Material Safety Data Sheet

Version : 1.02 Date of issue : 4/3/2008.

Akzo Nobel Coatings Inc. encourages and expects you to read and understand this entire MSDS, as there is important information
throughout the document. Further, Akzo Nobel Coatings Inc. expects you to follow the precautions identified in this document unless
your use conditions would necessitate other appropriate methods or actions.

To promote safe handling, each customer or recipient should: 1) Notify its employees, agents, contractors, and others whom it knows
or believes will use this material of the information contained in this MSDS and any other information regarding hazards and safety; 2)
Furnish this same information to each of its customers for the product; 3) Request its customers to notify their employees, customers,
and other users of the product of this information; and 4) Notify its employees, agents, contractors, and others that the precautions
identified for this product and any other products with which mixtures may be created are transferable and cumulative to the mixture.

Section 1. Chemical product and company identification

Manufacturer Canadian Supplier
Akzo Nobel Coatings Inc. Akzo Nobel Coatings Ltd.
5555 Spalding Drive 110 Woodbine Downs Blvd.
Norcross, GA 30092 Unit #4 Etobicoke, Ontario
Canada M9W 5S6
USA 1-800-618-1010 1-800-618-1010
IN CASE OF EMERGENCY (HEALTH OR SPILLS):
CHEMTREC (800) 424-9300 (Inside the US)
CHEMTREC International (703) 527-3887 (Outside the US, collect calls accepted)
Product code : 384269
Product name : Autobase 333C Toner
MSDS # : 384269S01100004130EN10366
For the most recent update to this Material Safety Data Sheet, visit our website at http://www.akzonobelcarrefinishes.net
For additional information call our the Akzo Nobel Car Refinishes Techline at 1-800-618-1010.

Section 2. Hazardous ingredients

Name CAS # % by Vapor Exposure Limits (ACGIH-TLV/OSHA-PEL)
weight pressure
butyl acetate 123-86-4 25 - 35 1.3 kPa (10 ACGIH TLV (United States).
mm Hg) (at TWA: 150 ppm 8 hour/hours.
20°C) STEL: 200 ppm 15 minute/minutes.
OSHA PEL (United States).
TWA: 150 ppm 8 hour/hours.
methoxypropanol 107-98-2 10 - 25 1.2 kPa (8.7 ACGIH TLV (United States).
mm Hg) (at TWA: 100 ppm 8 hour/hours.
20°C) STEL: 150 ppm 15 minute/minutes.
xylene, mixed isomers 1330-20-7 5 - 10 0.7 kPa (5.1 ACGIH TLV (United States).
mm Hg) (at TWA: 100 ppm 8 hour/hours.
20°C) STEL: 150 ppm 15 minute/minutes.
OSHA PEL (United States).
TWA: 100 ppm 8 hour/hours.
aluminum 7429-90-5 5 - 10 Not available. Not available.
4-hydroxy-4-methyl-2-pentanone 123-42-2 5 - 10 0.1 kPa (0.8 ACGIH TLV (United States).
mm Hg) (at TWA: 50 ppm 8 hour/hours.
20°C) OSHA PEL (United States).
TWA: 50 ppm 8 hour/hours.
melamine-formaldehyde resin ......... 1-5 Not available. Not available.
isobutanol 78-83-1 1-5 1.2 kPa (9 mm ACGIH TLV (United States).
Hg) (at 20°C) TWA: 50 ppm 8 hour/hours.
OSHA PEL (United States).
TWA: 100 ppm 8 hour/hours.
ethyl benzene 100-41-4 1-5 0.9 kPa (7.1 ACGIH TLV (United States).
mm Hg) (at TWA: 100 ppm 8 hour/hours.
20°C) STEL: 125 ppm 15 minute/minutes.

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OSHA PEL (United States).
TWA: 100 ppm 8 hour/hours.
aliphatic hydrocarbon 64742-88-7 1-5 0.02 kPa (0.1 ACGIH TLV (United States).
mm Hg) (at TWA: 100 ppm 8 hour/hours.
20°C)
petroleum distillate (naphtha) 8030-30-6 1-5 Not available. ACGIH TLV (United States).
TWA: 400 ppm 8 hour/hours.
OSHA PEL (United States).
TWA: 100 ppm 8 hour/hours.
butanol 71-36-3 1-5 0.7 kPa (5.5 ACGIH TLV (United States).
mm Hg) (at TWA: 20 ppm 8 hour/hours.
20°C) OSHA PEL (United States).
TWA: 100 ppm 8 hour/hours.
styrene (as volatile) 100-42-5 0.1 - 1 0.6 kPa (4.5 ACGIH TLV (United States). Skin
mm Hg) (at TWA: 20 ppm 8 hour/hours.
20°C) STEL: 40 ppm 15 minute/minutes.
OSHA PEL (United States).
CEIL: 200 ppm
TWA: 100 ppm 8 hour/hours.

