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Jee Main 29 Jan 2025 Paper Shift 2

The document contains a series of mathematical problems and solutions related to the JEE-Main examination scheduled for January 2025. It includes various topics such as calculus, algebra, geometry, and probability, with detailed solutions provided for each problem. The problems are designed to test the understanding and application of mathematical concepts in preparation for the exam.

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301 views21 pages

Jee Main 29 Jan 2025 Paper Shift 2

The document contains a series of mathematical problems and solutions related to the JEE-Main examination scheduled for January 2025. It includes various topics such as calculus, algebra, geometry, and probability, with detailed solutions provided for each problem. The problems are designed to test the understanding and application of mathematical concepts in preparation for the exam.

Uploaded by

alexexperiment123
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Ans. Sol. Ans. Sol. JEE-MAIN EXAMINATION - JANUARY 2025 (HELD ON WEDNESDAY 29th JANUARY 2025) TIME : 300 PM TO 6:00 PM SECTION-A Ifthe set of all a © R, for which the equation 2x" + (a—5)x + 15 = 3a has no real root, is the interval (a), and X= {x © Z:aL,x#2, G2DG+9), 9 (x-4\x +1) x>l,x#2, 49+ 121416 5. Let the function fix) = (x' — I))x’ — ax + 2| + cosix) be not differentiable at the two points x = a = 2 and x = B. Then the distance of the point (a) from the line 12x + Sy + 10= 0 is equal to a3 4 @)2 as Ans. (1) Sol. cos)x| is always differentiable wwe have to check only for ~ ax +2} Not differentiable at x'-axt+2 One root is given, a= 2 4-2a+2=0 a=3 other root B= 1 but for x= 1 f{x) is differentiable (Drop) Ans. Sol. 2 Ans. Sol. Let a straight line L pass through the point PQ2-1,3) and be perpendicular to the lines If the line L. intersects the yz-plane at the point Q, then the distance between the points P and Q is, (2 2) V0 @)3 (4) 23, @ Vector parallel 1 ij k =|2 1-2) =10i-10j+5k 13 4 =SQi-25+K) Equation of 'L! 2_y+l cae (say) Let QQR+2,-24— 1,243) 3242-0 sh=-1 => Q(0, 1,2) (P,Q) =3 Let S = NU {0}. Define a relation R from S to R by: {os v):logy=nlog,(2} ee}. ‘Then, the sum of all the elements in the range of R is equal to a 5 OF QF 10 5 Oy o> @ S=(0,1,2,3 ou} : sess?) 8 Ans. Sol. Required sum = (2) + 3) “ls Let the line x + y= 1 meet the axes of x and y at A ‘and B, respectively. A right angled triangle AMN is inscribed in the triangle OAB, where O is the ‘origin and the points M and N lie on the lines OB and AB, respectively. If the area of the triangle AMN is of the area ofthe triangle OAB and AN : NB = 2: 1, then the sum of all possible value(s) of is 2: 1 Ms 5 3) 5 @> “ Area of AAOB Area of AAMN = 9°29 Equation of AB is x+y=1 OA = 1, AM=see(45° 8) AN = see(45°—0) cos0 MN = see(45°— 0) sind 9. Ans. Sol. AaaMsy= Le scts* Opitos 1 tnd =2, 2 tan0 = 2 is rejected AN} coo =2 NB [Link] + By = 109 is the equation of the chord of the ay x 51 ellipse +21, whose mid point is (5,1), 9 a ( 2) then «+B is equal to (37 046 (3) 58 @n eB) 70.2) Equation of chord T = S, ‘G)Q)-2e4 oo twos => 40x + 18y = 109 => a=40,B=18 > at BHs8 If all the words with or without meaning made using all the letters of the word “KANPUR” are arranged as in a dictionary, then the word at 440° position in this arrangement, is () PRNAKU (2) PRKANU (3) PRKAUN (4) PRNAUK, Ans. (3) Sol. A, KN, PLR, U => 440" word Let o,f (0. # B) be the values of m, for which the ‘equations x + y + z= 1; x + 2y + 42 = m and x + dy + 102m’ have infinitely many solutions. Then the value of 34 (n* +n?) is equa to: 440 (2) 3080 (3) 3410 (4) 560 a pad A=[1 2 4]=1@0~-16)- 100-4) + 14-2) 4 19) =4-6+2=0 For infinite solutions m'=3x+ m=1,2 a=1,p=2 & Lint +n" Joan , 10a n2 2 6 = 554385 =440 12, Let A = [a] be @ matrix of order 3 * 3, with ay =(V2)". tf the sum of all the elements in the third row of A’ is a+ BV, a,BeZ, then +B is equal 0 (280 (2) 168 (3) 210 (4) 224 Ans, (4) (a) (8) (8) sol. a=|(v2)° (v2)' (v2) Be 28 4 A=|2v2 4 2 4 42 8 ee | 2 v2 2 wW2/|J2 2 we 2 w2 4 [| 2 22 4 (24448) (2V2+4V2+8V2) (44+8+16), ‘Sum of elements of 3" row = 4(14 + 14y2 +28) = 4(42+ 14y2) = 168 + S6V2 a+ Bv2 ~ a+P= 168 +56=224 13. Let P be the foot of the perpendicular from the point (1, 22) om he fine L ; 54-94 252 Let the line #=(-i+j-2k)+2(i-j+K),2eR, intersect the line Lat Q. Then 2(PQ)" is equal to: «27 (2)25 (3)29 419 Ans. (1) Sol. ACI, 2, 2) =1,24+2) H- 3,201, Putte =0 3H, 1,2)=0 wt pt3+ 4p 0 p= 1 2 sta )2) (3 4) 22 Now general [Link] L, is Q-1+2, 1 Equate it with general pt of L 2 | 2u+ pe l=-14A)—p— 24h w=A-2 200-2) M-4+2=242 - 2(PQ)'= (5) n 14, Let acirele C pass through the points (4, 2) and (0, 2), and its centre lie on 3x + 2y +2=0. Then the length of the chord, of the circle C, whose mid- point is (1, 2), is: 3 3 (3) v2 (4) W2 Ans. @) Sol. 15, Ans. Sol. (4,2) = OM is vertical ON eer a0 mid point of chord is N=(1,2) =. ON= 37 length of chord = 2° (ON) =2@0=37 =2N3 Let A= [a,] be a2 * 2 matrix such that a, © {0,1} forall i and j. Let the random variable X denote the possible values of the determinant of the matrix A. ‘Then, the variance of X is: L 3 OF Qe i 3 Ors OF 16. Ans. Sol. 17. Ans. Sol. 18. Bag 1 contains 4 white balls and 5 black balls, and Bag 2 contains n white balls and 3 black balls. One ball is drawn randomly from Bag | and transferred to Bag 2. A ball is then drawn randomly from Bag 2. Ifthe probability, that the ball drawn is whit 29/45, then n is equal to: (3 Q)4 GB)5 (46 4 Bag 1 = (4W, SB} Bag 2 = {nW, 3B} 4 n+l 5) n 29 o*ne4 oO" ned 45 fn=4) The remainder, when 7” is divided by 23, is equal to ayia 9 @i7 (a6 o 7! = 7 (7) = 7 343)" = 7 (345 -2)" 78 =23K, +72" Now 7.2"= 7.25. = 28. 256)" = 28 (253 + 3)' 28 x 81> (23 + 5) (69+ 12) 23K, +60 :, Remainder = Let f(x)=[e(t8-9e+20)a, 1 < x < 5. IF the range of fis (a, B], then 4(c. + B) equals: is? (2)283 @) 12s (4) 154 Ans. (1) Sol. f(a) = = ~ 3664) |+ 10(16)=32=B. e-) 19, Let & be a unit vector perpendicular to the vectors a+ Bi 57 i-2}+3k and €=21+3)-K, and makes an angle of cos (1) withthe vestor i+ joka makes an angle of © with the vector F+a}+8, then the value of a. is : a) 3 @ ve @) V6 ae ‘Ans. (3) Sok Let vais jek Hk 23 j2 3 -l bx: =-Tie7j+7k (rejected) 20. Ans. Sol. adsorb) Vita? +1 Now cos= for +2=-a (2. a<0) 3a? +6 = 40" = a= V6 If for the solution curve y = f(x) of the differential 2eseex (1+2secx)'” x 5)1(2)=8 nn (2) is equal to: 4 (tnx caution %+(1ans)y 2)"\3 J" 10 o+3 1 © ola) © solar) OTF 4 ae “ 21. Ans. Sol. 2 pseex=— se} nal) if 2a{(s [J denotes the greatest integer function, then o. is equal to «2 aim SECTION-B lax 2 +[2sin J} dx = 2 + a, where 2 Sol. Ans. It n(x (in Ans. 3) An electric dipole is placed at a distance of 2 em from an infinite plane sheet having ps density 0. Choose the correct option from the following, itive charge SEeES” (1) Torque on dipole