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RO Membrane Technology Overview

VONTRON Membrane is a leading manufacturer of separation membranes, with a significant global presence and over 1 billion RMB in annual sales. The company focuses on advanced membrane technologies for various applications, including seawater desalination and wastewater treatment. VONTRON also emphasizes research and development, maintaining numerous patents and partnerships to enhance its product offerings.

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0% found this document useful (0 votes)
169 views34 pages

RO Membrane Technology Overview

VONTRON Membrane is a leading manufacturer of separation membranes, with a significant global presence and over 1 billion RMB in annual sales. The company focuses on advanced membrane technologies for various applications, including seawater desalination and wastewater treatment. VONTRON also emphasizes research and development, maintaining numerous patents and partnerships to enhance its product offerings.

Uploaded by

muchamad fandi
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

VONTRON MEMBRANE

GLOBLE APPLICATION
沃顿膜产品的海外应用

2024版

1
Contents
目录

01 02 03
About Us Membrane Materials Oversea Project Application

2
PART 1
About US
关于我们

3
New technology | New energy |New Materials
新技术 | 新能源 | 新材料

234.3 B Over 110 170,000


in revenue RMB Overseas Employees
of 2023 Subsidiaries

Top300 9 New
in Global 500 Industry
Sector

21 National 18 Oversea 11 National


enterprise R&D institutions
R&D centers
technology CONNECTING THE WORLD THOUGH BETTER MOBILITY
centers
连接世界 与你同行

4
VONTRON TECHNOLOGY Improving the environment and sharing the health
沃顿科技 改善环境 分享健康

Key
business
1.7 billion Membrane
1500
in revenue RMB Separation employees
of 2023 Business

Design,construction &
R&D and manufacture
Supportive 3 Core
of membrane
operation of membrane
seperation projects
Business Business Unit business
Brown Fiber Membrane
Materials Materials

1
1
Academicion
National & Local 4
Joint Engineering Provincial level
workstation technical center
Center

R&D and Application of Mergers, acquisitions and


palm fiber industry incubation

5
Core Business
Membrane Materials
核心业务 | 膜材料

A globally renowned manufacturer of spiral-wound


separation membranes and the leading RO
enterprise in China.

National and Local Joint Engineering


Research Center for Separation
Membrane Materials and Applications

Annual sales have exceeded 1 billion


RMB, reaching 130 countries and
serving 70 million customers.

6
NSF/ANSI 58 Quality management Environmental Occupational health and
system (ISO 9001) management system safety management
(ISO 14000) system (OHSAS 18001)

NSF/ANSI 61 Chinese sanitary approval of Halal Certificate EU hazardous ingredients


water-related products directive standard (RoHS)

7
DISTRIBUTION
服务网络

25%

Residential
>70 000 000支

15%

Industrial
>2 000 000支

8
R&D
研发实力 Joint R & D base of advanced membrane materials
Joint R & D base of water treatment membrane
National R&D Platform

National and Local Joint Engineering


Research Center for Separation Membrane
Materials and Applications

Industry-university-research
cooperation
Joint R & D base of advanced membrane materials
Joint R & D base of water treatment membrane

Significant R&D investment


ratio
In 2023, the R&D expenses totaled 121.31
million yuan, 7.11% of the revenue.

9
R&D
研发实力
Design of membrane materials and
Application technology of system design
components

Design of manufacture equiptment Chemistry analysis & test

10
R&D
研发实力
9 major R&D projects
◉ National Key R&D plans(2, 2016-2020)
National science and technology support plans (3, 2014-2017)
National 863 Projects (3, 2004-2014)

◉ 20 national & industry standards


GB/T 32373-2015 methods of RO testing

GB/T 34241-2017 Mixed polyamide spiral wound reverse


osmosis membrane elements
8%
GB/T 34242-2017 Methods of NF testing
25%
◉ 157 authorized patents
44%
73 invention patents,65 utinity model patents,
19 appearance design patents 23%
Membrane manufacture 25%、components23%
equiptment 44%、application 8%

