 JK–1 respectively. This 27. Which of the following processes is a non-
reaction will be spontaneous at spontaneous process?
1) 710 K 2) 910 K 1) Dissolution of sugar or salt in water
3) 1110 K 4) 510 K 2) Mixing of different gases through diffusion
23. A reaction occurs spontaneously if 3) Precipitation of copper when zinc rod is
1) T∆S < ∆H and both ∆H and ∆S are +ve dipped in aqueous solution of copper
2) T∆S > ∆H and both ∆H and ∆S are +ve sulphate
3) T∆S = ∆H and both ∆H and ∆S are +Ve 4) Flow of heat from a cold body to hot body
4) T∆S > ∆H and ∆H is +ve and ∆S is -ve in contact
 4 Test ID : 927
28. Assertion (A) : Heat of neutralization of 32. If W1, W2, W3 and W4 for an ideal gas are
HNO3 and NaOH is same as that of HCl and magnitude of work done in adiabatic,
KOH. isothermal, isobaric and isochoric reversible
Reason (R) : Both HNO3 and HCl are strong expansion processes, the correct order will be
acids and NaOH and KOH are strong base.
1) Both (A) and (R) are true and (R) is the >
correct explanation of (A)

>
2) Both (A) and (R) are true but (R) is not the
correct explanation of (A)
3) (A) is true but (R) is false 1) W1 > W2 > W3 > W4
4) Both (A) and (R) are false 2) W3 > W2 > W1 > W4
29. Assertion (A) : An exothermic process which 3) W3 > W2 > W4 > W1
is non-spontaneous at high temperature may 4) W3 > W1 > W2 > W4
become spontaneous at low temperature. 33. Select the incorrect statement.
Reason (R) : Spontaneous process is an 1) An adiabatic system cannot exchange
irreversible process and may be reversed by energy with its surroundings
some external agency. 2) A thermodynamic property which is
1) Both (A) and (R) are true and (R) is the intensive is additive
correct explanation of (A) 3) Work done is zero in an isochoric process
2) Both (A) and (R) are true but (R) is not the 4) A thermodynamic property which is
correct explanation of (A) extensive is additive
3) (A) is true but (R) is false 34. Assertion (A) : When Cu(II) and sulphide
4) Both (A) and (R) are false ions are mixed, they react together extremely
30. 1 mole of a monoatomic ideal gas is expanded quickly to give a solid.
from state – I to state – II at 300K. Reason (R) : The equilibrium constant of
Cu2+(aq) + S2–(aq) ⇌ CuS(s) is high because the
solubility product is low.
1) (A) is false and (R) is true
2) Both (A) and (R) are false
3) Both (A) and (R) are true but (R) is not the
Work done is correct explanation for (A)
1) –1729 J 2) +1729 J 4) Both (A) and (R) are true but (R) is the
3) –758 J 4) 17.07 J correct explanation for (A)
31. The heats of neutralization of four acids A, B, 35. 1 mole of KMnO4 can oxidise completely ‘x’
C and D are –13.7, –9.4, –11.2 and –12.4 moles of FeSO4 in acid medium then ‘x’ is
k.cal/g equiv. respectively, when they are
1) 2 2) 3
neutralized by a common base. The acidic
3) 4 4) 5
character obeys the order
36. The ratio of number of water molecules in
1) A > B > C > D
potash alum and Mohr’s salt is
2) A > D > C > B
1) 5 2) 3
3) D > C > B > A
3) 4 4) 1
4) D > B > C > A
 5 Test ID : 927
37. Volume of 0.1M NaOH needed for the 41. In titration of KMnO4, dil. HCl can’t be used
neutralization of 20 mL of 0.05M oxalic acid in place of dil. H2SO4 because
is 1) KMnO4 reacts with HCl to produce Cl2 gas
1) 20 mL 2) 10 mL 2) Reaction with HCl some KMnO4 is used
3) 5 mL 4) 15 mL 3) Require excess KMnO4 than require
necessary
38. Assertion (A) : 1 mole of FeC2O4 is oxidized
4) HCl does not react with KMnO4
by 0.6 mole of MnO4– in acidic medium.
42. When KMnO4 solution is added to oxalic acid
Reason (R) : MnO4– oxidises both Fe2+ as
solution, initially its colour slowly disappear
well as C2O42–.
but after sometime it disappear quickly;
1) (A) is false and (R) is true because
2) Both (A) and (R) are false 1) Mn2+ acts as self catalyst
3) Both (A) and (R) are true but (R) is not the 2) Reaction is exothermic
correct explanation for (A) 3) MnO4– catalyse the reaction
4) CO2 produced as a product
4) Both (A) and (R) are true but (R) is the
correct explanation for (A) 43. Ratio of moles of Fe(II) oxidized by equal
volumes of equimolar KMnO4 and K2Cr2O7
39. Given below are two statements.
solutions in acidic medium will be
Statement I : In permanganometric titrations
1) 5 : 3 2) 1 : 1
KMnO4 acts as self indicator. 3) 1 : 2 4) 5 : 6
Statement II : In dichrometric titrations 44. P-V plot for two gases (assuming ideal) during
K2Cr2O7 cannot act as self indicator. adiabatic processes are given in the figure.
1) Both statement I and II are correct Plot A and plot B should correspond
2) Both statement I and II are incorrect respectively
3) Statement I is correct but statement II is
incorrect P A
4) Statement I is incorrect but statement II is B
correct V

40. Only 2 mL of KMnO4 solution of unknown 1) He and H2 2) H2 and He

molarity is required to reach the end point of a 3) He and Ne 4) H2 and Cl2
titration of 20mL of oxalic acid (2M) in acidic 45. If ∆Hf° (C2H4) and ∆Hf° (C2H6) are X1 and X2
medium. The molarity of KMnO4 solution k.cal mol–1, then heat of hydrogenation of
should be C2H4 is
1) X1 + X2 2) X1 – X2
1) 4M 2) 3M
3) X2 – X1 4) X1 + 2X2
3) 2M 4) 8M

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