is zero and net force is directed away from the sheet. (2) Torque on dipole is zero and net force acts towards the sheet. (3) Potential energy of dipole is minimum and torque is zero. (4) Potential energy and torque both are maximum @) + or +) O--@ +] a 4a 29. Sol. Ans. Ans. In an experiment with photoelectric effect, the stopping potential (1) increases with inerease in the wavelength of the incident light (2) increases with increase in the intensity of the incident ight is () times the maximum kinetic energy of . the emitted photoelectrons (4) decreases with inerease in the intensity of the incident light 8 hc Wrevy HE W+(Kuu) e Vs Ans. (3) ‘A point charge causes an electric flux of -2 * 10° Nm'C' to pass through a spherical Gaussian surface of 80 em radius, centred on the charge ‘The value of the point charge is: Given, ()-177 «10°C (2)-15.7 10°C @) 177 «10°C (4) 15.7 «10°C a -2x10¢ NO = (8.85 « 10") x (2 10) q=-177% 10°C Ans. (1) Pressure, Bi. Va Ve Ve Volume A poly-atomie molecule (C, = 3R, C, = 4, where R is gas constant) goes from phase space point AQ, = 10" Pa, V, = 4 * 10m’) to point B (P, = * 10" Pa, V, = 6 * 10m) to point C (P, = 10° Pa, V, =8* 10m). A to B is an adiabatic path and B to C is an isothermal path. ‘The net heat absorbed per unit mole by the system is (1) SOOR(In3 + Ind) (3) SOOR In2 @) AQ,, = 0 adiabatic Que = AW (2) 450R(In4 (4) 400R Ind In3) Ans. Sol. =netn{ Y | —asoren{ S10 Ve oxo =4sonva($)=4s0R nt 03) AQ= AQ + AQ,. AQ=450 R (nd ~ fn3) Note : Solution is based on direct data, B and C are not satisfying the condition of isothermal process. Ans. (2) ‘Two identical symmetric double convex lenses of focal length fare cut into two equal parts L,, L, by AB plane and L, L, by XY plane as shown in figure respectively. The ratio of focal lengths of Tenses L, and L, is 32. x L, i is BOR L, L Y ais Ql @)2:1 1:2 Ans. (4) 33. Sol. Ans. Ans. Ans. (4) A plane electromagnetic wave propagates along the + x direction in free space. The components of the electric field, E and magnetic field, B vectors associated with the wave in Cartesian frame are : (E,B, QE,B, QE, B, @E,B, @ ely 8 Direction of propogation =ExB Ans. (2) Air] (Glass Glass] rp & Nero 7 Two concave refracting surfaces of equal radii of ‘curvature and refractive index 1.5 face each other in air as shown in figure. A point object O is placed midway, between P and B. The separation between the images of ©, formed by cach refracting surface is (1) 02148 2)0.1148 (041K (4) 0.124R, @ 38. Ans. Sol. Distance between images n-(oen2n)-o114R option (2) Two bodies A and B of equal mass are suspended from two massless springs of spring constant k, and k,, respectively. If the bodies oscillate vertically such that their amplitudes are equal, the ratio of the maximum velocity of A to the maximum velocity of B is k of k 3) Ke OF a V,=Ao, V,=Ao, A 36. Sol. Ans. Given below are two statements. One is labelled as. Assertion (A) and the other is labelled as Reason ®. B Three identical spheres of same mass undergo one dimensional motion as shown in figure with initial velocities v mis, v,=2 mis, v= 4 mis If we wait sufficiently long for elastic collision to happen, then v,=4 m/s, vy, =2 mis, v, = 5 mis will be the final velocities. Reason (R) In an clastic collision between identical masses, two objects exchange their velocities, In the light of the above statements, choose the correct answer from the options given below (1) Both (A) and (R) are true