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Paper / Subject Code: 40325 / Chemical Engineering Thermodynamics II

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1T00534 - S.E.(Chemical Engineering)(SEM-IV)(Choice Base Credit Grading System ) (R- 20-21) (C Scheme) / 40325 -

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Chemical Engineering Thermodynamics II QP CODE: 10012893 DATE: 19/12/2022

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Time: 3 Hours Max Marks: 80

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N.B. (1) Question No 1 is compulsory

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(2) Attempt any three questions out of remaining five questions

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(3) Assumption made, if any should be clearly stated

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(4) Figures to the right indicate full marks.

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Q1 Solve any Four out of Five 20

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a) Give the difference between ideal and non-ideal solution

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b) Explain Chemical Potential

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c) Define Activity and activity coefficients

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d) Explain Refrigerator capacity
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e) Explain Properties of refrigerant used in refrigeration system
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a) Derive Gibbs-Duhem equation. 10

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Define excess property and Property change of Mixing and show that the 10
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property change of mixing and excess properties are identical.

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a) Discuss in brief phase equilibria in single component system 10

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b) Explain in brief UNIQUAC equation and UNIFAC method 7 10

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a) The vapour pressures of aceton (1) and acetonitrile (2) can be evaluatedby the 10

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Antoine equations.
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2940.46 2945.47
ln𝑝1𝑠 = 14.5463 - 𝑇−35.93 ln𝑝2𝑠 =14.2724 - 𝑇−49.15
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where T is in K and P is in kPa. Assuming that the solution formed by these are
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ideal, calculate
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a) 𝑥1 and 𝑦1 at 327 K and 65 kPa

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b) T and 𝑦1 at 65 kPa and 𝑥1 = 0.4

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c) P and 𝑦1 at 327 K and 𝑥1 = 0.4

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b) What are azeotropes? With proper phase diagrams, distinguish between minimum 10
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and maximum boiling azeotropes

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a) Explain: 10
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i) Equilibrium conversion
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i) ii) Effect of Temperature on Equilibrium constant

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b) Discuss the phase rule for non-reacting and reacting systems .Determine the 10
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number of degrees of freedom in a gaseous system consisting of CO, CO2, H2, H2O
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and CH4 in chemical equilibrium.

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a) Define Refrigeration. Discuss Vapour absorption refrigeration cycle 10

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b) Explain in detail criteria of Chemical Reaction equilibrium 10

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