11
Membrane manufacturing
膜片制造
Morphology of the
desalting layer
Precise control
low high
water flux

Thickness of the
polyamide layer
Precise control
short long
tolerance

Control technology of Fully Automatic & Integrated


polyamine mixed World’s second dry type membrane
crosslinking prodcution line
conventioal NF Specialty separation
NF

12
Components & Assembling
组件制造

Fully Automatic rolling technology


End-cup hydrothermal rotary melting Permeate carrier material
assembling technology cutting

* The three factors (grid thickness, active area


and flux) are indendent, should be weighed
according to the demand

Iterative development of New feed spacer Pressure- resistant 50% more


assembling technology pressure drop 53%
less Patented (U arc water
LD Feed distribution end-cup) rotary
Spacer melting technology

13
TRACEABLE QUALITY CONTROL
可追溯质量控制

原材料品控 厚度检测(厚度仪)
Raw material quality control Thickness Detection

气相色谱,GC-MS
膜片检测(膜片测试台) 缺陷检测(高速CCD)
分光光度计,UV-Vis
Membrane test Defect detection 傅里叶红外,FTIR

密封性检测(气检台) 性能测试(元件测试台) 三年产品留样


Sealing test Performance test Product retention (stored for 3 years)

14
Systematic Service
服务体系
Provide technical services throughout the entire process and cycle.

Pre-sales technical support In sales technical service After sales technical service
Pre-sales technical discussion Technical discussion System troubleshooting and handling
Design suggestions for water treatment process flow Small and medium-sized experimental evaluation Chemical cleaning guide
RO system design Constructing & Commissioning Product follow up
Technical parameter documents for bidding RO improving suggestions during operation Elements inspection & analysis if return
Water quality test and analysis Contamination Analysis

15
PART 2
CORE BUSINESS - MEMBRANE
MATERIAL
核心业务 | 膜材料

16
Industial Products
膜产品
20+ series 200+ models
Currently China’s most comprehensive manufacturer and service provider of dry-type RO membrane

Reverse Osmosis Nanofiltration Ultrafiltration


RO NF UF
• Low Pressure LP-LD Series
• Low Pressure LP Series • Municipal Tapurim Series • Spiral Wound VUF Series Strengthened
• Ultra Low Pressure ULP-LD Series
Helixfil Series
• Ultra Low Pressure ULP Series • Water Treatment VNF Series • Flat VMR Series
• Fouling Resistant PURO Series
• Extremely Low Pressure XLP Series • Material Separation MASE Series • Hollow Fiber VUF Series

• Fouling Resistant FR Series • High Pressure MASE 80 Series


• High Pollution Resistant ZERO-FR Series
• Oxidation Resistant HOR Series • Acid Resistant Acidstab Series
• High Pressure ZERO-HP Series
• Seawater Desalination SW Series • Alkaline Resistant Alkalistab Zero Liquid Discharge
Series ZERO Series • Ultra-high Pressure ZERO-UHP Series
• Heat Sanitizable VHD Series
• Nanofiltration Separation ZERO-XS Series

17
Seawater Reverse Osmosis Membrane

Patented U Arc Water Solve the Wastewater Problem


Distrinbution End Cup2 Designed for harsh treatment condition
(SW8040FR-400)
50%more pressure resistence

Test condition:operating pressure 800 psi(5.52 MPa),32000 mg/L NaCl solution,


temperature 25℃,pH 8,recycle rate 8%

SW series is used for seawater desalination. It can imprive permeate flow by Patented alloy support layer1
optimizing membrane element structure. It has the features of high rejection rate, Maintain high desalination rate under
stable performance, low operating cost and small equiptment investment. high-temperature conditions
Can be used for small-scale seawater desalination systems, large-scale seawater desalination
1Invention patent number: CN102908914 B 2Invention Patent Number: CN207822812U
projects, high salinity concentrate reduction, and concentration of high-concentration brine.