but (R) is NOT the correct explanation of (A) 2) (A) is true but (R) is false (3) Both (A) and (R) are true and (R) is the correct explanation of (A) (4) (A) is false but (R) is true @ In clastic collision for same mass, velocities interchange 37. Ans. Sol. 38. Ans, Sol. ‘A sand dropper drops sand of mass mit) on a conveyer belt at a rate proportional to the square root of speed (¥) ofthe bel, ie. Sa JF IPP is the power delivered to run the belt at constant speed then which of the following relationship is true? Pav 2) Pay @Pxv Pav @ Power= FV Pip =m] qa) (w= Cv" Ans. (4) A convex lens mode of glass (refractive index = 1.5) has focal length 24 cm in air. When it is totally immersed in water (refractive index = 1.33), its focal length changes to () em (2) 96 em (3) 24em, (4) 48 em, @) 39. Sol. Ans. A capacitor, C, = 6 F is charged to a potential difference of V, = SV using a SV battery. The battery is removed and another capacitor, C, = 12 place of the battery. When the switch ‘S’ is closed, the charge flows between the capacitors for some time until equilibrium HF is inserted condition is reached. What are the charges (q, and 4,) on the capacitors C, and C, when equilibrium condition is reached. s ce (1) q,= 15 nC, 4, =30 we (2). q, = 30 WC, q, = 15 uC 3).q,= 10 HC, g, = 20 we (4) 4, = 20 nC, 10 uC @ aly C6uF =" SV=V, C,=12uF -a| 6 5=30uC Finally s a-6Ve] + ther . a=12V. 40. ‘Three equal masses m are kept a vertices (A, B, C) of an equilateral triangle of side ain five space. At t= 6, V,=V,AC, they are given an. initial velocity Vo=VBA and ¥,=V,CB Here, AC,CB and BA’ are unit vectors along the edges of the triangle. If the three masses interact gravitationally, then the magnitude of the net angular momentum of the system at the point of collision is when Q)3amv, Ans. Sol. a Match List-l with List List (A)__[ Young's Modulus |) (B) | Torque’ a (©__| Coefficient of Viscosity | (IM) (D) | Gravitational Constant_[V) Ans. Choose the correct answer from the options given below ()(AY(, (B)-C), (CCU, (DAV) (2)(A}AD, (BY), (C1V), (D)-AM) (AHO), (BID, (CAM, (DAD) (4) (AHA), (B)-IV), (C0), (D)-A1) @ = MEE eer? ay xP MUT? (lv) 2. M'LT? (Ill) List List-Il (A) [Magnetic [| Ampere induction meter (B) [Magnetic | GI)_| Weber intensity (©_| Magnetic fx | Gm) | Gauss (D) [Magnetic | (V) | Ampere ‘moment meter Ans. Sol. 43. Ans, Choose the correet answer from the options given below (AYA, (B)-0V), (O-(, 2) (AKAD, BAY), (CD, DO G) (A), (BCID, (CD, (OAV) (4 (AYU), B)-L, (CU), (DIV) @ (A) Magnetic induction -> Gauss (IID) (B) Magnetic intensity (»- 2)» ampere mete ay) H (©) Magnetic flux — Weber (Wb) (II) (D) Magnetic moment > Ampere-meter” ("=ia) Note : None of the option(s) are correct but if wwe need to choose most appropriate option then the answer is (2) ‘The tuth table forthe cireuit given below is: A B @ @) @) a Sol. ve XOR (Exclusive OR) A cup of coffee cools from 90°C to 80°C in t minutes when the room temperature is 20°C. The time taken by the similar cup of coffee to cool from 80°C to 60°C at the same room temperature B 10 yer 2) Or OF OG 5 ay oe OF Ans. (1) By using average form of Newton's law of cooling @ i) cai) loxt’ _ 65 120 50 8,8, ass 45. The number of spectral lines emitted by atomic hydrogen that is in the 4" energy level, is (Me 0 @)3 @! Ans. Sol. Total possible transition = 6 SECTION-B 46. The magnetic field inside a 200 turns solenoid of radius 10 em is 2.9 * 10* Tesla. If the solenoid carries a current