MASTERED REVISION
PREDICTION 3 – AUGUST 2022
MARKING SCHEME
1 a) i) yellow-it has moved a short distance from the origin
ii). yellow dye
b) P,R, and S, Aluminium oxide is amphoteric in nature
c) i) Soap/soapy detergent ii) soap less detergent
ii) Advantage - Forms no scum with hard water
Disadvantage –Non biodegradable hence causes environmental pollution
2 a) i) Bauxite
ii) silica/iron(ii)chloride
b)
ii) I. a lot of electrical energy is required to melt the ore
II. Addition of molten crayolite
iii It has a lower melting point than the ore
c) Q=It
=40000x60x60
=144000000C
27kg requires 96500C
? requires 144000000C
=1492.2kg
1
3 i) C and F
ii) A and E
iii) E and D
b) i)
ii) in aqueous form it contains free and mobile ions
c) i) WCl2, XCl4
ii) Chlorine is a diatomic gas with a molecular structure while PCl3 has strong
covalent bonds with many van der waals forces
iii) MgCl2 is an ionic compound with a giant ionic structure while AlCl3 is covalent
with molecular structure with weak Van der walls forces
iv) Lack of free ions in liquid form since it has molecules
4. a) W- 1,2 dichlorobutane
X- But-1-ene
Y -Sodium butanoate
V- Potasium butoxide
b) Step I-hydrogenation
Step III neutralization
Step IV oxidation
c) i) water and conc.sulphuric(VI) acid, /steam at 300oc
ii) Sodium hydroxide, heat
iii) acidified potasiumpermanganate (VII)or dichromate , warm
d) i) CH3CH2C=CH + HBr CH3CH2CH=CHBr
ii) CH3CH2CH=CH +Br2 CH3CH2CHBrCHBr
iii) CH3CH2CH3 +Cl2 CH3CHBrCH2Br
e) i) add sodiumhydrogencarbonate to each sample in atest tube, the one that
2
gives effervescence is CH3C00H
ii) Ethanol has hydrogen bonds while CH30CH3 doesn’t have hydrogen bonds
5. a) i) concentrated sulphuric acid
ii) Sodium chloride, Nacl
iii) H2SO4 +2NaCl Na2SO4 +2HCl or NaHSO4
iv) Gentle heating
b) i) Concentrated sulphuric(VI)acid
ii) Downward delivery
c)
d) HCl in water is ionized while HCl in methylbenzene exists as a molecule
e) A-rusting occurs, all conditions for rusting present
B-will not rust, calcium chloride removes moisture
C- no rust, zinc protects iron from rusting since it corrodes in place of iron
f) to dry ammonia
6 a), i) CaCO3 +HCl CaCl2 +C02 +H20
ii) Flask B –is to remove traces of HCl
Flask C- to dry the CO2gas
iii) It is denser than air
iv) Reacts with calcium carbonate to form calcium sulphate which is insoluble
v) White ppt is formed
vi) CaCO3(s)+CO2(g) + H2O (l) 2 Ca(HCO3)2
b) Used in fire extinguishers
In fizzy drinks
7 a) i) 0.25g
ii) 35.2oC
Rise =8.9oC
b) i) 60
ii) 0.25/60
= 0.0041667moles
iii) 0.0041667moles produces 200 x 4.2 x 8.9J
1mole produces ?
=200x 4.2 x 8.9
0.0041667
=1794.2kJ/mol
3
c) Yellow colour intensifies, addition of NaOH increases concentration of OH
equilibrium shifts to the left to reduce the concentration of the stress hence yellow
colour
8. i) a) Nitrogen-fractional distillation of liquid air
b) Hydrogen –cracking of long chain alkanes
ii) Finely divided iron catalyst, pressure (200-500atm), temperature (400-500oC)
iii) P- platinum-rhodium
M-nitrogen(II)oxide
iv) a) 4NH3(g) + 5O2(g) 4NO(g) +6 H2O(l)
b) 2NO2(g) + H2O(l) HNO2(aq) + HNO3(aq)
v) -reduce cost of production by minimizing on wastage
-reduces pollution to the environment of NO2
vi) Place liquid in a test tube, add iron(II) sulphate then slowly run con H2S04
through the solution, a brown ring forms at the junction of the two layers
confirming presence of N03-
Or to the nitrate solution, add aluminum foil followed by sodium hydroxide
solution, heat the solution to boil, ammonia gas is produced which turns red
litmus paper blue
