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Ciguatera Risk in Diesel No. 2 Fuel

The document is a Safety Data Sheet for Diesel No. 2 Test Fuel, detailing its identification, hazards, and emergency measures. It classifies the fuel as flammable and harmful, with specific precautions for handling and first aid responses. The supplier is Chevron Phillips Chemical Company, and the document includes extensive emergency contact information and regulatory compliance details.

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0% found this document useful (0 votes)
25 views55 pages

Ciguatera Risk in Diesel No. 2 Fuel

The document is a Safety Data Sheet for Diesel No. 2 Test Fuel, detailing its identification, hazards, and emergency measures. It classifies the fuel as flammable and harmful, with specific precautions for handling and first aid responses. The supplier is Chevron Phillips Chemical Company, and the document includes extensive emergency contact information and regulatory compliance details.

Uploaded by

ptkk.dikiprayogo
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

SAFETY DATA SHEET

Diesel No. 2 Test Fuel


Version 1.12 Revision Date 2024-05-21

According to Regulation (EC) No. 1907/2006, Regulation (EC) No. 2020/878

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Product information
Product Name : Diesel No. 2 Test Fuel
Material : 1126733, 1126729, 1126732, 1126728, 1126711, 1126727,
1126710, 1126726, 1126205, 1125693, 1124271, 1101406,
1117144, 1114932, 1114380, 1114379, 1111796, 1111792,
1111793, 1111721, 1108397, 1097307, 1096433, 1083233,
1096612, 1084817, 1097324, 1097322, 1097310, 1089768,
1079939, 1097309, 1090864, 1077073, 1077061, 1090863,
1069145, 1100027, 1099634, 1090866, 1099603, 1090314,
1097785, 1087561, 1092489, 1076410, 1102501, 1097387,
1090432, 1090433, 1100452, 1097386, 1078955, 1100842,
1077075, 1097308, 1100531, 1069147, 1090862, 1078060,
1077077, 1068920, 1078988, 1017963, 1017962, 1036152,
1024299, 1024300, 1017964, 1024301, 1017977, 1024303,
1017981, 1017980, 1017965, 1017978, 1017967, 1017966,
1017979, 1024297, 1024293, 1029744, 1024292, 1017982,
1024294, 1024296, 1024302, 1024304, 1024309, 1024308,
1024307, 1024306, 1024295, 1024305, 1024298, 1029490,
1104964, 1104939, 1104952, 1104938, 1104941, 1104963,
1104956, 1104955, 1104953

EC-No.Registration number
Chemical name CAS-No. Legal Entity
EC-No. Registration number
Index No.
Diesel fuel, no. 2 68476-34-6 Chevron Phillips Chemicals International NV
270-676-1 01-2119475502-40-0023
649-227-00-2

1.2
Relevant identified uses of the substance or mixture and uses advised against

Relevant Identified Uses : Manufacture


Supported Distribution
Use as an intermediate
Use as a fuel - industrial
Use as a fuel – professional

1.3
Details of the supplier of the safety data sheet
SDS Number:100000013879 1/55
SAFETY DATA SHEET
Diesel No. 2 Test Fuel
Version 1.12 Revision Date 2024-05-21

Company : Chevron Phillips Chemical Company LP


Specialty Chemicals
10001 Six Pines Drive
The Woodlands, TX 77380

Local : Chevron Phillips Chemicals International N.V.


Airport Plaza (Stockholm Building)
Leonardo Da Vincilaan 19
1831 Diegem
Belgium

SDS Requests: (800) 852-5530


Responsible Party: Product Safety Group
Email:[email protected]

1.4
Emergency telephone:

Health:
866.442.9628 (North America)
1.832.813.4984 (International)
Transport:
CHEMTREC 800.424.9300 or 703.527.3887(int'l)
Asia: CHEMWATCH (+612 9186 1132) China: 0532 8388 9090
Mexico CHEMTREC 01-800-681-9531 (24 hours)
South America SOS-Cotec Inside Brazil: 0800.111.767 Outside Brazil: +55.19.3467.1600
Argentina: +(54)-1159839431
EUROPE: BIG +32.14.584545 (phone) or +32.14583516 (telefax)
Austria: VIZ +43 1 406 43 43 (24 hours/day, 7 days/week)
Belgium: 070 245 245 (24 hours/day, 7 days/week)
Bulgaria: +359 2 9154 233
Croatia: +3851 2348 342 (24 hours/day, 7 days/week)
Cyprus: 1401
Czech Republic: Toxicological Information Center +420 224 919 293, +420 224 915 402
Denmark: Danish Poison Center (Giftlinjen): +45 8212 1212
Estonia: BIG +32.14.584545 (phone) or +32.14583516 (telefax)
Finland: 0800 147 111 09 471 977 (24 hours/day)
France: ORFILA number (INRS): + 33 (0) 1 45 42 59 59 (24 hours/day, 7 days/week)
Germany: BIG +32.14.584545 (phone) or +32.14583516 (telefax)
Greece: (0030) 2107793777 (24 hours/day, 7 days/week)
Hungary: +36-80-201-199 (24 hours/day, 7 days/week)
Iceland: 543 2222 (24 hours/day, 7 days/week)
Ireland: BIG +32.14.584545 (phone) or +32.14583516 (telefax)
Italy: POISON CENTER MILAN – Azienda Ospedaliera Niguarda Ca` Grande Tel. +39 02
66101029; POISON CENTER ROME – Policlinico “Agostino Gemelli”, Servizio di tossicologia
clinica Tel. +39 06 3054343; POISON CENTER ROME – Ospedale Pediatrico Bambino Gesù
Tel. +39 06 68593726;POISON CENTER ROME – Policlinico “Umberto I” Tel. +39 06 4997 8000;
POISON CENTER FOGGIA – Azienda Ospedaliera Universitaria Riuniti Tel. +39 0881 732326;
POISON CENTER NAPLES – Azienda Ospedaliera “Antonio Cardarelli” Tel. +39 081 7472870;
POISON CENTER FLORENCE – Azienda Ospedaliera universitaria Careggi Tel. +39 055
7947819; POISON CENTER PAVIA – IRCCS Fondazione Salvatore Maugeri Tel. +39 0382
24444; POISON CENTER BERGAMO – Azienda Ospedaliera “Papa Giovanni XXIII” Tel. 800 883
300; POISON CENTER VERONA – Azienda Ospedaliera Universitaria integrata Tel. 800 011
858;
Latvia: State Fire and Rescue Service, phone number: 112; Toxicology and Sepsis Clinic
Poisoning and Drug Information Center, Hipokrāta 2, Riga, Latvia, LV-1038, phone number +371
67042473. (24 hours.)
SDS Number:100000013879 2/55
SAFETY DATA SHEET
Diesel No. 2 Test Fuel
Version 1.12 Revision Date 2024-05-21
Liechtenstein: BIG +32.14.584545 (phone) or +32.14583516 (telefax)
Lithuania: +370 (85) 2362052
Luxembourg: (+352) 8002 5500 (24 hours/day, 7 days/week)
Malta: +356 2395 2000
The Netherlands: NVIC: +31 (0)88 755 8000
Norway: 22 59 13 00 (24 hours/day, 7 days/week)
Poland: BIG +32.14.584545 (phone) or +32.14583516 (telefax)
Portugal: CIAV phone number: +351 800 250 250
Romania: +40213183606
Slovakia: +421 2 5477 4166
Slovenia: Phone number: 112
Spain: National Emergency Telephone Number of Spanish Poison Centre: +34 91 562 04 20 (24
hours/day, 7 days/week)
Sweden: 112 – ask for Poisons Information

Responsible Department : Product Safety and Toxicology Group


E-mail address : [email protected]
Website : www.CPChem.com

SECTION 2: Hazards identification

2.1
Classification of the substance or mixture
REGULATION (EC) No 1272/2008

Flammable liquids, Category 3 H226:


Flammable liquid and vapor.
Short-term (acute) aquatic hazard, H401:
Category 2 Toxic to aquatic life.
Acute toxicity, Category 4 H332:
Harmful if inhaled.
Skin irritation, Category 2 H315:
Causes skin irritation.
Carcinogenicity, Category 2 H351:
Suspected of causing cancer.
Specific target organ toxicity - repeated H373:
exposure, Category 2, Liver May cause damage to organs through prolonged or
repeated exposure.
, Blood
, thymus
Aspiration hazard, Category 1 H304:
May be fatal if swallowed and enters airways.
Long-term (chronic) aquatic hazard, H411:
Category 2 Toxic to aquatic life with long lasting effects.

2.2
Labeling (REGULATION (EC) No 1272/2008)
Hazard pictograms :

Signal Word : Danger

Hazard Statements : H226 Flammable liquid and vapor.


H304 May be fatal if swallowed and enters
airways.
H315 Causes skin irritation.
SDS Number:100000013879 3/55
SAFETY DATA SHEET
Diesel No. 2 Test Fuel
Version 1.12 Revision Date 2024-05-21
H332 Harmful if inhaled.
H351 Suspected of causing cancer.
H373 May cause damage to organs (Liver, Blood,
thymus) through prolonged or repeated
exposure.
H411 Toxic to aquatic life with long lasting effects.

Precautionary Statements : Prevention:


P210 Keep away from heat, hot surfaces, sparks,
open flames and other ignition sources. No
smoking.
P260 Do not breathe dust/ fume/ gas/ mist/
vapors/ spray.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/
eye protection/ face protection/ hearing
protection.
Response:
P301 + P310 IF SWALLOWED: Immediately call a
POISON CENTER/ doctor.
P331 Do NOT induce vomiting.
P370 + P378 In case of fire: Use dry sand, dry chemical
or alcohol-resistant foam to extinguish.
P391 Collect spillage.

Hazardous ingredients which must be listed on the label:


• 68476-34-6 Diesel fuel, no. 2

2.3
Other hazards
Results of PBT and vPvB : This substance/mixture contains no components considered to
assessment be either persistent, bioaccumulative and toxic (PBT), or very
persistent and very bioaccumulative (vPvB) at levels of 0.1%
or higher.

Endocrine disrupting : The substance/mixture does not contain components


properties considered to have endocrine disrupting properties according
to REACH Article 57(f) or Commission Delegated regulation
(EU) 2017/2100 or Commission Regulation (EU) 2018/605 at
levels of 0.1% or higher.

SECTION 3: Composition/information on ingredients

3.1 - 3.2
Substance or Mixture
Synonyms : Diesel 0.05 LS Emiss Cert Test Fuel- Cummins
Diesel 2007 Emission Certification Fuel
Diesel CEC (RF-73-T-90)
Diesel Euro-II Cert Fuel
Diesel Euro-IV Cert Fuel
Diesel Reference Fuels, Diesel Cert Fuel, Oil Classification
Diesel
Diesel 0.05 LS Emiss Cert Test Fuel- ITE
Diesel Euro-III Cert Fuel

SDS Number:100000013879 4/55


SAFETY DATA SHEET
Diesel No. 2 Test Fuel
Version 1.12 Revision Date 2024-05-21
Diesel Special Test Fuel
Locomotive Diesel Certification Fuel
PC-10 Diesel Test Fuel
Diesel CEC (RF-03-A-84)
Ultra High Cetane Check Fuel (ASTM) Diesel
Diesel 2004 Tier 2 Fuel
0.05% Sulfur Diesel Fuel - JASO
No Sulfur (less than 3 PPM) Diesel Test Fuel
Diesel Caterpillar F173
Diesel Caterpillar 1E2973
Caterpillar China Certification Diesel Fuel Stage III
DIESEL PC-10 TEST FUEL

Molecular formula : UVCB

Hazardous ingredients
Chemical name CAS-No. Classification Concentration Specific Conc.
EC-No. (REGULATION (EC) [wt%] Limits, M-factors
Index No. No 1272/2008) and ATEs

Diesel fuel, no. 2 68476-34-6 Flam. Liq. 3; H226 100


270-676-1 Acute Tox. 4; H332
649-227-00-2 Skin Irrit. 2; H315
Carc. 2; H351
STOT RE 2; H373
Asp. Tox. 1; H304
Aquatic Chronic 2;
H411

Naphthalene 91-20-3 Flam. Sol. 2; H228 0- 1


202-049-5 Acute Tox. 4; H302
601-052-00-2 Carc. 2; H351
Aquatic Acute 1; H400
Aquatic Chronic 1;
H410

For the full text of the H-Statements mentioned in this Section, see Section 16.

SECTION 4: First aid measures

4.1
Description of first-aid measures

General advice : Move out of dangerous area. Show this material safety data
sheet to the doctor in attendance. Material may produce a
serious, potentially fatal pneumonia if swallowed or vomited.

If inhaled : Consult a physician after significant exposure. If unconscious,


place in recovery position and seek medical advice.

In case of skin contact : If skin irritation persists, call a physician. If on skin, rinse well
with water. If on clothes, remove clothes.

In case of eye contact : Flush eyes with water as a precaution. Remove contact
lenses. Protect unharmed eye. Keep eye wide open while
rinsing. If eye irritation persists, consult a specialist.

If swallowed : Keep respiratory tract clear. Do NOT induce vomiting. Do not


SDS Number:100000013879 5/55
SAFETY DATA SHEET
Diesel No. 2 Test Fuel
Version 1.12 Revision Date 2024-05-21
give milk or alcoholic beverages. Never give anything by
mouth to an unconscious person. If symptoms persist, call a
physician. Take victim immediately to hospital.

4.2 Most important symptoms and effects, both acute and delayed
4.3 Indication of any immediate medical attention and special treatment needed

SECTION 5: Firefighting measures

Flash point : 47°C (117°F)


minimum

Autoignition temperature : No data available

5.1
Extinguishing media

Suitable extinguishing : Alcohol-resistant foam. Carbon dioxide (CO2). Dry chemical.


media

5.2
Special hazards arising from the substance or mixture
Specific hazards during fire : Do not allow run-off from fire fighting to enter drains or water
fighting courses.

5.3
Advice for firefighters
Special protective : Wear self-contained breathing apparatus for firefighting if
equipment for fire-fighters necessary.

Further information : Collect contaminated fire extinguishing water separately. This


must not be discharged into drains. Fire residues and
contaminated fire extinguishing water must be disposed of in
accordance with local regulations. For safety reasons in case
of fire, cans should be stored separately in closed
containments. Use a water spray to cool fully closed
containers.

Fire and explosion : Do not spray on a naked flame or any incandescent material.
protection Take necessary action to avoid static electricity discharge
(which might cause ignition of organic vapors). Keep away
from open flames, hot surfaces and sources of ignition.

Do not spray on a naked flame or any incandescent material.


Take necessary action to avoid static electricity discharge
(which might cause ignition of organic vapors). Keep away
from open flames, hot surfaces and sources of ignition.

Hazardous decomposition : Hydrocarbons. Carbon oxides.


products

SECTION 6: Accidental release measures

6.1
Personal precautions, protective equipment and emergency procedures

Personal precautions : Use personal protective equipment. Ensure adequate


ventilation. Remove all sources of ignition. Evacuate

SDS Number:100000013879 6/55


SAFETY DATA SHEET
Diesel No. 2 Test Fuel
Version 1.12 Revision Date 2024-05-21
personnel to safe areas. Beware of vapors accumulating to
form explosive concentrations. Vapors can accumulate in low
areas.
6.2
Environmental precautions

Environmental precautions : Prevent product from entering drains. Prevent further leakage
or spillage if safe to do so. If the product contaminates rivers
and lakes or drains inform respective authorities.

6.3
Methods and materials for containment and cleaning up
Methods for cleaning up : Contain spillage, and then collect with non-combustible
absorbent material, (e.g. sand, earth, diatomaceous earth,
vermiculite) and place in container for disposal according to
local / national regulations (see section 13).
6.4
Reference to other sections
For additional details, see the Exposure Scenario in the Annex portion

SECTION 7: Handling and storage

7.1
Precautions for safe handling
Handling

Advice on safe handling : Avoid formation of aerosol. Do not breathe vapors/dust. Avoid
exposure - obtain special instructions before use. Avoid
contact with skin and eyes. For personal protection see
section 8. Smoking, eating and drinking should be prohibited
in the application area. Take precautionary measures against
static discharges. Provide sufficient air exchange and/or
exhaust in work rooms. Open drum carefully as content may
be under pressure. Dispose of rinse water in accordance with
local and national regulations.