18
Strengthened RO Membrane Elements Series

High-precision rolling technology Brand New Low Differential (LD)


Reduced operational resistance
34mil Feed Spacer

Test condition:operating pressure 225psi(1.55MPa),2000 mg/L Nacl,temperature 25℃,pH 7.0±0.5, recycle rate 15%
1&2 operating Pressure 150psi(1.03MPa),1500 mg/L Nacl,temperature 25℃, pH 7.0±0.5, recycle rate 15%
3 operating Pressure 150psi(1.03MPa),2000 mg/L Nacl ,temperature 25℃,pH 7.0±0.5, recycle rate 15%

The LP400-LD and ULP400-LD elements adopt a brand new low differential pressure 34mil feed spacer, which improves
the turbulence on the membrane surface and effectively reduces the risk of colloidal congestion and cleaning frequency.

ULP440-MAX and LP440-MAX can increase permeate flow by 15% and 20% respectively, while maintaining the
required rejection rate.
PURO-Ⅰ membrane elements are more fouling-resistant and more resilient to a wide range of chemical cleaning thanks Patented U Arc Water Rotray Melting
to the improved cross-link strength of the Polyamide desalting/barrier layer.
distribution End Cup* Technology
PURO-Ⅱ membrane elements have higher endurance to chemical cleaning and obviously higher fouling resistance
50% more pressure resistance Strenthened end cup structure
owing to the brand-new design of low differencial pressure feed spacer.
PURO-FRLE ultra-low pressure RO membrane features fouling resistance and low energy consumption, and is suitable
for treating industrial sewage with low salinity, such as electronic sewage and surface water. *Invention patent number: CN 207822812 U

19
Municipal Nanofiltration Series

Wide Application Range Fluid structure design


rejection rate 10%~90% Differential Pressure between
membranes 30% lower
Test condition: operating pressure 70 psi(0.48 MPa),NaCl、MgSO4、CaCl2 mixed
solution,temperature 25℃,pH7.0 ± 0.5,recycle rate 15%

Organics, microbes, viruses, and most metal ions with two or higher valence can be
filtered by Tapurim Series NF element, while part of sodium, potassium, calcium,
magnesium ions, etc., can be retained in the permeated water.
TAPU-LS Element is designed primarily for the removal of organics while keeping most of the
monovalent ions retained in the permeated water and is applicable to the removal of organics
and inorganics from raw water with low salinity.
TAPU-MS Element has a higher rejection rate of monovalent ions while maintaining a
proper rejection rate of organics, which is applicable to the removal of organic and
inorganic matter in mid-salinity raw water. Extrmely Low Energy Healthy Water
TAPU-HS Element has a rejection rate of 80-95% for chlorides, applicable to the rejection of Consumption TOC rejection rate over 90%
Operating pressure ≤ 5bar
organic and inorganic matters in mid and high-salinity raw water.

20
Zero Liquid Discharge Series

Excellent ZLD/MLD Performance Comprehensively Improved


Transfer highly polluted brine to resources Membrane Sheet and Structure
Overcome the conventional pressure
resistance performance

Test condition:
operating pressure 225psi(1.55MPa),2000 mg/L Nacl,temperature 25℃,pH 7.0±0.5,rejection rate 15%
1&2 operating pressure 800psi(5.52MPa),32000 mg/L Nacl,temperature 25℃,pH 8.0,recycle rate 8%

3 operating pressure 100psi(0.69MPa),2000 mg/L MgSO4,temperature 25℃,pH 7.0±0.5,recycle rate 15%

ZERO-FR10 is an advanced fouling-resistant element technology designed for high TDS levels of 5000-15000 ppm
and high COD wastewater reclaiming in the Zero Liquid Discharge process. Based on the new generation of
membrane separation layer technology and unique component structure, it is a low-pressure drop, long cleaning
cycle, and high-chemical-cleaning-resistant membrane element product.

ZERO-HP70 is a series of high-pressure reverse osmosis membrane elements. The highly desalinized membrane
product is developed for TDS 15000-35000 ppm brine concentration. Based on the SW serial element to improve
the performance of bearing higher pressure, the Zeta potential and hydrophilicity of the membrane are also
enhanced.

