Atomic Structure and GOC
Atomic Structure and GOC
A.P,TELANGANA,KARNATAKA,TAMILNADU,MAHARASHTRA,DELHI,RANCHI,CHANDIGARH
CHEMISTRY
is an isoelectonic pair having d10 electronic with a velocity 6.4 104 m / s . What is the
configuration in each ? minimum energy needed to remove an
3) 35, 35 and 45 4) 80, 45 and 35 6. The vividh bharati station of All India Radio,
3. Which of the following ions is isoelectronic Delhi broadcasts on a frequency of
1250 kHz. The wave length of the
with O2–
electromagnetic radiation emitted by the
1) S2 2) Mg2
transmitter is (speed of light is 3 × 108 ms–1)
3
3) Sc 4) K
1) 240cm 2) 240m
4. A monochromatic infrared range finder of
3) 241cm 4) 241m
power 6.625 watt emits photons with wave
7. Which of the following series of transitions
length 300 nm in 10 seconds. The number of
in the spectrum of Hydrogen atom falls in the
photons emitted in 10 seconds is (Given
ultraviolet region ?
34
C=3×108ms–1, h = 6.625 10 Js , 1) Balmer 2) Paschen
Avogadro number = 6.022 1023 , 1 watt = 3) Lyman 4) Brackett
3 × 10–12
19
1) 2) 3 10
3) 3 1019 4) 3 1012
6.63 10 34
Js . The speed of light is indicating that the energy of the electron in
the atom is lower than the energy of a free
3 1017 nm sec 1 . Which value is closest to
electron at rest.
the wavelength, in nano metre of a quantum
4) The energy of second orbit in He+ is
of light of frequency of 5 1016 s 1
?
1) 6 2) 5 same as that of third orbit in Li+2
10. According to law of photo chemical electron in the fourth Bohr orbit is [Given
Avogadro number = 6.022 1023 ) 14. Incorrect set of quantum numbers from the
following is
1.197 10 3
1.197 106
1) 2) 1) n = 4, l = 2, m = –1, s = – 1/2
2) n = 3, l = 2, m = –3, s = + 1/2
1.197 106 1.9875 10 3
3) 4) 3) n = 2, l = 0, m = 0, s = +1/2
4) n = 3, l = 2, m = –2, s = +1/2
11. If the radius of hydrogen atom in the ground
15. Statement-1:The wave function may have
state is 53 pm, the radius of the second orbit
positive or negative value depending upon
in He+ is
the values of coordinates.
1) 53pm 2) 106pm
Statement-2:The pobability of finding the
3) 26.5pm 4) 212pm
electron at a point within atom is
12. Based on the equation
proportional to square of orbital wave
2.178 1018 Z 2
E J atom , certain function ( 2) .
n2
1)Statement-1is true but Statement-2 is false.
conclusions are written.Which of them is
2)Statement-1is false but Statement-2 is true.
incorrect?
3)Both Statement-1 and Statement-2 are
1) Equation can be used to calculate the
true.
energy of stationary orbits of one electron
4)Both Statement-1 and Statement-2 are
species only.
false.
2) As n value increases the energy of
16. The element expected to form smallest ion
electron decrease i.e becomes more negative.
to achieve nearest Noble gas configuration is
26. The number of sub levles in the quantum 32. The angular momentum of electron in
level n =3 is h
2p – orbital is equal to h
1) 1 2) 2 2
3) 3 4) 4 1) 2 3h 2) 0
27. How many electrons can fit in the orbital for
3) 6h 4) 2h
which n=4 and l =2 ?
33. What is the maximum number or orbitals that
1) 2 2) 10
can be identified with the following quantum
3) 6 4) 5
numbers n = 3, m 0 ?
28. Which d-orbital has its four lobes along the
axes 1) 1 2) 2
3) 3 4) 4
1) d xy 2) d
x2 y 2
34. The maximum number of electrons that can
3) d 4) d xz be associated with quantum numbers n = 4,
z2
1) 5s 2 4d8 2) 5s1 4d 9
3) 5s o 4d10 4) 5s 2 3d10
KEY
1) 1 2) 1 3) 2 4) 1 5) 2 6) 2 7) 3 8) 2 9) 1 10) 1
11) 1 12) 2 13) 2 14) 2 15) 3 16) 2 17) 1 18) 1 19) 4 20) 4
21) 4 22) 2 23) 3 24) 1 25) 4 26) 3 27) 1 28) 2 29) 4 30) 3
31) 4 32) 4 33) 3 34) 3 35) 3 36) 37) 38) 39) 40)
be
1 1) P 2) S
1) 1 2 2) 1 2
2 3) Cl 4) K
3) 1 22 4) 1 42 11. The relation between nl ( nl =the no. of
07. The value of planck’s constant is permissible values of azimuthal quantum
6.63 1034 JS . The speed of hight is number (l)) for a given value of principal
Choose the correct answer from the options 1) The uncertainity principle is
given below h
E t
a b c d 4
Sri Chaitanya
Page 7
Sec :
Chemistry
24. Which is correct order of increasing energy 27. What is the maximum number of orbitals
of the listed orbitals in the atom of cerium that can be identified with the following
(atomic no. z = 58) quantum numbers? n=2, l = 1, m = -1
1) 6s, 6p, 5d, 4f 2) 4f, 5d, 6p, 6s 1) 1 2) 2
3) 6s, 4f, 5d, 6p 4) 5d, 6s, 4f, 6p 3) 3 4) 4
25. The number of 4p electrons in Fe+2 (z=26) is 28. What is the maximum number of electrons
equal to the number of electrons in which of that can be associated with the following
the following set of quantum numbers? n = 4, l = 2
1) d – electrons in Fe (z=26) and m = -1
2) p – electrons in Ne (z=10) 1) 4 2) 2
3) s – electrons in An (z=13) 3) 10 4) 6
2+
4) p – electrons in Be (z=4) 29. The outer electronic configuration of
26. The orbital angular momentum of electron Th (at no. = 90) is
in s and p orbitals are respectively 1) 5f0 7s2 7p2 2) 5f0 6d2 7s2
h 3) 5f0 6d4 4) 5f2 6d0 7s2
2
1) 0, 0 2) 2 , 6
3) 0, 2 4) 0, 6
KEY
1) 3 2) 2 3) 1 4) 4 5) 2 6) 3 7) 3 8) 4 9) 1 10) 4
11) 2 12) 4 13) 4 14) 4 15) 4 16) 2 17) 3 18) 3 19) 3 20) 3
21) 1 22) 3 23) 2 24) 3 25) 4 26) 3 27) 1 28) 2 29) 2
2. The number of and bonds in between
GENERAL ORGANIC CHEMISTRY
carbon atoms in 3 – ethyl – 4 methyl penta –
1. What is the hybridization shown by C1 and
1, 3 – diene
C2 carbons respectively in the given
(1) 7 and 2 bonds
compound ?