of 0.29 A, then the length of the solenoid is xem. Ans. (8) Sol. Assuming long solenoid N pou,(% w( c } -__nuni_(410°)(200)(029) B 29x10" =8rem 47. A parallel plate capacitor consisting of two eireular plates of radius 10 cm is being charged by a constant current of 0.15 A. Ifthe rate of change of potential difference between the plates is 7 = 10° Vis then the integer value ofthe distance between the parallel plates is~ (Tate.e,=9%10 hm, ‘Ans. (1320) Sol. (oxo (70 1 IE (710")m ons 10) = 1320 ym 48. A physical quantity Q is related to four observables abt 2,b,e,das follows : Q= Ord where, a= (60 + 3)Pas b= (20 + 0.1)m; = (40-4 0.2) Nsm* and d= (50 + 0.1)m, them th r = em the pereentage error in Q is = where Ans. (77) sol. Q=% " ed = AQ100-[ A842 AE 4 }.100 92) (92) 94 Loo 20)*\40) "50 49. Two planets, A and B are orbiting a common star in circular orbits of radii R, and R,, respectively, with R, = 2R,. The planet Bis 4/2 times more momentum (L,) of planet B to that of planet A(L,) is closest to integer Ans. () here M is mass of star Ea_mo [Ro Lym, VRy Two cars P and Q are moving on a road in the same direction. Acceleration of car P increases linearly with time whereas car Q moves with a ‘constant acceleration, Both cars eross each other at time t = 0, for the first time. The maximum possible number of crossing(s) (including. the ‘erossing at t= 0) is Ans. @) Sol. dt, kis constant a,ais constant y= 8 — a = a—Kt $ inital velocities are not mentioned in question, 0 will have to assume two eases. Case-l ‘yan ayy in same direction P Total number of crossing = 2 Case-Il uu,» and a,, in opposite direction A P Qhrakt Total number of crossing = 3 si. 32. 33. Sol. Ans. Ans. Ans. SECTION-A ‘The calculated spin-only magnetic moments of K,(Fe(OH),] and K,{Fe(OH),] respectively are (1) 4.90 and 4.90 BM. (2) 5.92 and 4.90 B.M. (3) 3.87 and 4.90 BM. (4) 4.90 and 5.92 BM. @ For hydrogen like species, which of the following graphs provides the — most appropriate representation of E vs Z plot for a constant n'? [E: Energy of the stationary state, Z.: atomic number, n= principal quantum number] a is @ is @) is @ is Given below are two statements : Statement (I) : In. partition chromatography, stationary phase is thin film of liquid present in the inert support. Statement (I) : In paper chromatography, the material of paper acts as a stationary phase. In the light of the above statements, choose the correct answer from the options given below (1) Both Statement I and Statement (2) Statement I is true but Statement IT is false (3) Both Statement I and Statement II are true (4) Statement I is false but Statement IT is true @) Statement lis true. In partition chromatography, stationary phase is thin liquid film present in the inert support. are false Statement IL is false. Because stationary phase in paper chromatography is water. 54. Ans. Sol. 55. Ans. Sol. 56. Ans. Identify the essential amino acids from below (A) Valine (B) Proline © Lysine (D) Threonine (E) Tyrosine Choose the correct answer from the options given below (1) (A)(©) and (D) only (2)(A){C) and (E) only (3) (B)(©) and (E) only (4) (AD) and (E) only @ Valine, Lysine and Threonine are essential amino acids, ‘Which among the following halides will generate the most stable carbocation in Nucleophillic substitution reaction ? on ee Phy Be 6) oo amr Ph @) Stability order of carbocation Phe Ph ® no “er or Oo ee Ph Consider the equilibrium CO(g) + 3HAg) = CHA) + H.0(8) If