Experiment 16
qualitative analysis.
sa by
given salt
presentin the
Aim : To detect the positive and negative ions
Laboratory Manualh d
|Reference: Experiment No. 7.1 of
Apparatus Required :
uladus Bt tube aaldex,
Iest kubeHeasuxiog
text tube tand sanel faten pap
[A] Dry tests of inorganic salt :
Inference
Test Observation
SI. No.
my
1. Colour
Blue be preertt
ahsent
2. Smell
specik snell
Bnvolved (o2+ be
3 Heat 0.5g of salt NO gas ohen (old
Pin k
in a dry test tube blue ohen hot
o dsstinct Colour
4 Flame test
ane Seen cbsent
5. Borax bead test
6. Charcoal cavity test
7. Cobalt Nitrate test
|B] Tests for detection of anion :
SI. No. Test Observation Inference
1. 0.1g salt + dilute H,SO,
on heating
Brown tarnes
Is psesent
54
2. 0.lg salt + 1 mL concentrated No spe cikic (olared , Br, I
abs ent
H,so, on heating gas en volved
3 Water extract or ácidified sodium
carbonate extract by dilute HCI S04
absent
+ BaCl,
NONo wbite ppt.
4. Water extract of salt or sodium
carbonate extract + acetic acid So2
(till solution becomes acidic) + 4
lead acetate
No uoite ppt odbient
5. Water extract or sodium
carbonate extract + concentrated
HNO, + ammonium molybdate
Qbsent
[C] Confirmatory tests of anion :
SI. No. Test Observation Inference
Brown sing ohtund Peent
erous dufphate
Sofution t Conco
Hasly daopuise
|(ongumcd )
[D] Chemical equations of anion :
NaNO,t H,5D4 NaHSe4 t HNO3
Grë So4 + 3H2 SO t 9HNOY 3Fe2(se,, t4Hz0+2NO
[E] Group tests for detection of cation : +
Preparation of original solution : Original solution (0.S.) = Salt ater (Solvent)
SI. No. Inference
Test Observation
1 Salt + dilute NaOH ammonQ| Group (0) is henL
solution, on heating Nosmell of
2 0.S. + dilute HCI Group (1) is Qbseat
No btac k ppt
3. 0.S. + dilute HCI + on Group () is ben
No
Ppt.blackHouo
obfained
passing H,S gas
4 0.S. + 2-3 drops of No bxon/wtte Group (I) is Qbsent
concentrated HNO, + heat
+ 0.2 g NH,CI + add ppt. obtined
NH,OH solution in excess
(till it smells of ammonia)
5 0.S. + 0.2g NH,Cl + Group (IV) is pxesent
NH,OH (add till it smells
of ammonia) + on passing
HS gas Black ppt. olbtwned
6. 0.S. + 0.2g NH,Cl + Group (V) is lbsent
NH,OH (add till it smells
of ammonia) + 0.5g Wosite ppt obtinkd
(NH),CO,
7. 0.S. + 0.2g NH,CI + Group (VI) is bsent
NH,OH(add till it smells
of ammonia) + Na,HPO,
solution
[F] Analysis of group cations :
SI. No. Test Observation Inference
1. Salt t NaOH + yelow pet obtined
Potassium nitbates pent
cetfe acld
56
(GI ConfirmatorY tests of cation :
SI. No. Test
Observation Inference
1 O.s.Potussium t Yelouo pot obteinQd
Nitote tAcetfe (ongismed
acfd
[H) Chemical equations of cation :
COg+ HN03 +3 HO ’OCty tNOu tS+2H20
(Olg+ TKNO, t 2CHh(00H> kgToC Ne,)I +2kCt +oCH gt00R +
NOtH20
[I] Result table :
Cation of inorganie Anion of inorganic Molecular formula and
salt and its name salt and its name name of inorganic salt
Nog CoCNOB)
(obat
Nitote Cobalt htate
Sign of subject teacher/Lab teacher
57
