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Highest Boiling Point of Aqueous Solutions

The document contains a chemistry worksheet focused on solutions, with questions covering boiling point elevation, osmotic pressure, colligative properties, and calculations related to freezing point depression and boiling point elevation. Each question tests the student's understanding of key concepts and formulas in solution chemistry. The total marks for the worksheet are 25, and it includes both theoretical and calculation-based questions.

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45 views2 pages

Highest Boiling Point of Aqueous Solutions

The document contains a chemistry worksheet focused on solutions, with questions covering boiling point elevation, osmotic pressure, colligative properties, and calculations related to freezing point depression and boiling point elevation. Each question tests the student's understanding of key concepts and formulas in solution chemistry. The total marks for the worksheet are 25, and it includes both theoretical and calculation-based questions.

Uploaded by

ditshivang
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

FMT : CHEMISTRY (SOLUTIONS)

NAME OF THE STUDENT :

CLASS/SEC : DATE :

TOTAL MARKS : 25 MARKS OBTAINED :


Q1) Solution A is obtained by dissolving 1 g of urea in 100 grams of water
and solution B is obtained by dissolving 1 g of glucose in 100 grams of
water. Which solution will have a higher boiling point and why ? [1 mark]
Q2) On mixing equal volume of water and ethanol, what type of deviation
would you expect from Raoult’s Law ? [1 mark]
Q3) Two liquids X and Y boil at 110! C & 130! C respectively. Which of them
has higher vapor pressure at 50! 𝐶 ?
Q4) Which of the following aqueous solution will have highest boiling point
? [1 mark]
(A) 1.0 M KCl (B) 1.0 M K " SO#
(C) 2.0 M KCl (D) 2.0 M K " SO#
Q5) Define osmotic pressure with the help of formula. [1 mark]
Q6) Define azeotropes. What type of azeotrope is formed by positive
deviation from Raoult’s law ? [1 mark]
Q7) For a 5% m/v solution of urea, calculate the osmotic pressure at 300 K.
(R = 0.0821 atm K $% mol$% ) [2 marks]
Q8) (i) Write the colligative property which is used to find the molecular
mass of macromolecules.
(ii) In non-ideal solution, what type of deviation shows the formation of
minimum boiling azeotrope ? [2 marks]
Q9) Visha took two solutions – one containing 7.5 grams of urea (molar
mass = 60 g/mol) and the other containing 42.75 grams of substance Z in
100 grams of water respectively. It was observed that both the solutions
froze at the same temperature. Calculate the molar mass of Z. [2 marks]
Q10) State Henry’s law correlating the pressure of a gas and its solubility in
a solvent. Also mention two applications of the law. [2 marks]
Q11) Calculate the freezing point of a solution containing 60 grams of
glucose (molar mass = 180 grams per mole) in 250 grams of water.
(K & (water) = 1.86 Kkg $% mol$% ) [2 marks]
Q12) What is meant by van’t Hof factor ? The osmotic pressure of a 0.0103
molar solution of an electrolyte is found to be 0.70 atm at 27! C. Calculate
the van’t Hof factor. (R= 0.082 atm K $% mol$% ) [3 marks]
Q13) Calculate the freezing point depression expected for 0.05 m aqueous
solution of Na" SO# . If the solution actually freezes at −0.0320! C, what
would be the value of van’t Hof factor ? (K & (water)= 1.86 ! C mol$% )
[3 marks]
Q14) Calculate the boiling point of solution when 2 grams of Na" SO# (M=
142 grams per mole) was dissolved in 50 grams of water, assuming
complete ionization of Na" SO# . (K ' (water) = 0.52 K kg mol$% ) [3 marks]

ANSWERS

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