the pressure applied over the system increases by ‘two fold at constant temperature then (A) Concentration of reactants and products (B) Equilibrium will shift in forward direction. (©) Equilibrium — constant concentration of products inereases (D) Equilibrium constant remains unchanged as concentration of reactants and produets. remain Choose the correct answer from the options given below (1) (A) and (B) only (3) (B) and (C) only qa (2)(A), (B) and (D) only (4) (A), (B) and (©) only 57. Ans. Sol. Given below are two statements : Statement (I) : NaCl is added to the ice at 0°C, present in the ice cream box to prevent the melting of ice cream. Statement (I) : On addition of NaCI to ice at 0°C, there is a depression in freezing point. In the light of the above statements, choose the correct answer from the options given below : (1) Statement I is false but Statement II is true (2) Both Statement and Statement I are true (3) Both Statement I and Statement II are false (4) Statement I is true but Statement IT is false 2) Given below are two statements Statement (I) : On nitration of m-xylene with HINO;, HO, a nitrobenzene-1, 3-dicarboxylic acid is obtained as followed by oxidation, the major product. Statement (11) : NOs group is m-directing group, In the light of the above statements, choose the ‘correct answer from the options given below : (1) Both Statement I and Statement Il are false (2) Statement I is false but Statement IT is true (3) Both Statement [and Statement I are true (4) Statement I is true but Statement IL is false ‘Hs group is o/p-directing while- ) Statement on on, 6 [Link]. o, ch, cH, (m-xylene) Ko. [eosin coon ‘coon Xo; Statement-II -CH, group is o/p directing while NO; group is ‘meta directing, 59. Ans. 60. 0.1 M solution of KI reacts with excess of H:SO. and KIO solution. According to equation SI-HO; +61" 31, +3H,0 Identify the correct statements (A) 200 mL of KI solution reacts with 0.004 mol of KIO; (B) 200 mL of KI solution reacts with 0,006 mol of H,SO, (3) 0.5 L of KI solution produced 0.005 mol of I> (4) Equivalent weight of KIO, is equal to (Molecuarweigt U 5 (Choose the correet answer fom the options given below: (1) (A) and (D) only (2) (B) and (C) only (3)(A) and (B) only (4) (C) and (D) only @ Match List-I with Liste List IT Batteries/Cell ‘Anode - Zn/Hg eee Cathode - Hg +C o Hearing aids | (I) _| Hydrogen fuel cell ‘Anode = Zn; a Cathode - Carbon Invertors, Apollo ‘Anode ~ Pb ; Co) \ space ship Cathode — Pb | PbO, a) Ans. ol. Ans. ‘Choose the correct answer from the options given below () (AYA), (B)-(, (HV), (DUD 2) (AMID, (BID, (C)-A1V), (D0) @)(AYAV), (BCID, (-(), (D)-) (4) (A)AUD, (BID, (CLV), (D)-(D) @ Or gas will be evolved as a product of electrolysis of: (A) an aqueous solution of AgNOs using silver electrodes. (B) an aqueous solution of AgNO; using platinum electrodes. (© a dilute solution of H:S0, using platinum electrodes. (D) a high concentration solution of H: platinum electrodes. Choose the correct answer from the options given below () (B) and (©) only (3)(B) and (D) only @ $0: using (2)(A) and (D) only (4) (A) and (©) only. 02. Ans. Sol. Ans. 68. Ans. Identify the homoleptic complexes with odd number of d electrons in the central metal. (A) [Fe0 (B) [Fe(CN)] (© [Fe(CN);NOP (D) [Coch (&) [Co(H,0), Fs] Choose the correct answer from the options given below (1) (B) and (D) only (2)(C) and (E) only (3) (A), (B) and (D) only (4) (A), (C) and (E) only 1) Total number of sigma (a) and pi(r) bonds respectively present in hex-1-en-4-yne are = (1) 13 and 3 (2) 1 and 3 (3) 3 and 13 (4) 14 and 3 a aN bonds = 13 bonds = 3 If C(diamond)->C(graphite) + X kJ mol" C(diamond) + 0.