Advice on protection : Do not spray on a naked flame or any incandescent material.


against fire and explosion Take necessary action to avoid static electricity discharge
(which might cause ignition of organic vapors). Keep away
from open flames, hot surfaces and sources of ignition.
Do not spray on a naked flame or any incandescent material.
Take necessary action to avoid static electricity discharge
(which might cause ignition of organic vapors). Keep away
from open flames, hot surfaces and sources of ignition.

7.2
Conditions for safe storage, including any incompatibilities

Storage

Requirements for storage : No smoking. Keep container tightly closed in a dry and well-
areas and containers ventilated place. Containers which are opened must be
carefully resealed and kept upright to prevent leakage.
Observe label precautions. Electrical installations / working
materials must comply with the technological safety standards.

SDS Number:100000013879 7/55


SAFETY DATA SHEET
Diesel No. 2 Test Fuel
Version 1.12 Revision Date 2024-05-21

SECTION 8: Exposure controls/personal protection

Ingredients with workplace control parameters

SK
Zložky Podstata Hodnota Kontrolné parametre Poznámka
Naphthalene SK OEL NPEL priemerný 10 ppm, 50 mg/m3 K,
SK OEL NPEL krátkodobý 15 ppm, 80 mg/m3 K,
K Znamená, ze faktor môže byt' l'ahko absorbovaný kožou. Niektoré faktory, ktoré l'ahko prenikajú kožou, môžu spôsobovat' až
smrtel'né otravy, éasto bez varovných príznakov (napr. anilín, nitrobenzén, nitroglykol, fenoly a pod.). Pri látkach s významným
prienikom cez kožu, éi už v podobe kvapalín alebo pár, je osobitne dôležité zabránit' kožnému kontaktu.

SI
Sestavine Osnova Vrednost Parametri nadzora Pripomba
Naphthalene SI OEL MV 10 ppm, 2, K,
SI OEL MV 50 mg/m3 2, K, Inhalabilna frakcija
SI OEL KTV 10 ppm, 2, K,
SI OEL KTV 50 mg/m3 2, K, Inhalabilna frakcija
2 Rakotvorne snovi - kategorija 2
K Lastnost lažjega prehajanja snovi v organizem skozi kožo

SE
Beståndsdelar Grundval Värde Kontrollparametrar Anmärkning
Naphthalene SE AFS NGV 10 ppm, 50 mg/m3
SE AFS KGV 15 ppm, 80 mg/m3 V,
V Vägledande korttidsgränsvärde ska användas som ett rekommenderat högsta värde som inte bör överskridas

RU
Компоненты Основа Величина Параметры контроля Заметка
Нафталин RU OEL ПДК разовая 20 mg/m3 4, пары и/или газы
RU OEL ПДК разовая 20 mg/m3 4, пары и/или газы
4 4 класс - умеренно опасные

RS
Компоненты Основа Величина Параметры контроля Заметка
Нафталин RS OEL GVI 10 ppm, 50 mg/m3 Carc. cat. 3, EU,
Carc. cat. 3 Chemical substances that cause concern about possible carcinogenic effects for humans
EU Substance mentioned in indicative exposure limit values in Directive 91/322 / EEC

RO
Componente Sursă Valoare Parametri de control Notă
Naphthalene RO OEL TWA 10 ppm, 50 mg/m3 C2,
C2 susceptibil de a provoca apariţia cancerului

PT
Componentes Bases Valor Parâmetros de Nota
controlo
Diesel fuel, no. 2 PT OEL VLE-MP 100 mg/m3 P, A3,
P, A3, Fração inalável e
PT OEL VLE-MP 100 mg/m3 vapor
Naphthalene PT OEL VLE-MP 10 ppm, P, A3,
PT DL 305/2007 oito horas 10 ppm, 50 mg/m3
A3 Agente carcinogénico confirmado nos animais de laboratório com relevância desconhecida no Homem.
P Perigo de absorção cutânea

PL
Składniki Podstawa Wartość Parametry dotyczące Uwaga
kontroli
Naphthalene PL NDS NDS 20 mg/m3
PL NDS NDSch 50 mg/m3

NO
Komponenter Grunnlag Verdi Kontrollparametrer Nota
FOR-2011-12-06-
Naphthalene 1358
GV 10 ppm, 50 mg/m3

NL
Bestanddelen Basis Waarde Controleparameters Opmerking
Naphthalene NL WG TGG-8 uur 50 mg/m3
NL WG TGG-15 min 80 mg/m3

MT
Components Basis Value Control parameters Note
Naphthalene MT OEL TWA 10 ppm, 50 mg/m3

SDS Number:100000013879 8/55


SAFETY DATA SHEET
Diesel No. 2 Test Fuel
Version 1.12 Revision Date 2024-05-21
MK
Съставки Основа Стойност Параметри на Бележка
контрол
Naphthalene MK OEL MV 10 ppm, 50 mg/m3

LV
Sastāvdaļas Bāze Vērtība Pārvaldības parametri Piezīme
Naphthalene LV OEL AER 8 st 10 ppm, 50 mg/m3

LU
Composants Base Valeur Paramètres de Note
contrôle
Naphthalene LU OEL TWA 10 ppm, 50 mg/m3

LT
Komponentai Šaltinis Vertė Kontrolės parametrai Pastaba
Diesel fuel, no. 2 LT OEL IPRD 200 mg/m3
LT OEL TPRD 300 mg/m3
Naphthalene LT OEL IPRD 10 ppm, 50 mg/m3

IS
Komponenter Grunnlag Verdi Kontrollparametrer Nota
Naphthalene IS OEL TWA 10 ppm, 50 mg/m3

IE
Components Basis Value Control parameters Note
Naphthalene IE OEL OELV - 8 hrs (TWA) 10 ppm, 50 mg/m3

HU
Komponensek Bázis Érték Ellenőrzési Megjegyzés
paraméterek
Naphthalene HU OEL AK-érték 50 mg/m3 N, EU91, i,
EU91 91/322/EGK irányelvben közölt érték
i Ingerlő anyag (izgatja a bőrt, nyálkahártyát, szemet vagy mindhármat)
N Irritáló anyagok, egyszerű fojtógázok, csekély egészségkárosító hatással bíró anyagok. Korrekció NEM szükséges.

HR
Sastojci Temelj Vrijednost Nadzorni parametri Bilješka
Diesel fuel, no. 2 HR OEL GVI 100 ppm, 400 mg/m3
Naphthalene HR OEL GVI 10 ppm, 50 mg/m3
HR OEL 15 ppm, 75 mg/m3

GR
Συστατικά Βάση Τιμή Παράμετροι ελέγχου Σημείωση
Naphthalene GR OEL TWA 10 ppm, 50 mg/m3

FR
Composants Base Valeur Paramètres de Note
contrôle
C2, Valeurs limites
Naphthalene FR VLE VME 10 ppm, 50 mg/m3
indicatives,
C2 Cancérigène de catégorie 2 - Substances preoccupantes en raison d'effets cancerogenes possibles
Valeurs limites Valeurs limites indicatives
indicatives

FI
Aineosat Peruste Arvo Valvontaa koskevat Huomautus
muuttujat
Naphthalene FI OEL HTP-arvot 8h 1 ppm, 5 mg/m3
FI OEL HTP-arvot 15 min 2 ppm, 10 mg/m3

ES
Componentes Base Valor Parámetros de control Nota
Naphthalene ES VLA VLA-ED 10 ppm, 53 mg/m3 vía dérmica,
ES VLA VLA-EC 15 ppm, 80 mg/m3 vía dérmica,
vía dérmica Vía dérmica

EE
Komponendid, osad Alused Väärtus Kontrolliparameetrid Märkused
Naphthalene EE OEL Piirnorm 10 ppm, 50 mg/m3

DK
Komponenter Basis Værdi Kontrolparametre Note
Naphthalene DK OEL GV 10 ppm, 50 mg/m3 K,
K Betyder, at stoffet er optaget på listen over stoffer, der anses for at være kræftfremkaldende.

SDS Number:100000013879 9/55


SAFETY DATA SHEET
Diesel No. 2 Test Fuel
Version 1.12 Revision Date 2024-05-21
DE
Inhaltsstoffe Grundlage Wert Zu überwachende Bemerkung
Parameter
H, Y, Dampf und
Naphthalene DE TRGS 900 AGW 0,4 ppm, 2 mg/m3 Aerosole, einatembare
Fraktion
H Hautresorptiv
Y Ein Risiko der Fruchtschädigung braucht bei Einhaltung des Arbeitsplatzgrenzwertes und des biologischen Grenzwertes (BGW)
nicht befürchtet zu werden

CZ
Složky Základ Hodnota Kontrolní parametry Poznámka
Naphthalene CZ OEL PEL 50 mg/m3
CZ OEL NPK-P 100 mg/m3

CY
Συστατικά Βάση Τιμή Παράμετροι ελέγχου Σημείωση
Naphthalene CY OEL TWA 10 ppm, 50 mg/m3

CH
Inhaltsstoffe Grundlage Wert Zu überwachende Bemerkung
Parameter
H, Carc.Cat.3, NIOSH,
Naphthalene CH SUVA MAK-Wert 10 ppm, 50 mg/m3 OSHA,
Carc.Cat.3 Krebserzeugende Stoffe Kategorie 3
H Vergiftung durch Hautresorption möglich; Bei Stoffen, welche die Haut leicht zu durchdringen vermögen, kann durch die
zusätzliche Hautresorption die innere Belastung wesentlich höher werden als bei alleiniger Aufnahme durch die Atemwege.
NIOSH National Institute for Occupational Safety and Health
OSHA Occupational Safety and Health Administration

BG
Съставки Основа Стойност Параметри на Бележка
контрол
Naphthalene BG OEL TWA 50 mg/m3
BG OEL STEL 75 mg/m3

BE
Bestanddelen Basis Waarde Controleparameters Opmerking
Diesel fuel, no. 2 BE OEL TGG 8 hr 100 mg/m3 D,
BE OEL TGG 8 hr 100 mg/m3 D, damp en aërosol
Naphthalene BE OEL TGG 8 hr 10 ppm, 53 mg/m3 D,
BE OEL TGG 15 min 15 ppm, 80 mg/m3 D,
D Opname van het agens via de huid, de slijmvliezen of de ogen vormt een belangrijk deel van de totale blootstelling. Deze opname
kan het gevolg zijn van zowel direct contact als zijn aanwezigheid in de lucht.

AT
Inhaltsstoffe Grundlage Wert Zu überwachende Bemerkung
Parameter
Naphthalene AT OEL MAK-TMW 10 ppm, 50 mg/m3 H,
H Besondere Gefahr der Hautresorption

Biological exposure indices

SK
Názov látky Č. CAS Kontrolné parametre Doba odberu Aktualizácia
vzorky

SDS Number:100000013879 10/55


SAFETY DATA SHEET
Diesel No. 2 Test Fuel
Version 1.12 Revision Date 2024-05-21
Naphthalene 91-20-3 1-hydroxypyrén: 5,66 µg/l V tejto Koniec 2015-04-08
prílohe sú uvedené aj niektoré vystavenia alebo
chemické faktory s karcinogénnym pracovnej zmeny
účinkom (kategória 1A a kategória
1B). Pre tieto chemické faktory
platí, že dodržanie BMH nevylučuje
riziko škodlivých zdravotných
účinkov, preto sú určené ako
základ pre biomonitoring
exponovaných osôb a zdravotný
dohľad vykonávaný lekárom
pracovnej zdravotnej služby podľa
§ 13 a prílohy č. 4 nariadenia vlády
Slovenskej republiky č. 356/2006 Z.
z. o ochrane zdravia zamestnancov
pred rizikami súvisiacimi s
expozíciou karcinogénnym a
mutagénnym faktorom pri práci v
znení neskorších predpisov. (moč)
Karcinogén kategórie 1B ()
1-hydroxypyrén: 0.0259 nmol/l V Koniec 2015-04-08
tejto prílohe sú uvedené aj niektoré vystavenia alebo
chemické faktory s karcinogénnym pracovnej zmeny
účinkom (kategória 1A a kategória
1B). Pre tieto chemické faktory
platí, že dodržanie BMH nevylučuje
riziko škodlivých zdravotných
účinkov, preto sú určené ako
základ pre biomonitoring
exponovaných osôb a zdravotný
dohľad vykonávaný lekárom
pracovnej zdravotnej služby podľa
§ 13 a prílohy č. 4 nariadenia vlády
Slovenskej republiky č. 356/2006 Z.
z. o ochrane zdravia zamestnancov
pred rizikami súvisiacimi s
expozíciou karcinogénnym a
mutagénnym faktorom pri práci v
znení neskorších predpisov. (moč)
Karcinogén kategórie 1B ()
1-hydroxypyrén: 3.77 µg/g Koniec 2015-04-08
kreatinínu V tejto prílohe sú vystavenia alebo
uvedené aj niektoré chemické pracovnej zmeny
faktory s karcinogénnym účinkom
(kategória 1A a kategória 1B). Pre
tieto chemické faktory platí, že
dodržanie BMH nevylučuje riziko
škodlivých zdravotných účinkov,
preto sú určené ako základ pre
biomonitoring exponovaných osôb
a zdravotný dohľad vykonávaný
lekárom pracovnej zdravotnej
služby podľa § 13 a prílohy č. 4
nariadenia vlády Slovenskej
republiky č. 356/2006 Z. z. o
ochrane zdravia zamestnancov
pred rizikami súvisiacimi s
expozíciou karcinogénnym a
mutagénnym faktorom pri práci v
znení neskorších predpisov. (moč)
Karcinogén kategórie 1B ()

SDS Number:100000013879 11/55


SAFETY DATA SHEET
Diesel No. 2 Test Fuel
Version 1.12 Revision Date 2024-05-21
1-hydroxypyrén: 1.95 µmol/mol Koniec 2015-04-08
kreatinínu V tejto prílohe sú vystavenia alebo
uvedené aj niektoré chemické pracovnej zmeny
faktory s karcinogénnym účinkom
(kategória 1A a kategória 1B). Pre
tieto chemické faktory platí, že
dodržanie BMH nevylučuje riziko
škodlivých zdravotných účinkov,
preto sú určené ako základ pre
biomonitoring exponovaných osôb
a zdravotný dohľad vykonávaný
lekárom pracovnej zdravotnej
služby podľa § 13 a prílohy č. 4
nariadenia vlády Slovenskej
republiky č. 356/2006 Z. z. o
ochrane zdravia zamestnancov
pred rizikami súvisiacimi s
expozíciou karcinogénnym a
mutagénnym faktorom pri práci v
znení neskorších predpisov. (moč)
Karcinogén kategórie 1B ()
GB

Substance name CAS-No. Control parameters Sampling time Update


Naphthalene 91-20-3 1-hydroxypyrene: 4 µmol/mol After shift 2011-12-18
creatinine (Urine)

8.2
Exposure controls
Engineering measures
Adequate ventilation to control airborned concentrations below the exposure guidelines/limits.
Consider the potential hazards of this material (see Section 2), applicable exposure limits, job
activities, and other substances in the work place when designing engineering controls and selecting
personal protective equipment. If engineering controls or work practices are not adequate to prevent
exposure to harmful levels of this material, the personal protective equipment listed below is
recommended. The user should read and understand all instructions and limitations supplied with
the equipment since protection is usually provided for a limited time or under certain circumstances.

Personal protective equipment

Respiratory protection : If ventilation or other engineering controls are not adequate to


maintain minimal oxygen content of 19.5% by volume under
normal atmospheric pressure, a supplied-air NIOSH approved
respirator may be appropriate. If exposure to harmful levels of
airborne material may occur, a NIOSH approved respirator that
provides protection may be appropriate, such as:. Air-Purifying
Respirator for Organic Vapors. A positive pressure, air-
supplying respirator may be appropriate if there is potential for
uncontrolled release, aerosolization, exposure levels are not
known, or other circumstances where air-purifying respirators
may not provide adequate protection.