ZERO-UHP120 is a series of ultra-high pressure reverse osmosis membrane elements. The membrane
product is developed for TDS 35000-70000 ppm brine concentration with a maximum operating pressure up Recycled Use of Water
to 120 bar, suitable for concentration and reduction of high salinity wastewater discharge. Supporting sustainable development
ZERO-XS90 ZERO-XS 90 is a series of nanofiltration separation membrane elements. It is a highly selective
fouling-resistant nanofiltration membrane product developed for sodium chloride and sodium sulfate of Low
energy consumption resource recycling. It is suitable for the selective separation of TDS 35000-70000 ppm
high pollution concentrated brine in zero liquid discharge process of chlor-alkali, desulfurization wastewater,
21
remove sodium sulfate from dyeing wastewater.
Material Separation NF Series

High-precision Rolling Technology New Low Differential (LD)


Reduced operational resistance 34mil Feed Spacer

Test condition: operating pressure 100 psi(0.69 MPa),2000 mg/L MgSO4 solution,temperature
25℃,pH7.0 ± 0.5,recycle rate 15%

Material Separation NF Membrane is primarily used in the separation of monovalent salt and divalent salt,
as well as in hardness removal, denitration separation and concentration of liquid, with the molecular
weight cutoff covering 200-800 Dal.
MASE-SP is designed to reject part of the multivalent ions while allowing the permeation of monovalent
ions, and is applicable to purifi cation of high-concentrated saline water.

MASE-SL is designed to reject the multi-valent ions and organics while allowing the permeation of monovalent
Patented U Arc Water Rotray Melting
ions, and is applicable to purifi cation, decolorization and organism rejection of high_x0002_concentrated
saline water.
distribution End Cup* Technology
50% more pressure resistance Strenthened end cup structure
MASE-PS MASE-PS has a moderate rejection rate of monovalent ion, applicable to rejecting organics such
as pesticide, herbicide, etc. in high-salt water.

MASE-CR MASE-CR has a high rejection rate of monovalent ion, which can be applied in the reuse of *Invention patent number: CN 207822812 U
rejected water with 5000-10000mg/L salinity
22
PART 3
海外项目应用
Oversea Projects Application

23
电力行业工程案例—中东某海水电厂

VONTRON Seawater Power plan Project - in Saudi Arabia


SW系统简介:海水系统共有4套SWRO系统,单套20×7=140,设计产水量≥80t/h,回收率≥43%,运行温度26-34℃,海水TDS≤ 41170.14mg/L(二级系统浓水回一级
海水系统进水),pH=8.2。
SW system introduction: There are 4 seawater systems, with a single set of 140 pieces, the designed water output ≥80t/h, recovery ≥43%, operating temperature between 26
℃ and 34℃, seawater TDS ≤ 41,170mg/L (concentrated water from secondary RO returns to the feed seawater of primary RO), and pH=8.2.
工艺流程:海水(红海海水)→絮凝沉淀→多介质(DMF)→活性炭(ACF)→保安过滤器→SW系统→产水箱→二级RO系统→离子交换→锅炉补给水
Process flow: Seawater (Red Sea Seawater) → Flocculation and Sedimentation → Multi-Media Filter (MMF) → Activated Carbon Filter (ACF) → Middle Water Tank → Boost
Pump → Security Filter → High-Pressure Pump →SW system → Permeate Water Tank → Secondary RO system → Ion Exchange → boiler make-up water.

24
VONTRON Seawater Membrane Project Example-RABEC in Saudi Arabia
电力行业工程案例—中东某海水电厂
表1-原海水水质(红海海水)
Table 1- Raw Seawater Quality