(8) > COAg) + KI mol" C(graphite) + Ox(@) > COXg) + Zk mol! At constant temperature. Then ()X=¥+Z (Q)-X=Y+Z @)X=-¥+Zz (@)X=Y-Z @ Given below are two statements : Statement (I): It is impossible to specify simultaneously with arbitrary precision, both the Iinear momentum and the position of a particle. Statement (II) : If the uncertainty in the measurement of position and uncertainty in measurement of momentum are equal for an electron, then the uncertainty in the measurement ht of velocity is x 2m In the light of the above statements, choose the correct answer from the options given below : (1) Statement I is true but Statement IT is false (2) Both Statement I and Statement IT are true. (3) Statement I is false but Statement IT is true. (4) Both Statement I and Statement II are false. @ 66. Ans. Sol. 7. Ans. Ans. Which one of the following reaction sequences will give an azo dye? ), (i) Sn/HCL oC tata ii) Gi) NaNOJHCL (iii)B-naphthol, NaOH ome Hy soct, 2 (os ame t : OH p-naphtho lol “or Drug X becomes after 50% decomposition. The original concentration of drug in a bottle was 16 mg/mL which becomes 4 ‘mg/mL in 12 months. The expiry time of the drug ineffective in months is ‘Assume that the decomposition of the drug follows first order kinetics, a 2 @)3 ae @ The type of oxide formed by the element among Li, Na, Be, Mg, B and Al that has the least atomic radius is = (I) A:05 @)Aao o 2) a0, (4) 0 Sol. nm. Ans. n First ionisation enthalpy values of fist four group 15 clements are given below. Choose the comect value for the clement that sa main component of apatite family (1) 1012kI mot! (2) 1402KI mot" (3) 834K mot! (4)947 KI mot! Ans. (1) 70. Whichone ofthe following, with HB wil give pheno? Ci, oct AT Roan 0. cb ® ‘ocHs oT 5H cc se) on cH Ans. (2) or ‘CH, HBr | =o on or +CHBr Phenol SECTION-B ‘Consider the following low-spin complexes Ks[Co(NO:), Ke[Fe(CN)e. Ks[Fe(CN)ahe ‘Cus{Fe(CN)e] and ZnafFe(CN)a] The sum of the spin-only magnetic moment values ‘of complexes having yellow colour is BM. (answer is nearest integer) o Isomeric hydrocarbons -> negative Baeyer’s test (Molecular formula CH) The total number of different non-aliphatie substitution sites is - @ oO Above two isomers of Cul, have four different sites for aromatic electrophilic substitution reaction, ymers from above with four 73. In the Claisen-Schmidt reaction to prepare, dibenzalacetone from 5.3 g benzaldehyde, a total of 3.51 g of product was obtained. The percentage yield in this reaction was %. Ans. (60) ° Sok Phen yA ° me Benzaldchyde 53 gm 5 : ra Ph Ph 53 J Mot Dibenzalacetone ose (Product) 3.51 gm u 351 _oo1sMot 24 (Actual ‘Theoretical 0.015 % yield 100 1/40 = 60% 74, In the sulphur estimation, 0.20 g of a pure organic compound gave 0.40 g of barium sulphate. ‘The percentage of sulphur in the compound is__ x 10%, (Molar mass ; O = 16, $ = 32, Ba = 137 in g mot") Ans. (275) Sol. Organic Compound —> BaSO, 0.20 gm 0.40 gm 0.40 040 nol(BaSO, 355 MOUBASO,) 0.0 240 rol (Sulphur 333 mo! (Sulphur) 0.40 * 32 gm (sulphur) ayy * 32 em (sulphur) 0.40%32 199 %8 = —233__ = 7.5% 0 275 x 10" % 020 . Total number of non bonded electrons present in NO; ion based on Lewis theory is Ans. (12)

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