Hand protection : The suitability for a specific workplace should be discussed


with the producers of the protective gloves. Please observe
the instructions regarding permeability and breakthrough time
which are provided by the supplier of the gloves. Also take into
consideration the specific local conditions under which the
product is used, such as the danger of cuts, abrasion, and the
contact time. Gloves should be discarded and replaced if there
is any indication of degradation or chemical breakthrough.

Eye protection : Eye wash bottle with pure water. Tightly fitting safety goggles.

SDS Number:100000013879 12/55


SAFETY DATA SHEET
Diesel No. 2 Test Fuel
Version 1.12 Revision Date 2024-05-21
Skin and body protection : Choose body protection in relation to its type, to the
concentration and amount of dangerous substances, and to the
specific work-place. Wear as appropriate:. Flame retardant
antistatic protective clothing. Workers should wear antistatic
footwear.

Hygiene measures : When using do not eat or drink. When using do not smoke.
Wash hands before breaks and at the end of workday.

For additional details, see the Exposure Scenario in the Annex portion

SECTION 9: Physical and chemical properties

9.1
Information on basic physical and chemical properties
Appearance
Form : liquid
Physical state : liquid
Color : Pale yellow to brown (if undyed), red to purple (dyed)
Odor : Mild

Safety data
Flash point : 47°C (117°F)
minimum

Lower explosion limit : No data available

Upper explosion limit : No data available

Oxidizing properties : no

Autoignition temperature : No data available

Molecular formula : UVCB

Molecular weight : Not applicable

pH : Not applicable

Pour point : No data available

Melting point/freezing point No data available

Boiling point/boiling range : 191-343°C (376-649°F)

Vapor pressure : No data available

Relative density : 0,87


at 16 °C (61 °F)

Density : 0,75 - 0,90 g/cm3

Water solubility : negligible

SDS Number:100000013879 13/55


SAFETY DATA SHEET
Diesel No. 2 Test Fuel
Version 1.12 Revision Date 2024-05-21
Partition coefficient: n- : No data available
octanol/water
Viscosity, kinematic : 2,55 cSt
at 40°C (104°F)

Relative vapor density : No data available

Evaporation rate : No data available

Percent volatile : > 99 %

100 %

SECTION 10: Stability and reactivity

10.1

Reactivity : Stable under recommended storage conditions.

10.2

Chemical stability : This material is considered stable under normal ambient and
anticipated storage and handling conditions of temperature
and pressure.

10.3
Possibility of hazardous reactions

Hazardous reactions : Hazardous reactions: Hazardous polymerization does not


occur.

Hazardous reactions: Vapors may form explosive mixture with


air.

10.4
Conditions to avoid : Heat, flames and sparks.

10.5
Materials to avoid : May react with oxygen and strong oxidizing agents, such as
chlorates, nitrates, peroxides, etc.
10.6
Hazardous decomposition : Hydrocarbons
products Carbon oxides

Other data : No decomposition if stored and applied as directed.

SECTION 11: Toxicological information

11.1
Information on toxicological effects

Acute oral toxicity


Diesel fuel, no. 2 : LD50: > 5.000 mg/kg
SDS Number:100000013879 14/55
SAFETY DATA SHEET
Diesel No. 2 Test Fuel
Version 1.12 Revision Date 2024-05-21
Species: Rat
Sex: male and female
Method: OECD Test Guideline 401

Naphthalene LD50: 500 mg/kg


Method: Converted acute toxicity point estimate

Acute inhalation toxicity


Diesel fuel, no. 2 : LC50: 4,1 mg/l
Exposure time: 4 h
Species: Rat
Sex: male and female
Test atmosphere: dust/mist
Method: OECD Test Guideline 403
Test substance: yes

Acute dermal toxicity


Diesel fuel, no. 2 : LD50 Dermal: > 4.300 mg/kg
Species: Rabbit
Sex: male and female
Test substance: yes

Diesel No. 2 Test Fuel


Skin irritation : Skin irritation

Diesel No. 2 Test Fuel


Eye irritation : Vapors may cause irritation to the eyes, respiratory system
and the skin.

Diesel No. 2 Test Fuel


Sensitization : No data available

Repeated dose toxicity


Diesel fuel, no. 2 : Species: Rat, Male and female
Sex: Male and female
Application Route: Dermal
Dose: 0, 30, 125, 500 mg/kg
Exposure time: 13 wks
Number of exposures: daily, 5 days/week
NOEL: 30 mg/kg
Method: OECD Guideline 411
Target Organs: Thymus, Liver, Bone marrow
Information given is based on data obtained from similar
substances.

SDS Number:100000013879 15/55


SAFETY DATA SHEET
Diesel No. 2 Test Fuel
Version 1.12 Revision Date 2024-05-21
Species: Rat, Male and female
Sex: Male and female
Application Route: inhalation (dust/mist/fume)
Dose: 0, 0.35, 0.88, 1.71 mg/l
Exposure time: 13 wks
Number of exposures: Twice/wk
NOEL: > 1,71 mg/l
Method: OECD Guideline 413

Genotoxicity in vitro
Diesel fuel, no. 2 : Test Type: Ames test
Result: positive

Test Type: Mouse lymphoma assay


Result: negative

Naphthalene Test Type: Ames test


Result: negative

Test Type: Sister Chromatid Exchange Assay


Result: negative

Test Type: Unscheduled DNA synthesis assay


Result: negative

Genotoxicity in vivo
Diesel fuel, no. 2 : Test Type: Dominant lethal assay
Species: Mouse
Dose: 100 or 400 ppm
Result: negative

Naphthalene Test Type: Mouse micronucleus assay


Result: negative

Carcinogenicity
Diesel fuel, no. 2 : Species: Mouse
Sex: male
Dose: 0, 25 ul
Exposure time: lifetime
Number of exposures: 3 times/wk
Remarks: Moderate dermal carcinogen

Naphthalene Species: Mouse


Sex: male
Dose: 10, 30 ppm
Exposure time: 105 weeks
Number of exposures: 6 hours/day, 5 days/week
Test substance: yes
Print Date: No information available.
Remarks: No evidence of carcinogenicity

SDS Number:100000013879 16/55


SAFETY DATA SHEET
Diesel No. 2 Test Fuel
Version 1.12 Revision Date 2024-05-21
Species: Mouse
Sex: female
Dose: 10, 30 ppm
Exposure time: 105 weeks
Number of exposures: 6 hours/day, 5 days/week
Test substance: yes
Print Date: No information available.
Remarks: increased incidence of alveolar/bronchiolar
adenomas

Species: Rat
Sex: male and female
Dose: 10, 30, 60 ppm
Exposure time: 105 weeks
Number of exposures: 6 hours/day, 5 days/week
Test substance: yes
Print Date: No information available.
Remarks: nose respiratory epithelial adenoma, increased
incidence of olfactory neuroblastomas

Developmental Toxicity
Diesel fuel, no. 2 : Species: Rat
Application Route: Inhalation
Dose: 0, 86.9, 408.8 ppm
Number of exposures: 6 h/d
Test period: GD 6-15
Method: OECD Guideline 414
NOAEL Teratogenicity: 408.8 ppm
NOAEL Maternal: 408.8 ppm
Information given is based on data obtained from similar
substances.

Species: Rat
Application Route: Dermal
Dose: 30, 125, 500, 1000 mg/kg
Exposure time: daily
Test period: GD 0-20
Method: OECD Guideline 414
NOAEL Teratogenicity: 125 mg/kg
Information given is based on data obtained from similar
substances.

Naphthalene Species: Rabbit


Application Route: oral gavage
Dose: 40, 200, 400 mg/kg
Test period: 29 d, GD 6-18
NOAEL Teratogenicity: 400 mg/kg

Diesel No. 2 Test Fuel


Aspiration toxicity : May be fatal if swallowed and enters airways.

Specific Target Organ Toxicity (Repeated Exposure)


Diesel fuel, no. 2 : Target Organs: Liver, Blood, thymus
Assessment: May cause damage to organs through prolonged
or repeated exposure.

SDS Number:100000013879 17/55


SAFETY DATA SHEET
Diesel No. 2 Test Fuel
Version 1.12 Revision Date 2024-05-21
CMR effects
Diesel fuel, no. 2 : Carcinogenicity: Limited evidence of carcinogenicity in animal
studies
Teratogenicity: Animal testing did not show any effects on
fetal development.

Naphthalene Carcinogenicity: Limited evidence of carcinogenicity in animal


studies

11.2
Information on other hazards

Diesel No. 2 Test Fuel


Further information : Solvents may degrease the skin.
Endocrine disrupting : The substance/mixture does not contain components
properties considered to have endocrine disrupting properties according
to REACH Article 57(f) or Commission Delegated regulation
(EU) 2017/2100 or Commission Regulation (EU) 2018/605 at
levels of 0.1% or higher.

SECTION 12: Ecological information

12.1
Toxicity

Toxicity to fish

Diesel fuel, no. 2 : LL50: 21 mg/l


Exposure time: 96 h
Species: Oncorhynchus mykiss (rainbow trout)
semi-static test Method: OECD Test Guideline 203

Naphthalene LC50: 3,2 mg/l


Exposure time: 96 h
Species: Pimephales promelas (fathead minnow)

Toxicity to daphnia and other aquatic invertebrates

Diesel fuel, no. 2 : EC50: 2 mg/l


Exposure time: 48 h
Species: Daphnia magna (Water flea)
Method: OECD Test Guideline 202

Naphthalene LC50: 2,16 mg/l


Exposure time: 48 h
Species: Daphnia magna (Water flea)

Toxicity to algae

Diesel fuel, no. 2 : ErL50: 22 mg/l


Exposure time: 72 h
Species: Raphidocellus subcapitata (algae)
static test Analytical monitoring: no
Method: OECD Test Guideline 201

SDS Number:100000013879 18/55


SAFETY DATA SHEET
Diesel No. 2 Test Fuel
Version 1.12 Revision Date 2024-05-21
Naphthalene EC50: 2,96 mg/l
Exposure time: 48 h
Species: Selenastrum capricornutum (algae)

12.2
Persistence and degradability

Biodegradability

Diesel fuel, no. 2 : aerobic


Result: Not readily biodegradable.
57,5 %
Testing period: 28 d
Method: OECD Test Guideline 301F

12.3
Bioaccumulative potential

Bioaccumulation

Diesel fuel, no. 2 : Accumulation in aquatic organisms is expected.

12.4
Mobility in soil

Mobility

Diesel fuel, no. 2 : No data available

12.5
Results of PBT and vPvB assessment
Results of PBT assessment : This substance/mixture contains no components considered
to be either persistent, bioaccumulative and toxic (PBT), or
very persistent and very bioaccumulative (vPvB) at levels of
0.1% or higher.

12.6
Endocrine disrupting properties

Endocrine disrupting : The substance/mixture does not contain components


properties considered to have endocrine disrupting properties according
to REACH Article 57(f) or Commission Delegated regulation
(EU) 2017/2100 or Commission Regulation (EU) 2018/605 at
levels of 0.1% or higher.

12.7
Other adverse effects

Additional ecological : Toxic to aquatic life with long lasting effects.


information
12.8
Additional Information

Ecotoxicology Assessment
Short-term (acute) aquatic : Toxic to aquatic life.
hazard
Long-term (chronic) aquatic : Toxic to aquatic life with long lasting effects.

SDS Number:100000013879 19/55


SAFETY DATA SHEET
Diesel No. 2 Test Fuel
Version 1.12 Revision Date 2024-05-21
hazard

SECTION 13: Disposal considerations

13.1
Waste treatment methods
The information in this SDS pertains only to the product as shipped.
Use material for its intended purpose or recycle if possible. This material, if it must be discarded,
may meet the criteria of a hazardous waste as defined by US EPA under RCRA (40 CFR 261) or
other State and local regulations. Measurement of certain physical properties and analysis for
regulated components may be necessary to make a correct determination. If this material is
classified as a hazardous waste, federal law requires disposal at a licensed hazardous waste
disposal facility.

Product : The product should not be allowed to enter drains, water


courses or the soil. Do not contaminate ponds, waterways or
ditches with chemical or used container. Send to a licensed
waste management company.

Contaminated packaging : Empty remaining contents. Dispose of as unused product.


Do not re-use empty containers. Do not burn, or use a cutting
torch on, the empty drum.

For additional details, see the Exposure Scenario in the Annex portion

SECTION 14: Transport information


14.1 - 14.7
Transport information
The shipping descriptions shown here are for bulk shipments only, and may not apply to
shipments in non-bulk packages (see regulatory definition).

Consult the appropriate domestic or international mode-specific and quantity-specific Dangerous


Goods Regulations for additional shipping description requirements (e.g., technical name or names,
etc.) Therefore, the information shown here, may not always agree with the bill of lading shipping
description for the material. Flashpoints for the material may vary slightly between the SDS and the
bill of lading.

US DOT (UNITED STATES DEPARTMENT OF TRANSPORTATION)


UN1202, DIESEL FUEL, 3, III

IMO / IMDG (INTERNATIONAL MARITIME DANGEROUS GOODS)


UN1202, DIESEL FUEL, 3, III, (47 °C c.c.), MARINE POLLUTANT, (DIESEL FUEL)

IATA (INTERNATIONAL AIR TRANSPORT ASSOCIATION)


UN1202, DIESEL FUEL, 3, III

ADR (AGREEMENT ON DANGEROUS GOODS BY ROAD (EUROPE))


UN1202, DIESEL FUEL, 3, III, (D/E), ENVIRONMENTALLY HAZARDOUS, (DIESEL
FUEL)

RID (REGULATIONS CONCERNING THE INTERNATIONAL TRANSPORT OF


DANGEROUS GOODS (EUROPE))
SDS Number:100000013879 20/55
SAFETY DATA SHEET
Diesel No. 2 Test Fuel
Version 1.12 Revision Date 2024-05-21
30,UN1202,DIESEL FUEL, 3, III, ENVIRONMENTALLY HAZARDOUS, (DIESEL FUEL)

ADN (EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE


OF DANGEROUS GOODS BY INLAND WATERWAYS)
UN1202, DIESEL FUEL, 3, III, ENVIRONMENTALLY HAZARDOUS, (DIESEL FUEL)

Maritime transport in bulk according to IMO instruments

SECTION 15: Regulatory information

15.1
Safety, health and environmental regulations/legislation specific for the substance or mixture
National legislation
Commission Regulation (EU) 2020/878 of 18 June 2020 amending Regulation (EC) No 1907/2006 of
the European Parliament and of the Council on the Registration, Evaluation, Authorisation and
Restriction of Chemicals (REACH)

Water hazard class : WGK 2 water endangering


(Germany)

15.2
Chemical Safety Assessment
Components : Fuels, diesel, no. 2 270-676-1

Major Accident Hazard : 96/82/EC Update: 2003


Legislation Flammable.
6
Quantity 1: 5.000 t
Quantity 2: 50.000 t

: 96/82/EC Update: 2003


Dangerous for the environment
9b
Quantity 1: 200 t
Quantity 2: 500 t

: ZEU_SEVES3 Update:
FLAMMABLE LIQUIDS
P5c
Quantity 1: 5.000 t
Quantity 2: 50.000 t

: ZEU_SEVES3 Update:
ENVIRONMENTAL HAZARDS
E2
Quantity 1: 200 t
Quantity 2: 500 t

: ZEU_SEVES3 Update:
Petroleum products: (a) gasolines and naphthas, (b)
kerosenes (including jet fuels), (c) gas oils (including diesel
fuels, home heating oils and gas oil blending streams),(d)
heavy fuel oils (e) alternative fuels serving the same purposes
SDS Number:100000013879 21/55
SAFETY DATA SHEET
Diesel No. 2 Test Fuel
Version 1.12 Revision Date 2024-05-21
and with similar properties as regards flammability and
environmental hazards as the products referred to in points (a)
to (d)
34
Quantity 1: 2.500 t
Quantity 2: 25.000 t

Notification status
Europe REACH : This product is in full compliance according to REACH
regulation 1907/2006/EC.
Switzerland CH INV : On the inventory, or in compliance with the inventory
United States of America (USA) : On or in compliance with the active portion of the
TSCA TSCA inventory
Canada DSL : All components of this product are on the Canadian
DSL
Australia AIIC : On the inventory, or in compliance with the inventory
New Zealand NZIoC : This substance may be used as a single component
chemical under an appropriate group standard
Japan ENCS : On the inventory, or in compliance with the inventory
Korea KECI : All substances in this product were registered, notified
to be registered, or exempted from registration by
CPChem through an Only Representative according to
K-REACH regulations. Importation of this product is
permitted if the Korean Importer of Record was
included on CPChem’s notifications or if the Importer of
Record themselves notified the substances.