Calcium (Ca2+) 436.69 mg/l Bicarbonate (HCO3‐) 144.04 mg/l


Magnesium (Mg2+) 1,432.36 mg/l Carbonate (CO32‐) 7.53 mg/l
Sodium (Na+) 12,878.02 mg/l Sulphate (SO42‐) 3,311.58 mg/l
Potassium (K+) 362.36 mg/l Chloride (Cl‐) 22,588.58 mg/l
Barium (Ba2+) 0.00 mg/l Fluoride (F‐) 1.26 mg/l
Strontium (Sr2+) 0.00 mg/l Nitrate (NO3‐) 0.00 mg/l
Boron (B) 6.80 mg/l Silica (SiO2) 0.29 mg/l
2019年第一批400ft2膜面积海水膜投入使用,连续450天的运行过程中,所有参数均符合客户的用水要求。
中东客户一直在寻求一种高产水量高脱盐率(低TDS),价格有优势同时必须能长期稳定运行的海水膜。主流品牌都与该客户进行了合作测试。VONTRON赢得了客户的最终选择。
2021年第二批 440ft2 膜面积海水膜正在其他系统上进行验证。
2023年第三批大批量采购。产水量和脱盐率性能达到系统设计值,系统性能表现良好,连续运行4年产水量和脱盐率维持稳定,满足客户使用需求。
The first batch of 400ft membrane area seawater membrane was put into service in 2019, and during 450 consecutive days of operation, all parameters met the customer's water requirements.
The Middle East customer had been looking for a seawater membrane with high water yield and high desalination rate (low TDS) at an advantageous price, and at the same time, it must be able to operate
stably for a long period of time. All major brands were tested with the customer and VONTRON was the final choice.
A second batch of 440ft seawater membranes is being validated on other systems in 2021.
A third large batch will be purchased in 2023.
The performance of water production and desalination rate reaches the design value of the system, the water production and desalination rate remain stable for 4 years of continuous operation, which
meets the customer's needs.
25
VONTRON Seawater Membrane Project Example-South Asia
海淡行业工程案例—南亚某海水淡化厂

系统简介:海水淡化厂共有3套一级SWRO和4套二级BWRO,总设计处理水量20,000m³/d,一级SWRO单套78*7=546排列,设计产水量≥280t/h,回收率≥41%,进水TDS≤ 46741mg/L,二级BWRO单套
(9:4)*6=78排列,设计产水量≥80t/h,回收率≥85% 。
System introduction: There are 3 sets of primary SWRO and 4 sets of secondary BWRO in the desalination plant, with a total design treatment capacity of 20,000m³/d. The primary SWRO is arranged in a single set
of 78*7=546, with a design capacity of ≥280t/h, a recovery rate of ≥41%, and an influent TDS of ≤ 46,741mg/L, and the secondary BWRO is arranged in a single set of 9:4*6=78 with a design capacity of ≥80t/h, and
a recovery rate of ≥85%. ≥80t/h, recovery rate ≥85%.
工艺流程:海水→沉淀池→多介质→保安过滤器→一级RO系统→二级RO系统→外供
Process flow: seawater → sedimentation tank → multi-media → security filter → primary RO system → secondary RO system → external supply

26
VONTRON Seawater Membrane Project Example-South Asia
海淡行业工程案例—南亚某海水淡化厂

MEMBRANE TRIAL REPORT RO SKID -F (VONTRON)


800 58200

58100
700
58000

600 57900

57800
500
57700
400
57600

300 57500

57400
200
57300

100 57200
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Common contd
Vontron make Membrane Permeate Conductivity in PV NO C8R7 (MODEL: SW 8040 HR 440)
CONCENTRATION Feed

27
VONTRON Power Plants Project -Southeast Asia
电力行业工程案例—东南亚某电厂

系统简介:该电厂目前有三个纯水车间,其中二车间锅炉补给水系统共有4套一级RO和2套二级RO,设计处理水量20,000m³/d,一级RO单套(20:10)*6=180排列,设计产水量≥135t/h,回收率≥75%,
进水TDS≤ 1760mg/L,二级RO单套(14:6)*6=120排列,设计产水量≥120t/h,回收率≥85% 。
System introduction: The power plant currently has three pure water workshops, of which the second workshop boiler make-up water system has four sets of primary RO and two sets of secondary RO, designed to
treat 20,000m³/d of water, a single set of primary RO (20:10)*6=180 arrangement, the designed water yield ≥ 135t/h, recovery rate ≥ 75%, influent TDS ≤ 1760mg/L, a single set of secondary RO (14:6)*6=120
arrangement, designed water yield ≥ 120t/h, recovery rate ≥ 85%. (14:6)*6=120 arrangement, design water production ≥ 120t/h, recovery rate ≥ 85%.
工艺流程:地表水+冷凝水→调节池 →絮凝沉淀→多介质→活性炭→中空超滤→水箱→保安过滤器→一级RO系统→产水箱→二级RO系统→离子交换数值→锅炉补给水
Process flow: surface water + condensate → conditioning tank → flocculation and precipitation → multi-media → activated carbon → hollow ultrafiltration → water tank → security filter → primary RO system →
water tank → secondary RO system → ion exchange value → boiler make-up water

