MASTERED REVISION
PREDICTION ONE – JULY 2022
Suggested MARK SCHEME CHEMISTRY PAPER 233/3
PROCEDURE I
1. Titre 1 2 3
Final burette reading cm³ 23.2 21.5 21.5
Initial burette reading cm³ 0.0 0.0 0.0
Volume of solution (V)cm³ 23.2 21.5 21.5 (4 marks)
Table I (5 marks)
Complete table (1 mark)
Decimal place (1 mark)
Accuracy (1 mark)
Principal of averaging (1 mark) (Working must be shown as indicated below)
Final answer (1 mark)
(5 marks)
(a) Average volume
½ ½
(b) Molarity of solution M. (2 marks)
1g – 250cm³
1000cm³ ½
½
½ = 0.1M ½ (2 marks)
(c) Moles of sodium hydroxide pipetted (1 mark)
½ = 0.0025 moles ½
(d) Moles of acid that reacted
2NaOH(aq) + H2Y Na2Y(aq) + 2H2O(l)
Mole ration acid: Base
1 2
Moles of acid = ½ moles of base = ½ x 0.0025 ½
= 0.00125 ½
(e) Moles of H2Y in 1.6g (1 mark)
½
= 0.014535 ½ (1 mark)
(f) Determining value of Y:
1.6g – 0.014535 moles
? 1 mole
½
2 + Y = 110.079
= 110.079 – 2 ½
= 108.079 (1 mark)
PROCEDURE II
(a) Temperature of solution V(ºC) 40ºC 50ºC 60ºC 70ºC 80ºC
Time for colour to
disappear (+) secˉ¹ 200.76 60.62 43.26 18.37 8.35
0.00498 0.0165 0.0231 0.0544 0.1198
Complete table (1 mark)
Decimal place (1 mark)
Accuracy (1 mark)
Trend – Decreasing (1 mark)
(b) Graph
- Both correctly labelled axis with units of variables (½ mark)
- Scale ½ cover ¾ page ½
- Plots 1 mark (must be visible)
- Shape (line) (1 mark)
(3 marks
I
sec 1
t
Temp C
(c) Time taken at 65ºC
½
Working out ½
Showing on graph ½
(d) Rate of reaction is directly proportional to increase in temperature or rate of reaction increases with
increase in temperature.¹
2. Observations Inferences
Solid dissolves to ½ form colourless solution ½ - Coloured ions absent ½
(1mk) i.e. Cu2+, Fe2+, Fe3+
- Solid is soluble ½ (1mk)
(i) Observations Inferences
No white precipitate formed ¹ (1mk) +
Na , K ,+
present
3 - ions (1mk)
2 – ions (½mk)
1 – ion (no mark) (1mk)
(ii) Observations Inferences
Burns with a yellow flame ¹ (1mk) Na+ present ¹ (1mk)
(iii) Observations Inferences
White precipitate (1mk) , , present
3 - ions (1mk)
2 – ions (½mk)
1 – ion (0mk) (1mk)
(iv) Observations Inferences
- Colourless gas produced ½ present ½
- Purple acidified KMnO4 changes to
colourless ½ (1mk)
3. (i) White crystals ¹
(ii) Observations Inferences
Solid ½ melts, burns with a yellow
sooty flame. ½
Reject: Burns with yellow flame. (1mk) C=C , CC
½ Present ½
(1mk)
(iii) Observations Inferences
Solid dissolves to form colourless Polar compound present ¹ (1mk)
solution ½ (1mk)
(iv) Observations Inferences
Solid ½ melts, burns with a yellow
CC ; C=C
ROH ½ Present ½
(1mk)
sooty flame.
Reject: Burns with yellow flame. (1mk)
(v) Observations Inferences
Purple acidified KMnO4 changes
to colourless. (1mk) CC ; C=C ½
ROH ½
(vi) Observations Inferences
PH = 1 or PH = 2 ¹ Strongly acidic ¹