Philippines PICCS : On the inventory, or in compliance with the inventory


Taiwan TCSI : On the inventory, or in compliance with the inventory
China IECSC : On the inventory, or in compliance with the inventory

SECTION 16: Other information

NFPA Classification : Health Hazard: 2


Fire Hazard: 2
Reactivity Hazard: 0
2
2 0

Further information
Legacy SDS Number : CPC00523

Significant changes since the last version are highlighted in the margin. This version replaces all
previous versions.

The information in this SDS pertains only to the product as shipped.


The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and is
not to be considered a warranty or quality specification. The information relates only to the
specific material designated and may not be valid for such material used in combination with any
other materials or in any process, unless specified in the text.
SDS Number:100000013879 22/55
SAFETY DATA SHEET
Diesel No. 2 Test Fuel
Version 1.12 Revision Date 2024-05-21

Key or legend to abbreviations and acronyms used in the safety data sheet
ACGIH American Conference of LD50 Lethal Dose 50%
Government Industrial Hygienists
AIIC Australian Inventory of Industrial LOAEL Lowest Observed Adverse Effect
Chemicals Level
DSL Canada, Domestic Substances NFPA National Fire Protection Agency
List
NDSL Canada, Non-Domestic NIOSH National Institute for Occupational
Substances List Safety & Health
CNS Central Nervous System NTP National Toxicology Program
CAS Chemical Abstract Service NZloC New Zealand Inventory of
Chemicals
EC50 Effective Concentration NOAEL No Observable Adverse Effect
Level
EC50 Effective Concentration 50% NOEC No Observed Effect Concentration
EGEST EOSCA Generic Exposure OSHA Occupational Safety & Health
Scenario Tool Administration
EOSCA European Oilfield Specialty PEL Permissible Exposure Limit
Chemicals Association
EINECS European Inventory of Existing PICCS Philippines Inventory of
Chemical Substances Commercial Chemical Substances
MAK Germany Maximum Concentration PRNT Presumed Not Toxic
Values
GHS Globally Harmonized System RCRA Resource Conservation Recovery
Act
>= Greater Than or Equal To STEL Short-term Exposure Limit
IC50 Inhibition Concentration 50% SARA Superfund Amendments and
Reauthorization Act.
IARC International Agency for Research TLV Threshold Limit Value
on Cancer
IECSC Inventory of Existing Chemical TWA Time Weighted Average
Substances in China
ENCS Japan, Inventory of Existing and TSCA Toxic Substance Control Act
New Chemical Substances
KECI Korea, Existing Chemical UVCB Unknown or Variable Composition,
Inventory Complex Reaction Products, and
Biological Materials
<= Less Than or Equal To WHMIS Workplace Hazardous Materials
Information System
LC50 Lethal Concentration 50% ATE Acute toxicity estimate

Full text of H-Statements referred to under sections 2 and 3.


H226 Flammable liquid and vapor.
H228 Flammable solid.
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H332 Harmful if inhaled.
H351 Suspected of causing cancer.
H373 May cause damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H401 Toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.

SDS Number:100000013879 23/55


SAFETY DATA SHEET
Diesel No. 2 Test Fuel
Version 1.12 Revision Date 2024-05-21

Annex

1. Short title of Exposure Scenario: Manufacture

Main User Groups : SU 3: Industrial uses: Uses of substances as such or in


preparations at industrial sites
Sector of use : SU3, SU8, SU9: Industrial Manufacturing (all), Manufacture of
bulk, large scale chemicals (including petroleum products),
Manufacture of fine chemicals
Process category : PROC1: Use in closed process, no likelihood of exposure
PROC2: Use in closed, continuous process with occasional
controlled exposure
PROC3: Use in closed batch process (synthesis or
formulation)
PROC4: Use in batch and other process (synthesis) where
opportunity for exposure arises
PROC8a: Transfer of substance or preparation
(charging/discharging) from/to vessels/large containers at
non-dedicated facilities
PROC8b: Transfer of substance or preparation (charging/
discharging) from/ to vessels/ large containers at dedicated
facilities
PROC15: Use as laboratory reagent
Environmental release category : ERC1: Manufacture of substances

Further information :
Manufacture of the substance or use as a process chemical or
extraction agent. Includes recycling/ recovery, material
transfers, storage, maintenance and loading (including marine
vessel/barge, road/rail car and bulk container), sampling and
associated laboratory activities

2.1 Contributing scenario controlling environmental exposure for:ERC1: Manufacture of


substances
Product characteristics
Remarks Substance is complex UVCB., Predominantly hydrophobic.

Maximum allowable site tonnage : 3.300


(MSafe) based on release
following total wastewater
treatment removal (tonnes/day):
(Msafe)

Environment factors not influenced by risk management


Flow rate : 18.000 m3/d
Dilution Factor (River) : 10
Dilution Factor (Coastal Areas) : 100

Other given operational conditions affecting environmental exposure


Continuous use/release
Number of emission days per year : 300
Emission or Release Factor: Air : 1%
Emission or Release Factor: Water : 0,003 %
Emission or Release Factor: Soil : 0,01 %

SDS Number:100000013879 24/55


SAFETY DATA SHEET
Diesel No. 2 Test Fuel
Version 1.12 Revision Date 2024-05-21

Technical conditions and measures / Organizational measures


Air : Treat air emission to provide a typical removal efficiency of
(%): (Effectiveness: 90 %)
Water : Treat onsite wastewater (prior to receiving water discharge) to
provide the required removal efficiency of ≥ (%):
(Effectiveness: 90,3 %)
Remarks : Common practices vary across sites thus conservative
process release estimates used.
Water : If discharging to domestic sewage treatment plant, provide the
required onsite wastewater removal efficiency of ≥ (%):
(Effectiveness: 0 %)
Remarks : Risk from environmental exposure is driven by freshwater
sediment.
Remarks : Prevent discharge of undissolved substance to or recover
from onsite wastewater.
Remarks : If discharging to domestic sewage treatment plant, no onsite
wastewater treatment required.
Remarks : Prevent discharge of undissolved substance to or recover
from wastewater.
Remarks : Do not apply industrial sludge to natural soils.
Remarks : Sludge should be incinerated, contained or reclaimed.

Conditions and measures related to municipal sewage treatment plant


Type of Sewage Treatment Plant : Municipal sewage treatment plant
Flow rate of sewage treatment : 10.000 m3/d
plant effluent
Effectiveness (of a measure) : 94,1 %
Percentage removed from waste : 94,1 %
water

Conditions and measures related to external treatment of waste for disposal


Waste treatment : During manufacturing no waste of the substance is generated.
Conditions and measures related to external recovery of waste
Recovery Methods : During manufacturing no waste of the substance is generated.

2.2 Contributing scenario controlling worker exposure for: PROC1: Use in closed
process, no likelihood of exposure

Product characteristics
Remarks Substance is complex UVCB., Predominantly hydrophobic.

Remarks : Liquid, vapour pressure < 0.5 kPa at STP


Remarks : With potential for aerosol generation.

Frequency and duration of use


Remarks : Covers daily exposures up to 8 hours (unless stated
differently)

Other operational conditions affecting workers exposure


Remarks : Operation is carried out at elevated temperature (> 20°C
above ambient temperature)., Assumes a good basic standard
of occupational hygiene is implemented.

Technical conditions and measures


Handle substance within a closed system., Store substance within a closed system.
Organizational measures to prevent /limit releases, dispersion and exposure
Avoid direct skin contact with product. Identify potential areas for indirect skin contact. Wear gloves
(tested to EN374) if hand contact with substance likely. Clean up contamination/spills as soon as they
SDS Number:100000013879 25/55
SAFETY DATA SHEET
Diesel No. 2 Test Fuel
Version 1.12 Revision Date 2024-05-21
occur. Wash off any skin contamination immediately. Provide basic employee training to prevent /
minimise exposures and to report any skin problems that may develop.
Conditions and measures related to personal protection, hygiene and health evaluation
Control any potential exposure using measures such as contained systems, properly designed and
maintained facilities and a good standard of general ventilation. Drain down systems and transfer lines
prior to breaking containment. Drain down and flush equipment where possible prior to maintenance.
Where there is potential for exposure: Ensure relevant staff are informed of exposure potential and
aware of basic actions to minimize exposures; ensure suitable personal protective equipment is
available; clear up spills and dispose of waste in accordance with regulatory requirements; monitor
effectiveness of control measures; provide regular health surveillance as appropriate; identify and
implement corrective actions.

2.2 Contributing scenario controlling worker exposure for: PROC2: Use in closed,
continuous process with occasional controlled exposure

Product characteristics
Remarks : Liquid, vapour pressure < 0.5 kPa at STP
Remarks : With potential for aerosol generation.

Frequency and duration of use


Remarks : Covers daily exposures up to 8 hours (unless stated
differently)

Other operational conditions affecting workers exposure


Remarks : Operation is carried out at elevated temperature (> 20°C
above ambient temperature)., Assumes a good basic standard
of occupational hygiene is implemented.

Technical conditions and measures


Handle substance within a closed system., Store substance within a closed system.

2.2 Contributing scenario controlling worker exposure for: PROC3: Use in closed batch
process (synthesis or formulation)

Product characteristics
Remarks : Liquid, vapour pressure < 0.5 kPa at STP
Remarks : With potential for aerosol generation.

Frequency and duration of use


Remarks : Covers daily exposures up to 8 hours (unless stated
differently)

Other operational conditions affecting workers exposure


Remarks : Operation is carried out at elevated temperature (> 20°C
above ambient temperature)., Assumes a good basic standard
of occupational hygiene is implemented.

Technical conditions and measures


Handle substance within a closed system.
Organizational measures to prevent /limit releases, dispersion and exposure
No other specific measures identified.

2.2 Contributing scenario controlling worker exposure for: PROC4: Use in batch and
other process (synthesis) where opportunity for exposure arises

Product characteristics

SDS Number:100000013879 26/55


SAFETY DATA SHEET
Diesel No. 2 Test Fuel
Version 1.12 Revision Date 2024-05-21
Remarks : Liquid, vapour pressure < 0.5 kPa at STP
Remarks : With potential for aerosol generation.

Frequency and duration of use


Remarks : Covers daily exposures up to 8 hours (unless stated
differently)

Other operational conditions affecting workers exposure


Remarks : Operation is carried out at elevated temperature (> 20°C
above ambient temperature)., Assumes a good basic standard
of occupational hygiene is implemented.

Conditions and measures related to personal protection, hygiene and health evaluation
Wear suitable gloves tested to EN374.

2.2 Contributing scenario controlling worker exposure for: PROC8a: Transfer of


substance or preparation (charging/discharging) from/to vessels/large containers at
non-dedicated facilities

Product characteristics
Remarks : Liquid, vapour pressure < 0.5 kPa at STP
Remarks : With potential for aerosol generation.

Frequency and duration of use


Remarks : Covers daily exposures up to 8 hours (unless stated
differently)

Other operational conditions affecting workers exposure


Remarks : Operation is carried out at elevated temperature (> 20°C
above ambient temperature)., Assumes a good basic standard
of occupational hygiene is implemented.

Technical conditions and measures


Drain down system prior to equipment opening or maintenance.
Conditions and measures related to personal protection, hygiene and health evaluation
Wear chemically resistant gloves (tested to EN374) in combination with ‘basic’ employee training.

2.2 Contributing scenario controlling worker exposure for: PROC8b: Transfer of


substance or preparation (charging/ discharging) from/ to vessels/ large containers at
dedicated facilities

Product characteristics
Remarks : Liquid, vapour pressure < 0.5 kPa at STP
Remarks : With potential for aerosol generation.

Frequency and duration of use


Remarks : Covers daily exposures up to 8 hours (unless stated
differently)

Other operational conditions affecting workers exposure


Remarks : Operation is carried out at elevated temperature (> 20°C
above ambient temperature)., Assumes a good basic standard
of occupational hygiene is implemented.

Technical conditions and measures


Handle substance within a closed system.
Conditions and measures related to personal protection, hygiene and health evaluation
Wear suitable gloves tested to EN374.
SDS Number:100000013879 27/55
SAFETY DATA SHEET
Diesel No. 2 Test Fuel
Version 1.12 Revision Date 2024-05-21

2.2 Contributing scenario controlling worker exposure for: PROC15: Use as laboratory
reagent

Product characteristics
Remarks : Liquid, vapour pressure < 0.5 kPa at STP
Remarks : With potential for aerosol generation.

Frequency and duration of use


Remarks : Covers daily exposures up to 8 hours (unless stated
differently)

Other operational conditions affecting workers exposure


Remarks : Operation is carried out at elevated temperature (> 20°C
above ambient temperature)., Assumes a good basic standard
of occupational hygiene is implemented.

Organizational measures to prevent /limit releases, dispersion and exposure


No other specific measures identified.

3. Exposure estimation and reference to its source

Environment
Contributing Exposure Specific Compartment Value type Level of Risk
Scenario Assessment conditions Exposure characterization
Method ratio (PEC/PNEC):
ERC1 Hydrocarbon Block Air 0,46 mg/m3
Method with
Petrorisk
Freshwater 0,036 mg/L 0,54
Freshwater 1,4 mg/kg wet 0,61
sediment weight
Marine water 0,0036 mg/L 0,054
Marine sediment 0,14 mg/kg 0,061
wet weight
Agricultural soil 0,17 mg/kg 0,015
wet weight
ERC1: Manufacture of substances

Workers/Consumers
Contributing Exposure Specific Value type Level of Exposure Risk characterization
Scenario Assessment conditions ratio (PEC/PNEC):
Method
PROC1, CS15 ECETOC TRA Worker – inhalation, 0,01 mg/m3 0,00
Modified long-term – systemic
Worker – dermal, long- 0,34 mg/kg/d 0,11
term – systemic
Worker – long-term – 0,11
systemic Combined
routes
PROC1, CS85 ECETOC TRA Worker – inhalation, 1 mg/m3 0,01
Modified long-term – systemic
Worker – dermal, long- 1,37 mg/kg/d 0,47
term – systemic
Worker – long-term – 0,49
systemic Combined
routes
PROC2, CS15, ECETOC TRA Worker – inhalation, 1 mg/m3 0,01
CS85 Modified long-term – systemic
Worker – dermal, long- 1,37 mg/kg/d 0,47
term – systemic
Worker – long-term – 0,49
SDS Number:100000013879 28/55
SAFETY DATA SHEET
Diesel No. 2 Test Fuel
Version 1.12 Revision Date 2024-05-21
systemic Combined
routes
PROC3, CS15 ECETOC TRA Worker – inhalation, 3 mg/m3 0,04
Modified long-term – systemic
Worker – dermal, long- 0,34 mg/kg/d 0,12
term – systemic
Worker – long-term – 0,16
systemic Combined
routes
PROC3, CS2 ECETOC TRA Worker – inhalation, 2,1 mg/m3 0,03
Modified long-term – systemic
Worker – dermal, long- 0,34 mg/kg/d 0,12
term – systemic
Worker – long-term – 0,15
systemic Combined
routes
PROC4, CS16 ECETOC TRA Worker – inhalation, 5 mg/m3 0,07
Modified long-term – systemic
Worker – dermal, long- 6,86 mg/kg/d 0,47
term – systemic
Worker – long-term – 0,55
systemic Combined
routes
PROC8a, CS39 ECETOC TRA Worker – inhalation, 2 mg/m3 0,03
Modified long-term – systemic
Worker – dermal, long- 13,71 mg/kg/d 0,47
term – systemic
Worker – long-term – 0,50
systemic Combined
routes
PROC8b, ECETOC TRA Worker – inhalation, 5 mg/m3 0,07
CS501, CS503 Modified long-term – systemic
Worker – dermal, long- 6,86 mg/kg/d 0,47
term – systemic
Worker – long-term – 0,55
systemic Combined
routes
PROC15, CS36 ECETOC TRA Worker – inhalation, 5 mg/m3 0,07
Modified long-term – systemic
Worker – dermal, long- 0,34 mg/kg/d 0,12
term – systemic
Worker – long-term – 0,19
systemic Combined
routes
PROC1: Use in closed process, no likelihood of exposure
CS15: General exposures (closed systems)
PROC1: Use in closed process, no likelihood of exposure
CS85: Bulk product storage
PROC2: Use in closed, continuous process with occasional controlled exposure
CS15: General exposures (closed systems)
CS85: Bulk product storage
PROC3: Use in closed batch process (synthesis or formulation)
CS15: General exposures (closed systems)
PROC3: Use in closed batch process (synthesis or formulation)
CS2: Process sampling
PROC4: Use in batch and other process (synthesis) where opportunity for exposure arises
CS16: General exposures (open systems)
PROC8a: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers
at non-dedicated facilities
CS39: Equipment cleaning and maintenance
PROC8b: Transfer of substance or preparation (charging/ discharging) from/ to vessels/ large
containers at dedicated facilities
CS501: Bulk closed loading and unloading
CS503: Bulk transfers (open systems)
PROC15: Use as laboratory reagent
CS36: Laboratory activities

