SURFACE INNOVATORS LLP

G-2 Creative Indl. Estate, Plot No. 12, Next To H.P. Petrol Pump, N.M. Joshi Marg,
Lower Parel (E), Mumbai – 400011, Ph.No. 022‐23005205/06
Email : [email protected] /[email protected]

MATERIAL SAFETY DATA SHEET

1. Identification of the Substance / Preparation

Name of product K-2 PASSIVATION

Manufacturer / Distributor SURFACE INNOVATORS LLP

G-2, Creative Industrial Estate,
Next to HP Petrol Pump, N. M. Joshi Marg,
Lower Parel, Mumbai – 400 011,
Maharashtra, India

2. Composition / Information on Ingredients

Hazardous Ingredients
CAS-No. EC-No. Name [% weight] Classification

007732-18-5 Water 60-80%

007697-37-2 Nitric acid ... 15-25%

Additives C: R 34

3. Special Hazards Information for Man and Environment

R-phrases
26/27/28 Toxic by inhalation, in contact with skin and if swallowed.
35 Causes severe burns.

Special hazards information for humans and environment

Corrosive product, dangerous for human health and environment. May
cause long-term harmful effects in the environment.

4. First Aid Measures

General information
Remove contaminated soaked clothing immediately and dispose of safely. Symptoms
of poisoning any may not occur for many hours, therefore keep under
medical supervision for at least 48 hours.
Seek medical treatment immediately.
In case of stronger and long effects, specially on skin and respiratory tract, medical
treatment is necessary.

In case of inhalation
In case of inhalation remove the casualty into fresh air and seek medical
 SURFACE INNOVATORS LLP
G-2 Creative Indl. Estate, Plot No. 12, Next To H.P. Petrol Pump, N.M. Joshi Marg,
Lower Parel (E), Mumbai – 400011, Ph.No. 022‐23005205/06
Email : [email protected] /[email protected]

advice. In case of inhalation of mist seek medical advice. Refer

for medical treatment.

In case of skin contact

After contact with skin, with calcium gluconate-gel give subsequent treatment.
In case of contact with skin wash off with water.
Immediate medical treatment necessary, as untreated burns can result in slow-healing wounds.

In case of eye contact

Eye rinsing with water carefully while protecting unhurt eye. Refer to medical treatment.

In case of ingestion
Refer to medical treatment.
If swallowed seek medical advice immediately and show the doctor packing or label.
If swallowed by mistake drink plenty of water and seek medical treatment.

Physician’s information / possible symptoms

The following symptoms may occur : Coughing

Physician’s information / possible dangers

Risk of pulmonary irritation
Risk of respiratory disorders
Risk of pulmonary oedema

Treatment ( Advice to doctor )

In the event of pulmonary irritation treat initially with dexamethasone metered-dose aerosol.
If swallowed, flush stomach.
Treatment of convulsions by Diazepam intravenous and Calcium gluconate ( 10 % ).
Treat with calcium gluconate – solution.
Keep under medical supervision for at least 48 hours.

5. Fire-Fighting Measures

Suitable extinguishing material

Water spray jet
Water mist

Special exposure hazards arising from the substance, combustible products or resulting gases
in fires, hazardous combustion gases are formed : Nitrogen oxides ( Nox )

Special protective equipment for firefighters

Use breathing apparatus with independent air supply.
Fire-fighting operations, rescue and clearing work under effect of combustion and smoulder gases just
may be done with breathing apparatus.

Additional information
Cool the endangerey containers with water spray jet.
Fire residues and contaminated firefighting water must be disposed in accordance with the local
regulations Collect contaminated firefighting water separately, must not be discharged into the drains.
 SURFACE INNOVATORS LLP
G-2 Creative Indl. Estate, Plot No. 12, Next To H.P. Petrol Pump, N.M. Joshi Marg,
Lower Parel (E), Mumbai – 400011, Ph.No. 022‐23005205/06
Email : [email protected] /[email protected]

6. Accidental Release Measures

Personal precautions
Remove persons to safety.

Personal protection by wearing close-fitting protective clothing and breathing

apparatus. Keep people away and stay on the upwind side. Use
personal protective clothing. Use breathing apparatus if exposed to
vapours / dust / aerosol. Wear acid-resistent boots.

Environment precautions
Do not seep away runed out product into ground or body of water.
Do not discharge into the drains/ surface waters / ground water. Collect
effluent.

Methods for cleaning up/taking up

Dilute with plenty of water.
Do not use organic absorbent material.
Take up with absorbent material (e.g. acid binder ).
Neutralize with sodium carbonate or slaked lime.
Cleaning measures with respiratory protection.
After taking up the material dispose according to regulation.

Additional Information
Information for safe handling see chapter 7.
Information for personal protective equipment see chapter 8.
Information for disposal see chapter 13.