(2) 6 and 2 bonds
O O
(3) 7 and 4 bonds
Cl C CH CH CH 2 C OH
(4) 6 and 3 bonds
2 3 3 3
(1) sp and sp (2) sp and sp 3. The type of hybridization of carbon atoms
(3) sp2 and sp2 (4) sp3 and sp2 numbered 1 and 3 in CH 2 CH C CH
Sri Chaitanya
Page 8
Sec :
Chemistry
following structure is
NH 2 As OH
(3)
As NH 2
HO
(1) 12 (2) 16
(3) 14 (4) 8
(4)
5. The correct IUPAC name of the following
8. The IUPAC name of the compound
compound is
O
OH
OH is
Cl (1) 3 hydroxy butanoic acid
(1) Isoprene (2) 4 – methyl – 2 – oxo – 1, 4 butane diol
(2) Chloroprene (3) 1, 4 dihydroxy – 2 – butanone
(3) 2 methyl – 1, 3 butadiene (4) 1, 4 dihydroxy – 2 – pentanone
(4) 2 chloro – 1, 3 butadiene 9. The structure of secondary butyl group in an
6. The correct IUPAC name of the following organic compound is
compound (1) CH3 CH 2 CH 2 CH 2
O CH 3
H CH 3 C
CH 3
(1) 3 methyl pent – 4 ene – al (2)
(2) 3 ethyl pent – 4 ene – al CH 3
(3) 3 methyl hex – 4 ene – al CH CH 2
(4) 2 methyl pent – 4 ene oic acid CH 3
(3)
7. The correct structure of 2, 5 dimethyl
CH3 CH CH 2 CH3
non – 3 – ene is (4)
10. Structure of the compound whose IUPAC
name is 3 – ethyl 4 methyl hept – 5 – en – 2
one
(1)
Sri Chaitanya
Page 9
Sec :
Chemistry
O O
O
(1) I. II.
O O
(2)
III.
O Which of the given compounds can exhibit
tautomerism ?
(1) I only (2) II only
(3)
(3) Both I and II (4) Both I and III
O 14. The enolic form of acetone as shown below
has
H 2C CH 3
(4) C
11. The compound which does not show
OH
metamerism is
(1) 9 and 2 bonds
(1) C 4 H10O (2) C4 H8
(2) 9 and 9 bonds
(3) C5 H10O (4) C5H10O 2
(3) 9 and 1 bond
12. Which among the given molecules can
exhibit tautomerism ? (4) 8 and 1 bond
O
III. IV. N
(1) I only (2) Both I and II
(2) H
(3) Both I and IV (4) Both III and IV
13. Given
N
(3)
Sri Chaitanya
Page 10
Sec :
Chemistry
CH 3 (1) R 3N (2) Cl
(3) SH SeH OH H H
H H
NO2 Cl
(3) (4) CH 3 C C C F
25. Which of the following is electrophile H H
(1) :CCl2 (2) NH3 29. Hyperconjugation occurs in
(3) H 2O (4) R NH 2
26. Which of the following is a nucleophile
Sri Chaitanya
Page 12
Sec :
Chemistry
Ph E. C H3
(1) A (2) B
D. CH 3 C H 2 (3) C (4) D
Sri Chaitanya
Page 13
Sec :
Chemistry
38. Ortho nitrophenol and para nitrophenol can 41. In Carius method of estimation of halogen
be separated by 0.15g of organic compound gave 0.12gr of
(1) Steam distillation AgBr. The percentage of bromine in the
(2) Crystallisation compound is
(3) Sublimation (1) 34.04 (2) 3.4
(4) Fractional distillation (3) 54.04 (4) 5.4
39. Sulphur can be detected by Lassaigne’s test. 42. 0.25gr of an organic compound gave 30cm3
The purple (violet) colour formed
of moist dinitrogen at 288K and 745mm
corresponds to the following formula
pressure. The percentage of nitrogen is
4
(1) Fe CN 5 NO (Aqueous tension at 288K = 12.7mm)
1) 1 2) 1 3) 2 4) 3 5) 4 6) 1 7) 1 8) 3 9) 4 10) 3
11) 2 12) 3 13) 3 14) 3 15) 2 16) 1 17) 4 18) 1 19) 2 20) 1
21) 2 22) 1 23) 2 24) 3 25) 1 26) 1 27) 3 28) 1 29) 3 30) 1
31) 4 32) 1 33) 1 34) 3 35) 2 36) 1 37) 4 38) 1 39) 3 40) 2
41) 1 42) 3 43) 2
Sri Chaitanya
Page 14