SDS Number:100000013879 29/55


SAFETY DATA SHEET
Diesel No. 2 Test Fuel
Version 1.12 Revision Date 2024-05-21

4. Guidance to Downstream User to evaluate whether he works inside the boundaries set
by the Exposure Scenario

Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management
Measures/Operational Conditions outlined in Section 2 are implemented.
Where other Risk Management Measures/Operational Conditions are adopted, then users should
ensure that risks are managed to at least equivalent levels.
Available hazard data do not enable the derivation of a DNEL for dermal irritant effects.
Available hazard data do not support the need for a DNEL to be established for other health
effects.
Risk Management Measures are based on qualitative risk characterisation.Guidance is based on
assumed operating conditions which may not be applicable to all sites; thus, scaling may be
necessary to define appropriate site-specific risk management measures.

Required removal efficiency for wastewater can be achieved using onsite/offsite technologies,
either alone or in combination.
Required removal efficiency for air can be achieved using on-site technologies, either alone or in
combination.
Scaled local assessments for EU refineries have been performed using site-specific data and are
attached in PETRORISK file – “Site-Specific Production” worksheet.

If scaling reveals a condition of unsafe use (i.e., RCRs > 1), additional RMMs or a site-specific
chemical safety assessment is required.
Taking into account the findings of the air- monitoring evaluation on benzene included as the Tier
2 analysis in the Low Boiling Point Naphtha category, the default “Air Removal Efficiency” of 90%
included in the SPERC has been shown to be over- conservative and that the 95% efficiency can
safely be claimed in a Tier II analysis. On this basis, the Tier 2 analysis demonstrates that no
refineries have RCRs>1 (see PETRORISK file in IUCLID section 13- “Tier 2 Site Specific
Production worksheet”).

1. Short title of Exposure Scenario: Distribution

Main User Groups : SU 3: Industrial uses: Uses of substances as such or in


preparations at industrial sites
Sector of use : SU3: Industrial Manufacturing (all)
Process category : PROC1: Use in closed process, no likelihood of exposure
PROC2: Use in closed, continuous process with occasional
controlled exposure
PROC3: Use in closed batch process (synthesis or
formulation)
PROC4: Use in batch and other process (synthesis) where
opportunity for exposure arises
PROC8a: Transfer of substance or preparation
(charging/discharging) from/to vessels/large containers at
non-dedicated facilities
PROC8b: Transfer of substance or preparation (charging/
discharging) from/ to vessels/ large containers at dedicated
facilities
PROC9: Transfer of substance or preparation into small
containers (dedicated filling line, including weighing)
PROC15: Use as laboratory reagent
Environmental release category : ERC1, ERC2, ERC3, ERC4, ERC5, ERC6a, ERC6b, ERC6c,
ERC6d, ERC7: Manufacture of substances, Formulation of
preparations, Formulation in materials, Industrial use of
processing aids in processes and products, not becoming part
of articles, Industrial use resulting in inclusion into or onto a
matrix, Industrial use resulting in manufacture of another
substance (use of intermediates), Industrial use of reactive
SDS Number:100000013879 30/55
SAFETY DATA SHEET
Diesel No. 2 Test Fuel
Version 1.12 Revision Date 2024-05-21
processing aids, Industrial use of monomers for manufacture
of thermoplastics, Industrial use of process regulators for
polymerisation processes in production of resins, rubbers,
polymers, Industrial use of substances in closed systems

Further information :
Bulk loading (including marine vessel/barge, rail/road car and
IBC loading) and repacking (including drums and small packs)
of substance, including its sampling, storage, unloading,
maintenance and associated laboratory activities. Excludes
emissions during transport.

2.1 Contributing scenario controlling environmental exposure for:ERC1, ERC2, ERC3,


ERC4, ERC5, ERC6a, ERC6b, ERC6c, ERC6d, ERC7: Manufacture of substances,
Formulation of preparations, Formulation in materials, Industrial use of processing aids
in processes and products, not becoming part of articles, Industrial use resulting in
inclusion into or onto a matrix, Industrial use resulting in manufacture of another
substance (use of intermediates), Industrial use of reactive processing aids, Industrial
use of monomers for manufacture of thermoplastics, Industrial use of process
regulators for polymerisation processes in production of resins, rubbers, polymers,
Industrial use of substances in closed systems
Product characteristics
Remarks Substance is complex UVCB., Predominantly hydrophobic.

Maximum allowable site tonnage : 2.900


(MSafe) based on release
following total wastewater
treatment removal (tonnes/day):
(Msafe)

Environment factors not influenced by risk management


Flow rate : 18.000 m3/d
Dilution Factor (River) : 10
Dilution Factor (Coastal Areas) : 100

Other given operational conditions affecting environmental exposure


Continuous use/release
Number of emission days per year : 300
Emission or Release Factor: Air : 0,1 %
Emission or Release Factor: Water : 0,0001 %
Emission or Release Factor: Soil : 0,001 %

Technical conditions and measures / Organizational measures


Air : Treat air emission to provide a typical removal efficiency of
(%): (Effectiveness: 90 %)
Water : Treat onsite wastewater (prior to receiving water discharge) to
provide the required removal efficiency of ≥ (%):
(Effectiveness: 0 %)
Remarks : Common practices vary across sites thus conservative
process release estimates used.
Water : If discharging to domestic sewage treatment plant, provide the
required onsite wastewater removal efficiency of ≥ (%):
(Effectiveness: 0 %)
Remarks : Prevent discharge of undissolved substance to or recover

SDS Number:100000013879 31/55


SAFETY DATA SHEET
Diesel No. 2 Test Fuel
Version 1.12 Revision Date 2024-05-21
from onsite wastewater.
Remarks : Risk from environmental exposure is driven by humans via
indirect exposure (primarily ingestion).
Remarks : No wastewater treatment required.
Remarks : Prevent discharge of undissolved substance to or recover
from wastewater.
Remarks : Do not apply industrial sludge to natural soils.
Remarks : Sludge should be incinerated, contained or reclaimed.

Conditions and measures related to municipal sewage treatment plant


Type of Sewage Treatment Plant : Municipal sewage treatment plant
Flow rate of sewage treatment : 2.000 m3/d
plant effluent
Effectiveness (of a measure) : 94,1 %
Percentage removed from waste : 94,1 %
water

Conditions and measures related to external treatment of waste for disposal


Waste treatment : External treatment and disposal of waste should comply with
applicable local and/or national regulations.
Conditions and measures related to external recovery of waste
Recovery Methods : External recovery and recycling of waste should comply with
applicable local and/or national regulations.

2.2 Contributing scenario controlling worker exposure for: PROC1: Use in closed
process, no likelihood of exposure

Product characteristics
Remarks Substance is complex UVCB., Predominantly hydrophobic.

Remarks : Liquid, vapour pressure < 0.5 kPa at STP


Remarks : With potential for aerosol generation.

Frequency and duration of use


Remarks : Covers daily exposures up to 8 hours (unless stated
differently)

Other operational conditions affecting workers exposure


Remarks : Assumes use at not more than 20°C above ambient
temperature, unless stated differently., Assumes a good basic
standard of occupational hygiene is implemented.

Technical conditions and measures


Avoid direct skin contact with product. Identify potential areas for indirect skin contact. Wear gloves
(tested to EN374) if hand contact with substance is likely. Clean up contamination/spills as soon as
they occur. Wash off skin contamination immediately. Provide basic employee training to
prevent/minimize exposures and to report any skin effects that may develop., Handle substance within a
closed system., Store substance within a closed system.
Conditions and measures related to personal protection, hygiene and health evaluation
Control any potential exposure using measures such as contained systems, properly designed and
maintained facilities and a good standard of general ventilation. Drain down systems and transfer lines
prior to breaking containment. Drain down and flush equipment where possible prior to maintenance.
Where there is potential for exposure: Ensure relevant staff are informed of exposure potential and
aware of basic actions to minimize exposures; ensure suitable personal protective equipment is
available; clear up spills and dispose of waste in accordance with regulatory requirements; monitor
effectiveness of control measures; provide regular health surveillance as appropriate; identify and
implement corrective actions.

SDS Number:100000013879 32/55


SAFETY DATA SHEET
Diesel No. 2 Test Fuel
Version 1.12 Revision Date 2024-05-21

2.2 Contributing scenario controlling worker exposure for: PROC2: Use in closed,
continuous process with occasional controlled exposure

Product characteristics
Remarks : Liquid, vapour pressure < 0.5 kPa at STP
Remarks : With potential for aerosol generation.

Frequency and duration of use


Remarks : Covers daily exposures up to 8 hours (unless stated
differently)

Other operational conditions affecting workers exposure


Remarks : Operation is carried out at elevated temperature (> 20°C
above ambient temperature)., Assumes a good basic standard
of occupational hygiene is implemented.

Technical conditions and measures


Handle substance within a closed system., Store substance within a closed system.

2.2 Contributing scenario controlling worker exposure for: PROC3: Use in closed batch
process (synthesis or formulation)

Product characteristics
Remarks : Liquid, vapour pressure < 0.5 kPa at STP
Remarks : With potential for aerosol generation.

Frequency and duration of use


Remarks : Covers daily exposures up to 8 hours (unless stated
differently)

Other operational conditions affecting workers exposure


Remarks : Operation is carried out at elevated temperature (> 20°C
above ambient temperature)., Assumes a good basic standard
of occupational hygiene is implemented.

Technical conditions and measures


Handle substance within a closed system.
Organizational measures to prevent /limit releases, dispersion and exposure
No other specific measures identified.

2.2 Contributing scenario controlling worker exposure for: PROC4: Use in batch and
other process (synthesis) where opportunity for exposure arises

Product characteristics
Remarks : Liquid, vapour pressure < 0.5 kPa at STP
Remarks : With potential for aerosol generation.

Frequency and duration of use


Remarks : Covers daily exposures up to 8 hours (unless stated
differently)

Other operational conditions affecting workers exposure


Remarks : Operation is carried out at elevated temperature (> 20°C
above ambient temperature)., Assumes a good basic standard
of occupational hygiene is implemented.

Conditions and measures related to personal protection, hygiene and health evaluation
Wear suitable gloves tested to EN374.
SDS Number:100000013879 33/55
SAFETY DATA SHEET
Diesel No. 2 Test Fuel
Version 1.12 Revision Date 2024-05-21

2.2 Contributing scenario controlling worker exposure for: PROC8a: Transfer of


substance or preparation (charging/discharging) from/to vessels/large containers at
non-dedicated facilities

Product characteristics
Remarks : Liquid, vapour pressure < 0.5 kPa at STP
Remarks : With potential for aerosol generation.

Frequency and duration of use


Remarks : Covers daily exposures up to 8 hours (unless stated
differently)

Other operational conditions affecting workers exposure


Remarks : Operation is carried out at elevated temperature (> 20°C
above ambient temperature)., Assumes a good basic standard
of occupational hygiene is implemented.

Technical conditions and measures


Drain down system prior to equipment opening or maintenance.
Conditions and measures related to personal protection, hygiene and health evaluation
Wear chemically resistant gloves (tested to EN374) in combination with ‘basic’ employee training.

2.2 Contributing scenario controlling worker exposure for: PROC8b: Transfer of


substance or preparation (charging/ discharging) from/ to vessels/ large containers at
dedicated facilities

Product characteristics
Remarks : Liquid, vapour pressure < 0.5 kPa at STP
Remarks : With potential for aerosol generation.

Frequency and duration of use


Remarks : Covers daily exposures up to 8 hours (unless stated
differently)

Other operational conditions affecting workers exposure


Remarks : Operation is carried out at elevated temperature (> 20°C
above ambient temperature)., Assumes a good basic standard
of occupational hygiene is implemented.

Technical conditions and measures


Handle substance within a closed system.
Conditions and measures related to personal protection, hygiene and health evaluation
Wear suitable gloves tested to EN374.

2.2 Contributing scenario controlling worker exposure for: PROC9: Transfer of


substance or preparation into small containers (dedicated filling line, including
weighing)

Product characteristics
Remarks : Liquid, vapour pressure < 0.5 kPa at STP
Remarks : With potential for aerosol generation.

Frequency and duration of use


Remarks : Covers daily exposures up to 8 hours (unless stated
differently)

SDS Number:100000013879 34/55


SAFETY DATA SHEET
Diesel No. 2 Test Fuel
Version 1.12 Revision Date 2024-05-21
Other operational conditions affecting workers exposure
Remarks : Operation is carried out at elevated temperature (> 20°C
above ambient temperature)., Assumes a good basic standard
of occupational hygiene is implemented.

Conditions and measures related to personal protection, hygiene and health evaluation
Wear suitable gloves tested to EN374.

2.2 Contributing scenario controlling worker exposure for: PROC15: Use as laboratory
reagent

Product characteristics
Remarks : Liquid, vapour pressure < 0.5 kPa at STP
Remarks : With potential for aerosol generation.

Frequency and duration of use


Remarks : Covers daily exposures up to 8 hours (unless stated
differently)

Other operational conditions affecting workers exposure


Remarks : Operation is carried out at elevated temperature (> 20°C
above ambient temperature)., Assumes a good basic standard
of occupational hygiene is implemented.

Organizational measures to prevent /limit releases, dispersion and exposure


No other specific measures identified.