7. Handling and Storage

Advice on safe handling

Avoid formation of aerosols.
While spraying wear respiratory protection.
Allow for sucking off.
Use only acid-proof equipment.
Extraction in situ required.
Take the usual precautions when handling with chemicals.

Advice on protection against fire and explosion

The product is not combustible, but supports burning.
Cover extinguished scene of the fire with 10% copper sulphate or sodium carbonate solution. If
necessary add surfactants.

Requirements for storage rooms and vessels

Keep in closed original container.
Use container that resist to strong acids.
Prevent penetration into the ground. Use
polythene containers.

Advice on storage compatability

 SURFACE INNOVATORS LLP
G-2 Creative Indl. Estate, Plot No. 12, Next To H.P. Petrol Pump, N.M. Joshi Marg,
Lower Parel (E), Mumbai – 400011, Ph.No. 022‐23005205/06
Email : [email protected] /[email protected]

Do not store together with reducing agents.

Data relevant for safety Value Temperature at Method Remark

 SURFACE INNOVATORS LLP
G-2 Creative Indl. Estate, Plot No. 12, Next To H.P. Petrol Pump, N.M. Joshi Marg,
Lower Parel (E), Mumbai – 400011, Ph.No. 022‐23005205/06
Email : [email protected] /[email protected]

PH value in delivery state <1 20degree celcius

Acid number 10-14MgKOH/g

Flash point not applicable

Flammable solid not applicable

Combustion temperature not applicable

Autoignition not applicable

Vapour pressure 10hPa 20degree celcius calculated

Density 1,2-1,3 g/cm3 20degree celcius

Bulk density Not Applicable

Solubility in water No restrictions

Viscosity 1 dynamic <50 20degree celcius Brookf-visk RVT Sp.5

MPa’s

Solvent concentration 0%

Explosive properties
Not applicable

Additional information

Physical dates refer to pure product.

10. Stability and Reactivity

Conditions to avoid
Reactions with concentrated sulphuric
acid. Reactions with strong acids.
Reactions with reducing agents.
Forma nitrous gases and hydrogen on action upon metals.
As oxidising agent, attacks organic substances such as wood, paper, fats.
If product is heated above decomposition temperature toxic vapours may
be
released. Reactions with alcohols.
Reactions with alkalies.
Reactions with alkalies and metals.

Hazardous decomposition products.

Nitrous gases
Nitrous oxides (Nox)
 SURFACE INNOVATORS LLP
G-2 Creative Indl. Estate, Plot No. 12, Next To H.P. Petrol Pump, N.M. Joshi Marg,
Lower Parel (E), Mumbai – 400011, Ph.No. 022‐23005205/06
Email : [email protected] /[email protected]
 SURFACE INNOVATORS LLP
G-2 Creative Indl. Estate, Plot No. 12, Next To H.P. Petrol Pump, N.M. Joshi Marg,
Lower Parel (E), Mumbai – 400011, Ph.No. 022‐23005205/06
Email : [email protected] /[email protected]

K–2 Passivation Chemicals

Nitric acid
UN-No. 2922 Class 8
Sub Class 6.1
PG II Marine pollutant
No
EmS – No. F-A, S-B
Remarks
2922 CORROSIVE LIQUID, TOXIC, N.O.S
 SURFACE INNOVATORS LLP
G-2 Creative Indl. Estate, Plot No. 12, Next To H.P. Petrol Pump, N.M. Joshi Marg,
Lower Parel (E), Mumbai – 400011, Ph.No. 022‐23005205/06
Email : [email protected] [email protected]

R-phrases
26/27/28 Very toxic by inhalation, in contact with skin and if swallowed.
35 Causes severe burns.

S-phrases
23.5 Do not breathe nitrous gases.
26 In case of contact with eyes, rinse immediately with plenty of water and seek
Medical advice.
2810 After contact with skin, wash immediately with plenty of water and with calcium gluconate-
gel give subsequent treatment.
36/37/39 Wear suitable protective clothing, gloves and eye/face protection. 45
In case of accident or if you feel unwell, seek medical advice immediately
( show the label where possible ).

! Hazardous ingredients for labeling

Nitric acid

National regulations

Restriction of occupation
Observe employment restrictions for young people.
Observe employment restrictions for mothers-to-be and nursing mothers. Observe
employment restrictions for women of child-bearing age.

Decree for case of Accident regulation; appendix II: No. 167.

Interference/remarks

Classification according to VbF : is not subject to decree for compostible liquids.

 SURFACE INNOVATORS LLP
G-2 Creative Indl. Estate, Plot No. 12, Next To H.P. Petrol Pump, N.M. Joshi Marg,
Lower Parel (E), Mumbai – 400011, Ph.No. 022‐23005205/06
Email : [email protected] /[email protected]