Section 3. Hazards identification

Emergency overview : Warning!
Potential acute health effects
Eyes : Irritating to eyes.
Other effects of eye contact may include : eye damage, redness, swelling, tearing,
Skin : Toxic in contact with skin. Severely irritating to the skin.
Other effects of skin contact may include: dehydration, dermatitis, discoloration,
Effects due to absorption through skin may include: blood effects, CNS effects, decreased blood
pressure, diarrhea, dizziness, drowsiness, fatigue, headache, incoordination, kidney damage, liver
damage, narcosis, nausea, vomiting, weakness,
Inhalation : Irritating to respiratory system.
Other effects of inhalation may include: anesthesia, blood effects, CNS effects, confusion, decreased
blood pressure, depression, diarrhea, dizziness, drowsiness, excitation, fatigue, headache,
incoordination, kidney damage, liver damage, narcosis, nausea, pulmonary edema, shortness of breath,
tremors, vomiting, weakness,
Ingestion : Toxic if swallowed.
Other effects of ingestion may include : abdominal pain, blood effects, CNS effects, diarrhea, dizziness,
drowsiness, fatigue, gastric disturbances, gastroenteritis, headache, incoordination, irritation, kidney
damage, liver damage, nausea, vomiting, weakness,
Potential chronic health : CARCINOGENIC EFFECTS: Classified 2B (Possible for humans.) by IARC [ethyl benzene]. Classified 2B
effects (Possible for humans.) by IARC [styrene].
MUTAGENIC EFFECTS: None by OSHA standard.
TERATOGENIC EFFECTS: Classified POSSIBLE for humans [ethyl benzene].
Contains material which may cause damage to the following organs: blood, kidneys, lungs, the
reproductive system, liver, heart, central nervous system (CNS).

This product under certain conditions could release formaldehyde in sufficient quantities to require
monitoring under OSHA regulations. Formaldehyde is a known carcinogen.
Routes of entry : Dermal contact. Eye contact. Inhalation. Ingestion.
Effects of Overexposure : HARMFUL IF ABSORBED THROUGH SKIN OR IF SWALLOWED.
CAUSES SEVERE SKIN IRRITATION.
CAUSES RESPIRATORY TRACT AND EYE IRRITATION.
FLAMMABLE LIQUID AND VAPOR.
VAPOR MAY CAUSE FLASH FIRE.
CONTAINS MATERIAL WHICH MAY CAUSE DAMAGE TO THE FOLLOWING ORGANS: BLOOD,
KIDNEYS, LUNGS, REPRODUCTIVE SYSTEM, LIVER, HEART, CENTRAL NERVOUS SYSTEM.
POSSIBLE CANCER HAZARD, CONTAINS MATERIAL WHICH CAN CAUSE CANCER.
Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Keep away
from heat, sparks and flame. Keep container closed. Use only with adequate ventilation. W ash
thoroughly after handling. Risk of cancer depends on duration and level of exposure.
Medical conditions : pulmonary conditions, skin disorders, liver conditions, kidney conditions, respiratory conditions,
aggravated by neurological disorders, cardiovascular diseases, anemia, reproductive system disorders,
overexposure

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NOTICE: Reports have associated repeated and prolonged OVEREXPOSURE to solvents with permanent brain and nervous system
damage. Intentional misuse by deliberately concentrating and inhaling the contents of this package may be harmful or fatal.
See toxicological information (section 11)

Section 4. First aid measures

Eye contact : Get medical attention immediately if symptoms occur. Immediately flush eyes with plenty of water for at
least 15 minutes, occasionally lifting the upper and lower eyelids. Check for and remove any contact
lenses.
Skin contact : Get medical attention immediately if symptoms occur. Flush contaminated skin with plenty of water.
Continue to rinse for at least 10 minutes. Remove contaminated clothing and shoes. W ash
contaminated clothing thoroughly with water before removing or wear gloves. Wash clothing before
reuse. Clean shoes thoroughly before reuse.
Inhalation : Get medical attention immediately if symptoms occur. Move exposed person to fresh air. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained
breathing apparatus. Keep person warm and at rest. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be
dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious, place in
recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing
such as a collar, tie, belt or waistband.
Ingestion : Get medical attention immediately. W ash out mouth with water. Remove dentures if any. Move
exposed person to fresh air. Keep person warm and at rest. If material has been swallowed and the
exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels
sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical
personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs.
Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and
get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie,
belt or waistband.
Medical conditions : pulmonary conditions, skin disorders, liver conditions, kidney conditions, respiratory conditions,
aggravated by neurological disorders, cardiovascular diseases, anemia, reproductive system disorders,
overexposure

Section 5. Fire fighting measures

Flammability of the : Flammable.
product
Auto-ignition temperature : The lowest known value is 231.85°C (449.3°F) (petroleum distillate (naphtha)).
Flash points : Closed cup: 25°C (77°F).