3. Exposure estimation and reference to its source

Environment
Contributing Exposure Specific Compartment Value type Level of Risk
Scenario Assessment conditions Exposure characterization
Method ratio (PEC/PNEC):
ERC1, ERC2, Hydrocarbon Block Air 0,024 mg/m3
ERC3, ERC4, Method with
ERC5, ERC6a, Petrorisk
ERC6b, ERC6c,
ERC6d, ERC7
Freshwater 0,0018 mg/L 0,048
Freshwater 1,4 mg/kg wet 0,055
sediment weight
Marine water 0,000057 0,00083
mg/L
Marine sediment 0,064 mg/kg 0,0019
wet weight
Agricultural soil 0,17 mg/kg 0,0017
wet weight
ERC1: Manufacture of substances
ERC2: Formulation of preparations
ERC3: Formulation in materials
ERC4: Industrial use of processing aids in processes and products, not becoming part of articles
ERC5: Industrial use resulting in inclusion into or onto a matrix
ERC6a: Industrial use resulting in manufacture of another substance (use of intermediates)
ERC6b: Industrial use of reactive processing aids
ERC6c: Industrial use of monomers for manufacture of thermoplastics
ERC6d: Industrial use of process regulators for polymerisation processes in production of resins,
rubbers, polymers
ERC7: Industrial use of substances in closed systems

Workers/Consumers
SDS Number:100000013879 35/55
SAFETY DATA SHEET
Diesel No. 2 Test Fuel
Version 1.12 Revision Date 2024-05-21

Contributing Exposure Specific Value type Level of Exposure Risk characterization


Scenario Assessment conditions ratio (PEC/PNEC):
Method
PROC1, CS15 ECETOC TRA Worker – inhalation, 0,01 mg/m3 0,00
Modified long-term – systemic
Worker – dermal, long- 0,34 mg/kg/d 0,12
term – systemic
Worker – long-term – 0,12
systemic Combined
routes
PROC1, CS67 ECETOC TRA Worker – inhalation, 1 mg/m3 0,01
Modified long-term – systemic
Worker – dermal, long- 1,37 mg/kg/d 0,47
term – systemic
Worker – long-term – 0,49
systemic Combined
routes
PROC2, CS15, ECETOC TRA Worker – inhalation, 1 mg/m3 0,01
CS67 Modified long-term – systemic
Worker – dermal, long- 1,37 mg/kg/d 0,47
term – systemic
Worker – long-term – 0,49
systemic Combined
routes
PROC3, CS2 ECETOC TRA Worker – inhalation, 3 mg/m3 0,04
Modified long-term – systemic
Worker – dermal, long- 0,34 mg/kg/d 0,12
term – systemic
Worker – long-term – 0,16
systemic Combined
routes
PROC4, CS16 ECETOC TRA Worker – inhalation, 5 mg/m3 0,07
Modified long-term – systemic
Worker – dermal, long- 6,86 mg/kg/d 0,47
term – systemic
Worker – long-term – 0,55
systemic Combined
routes
PROC8a, CS39 ECETOC TRA Worker – inhalation, 2 mg/m3 0,03
Modified long-term – systemic
Worker – dermal, long- 13,71 mg/kg/d 0,47
term – systemic
Worker – long-term – 0,50
systemic Combined
routes
PROC8b, ECETOC TRA Worker – inhalation, 5 mg/m3 0,07
CS501, CS503 Modified long-term – systemic
Worker – dermal, long- 6,86 mg/kg/d 0,47
term – systemic
Worker – long-term – 0,55
systemic Combined
routes
PROC9, CS6 ECETOC TRA Worker – inhalation, 5 mg/m3 0,07
Modified long-term – systemic
Worker – dermal, long- 6,86 mg/kg/d 0,47
term – systemic
Worker – long-term – 0,55
systemic Combined
routes
PROC15, CS36 ECETOC TRA Worker – inhalation, 5 mg/m3 0,07
Modified long-term – systemic
Worker – dermal, long- 0,34 mg/kg/d 0,12
term – systemic
Worker – long-term – 0,19
systemic Combined
routes
PROC1: Use in closed process, no likelihood of exposure
CS15: General exposures (closed systems)
PROC1: Use in closed process, no likelihood of exposure
CS67: Storage
PROC2: Use in closed, continuous process with occasional controlled exposure
SDS Number:100000013879 36/55
SAFETY DATA SHEET
Diesel No. 2 Test Fuel
Version 1.12 Revision Date 2024-05-21
CS15: General exposures (closed systems)
CS67: Storage
PROC3: Use in closed batch process (synthesis or formulation)
CS2: Process sampling
PROC4: Use in batch and other process (synthesis) where opportunity for exposure arises
CS16: General exposures (open systems)
PROC8a: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers
at non-dedicated facilities
CS39: Equipment cleaning and maintenance
PROC8b: Transfer of substance or preparation (charging/ discharging) from/ to vessels/ large
containers at dedicated facilities
CS501: Bulk closed loading and unloading
CS503: Bulk transfers (open systems)
PROC9: Transfer of substance or preparation into small containers (dedicated filling line, including
weighing)
CS6: Drum and small package filling
PROC15: Use as laboratory reagent
CS36: Laboratory activities

4. Guidance to Downstream User to evaluate whether he works inside the boundaries set
by the Exposure Scenario

Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management
Measures/Operational Conditions outlined in Section 2 are implemented.
Where other Risk Management Measures/Operational Conditions are adopted, then users should
ensure that risks are managed to at least equivalent levels.
Available hazard data do not enable the derivation of a DNEL for dermal irritant effects.
Available hazard data do not support the need for a DNEL to be established for other health
effects.
Risk Management Measures are based on qualitative risk characterisation.Guidance is based on
assumed operating conditions which may not be applicable to all sites; thus, scaling may be
necessary to define appropriate site-specific risk management measures.

Required removal efficiency for wastewater can be achieved using onsite/offsite technologies,
either alone or in combination.
Required removal efficiency for air can be achieved using on-site technologies, either alone or in
combination.
Further details on scaling and control technologies are provided in SpERC factsheet
(http://cefic.org/en/reach-for-industries-libraries.html).

1. Short title of Exposure Scenario: Use as an intermediate

Main User Groups : SU 3: Industrial uses: Uses of substances as such or in


preparations at industrial sites
Sector of use : SU3, SU8, SU9: Industrial Manufacturing (all), Manufacture of
bulk, large scale chemicals (including petroleum products),
Manufacture of fine chemicals
Process category : PROC1: Use in closed process, no likelihood of exposure
PROC2: Use in closed, continuous process with occasional
controlled exposure
PROC3: Use in closed batch process (synthesis or
formulation)
PROC4: Use in batch and other process (synthesis) where
opportunity for exposure arises
PROC8a: Transfer of substance or preparation
(charging/discharging) from/to vessels/large containers at
non-dedicated facilities
PROC8b: Transfer of substance or preparation (charging/
SDS Number:100000013879 37/55
SAFETY DATA SHEET
Diesel No. 2 Test Fuel
Version 1.12 Revision Date 2024-05-21
discharging) from/ to vessels/ large containers at dedicated
facilities
PROC15: Use as laboratory reagent
Environmental release category : ERC6a: Industrial use resulting in manufacture of another
substance (use of intermediates)

Further information :
Use of substance as an intermediate (not related to Strictly
Controlled Conditions). Includes recycling/ recovery, material
transfers, storage, sampling, associated laboratory activities,
maintenance and loading (including marine vessel/barge,
road/rail car and bulk container).

2.1 Contributing scenario controlling environmental exposure for:ERC6a: Industrial use


resulting in manufacture of another substance (use of intermediates)
Product characteristics
Remarks Substance is complex UVCB., Predominantly hydrophobic.

Maximum allowable site tonnage : 410.000


(MSafe) based on release
following total wastewater
treatment removal (kg/d):(Msafe)

Environment factors not influenced by risk management


Flow rate : 18.000 m3/d
Dilution Factor (River) : 10
Dilution Factor (Coastal Areas) : 100

Other given operational conditions affecting environmental exposure


Continuous use/release
Number of emission days per year : 300
Emission or Release Factor: Air : 0,1 %
Emission or Release Factor: Water : 0,003 %
Emission or Release Factor: Soil : 0,1 %

Technical conditions and measures / Organizational measures


Air : Treat air emission to provide a typical removal efficiency of
(%): (Effectiveness: 80 %)
Water : Treat onsite wastewater (prior to receiving water discharge) to
provide the required removal efficiency of ≥ (%):
(Effectiveness: 51,6 %)
Remarks : Common practices vary across sites thus conservative
process release estimates used.
Water : If discharging to domestic sewage treatment plant, provide the
required onsite wastewater removal efficiency of ≥ (%):
(Effectiveness: 0 %)
Remarks : Risk from environmental exposure is driven by freshwater
sediment.
Remarks : Prevent discharge of undissolved substance to or recover
from onsite wastewater.
Remarks : If discharging to domestic sewage treatment plant, no onsite
wastewater treatment required.
Remarks : Prevent discharge of undissolved substance to or recover
from wastewater.
Remarks : Do not apply industrial sludge to natural soils.
Remarks : Sludge should be incinerated, contained or reclaimed.

SDS Number:100000013879 38/55


SAFETY DATA SHEET
Diesel No. 2 Test Fuel
Version 1.12 Revision Date 2024-05-21

Conditions and measures related to municipal sewage treatment plant


Type of Sewage Treatment Plant : Municipal sewage treatment plant
Flow rate of sewage treatment : 2.000 m3/d
plant effluent
Effectiveness (of a measure) : 94,1 %
Percentage removed from waste : 94,1 %
water

Conditions and measures related to external treatment of waste for disposal


Waste treatment : This substance is consumed during use and no waste of the
substance is generated.
Conditions and measures related to external recovery of waste
Recovery Methods : This substance is consumed during use and no waste of the
substance is generated.

2.2 Contributing scenario controlling worker exposure for: PROC1: Use in closed
process, no likelihood of exposure

Product characteristics
Remarks Substance is complex UVCB., Predominantly hydrophobic.

Remarks : Liquid, vapour pressure < 0.5 kPa at STP


Remarks : With potential for aerosol generation.

Frequency and duration of use


Remarks : Covers daily exposures up to 8 hours (unless stated
differently)

Other operational conditions affecting workers exposure


Remarks : Operation is carried out at elevated temperature (> 20°C
above ambient temperature)., Assumes a good basic standard
of occupational hygiene is implemented.

Technical conditions and measures


Avoid direct skin contact with product. Identify potential areas for indirect skin contact. Wear gloves
(tested to EN374) if hand contact with substance is likely. Clean up contamination/spills as soon as
they occur. Wash off skin contamination immediately. Provide basic employee training to
prevent/minimize exposures and to report any skin effects that may develop., Handle substance within a
closed system., Store substance within a closed system.
Conditions and measures related to personal protection, hygiene and health evaluation
Control any potential exposure using measures such as contained systems, properly designed and
maintained facilities and a good standard of general ventilation. Drain down systems and transfer lines
prior to breaking containment. Drain down and flush equipment where possible prior to maintenance.
Where there is potential for exposure: Ensure relevant staff are informed of exposure potential and
aware of basic actions to minimize exposures; ensure suitable personal protective equipment is
available; clear up spills and dispose of waste in accordance with regulatory requirements; monitor
effectiveness of control measures; provide regular health surveillance as appropriate; identify and
implement corrective actions.

2.2 Contributing scenario controlling worker exposure for: PROC2: Use in closed,
continuous process with occasional controlled exposure

Product characteristics
Remarks : Liquid, vapour pressure < 0.5 kPa at STP
Remarks : With potential for aerosol generation.

SDS Number:100000013879 39/55


SAFETY DATA SHEET
Diesel No. 2 Test Fuel
Version 1.12 Revision Date 2024-05-21
Frequency and duration of use
Remarks : Covers daily exposures up to 8 hours (unless stated
differently)

Other operational conditions affecting workers exposure


Remarks : Operation is carried out at elevated temperature (> 20°C
above ambient temperature)., Assumes a good basic standard
of occupational hygiene is implemented.

Technical conditions and measures


Handle substance within a closed system., Store substance within a closed system.

2.2 Contributing scenario controlling worker exposure for: PROC3: Use in closed batch
process (synthesis or formulation)

Product characteristics
Remarks : Liquid, vapour pressure < 0.5 kPa at STP
Remarks : With potential for aerosol generation.

Frequency and duration of use


Remarks : Covers daily exposures up to 8 hours (unless stated
differently)

Other operational conditions affecting workers exposure


Remarks : Operation is carried out at elevated temperature (> 20°C
above ambient temperature)., Assumes a good basic standard
of occupational hygiene is implemented.

Technical conditions and measures


Handle substance within a closed system.
Organizational measures to prevent /limit releases, dispersion and exposure
No other specific measures identified.

2.2 Contributing scenario controlling worker exposure for: PROC4: Use in batch and
other process (synthesis) where opportunity for exposure arises

Product characteristics
Remarks : Liquid, vapour pressure < 0.5 kPa at STP

Frequency and duration of use


Remarks : Covers daily exposures up to 8 hours (unless stated
differently)

Other operational conditions affecting workers exposure


Remarks : Operation is carried out at elevated temperature (> 20°C
above ambient temperature)., Assumes a good basic standard
of occupational hygiene is implemented.

Conditions and measures related to personal protection, hygiene and health evaluation
Wear suitable gloves tested to EN374.

2.2 Contributing scenario controlling worker exposure for: PROC8a: Transfer of


substance or preparation (charging/discharging) from/to vessels/large containers at
non-dedicated facilities

Product characteristics
Remarks : Liquid, vapour pressure < 0.5 kPa at STP

SDS Number:100000013879 40/55


SAFETY DATA SHEET
Diesel No. 2 Test Fuel
Version 1.12 Revision Date 2024-05-21
Remarks : With potential for aerosol generation.

Frequency and duration of use


Remarks : Covers daily exposures up to 8 hours (unless stated
differently)

Other operational conditions affecting workers exposure


Remarks : Operation is carried out at elevated temperature (> 20°C
above ambient temperature)., Assumes a good basic standard
of occupational hygiene is implemented.

Technical conditions and measures


Drain down system prior to equipment opening or maintenance.
Conditions and measures related to personal protection, hygiene and health evaluation
Wear chemically resistant gloves (tested to EN374) in combination with ‘basic’ employee training.

2.2 Contributing scenario controlling worker exposure for: PROC8b: Transfer of


substance or preparation (charging/ discharging) from/ to vessels/ large containers at
dedicated facilities

Product characteristics
Remarks : Liquid, vapour pressure < 0.5 kPa at STP
Remarks : With potential for aerosol generation.

Frequency and duration of use


Remarks : Covers daily exposures up to 8 hours (unless stated
differently)

Other operational conditions affecting workers exposure


Remarks : Operation is carried out at elevated temperature (> 20°C
above ambient temperature)., Assumes a good basic standard
of occupational hygiene is implemented.

Technical conditions and measures


Handle substance within a closed system.
Conditions and measures related to personal protection, hygiene and health evaluation
Wear suitable gloves tested to EN374.

2.2 Contributing scenario controlling worker exposure for: PROC15: Use as laboratory
reagent

Product characteristics
Remarks : Liquid, vapour pressure < 0.5 kPa at STP
Remarks : With potential for aerosol generation.

Frequency and duration of use


Remarks : Covers daily exposures up to 8 hours (unless stated
differently)

Other operational conditions affecting workers exposure


Remarks : Operation is carried out at elevated temperature (> 20°C
above ambient temperature)., Assumes a good basic standard
of occupational hygiene is implemented.

Organizational measures to prevent /limit releases, dispersion and exposure


No other specific measures identified.