28
VONTRON Power industry engineering example-Southeast Asia
电子行业工程案例—东南亚某电子厂

系统简介:该电子厂共设6处超纯水车间,每个车间设有两套一级RO,一套二级RO,总设计处理水量24,000m³/d,一级RO单套(7:3)*6=60排列,设计产水量≥60t/h,回收率≥70%,进水TDS≤
350mg/L,二级RO单套(1:1)*6=12排列,设计产水量≥12t/h,回收率≥80% 。
System introduction: the electronics factory has a total of six ultrapure water workshop, each workshop has two sets of primary RO, a secondary RO, the total design water treatment capacity of
24,000m³/d, a single set of primary RO (7:3) * 6 = 60 arrangements, the design of the water production capacity of ≥ 60t / h, the recovery rate of ≥ 70%, the influent TDS ≤ 350mg / L, the second
set of single set of RO (1:1) * 6 = 12 arrangements, the design water production capacity of ≥ 12t / h, recovery rate of ≥ 80%. Design water production ≥ 12t / h, recovery rate ≥ 80%.
工艺流程:自来水→多介质→活性炭→水箱→保安过滤器→一级RO系统→产水箱→ 保安过滤器→二级RO系统→EDI→18兆欧MΩ超纯水
Process flow: tap water → multi-media → activated carbon → water tank → security filter → a RO system → water tank → security filter → secondary RO system → EDI → 18 megohm MΩ ultrapure water

29
VONTRON Municipal Membrane Project Example- Asia
市政行业工程案例—亚洲某自来水厂

260,000 m3/d
地表水 粗过 超滤
Surface 滤 ultra 最大Max310,000 m3/d
water crude NF
filtr
filtr
ation ation 138,000 m3/d

该水厂出水
当地饮用水标准 水质标准
水质项目Water Quality Project
Local drinking water standards effluent
Water quality standards
浊度(NTU) <2 < 0.2
总溶解固体量TDS(mg/L) < 500 < 250
总三卤甲烷THMs (mg/L) < 0.08 < 0.03
总菌落数Colong Forming Units (CFU/mL) < 100 < 1.0

产品应用Product Application
NaOH recovery for cotton mercerizing process waste caustic
棉丝光工艺工业中废碱回收再利用
Feed : 10 M3/Hr Product: 5.5 M3/Hr Reject : 4:5 M3/Hr
Pressure 25 Kg pressure
Recovery : 55 %
Temp.: 30 ℃

NaOH Concentration :
Feed : 44 GPL Product: 42 GPL Reject: 46 GPL

Feed Permeate Concentration


Array:3:1,
Total element nos.:24 nos

It is natural colour of cotton make of lignin, pactin, waxes


Hemicellulose concentration: less than 0.1 %)
And also soluble starch in NaOH, 200 ppm,All is NaOH
concentration

Cotton Mercerisation process 31


The rejected water from RO of Dyeing wastewater ETP system
Application :

Textile Common Effluent Treatment Plant - ZLD System

Raw Effluent - 5.5 MLD Design Capacity

Raw Effluent TDS - 10,000 mg/L

Treatment Scheme:

Collection --> Equalization --> Biological - MBR --> Resin Softening --> RO 1 --> MS3 --> Salt Recovery in MEE & Brine
Recovery in MS3

Array: (3:0)*4

Model: VNF-8040HP

No. of NF membrane: 12nos

Design Feed flow: 15m3/h

RR: 35%
32
NF pilot system data

33
沃顿科技股份有限公司
V O N T R O N T E C H N O L O G Y C O . , L T D .

34

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