Flammable limits : Not available.

Products of combustion : These products are carbon oxides (CO, CO 2), nitrogen oxides (NO, NO 2 etc.). Some metallic oxides.

Fire Hazards in Presence : Highly flammable in the presence of the following materials or conditions: open flames, sparks and static
of Various discharge.
Substances/Conditions Flammable in the presence of the following materials or conditions: oxidizing materials.
Vapors are heavier than air and may spread along floors. Vapor may travel a considerable distance to
source of ignition and flash back.
Explosion Hazards in : Not available.
Presence of Various
Substances/Conditions
Fire-fighting media and : SMALL FIRE: Use dry chemical powder.
instructions LARGE FIRE: Use alcohol foam or water spray or fog. Cool containers with water jet in order to prevent
pressure build-up, auto-ignition or explosion.
Protective clothing (fire) : Be sure to use an approved/certified respirator or equivalent.

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Section 6. Accidental release measures

Spill and Leak : Immediately contact emergency personnel. Eliminate all ignition sources. Keep unnecessary personnel
away. Use suitable protective equipment. Do not touch or walk through spilled material.
If emergency personnel are unavailable, contain spilled material. For small spills, add absorbent (soil
may be used in the absence of other suitable materials) and use a non-sparking or explosion-proof
means to transfer material to a sealable, appropriate container for disposal. For large spills, dike spilled
material or otherwise contain material to ensure runoff does not reach a waterway. Place spilled
material in an appropriate container for disposal.
Dispose of according to Section 13. If necessary, report spill to applicable government agency.

Section 7. Handling and storage

Handling : Do not ingest. Avoid contact with eyes, skin and clothing. Keep container closed. Use only with
adequate ventilation. Avoid breathing vapor or mist. Keep away from heat, sparks and flame. To avoid
fire or explosion, dissipate static electricity during transfer by grounding and bonding containers and
equipment before transferring material. Use explosion-proof electrical (ventilating, lighting and material
handling) equipment. Wash thoroughly after handling.
Use ventilation to remove decomposition products formed during welding or flame cutting of surfaces
coated with this product.
Storage : Store in an approved area. Keep container in a cool, well-ventilated area. Keep container tightly
closed and sealed until ready for use. Avoid all possible sources of ignition (spark or flame).
Other Precautions : All precautions must be observed. Empty container may retain product residues.

Section 8. Exposure controls, personal protection

Selection of personal protective equipment (PPE) is to be established by the employer performing a PPE hazard assessment. In the
U.S.A, OSHA requires completion of a documented PPE hazard assessment as described in 29 CFR 1910.132.

Engineering controls : Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors
below their respective occupational exposure limits. Ensure that eyewash stations and safety showers
are close to the workstation location.
Personal protection
Eyes : Safety glasses.
Body : Synthetic apron.
Respiratory : Wear appropriate respirator when ventilation is inadequate.
Hands : Impervious gloves.
Barrier creams are not a replacement for full physical protection
Feet : Wear appropriate protection.
Protective clothing :
(pictograms)

HYGIENIC PRACTICES: Good personal hygiene practices are required at all times when handling chemicals. These practices
include, but are not limited to, washing when safety equipment is removed, at the end of each shift or when going on breaks and
especially if contamination occurs.

Section 9. Physical and chemical properties

Physical state and : Liquid.
Appearance
Boiling/condensation : 56°C (132.8°F)
point
Flash points : Closed cup: 25°C (77°F).

Specific gravity : 0.973 (Water = 1)

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Vapor pressure : The highest known value is 1.3 kPa (10 mm Hg) (at 20°C) (butyl acetate).
Vapor density : Heavier than air
Volatile Content : 74.1% (w/w)
Evaporation rate : The highest known value is 1 (butyl acetate) compared with butyl acetate
VOC : 721 (g/l).

Section 10. Stability and reactivity

Stability and reactivity : The product is stable.
Conditions of instability : temperatures above 120 degrees, open flame, sparks, light, moisture, dusty conditions,
Incompatibility with various : Reactive or incompatible with the following materials: oxidizing materials, acids, alkalis and
substances moisture.
Hazardous Reaction Products : Possibly hazardous, short-term degradation products are not likely. However, long-term
degradation products may arise.
Hazardous polymerization : Will not undergo hazardous polymerization.