3. Exposure estimation and reference to its source


SDS Number:100000013879 41/55
SAFETY DATA SHEET
Diesel No. 2 Test Fuel
Version 1.12 Revision Date 2024-05-21

Environment
Contributing Exposure Specific Compartment Value type Level of Risk
Scenario Assessment conditions Exposure characterization
Method ratio (PEC/PNEC):
ERC6a Hydrocarbon Block Air 0,022 mg/m3
Method with
Petrorisk
Freshwater 0,0045 mg/L 0,067
Freshwater 1,5 mg/kg wet 0,12
sediment weight
Marine water 0,000057 0,0067
mg/L
Marine sediment 0,079 mg/kg 0,085
wet weight
Agricultural soil 0,17 mg/kg 0,0017
wet weight
ERC6a: Industrial use resulting in manufacture of another substance (use of intermediates)

Workers/Consumers
Contributing Exposure Specific Value type Level of Exposure Risk characterization
Scenario Assessment conditions ratio (PEC/PNEC):
Method
PROC1, CS15 ECETOC TRA Worker – inhalation, 0,01 mg/m3 0,00
Modified long-term – systemic
Worker – dermal, long- 0,34 mg/kg/d 0,11
term – systemic
Worker – long-term – 0,11
systemic Combined
routes
PROC1, CS85 ECETOC TRA Worker – inhalation, 1 mg/m3 0,01
Modified long-term – systemic
Worker – dermal, long- 1,37 mg/kg/d 0,47
term – systemic
Worker – long-term – 0,49
systemic Combined
routes
PROC2, CS15, ECETOC TRA Worker – inhalation, 1 mg/m3 0,01
CS85 Modified long-term – systemic
Worker – dermal, long- 1,37 mg/kg/d 0,47
term – systemic
Worker – long-term – 0,49
systemic Combined
routes
PROC3, CS15 ECETOC TRA Worker – inhalation, 3 mg/m3 0,04
Modified long-term – systemic
Worker – dermal, long- 0,34 mg/kg/d 0,12
term – systemic
Worker – long-term – 0,16
systemic Combined
routes
PROC3, CS2 ECETOC TRA Worker – inhalation, 2,1 mg/m3 0,03
Modified long-term – systemic
Worker – dermal, long- 0,34 mg/kg/d 0,12
term – systemic
Worker – long-term – 0,15
systemic Combined
routes
PROC4, CS16 ECETOC TRA Worker – inhalation, 5 mg/m3 0,07
Modified long-term – systemic
Worker – dermal, long- 6,86 mg/kg/d 0,47
term – systemic
Worker – long-term – 0,55
systemic Combined
routes
PROC8a, CS39 ECETOC TRA Worker – inhalation, 2 mg/m3 0,03
Modified long-term – systemic
Worker – dermal, long- 13,71 mg/kg/d 0,47

SDS Number:100000013879 42/55


SAFETY DATA SHEET
Diesel No. 2 Test Fuel
Version 1.12 Revision Date 2024-05-21
term – systemic
Worker – long-term – 0,50
systemic Combined
routes
PROC8b, ECETOC TRA Worker – inhalation, 5 mg/m3 0,07
CS501, CS503 Modified long-term – systemic
Worker – dermal, long- 6,86 mg/kg/d 0,47
term – systemic
Worker – long-term – 0,55
systemic Combined
routes
PROC15, CS36 ECETOC TRA Worker – inhalation, 5 mg/m3 0,07
Modified long-term – systemic
Worker – dermal, long- 0,34 mg/kg/d 0,12
term – systemic
Worker – long-term – 0,19
systemic Combined
routes
PROC1: Use in closed process, no likelihood of exposure
CS15: General exposures (closed systems)
PROC1: Use in closed process, no likelihood of exposure
CS85: Bulk product storage
PROC2: Use in closed, continuous process with occasional controlled exposure
CS15: General exposures (closed systems)
CS85: Bulk product storage
PROC3: Use in closed batch process (synthesis or formulation)
CS15: General exposures (closed systems)
PROC3: Use in closed batch process (synthesis or formulation)
CS2: Process sampling
PROC4: Use in batch and other process (synthesis) where opportunity for exposure arises
CS16: General exposures (open systems)
PROC8a: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers
at non-dedicated facilities
CS39: Equipment cleaning and maintenance
PROC8b: Transfer of substance or preparation (charging/ discharging) from/ to vessels/ large
containers at dedicated facilities
CS501: Bulk closed loading and unloading
CS503: Bulk transfers (open systems)
PROC15: Use as laboratory reagent
CS36: Laboratory activities

4. Guidance to Downstream User to evaluate whether he works inside the boundaries set
by the Exposure Scenario

Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management
Measures/Operational Conditions outlined in Section 2 are implemented.
Where other Risk Management Measures/Operational Conditions are adopted, then users should
ensure that risks are managed to at least equivalent levels.
Available hazard data do not enable the derivation of a DNEL for dermal irritant effects.
Available hazard data do not support the need for a DNEL to be established for other health
effects.
Risk Management Measures are based on qualitative risk characterisation.Guidance is based on
assumed operating conditions which may not be applicable to all sites; thus, scaling may be
necessary to define appropriate site-specific risk management measures.

Required removal efficiency for wastewater can be achieved using onsite/offsite technologies,
either alone or in combination.
Required removal efficiency for air can be achieved using on-site technologies, either alone or in
combination.
Further details on scaling and control technologies are provided in SpERC factsheet
(http://cefic.org/en/reach-for-industries-libraries.html).
SDS Number:100000013879 43/55
SAFETY DATA SHEET
Diesel No. 2 Test Fuel
Version 1.12 Revision Date 2024-05-21

1. Short title of Exposure Scenario: Use as a fuel - industrial

Main User Groups : SU 3: Industrial uses: Uses of substances as such or in


preparations at industrial sites
Sector of use : SU3: Industrial Manufacturing (all)
Process category : PROC1: Use in closed process, no likelihood of exposure
PROC2: Use in closed, continuous process with occasional
controlled exposure
PROC3: Use in closed batch process (synthesis or
formulation)
PROC8a: Transfer of substance or preparation
(charging/discharging) from/to vessels/large containers at
non-dedicated facilities
PROC8b: Transfer of substance or preparation (charging/
discharging) from/ to vessels/ large containers at dedicated
facilities
PROC16: Using material as fuel sources, limited exposure to
unburned product to be expected
Environmental release category : ERC7: Industrial use of substances in closed systems

Further information :
Covers the use as a fuel (or fuel additive) and includes
activities associated with its transfer, use, equipment
maintenance and handling of waste.

2.1 Contributing scenario controlling environmental exposure for:ERC7: Industrial use of


substances in closed systems
Product characteristics
Remarks Substance is complex UVCB., Predominantly hydrophobic.

Maximum allowable site tonnage : 5.000


(MSafe) based on release
following total wastewater
treatment removal (tonnes/day):
(Msafe)

Environment factors not influenced by risk management


Flow rate : 18.000 m3/d
Dilution Factor (River) : 10
Dilution Factor (Coastal Areas) : 100

Other given operational conditions affecting environmental exposure


Continuous use/release
Number of emission days per year : 300
Emission or Release Factor: Air : 0,5 %
Emission or Release Factor: Water : 0,001 %
Emission or Release Factor: Soil : 0%

Technical conditions and measures / Organizational measures


Air : Treat air emission to provide a typical removal efficiency of
(%): (Effectiveness: 95 %)
Water : Treat onsite wastewater (prior to receiving water discharge) to
provide the required removal efficiency of ≥ (%):
(Effectiveness: 97,7 %)
Remarks : Common practices vary across sites thus conservative
SDS Number:100000013879 44/55
SAFETY DATA SHEET
Diesel No. 2 Test Fuel
Version 1.12 Revision Date 2024-05-21
process release estimates used.
Water : If discharging to domestic sewage treatment plant, provide the
required onsite wastewater removal efficiency of ≥ (%):
(Effectiveness: 60,4 %)
Remarks : Risk from environmental exposure is driven by freshwater
sediment.
Remarks : If discharging to domestic sewage treatment plant, no onsite
wastewater treatment required.
Remarks : Prevent discharge of undissolved substance to or recover
from wastewater.
Remarks : Do not apply industrial sludge to natural soils.
Remarks : Sludge should be incinerated, contained or reclaimed.

Conditions and measures related to municipal sewage treatment plant


Type of Sewage Treatment Plant : Municipal sewage treatment plant
Flow rate of sewage treatment : 2.000 m3/d
plant effluent
Effectiveness (of a measure) : 94,1 %
Percentage removed from waste : 97,7 %
water

Conditions and measures related to external treatment of waste for disposal


Remarks : Combustion emissions limited by required exhaust emission
controls.
Remarks : Combustion emissions considered in regional exposure
assessment.
Conditions and measures related to external recovery of waste
Recovery Methods : External recovery and recycling of waste should comply with
applicable local and/or national regulations.

2.2 Contributing scenario controlling worker exposure for: PROC1: Use in closed
process, no likelihood of exposure

Product characteristics
Remarks Substance is complex UVCB., Predominantly hydrophobic.

Remarks : Liquid, vapour pressure < 0.5 kPa at STP


Remarks : With potential for aerosol generation.

Frequency and duration of use


Remarks : Covers daily exposures up to 8 hours (unless stated
differently)

Other operational conditions affecting workers exposure


Remarks : Assumes use at not more than 20°C above ambient
temperature, unless stated differently., Assumes a good basic
standard of occupational hygiene is implemented.

Technical conditions and measures


Avoid direct skin contact with product. Identify potential areas for indirect skin contact. Wear gloves
(tested to EN374) if hand contact with substance is likely. Clean up contamination/spills as soon as
they occur. Wash off skin contamination immediately. Provide basic employee training to
prevent/minimize exposures and to report any skin effects that may develop., Store substance within a
closed system.
Organizational measures to prevent /limit releases, dispersion and exposure
No other specific measures identified.
Conditions and measures related to personal protection, hygiene and health evaluation
Control any potential exposure using measures such as contained systems, properly designed and
maintained facilities and a good standard of general ventilation. Drain down systems and transfer lines
SDS Number:100000013879 45/55
SAFETY DATA SHEET
Diesel No. 2 Test Fuel
Version 1.12 Revision Date 2024-05-21
prior to breaking containment. Drain down and flush equipment where possible prior to maintenance.
Where there is potential for exposure: Ensure relevant staff are informed of exposure potential and
aware of basic actions to minimize exposures; ensure suitable personal protective equipment is
available; clear up spills and dispose of waste in accordance with regulatory requirements; monitor
effectiveness of control measures; provide regular health surveillance as appropriate; identify and
implement corrective actions.

2.2 Contributing scenario controlling worker exposure for: PROC2: Use in closed,
continuous process with occasional controlled exposure

Product characteristics
Remarks : Liquid, vapour pressure < 0.5 kPa at STP
Remarks : With potential for aerosol generation.

Frequency and duration of use


Remarks : Covers daily exposures up to 8 hours (unless stated
differently)

Other operational conditions affecting workers exposure


Remarks : Assumes use at not more than 20°C above ambient
temperature, unless stated differently., Assumes a good basic
standard of occupational hygiene is implemented.

Technical conditions and measures


Store substance within a closed system.

2.2 Contributing scenario controlling worker exposure for: PROC3: Use in closed batch
process (synthesis or formulation)

Product characteristics
Remarks : Liquid, vapour pressure < 0.5 kPa at STP
Remarks : With potential for aerosol generation.

Frequency and duration of use


Remarks : Covers daily exposures up to 8 hours (unless stated
differently)

Other operational conditions affecting workers exposure


Remarks : Assumes use at not more than 20°C above ambient
temperature, unless stated differently., Assumes a good basic
standard of occupational hygiene is implemented.

Organizational measures to prevent /limit releases, dispersion and exposure


No other specific measures identified.

2.2 Contributing scenario controlling worker exposure for: PROC8a: Transfer of


substance or preparation (charging/discharging) from/to vessels/large containers at
non-dedicated facilities

Product characteristics
Remarks : Liquid, vapour pressure < 0.5 kPa at STP
Remarks : With potential for aerosol generation.

Frequency and duration of use


Remarks : Covers daily exposures up to 8 hours (unless stated
differently)

SDS Number:100000013879 46/55


SAFETY DATA SHEET
Diesel No. 2 Test Fuel
Version 1.12 Revision Date 2024-05-21

Other operational conditions affecting workers exposure


Remarks : Assumes use at not more than 20°C above ambient
temperature, unless stated differently., Assumes a good basic
standard of occupational hygiene is implemented.

Technical conditions and measures


Drain down system prior to equipment opening or maintenance.
Conditions and measures related to personal protection, hygiene and health evaluation
Wear chemically resistant gloves (tested to EN374) in combination with ‘basic’ employee training.

2.2 Contributing scenario controlling worker exposure for: PROC8b: Transfer of


substance or preparation (charging/ discharging) from/ to vessels/ large containers at
dedicated facilities

Product characteristics
Remarks : Liquid, vapour pressure < 0.5 kPa at STP
Remarks : With potential for aerosol generation.

Frequency and duration of use


Remarks : Covers daily exposures up to 8 hours (unless stated
differently)

Other operational conditions affecting workers exposure


Remarks : Assumes use at not more than 20°C above ambient
temperature, unless stated differently., Assumes a good basic
standard of occupational hygiene is implemented.

Conditions and measures related to personal protection, hygiene and health evaluation
Wear suitable gloves tested to EN374.

2.2 Contributing scenario controlling worker exposure for: PROC16: Using material as
fuel sources, limited exposure to unburned product to be expected

Product characteristics
Remarks : Liquid, vapour pressure < 0.5 kPa at STP
Remarks : With potential for aerosol generation.

Frequency and duration of use


Remarks : Covers daily exposures up to 8 hours (unless stated
differently)

Other operational conditions affecting workers exposure


Remarks : Assumes use at not more than 20°C above ambient
temperature, unless stated differently., Assumes a good basic
standard of occupational hygiene is implemented.

Organizational measures to prevent /limit releases, dispersion and exposure


No other specific measures identified.

3. Exposure estimation and reference to its source

Environment
Contributing Exposure Specific Compartment Value type Level of Risk
Scenario Assessment conditions Exposure characterization
Method ratio (PEC/PNEC):
ERC7 Hydrocarbon Block Air 0,29 mg/m3
SDS Number:100000013879 47/55
SAFETY DATA SHEET
Diesel No. 2 Test Fuel
Version 1.12 Revision Date 2024-05-21
Method with
Petrorisk
Freshwater 0,055 mg/L 0,8
Freshwater 2,1 mg/kg wet 0,91
sediment weight
Marine water 0,0055 mg/L 0,08
Marine sediment 0,21 mg/kg 0,091
wet weight
Agricultural soil 0,17 mg/kg 0,01
wet weight
ERC7: Industrial use of substances in closed systems

Workers/Consumers
Contributing Exposure Specific Value type Level of Exposure Risk characterization
Scenario Assessment conditions ratio (PEC/PNEC):
Method
PROC1, CS15 ECETOC TRA Worker – inhalation, 1 mg/m3 0,01
Modified long-term – systemic
Worker – dermal, long- 1,37 mg/kg/d 0,47
term – systemic
Worker – long-term – 0,49
systemic Combined
routes
PROC1, CS67 ECETOC TRA Worker – inhalation, 1 mg/m3 0,01
Modified long-term – systemic
Worker – dermal, long- 0,14 mg/kg/d 0,05
term – systemic
Worker – long-term – 0,06
systemic Combined
routes
PROC2, CS15 ECETOC TRA Worker – inhalation, 1 mg/m3 0,01
Modified long-term – systemic
Worker – dermal, long- 1,37 mg/kg/d 0,47
term – systemic
Worker – long-term – 0,49
systemic Combined
routes
PROC2, CS67 ECETOC TRA Worker – inhalation, 1 mg/m3 0,01
Modified long-term – systemic
Worker – dermal, long- 0,14 mg/kg/d 0,05
term – systemic
Worker – long-term – 0,06
systemic Combined
routes
PROC3, CS107 ECETOC TRA Worker – inhalation, 1 mg/m3 0,01
Modified long-term – systemic
Worker – dermal, long- 0,34 mg/kg/d 0,12
term – systemic
Worker – long-term – 0,13
systemic Combined
routes
PROC8a, CS39, ECETOC TRA Worker – inhalation, 1 mg/m3 0,01
CS103 Modified long-term – systemic
Worker – dermal, long- 13,71 mg/kg/d 0,47
term – systemic
Worker – long-term – 0,49
systemic Combined
routes
PROC8b, CS8, ECETOC TRA Worker – inhalation, 5 mg/m3 0,07
CS14 Modified long-term – systemic
Worker – dermal, long- 6,86 mg/kg/d 0,47
term – systemic
Worker – long-term – 0,55
systemic Combined
routes
PROC16, CS107 ECETOC TRA Worker – inhalation, 1 mg/m3 0,03
Modified long-term – systemic
Worker – dermal, long- 0,03 mg/kg/d 0,01
term – systemic
Worker – long-term – 0,02

SDS Number:100000013879 48/55


SAFETY DATA SHEET
Diesel No. 2 Test Fuel
Version 1.12 Revision Date 2024-05-21
systemic Combined
routes
PROC1: Use in closed process, no likelihood of exposure
CS15: General exposures (closed systems)
PROC1: Use in closed process, no likelihood of exposure
CS67: Storage
PROC2: Use in closed, continuous process with occasional controlled exposure
CS15: General exposures (closed systems)
PROC2: Use in closed, continuous process with occasional controlled exposure
CS67: Storage
PROC3: Use in closed batch process (synthesis or formulation)
CS107: (closed systems)
PROC8a: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers
at non-dedicated facilities
CS39: Equipment cleaning and maintenance
CS103: Vessel and container cleaning
PROC8b: Transfer of substance or preparation (charging/ discharging) from/ to vessels/ large
containers at dedicated facilities
CS8: Drum/batch transfers
CS14: Bulk transfers
PROC16: Using material as fuel sources, limited exposure to unburned product to be expected
CS107: (closed systems)

4. Guidance to Downstream User to evaluate whether he works inside the boundaries set
by the Exposure Scenario

Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management
Measures/Operational Conditions outlined in Section 2 are implemented.
Where other Risk Management Measures/Operational Conditions are adopted, then users should
ensure that risks are managed to at least equivalent levels.
Available hazard data do not enable the derivation of a DNEL for dermal irritant effects.
Available hazard data do not support the need for a DNEL to be established for other health
effects.
Risk Management Measures are based on qualitative risk characterisation.Guidance is based on
assumed operating conditions which may not be applicable to all sites; thus, scaling may be
necessary to define appropriate site-specific risk management measures.

Required removal efficiency for wastewater can be achieved using onsite/offsite technologies,
either alone or in combination.
Required removal efficiency for air can be achieved using on-site technologies, either alone or in
combination.
Further details on scaling and control technologies are provided in SpERC factsheet
(http://cefic.org/en/reach-for-industries-libraries.html).

1. Short title of Exposure Scenario: Use as a fuel – professional

Main User Groups : SU 22: Professional uses: Public domain (administration,


education, entertainment, services, craftsmen)
Sector of use : SU 22: Professional uses: Public domain (administration,
education, entertainment, services, craftsmen)
Process category : PROC1: Use in closed process, no likelihood of exposure
PROC2: Use in closed, continuous process with occasional
controlled exposure
PROC3: Use in closed batch process (synthesis or
formulation)
PROC8a: Transfer of substance or preparation
(charging/discharging) from/to vessels/large containers at
non-dedicated facilities
SDS Number:100000013879 49/55
SAFETY DATA SHEET
Diesel No. 2 Test Fuel
Version 1.12 Revision Date 2024-05-21
PROC8b: Transfer of substance or preparation (charging/
discharging) from/ to vessels/ large containers at dedicated
facilities
PROC16: Using material as fuel sources, limited exposure to
unburned product to be expected
Environmental release category : ERC9a, ERC9b: Wide dispersive indoor use of substances in
closed systems, Wide dispersive outdoor use of substances in
closed systems

Further information :
Covers the use as a fuel (or fuel additive) and includes
activities associated with its transfer, use, equipment
maintenance and handling of waste.

2.1 Contributing scenario controlling environmental exposure for:ERC9a, ERC9b: Wide


dispersive indoor use of substances in closed systems, Wide dispersive outdoor use of
substances in closed systems
Product characteristics
Remarks Substance is complex UVCB., Predominantly hydrophobic.

Maximum allowable site tonnage : 140.000


(MSafe) based on release
following total wastewater
treatment removal (kg/d):(Msafe)

Environment factors not influenced by risk management


Flow rate : 18.000 m3/d
Dilution Factor (River) : 10
Dilution Factor (Coastal Areas) : 100

Other given operational conditions affecting environmental exposure


Continuous use/release
Number of emission days per year : 365

Technical conditions and measures / Organizational measures


Air : Release fraction to air from wide dispersive use (regional use
only)
Remarks : < 0.001 %
Water : Release fraction to wastewater wide dispersive use
Remarks : < 0.001 %
Soil : Release fraction to soil from wide dispersive use (regional use
only)
Remarks : < 0.001 %
Remarks : Common practices vary across sites thus conservative
process release estimates used.
Remarks : Risk from environmental exposure is driven by humans via
indirect exposure (primarily ingestion).
Remarks : No wastewater treatment required.
Air : Treat air emission to provide a typical removal efficiency of
(%):
Remarks : Not applicable
Water : Treat onsite wastewater (prior to receiving water discharge) to
provide the required removal efficiency of ≥ (%):
(Effectiveness: 0 %)
Water : If discharging to domestic sewage treatment plant, provide the
required onsite wastewater removal efficiency of ≥ (%):
SDS Number:100000013879 50/55
SAFETY DATA SHEET
Diesel No. 2 Test Fuel
Version 1.12 Revision Date 2024-05-21
(Effectiveness: 0 %)
Remarks : Prevent discharge of undissolved substance to or recover
from wastewater.
Remarks : Do not apply industrial sludge to natural soils.
Remarks : Sludge should be incinerated, contained or reclaimed.

Conditions and measures related to municipal sewage treatment plant


Type of Sewage Treatment Plant : Municipal sewage treatment plant
Flow rate of sewage treatment : 2.000 m3/d
plant effluent
Effectiveness (of a measure) : 94,1 %
Percentage removed from waste : 94,1 %
water

Conditions and measures related to external treatment of waste for disposal


Remarks : Combustion emissions limited by required exhaust emission
controls.
Remarks : Combustion emissions considered in regional exposure
assessment.
Conditions and measures related to external recovery of waste
Recovery Methods : External recovery and recycling of waste should comply with
applicable local and/or national regulations.

2.2 Contributing scenario controlling worker exposure for: PROC1: Use in closed
process, no likelihood of exposure

Product characteristics
Remarks Substance is complex UVCB., Predominantly hydrophobic.

Remarks : Liquid, vapour pressure < 0.5 kPa at STP


Remarks : With potential for aerosol generation.

Frequency and duration of use


Remarks : Covers daily exposures up to 8 hours (unless stated
differently)

Other operational conditions affecting workers exposure


Remarks : Assumes use at not more than 20°C above ambient
temperature, unless stated differently., Assumes a good basic
standard of occupational hygiene is implemented.

Technical conditions and measures


Avoid direct skin contact with product. Identify potential areas for indirect skin contact. Wear gloves
(tested to EN374) if hand contact with substance is likely. Clean up contamination/spills as soon as
they occur. Wash off skin contamination immediately. Provide basic employee training to
prevent/minimize exposures and to report any skin effects that may develop., Store substance within a
closed system.
Organizational measures to prevent /limit releases, dispersion and exposure
No other specific measures identified.
Conditions and measures related to personal protection, hygiene and health evaluation
Control any potential exposure using measures such as contained systems, properly designed and
maintained facilities and a good standard of general ventilation. Drain down systems and transfer lines
prior to breaking containment. Drain down and flush equipment where possible prior to maintenance.
Where there is potential for exposure: Ensure relevant staff are informed of exposure potential and
aware of basic actions to minimize exposures; ensure suitable personal protective equipment is
available; clear up spills and dispose of waste in accordance with regulatory requirements; monitor
effectiveness of control measures; provide regular health surveillance as appropriate; identify and
implement corrective actions.

SDS Number:100000013879 51/55


SAFETY DATA SHEET
Diesel No. 2 Test Fuel
Version 1.12 Revision Date 2024-05-21

2.2 Contributing scenario controlling worker exposure for: PROC2: Use in closed,
continuous process with occasional controlled exposure

Product characteristics
Remarks : Liquid, vapour pressure < 0.5 kPa at STP
Remarks : With potential for aerosol generation.

Frequency and duration of use


Remarks : Covers daily exposures up to 8 hours (unless stated
differently)

Other operational conditions affecting workers exposure


Remarks : Assumes use at not more than 20°C above ambient
temperature, unless stated differently., Assumes a good basic
standard of occupational hygiene is implemented.

Organizational measures to prevent /limit releases, dispersion and exposure


No other specific measures identified.

2.2 Contributing scenario controlling worker exposure for: PROC3: Use in closed batch
process (synthesis or formulation)

Product characteristics
Remarks : Liquid, vapour pressure < 0.5 kPa at STP
Remarks : With potential for aerosol generation.

Frequency and duration of use


Remarks : Covers daily exposures up to 8 hours (unless stated
differently)

Other operational conditions affecting workers exposure


Remarks : Assumes use at not more than 20°C above ambient
temperature, unless stated differently., Assumes a good basic
standard of occupational hygiene is implemented.

Organizational measures to prevent /limit releases, dispersion and exposure


No other specific measures identified.

2.2 Contributing scenario controlling worker exposure for: PROC8a: Transfer of


substance or preparation (charging/discharging) from/to vessels/large containers at
non-dedicated facilities

Product characteristics
Remarks : Liquid, vapour pressure < 0.5 kPa at STP
Remarks : With potential for aerosol generation.

Frequency and duration of use


Remarks : Covers daily exposures up to 8 hours (unless stated
differently)

Other operational conditions affecting workers exposure


Remarks : Assumes use at not more than 20°C above ambient
temperature, unless stated differently., Assumes a good basic
standard of occupational hygiene is implemented.

Conditions and measures related to personal protection, hygiene and health evaluation

SDS Number:100000013879 52/55


SAFETY DATA SHEET
Diesel No. 2 Test Fuel
Version 1.12 Revision Date 2024-05-21
Wear chemically resistant gloves (tested to EN374) in combination with ‘basic’ employee training.

2.2 Contributing scenario controlling worker exposure for: PROC8b: Transfer of


substance or preparation (charging/ discharging) from/ to vessels/ large containers at
dedicated facilities

Product characteristics
Remarks : Liquid, vapour pressure < 0.5 kPa at STP
Remarks : With potential for aerosol generation.

Frequency and duration of use


Remarks : Covers daily exposures up to 8 hours (unless stated
differently)

Other operational conditions affecting workers exposure


Remarks : Assumes use at not more than 20°C above ambient
temperature, unless stated differently., Assumes a good basic
standard of occupational hygiene is implemented.

Conditions and measures related to personal protection, hygiene and health evaluation
Wear suitable gloves tested to EN374.

2.2 Contributing scenario controlling worker exposure for: PROC16: Using material as
fuel sources, limited exposure to unburned product to be expected

Product characteristics
Remarks : Liquid, vapour pressure < 0.5 kPa at STP
Remarks : With potential for aerosol generation.

Frequency and duration of use


Remarks : Covers daily exposures up to 8 hours (unless stated
differently)

Other operational conditions affecting workers exposure


Remarks : Assumes use at not more than 20°C above ambient
temperature, unless stated differently., Assumes a good basic
standard of occupational hygiene is implemented.

Technical conditions and measures


Provide a good standard of general ventilation (not less than 3 to 5 air changes per hour), Ensure
operation is undertaken outdoors.

3. Exposure estimation and reference to its source

Environment
Contributing Exposure Specific Compartment Value type Level of Risk
Scenario Assessment conditions Exposure characterization
Method ratio (PEC/PNEC):
ERC9a, ERC9b Hydrocarbon Block Air 0,02 mg/m3
Method with
Petrorisk
Freshwater 0,0015 mg/L 0,043
Freshwater 1,4 mg/kg wet 0,05
sediment weight
Marine water 0,000028 0,00041
mg/L
Marine sediment 0,063 mg/kg 0,0014
wet weight

SDS Number:100000013879 53/55


SAFETY DATA SHEET
Diesel No. 2 Test Fuel
Version 1.12 Revision Date 2024-05-21
Agricultural soil 0,17 mg/kg 0,0054
wet weight
ERC9a: Wide dispersive indoor use of substances in closed systems
ERC9b: Wide dispersive outdoor use of substances in closed systems

Workers/Consumers
Contributing Exposure Specific Value type Level of Exposure Risk characterization
Scenario Assessment conditions ratio (PEC/PNEC):
Method
PROC1, CS15 ECETOC TRA Worker – inhalation, 1 mg/m3 0,01
Modified long-term – systemic
Worker – dermal, long- 1,34 mg/kg/d 0,46
term – systemic
Worker – long-term – 0,48
systemic Combined
routes
PROC1, CS67 ECETOC TRA Worker – inhalation, 0,01 mg/m3 0,00
Modified long-term – systemic
Worker – dermal, long- 0,34 mg/kg/d 0,12
term – systemic
Worker – long-term – 0,12
systemic Combined
routes
PROC2, CS15 ECETOC TRA Worker – inhalation, 1 mg/m3 0,01
Modified long-term – systemic
Worker – dermal, long- 1,34 mg/kg/d 0,46
term – systemic
Worker – long-term – 0,48
systemic Combined
routes
PROC3, CS107 ECETOC TRA Worker – inhalation, 1 mg/m3 0,01
Modified long-term – systemic
Worker – dermal, long- 0,34 mg/kg/d 0,12
term – systemic
Worker – long-term – 0,13
systemic Combined
routes
PROC8a, CS39 ECETOC TRA Worker – inhalation, 1 mg/m3 0,01
Modified long-term – systemic
Worker – dermal, long- 13,71 mg/kg/d 0,47
term – systemic
Worker – long-term – 0,49
systemic Combined
routes
PROC8a, CS103 ECETOC TRA Worker – inhalation, 5 mg/m3 0,07
Modified long-term – systemic
Worker – dermal, long- 13,71 mg/kg/d 0,47
term – systemic
Worker – long-term – 0,55
systemic Combined
routes
PROC8b, CS14, ECETOC TRA Worker – inhalation, 5 mg/m3 0,07
CS507 Modified long-term – systemic
Worker – dermal, long- 6,86 mg/kg/d 0,47
term – systemic
Worker – long-term – 0,55
systemic Combined
routes
PROC8b, CS8 ECETOC TRA Worker – inhalation, 1 mg/m3 0,01
Modified long-term – systemic
Worker – dermal, long- 6,86 mg/kg/d 0,47
term – systemic
Worker – long-term – 0,49
systemic Combined
routes
PROC16, CS107 ECETOC TRA Worker – inhalation, 14 mg/m3 0,20
Modified long-term – systemic
Worker – dermal, long- 0,34 mg/kg/d 0,12
term – systemic
Worker – long-term – 0,32

SDS Number:100000013879 54/55


SAFETY DATA SHEET
Diesel No. 2 Test Fuel
Version 1.12 Revision Date 2024-05-21
systemic Combined
routes
PROC1: Use in closed process, no likelihood of exposure
CS15: General exposures (closed systems)
PROC1: Use in closed process, no likelihood of exposure
CS67: Storage
PROC2: Use in closed, continuous process with occasional controlled exposure
CS15: General exposures (closed systems)
PROC3: Use in closed batch process (synthesis or formulation)
CS107: (closed systems)
PROC8a: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers
at non-dedicated facilities
CS39: Equipment cleaning and maintenance
PROC8a: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers
at non-dedicated facilities
CS103: Vessel and container cleaning
PROC8b: Transfer of substance or preparation (charging/ discharging) from/ to vessels/ large
containers at dedicated facilities
CS14: Bulk transfers
CS507: Refueling
PROC8b: Transfer of substance or preparation (charging/ discharging) from/ to vessels/ large
containers at dedicated facilities
CS8: Drum/batch transfers
PROC16: Using material as fuel sources, limited exposure to unburned product to be expected
CS107: (closed systems)

4. Guidance to Downstream User to evaluate whether he works inside the boundaries set
by the Exposure Scenario

Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management
Measures/Operational Conditions outlined in Section 2 are implemented.
Where other Risk Management Measures/Operational Conditions are adopted, then users should
ensure that risks are managed to at least equivalent levels.
Available hazard data do not enable the derivation of a DNEL for dermal irritant effects.
Available hazard data do not support the need for a DNEL to be established for other health
effects.
Risk Management Measures are based on qualitative risk characterisation.Guidance is based on
assumed operating conditions which may not be applicable to all sites; thus, scaling may be
necessary to define appropriate site-specific risk management measures.

Required removal efficiency for wastewater can be achieved using onsite/offsite technologies,
either alone or in combination.
Required removal efficiency for air can be achieved using on-site technologies, either alone or in
combination.
Further details on scaling and control technologies are provided in SpERC factsheet
(http://cefic.org/en/reach-for-industries-libraries.html).

SDS Number:100000013879 55/55

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