Section 11. Toxicological information

butyl acetate LD50 10768 mg/kg Oral Rat
LD50 8770 mg/kg Dermal Guinea pig
LC50 390 ppm (4 Inhalation Rat
hour/hours)
methoxypropanol LD50 6600 mg/kg Oral Rat
LD50 13000 mg/kg Dermal Rabbit
LC50 10000 ppm (5 Inhalation Rat
hour/hours)
xylene, mixed isomers LD50 4300 mg/kg Oral Rat
LD50 >1700 mg/kg Dermal Rabbit
LC50 5000 ppm (4 Inhalation Rat
hour/hours)
4-hydroxy-4-methyl-2-pentanone LD50 2520 mg/kg Oral Rat
LD50 13500 mg/kg Dermal Rabbit
isobutanol LD50 2460 mg/kg Oral Rat
LD50 >3400 mg/kg Dermal Rabbit
LC50 19200 mg/m 3 (4 Inhalation Rat
hour/hours)
ethyl benzene LD50 3500 mg/kg Oral Rat
LD50 15486 mg/kg Dermal Rabbit
LC50 55000 mg/m 3 (2 Inhalation Rat
hour/hours)
petroleum distillate (naphtha) LD50 >5000 mg/kg Oral Rat
LD50 >3000 mg/kg Dermal Rabbit
butanol LD50 790 mg/kg Oral Rat
LD50 3400 mg/kg Dermal Rabbit
LC50 8000 ppm (4 Inhalation Rat
hour/hours)
styrene (as volatile) LD50 2650 mg/kg Oral Rat
LC50 11800 mg/m 3 (4 Inhalation Rat
hour/hours)

Section 12. Ecological information

Products of degradation : These products are carbon oxides (CO, CO 2) and water, nitrogen oxides (NO, NO 2 etc.). Some metallic
oxides.
Toxicity of the products : The products of degradation are less toxic than the product itself.
of biodegradation

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Section 13. Disposal considerations

Waste information : The generation of waste should be avoided or minimized wherever possible. Avoid dispersal of spilled
material and runoff and contact with soil, waterways, drains and sewers. Disposal of this product,
solutions and any by-products should at all times comply with the requirements of environmental
protection and waste disposal legislation and any regional local authority requirements.
Empty containers should be recycled or disposed through an approved waste management facility.
Consult your local or regional authorities.

Section 14. Transport information

Regulatory UN Proper shipping name Class Packing group Label Additional information
information number
DOT Consult your shipping
Classification specialist or transport
agency for appropriate
assignment of the DOT
information.
TDG UN1263 PAINT 3 III -
Classification
3

IMDG Class UN1263 PAINT 3 III -

IATA-DGR UN1263 PAINT 3 III -

Class
3

Marine pollutant : No.

Section 15. Regulatory information

U.S. Federal regulations : All components in this product have been verified as being on the TSCA Inventory.
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
(HAPS) : Clean Air Act (CAA) 112 regulated toxic substances: toluene; ethyl benzene; xylene, mixed isomers;
styrene; formaldehyde; cumene
Product name CAS number % by weight
SARA 313 TRI - Reporting : xylene, mixed isomers 1330-20-7 9.46
requirements aluminum 7429-90-5 6.40
ethyl benzene 100-41-4 2.22
butanol 71-36-3 1.04
styrene 100-42-5 0.24
State regulations : WARNING: This product contains chemicals known to the State of California to cause cancer and birth
defects or other reproductive harm.
International regulations
International lists : All components of this product are on the CEPA DSL inventory.

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Section 16. Other information

HMIS® III Health * 2 WHMIS (Canada)
Hazardous Material Flammability 3
Information System Physical Hazard 0
(U.S.A.)® Class B-2: Flammable liquid
Personal protection
Class D-1B: Material causing immediate and serious toxic effects
(HMIS® III is a registered trademark of the National Paint and Coatings Association) (Toxic).
Class D-2A: Material causing other toxic effects (Very toxic).
Class D-2B: Material causing other toxic effects (Toxic).

Notice to reader
The absence of a positive finding indicates that we believe, to the best of our knowledge, that the
negative is true.
Do not handle until the manufacturer’s safety precautions have been read and understood.
Regulations require that all employees be trained on Material Safety Data Sheets for all products
with which they come in contact.

Disclaimer: While Akzo Nobel Coatings believes that the data contained herein are accurate and
derived from qualified sources, the data are not to be taken as a warranty or representation for
which Akzo Nobel Coatings assumes legal responsibility. They are offered solely for your
consideration, investigation and verification. Any use of these data and information must be
determined by the user to be in accordance with applicable Federal, State, Provincial and local laws
and regulations.