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Chemistry Paper 1

This document is a marking scheme for a Chemistry paper, detailing answers to various questions related to chemical reactions, properties of substances, and calculations involving molarity and reaction rates. It includes specific chemical equations, definitions, and explanations of concepts such as esterification and neutralization. The document serves as a guide for grading student responses based on the provided answers.

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70 views4 pages

Chemistry Paper 1

This document is a marking scheme for a Chemistry paper, detailing answers to various questions related to chemical reactions, properties of substances, and calculations involving molarity and reaction rates. It includes specific chemical equations, definitions, and explanations of concepts such as esterification and neutralization. The document serves as a guide for grading student responses based on the provided answers.

Uploaded by

kisundiwilliam
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOC, PDF, TXT or read online on Scribd

MASTERED REVISION

PREDICTION 3 – AUGUST 2022


CHEMISTRY PAPER 233/1
MARKING SCHEME

1 a) They should be prepared in a fume chamber or in the open.


b) Chlorine, Fluorine, Bromine, Iodine, Carbon (II) Oxide, H2S, NO2, SO2, or SO3
any 2
2. A - ammonium hydroxide½
B - sulphuric(VI) acid½
C - ethanoic acid½
D - sodium hydroxide½

3. (i) Isotope(s)
(ii) Same number of electrons (1)
(Same number) of electrons in the outer shell (1)

4 • conduct electricity
 conduct heat
 Malleable
 Ductile
 Shiny / lustrous

5. Rate of N2 = √ mm.CO2½
Rate of CO2 √ mmN2
Rate of N2 = /40 = 3cm3/s½
120

3 = √ 44
X √ 28
X = 2.39cm3/s1
Time = 240/2.39
= 100.4cm3/s1

6. R, Q, T, U1

7. (i) C ½and A½


(ii) F1
(iii).F ½and D½

8. (i) B / diamond (1) D / nitrogen / N2 (1) 2 1


(ii) D / nitrogen / N2 1 1(a)
(iii) C / lithium chloride / LiC

1
9. Carbon(IV) oxide is molecular with simple molecular structure1 while S02 has a giant
covalent structure1

10. (i) Ammonium carbonate1


(ii) on being heated it gives off CO2 and NH31, ammonia gas reacts with Cu2+ to form a
complex ion which is a deep blue solution1, while CO2 reacts with calcium hydroxide
to form calcium hydroxide which is a white ppt
Equations -½mk each

11. HCl is a strong acid hence fully ionized1 while ethanoic acid is not fully ionized in water1

12. Orange colour intensifies,1 forward reaction is favoured1

13. (i) But-2ene1


(ii) 3-ethyl hexane1

14. 60g ----------------80cm31


?-----------------100cm3
100 x 601 =75g/100g of H2O1
80
15. (i) Platinum
(ii) Chlorine

16. (a) beaker b1


(b). HCl in methylbenzene is not ionized½, hence no ions to react with sodium carbonate
to produce carbon(iv)oxide½

17. In separate boiling tubes, heat½ the samples. The one that decomposes½ to give a gas that
forms a white ppt with calcium hydroxide is NaHCO3, the one that is½ not decomposed is
sodium carbonate½ / or add water to the two salts in separate test tubes to make a solution.
Dip blue litmus paper in each solution. The one in which blue litmus paper turns red is
NaHCO3

18. a) Lead oxide changes from white grey solid½


Colorless vapour forms on the cooler parts of the combustion tube½
b) PbO (s) + H2(g) Pb(s) + H2O(l)1

19. Mass of C 12/44 x 4.2 = 1.145g½


Mass of H = 2/18 x 1.71 =0.19g½

C H
1.1450.19½
12 1

0.0954 0.19½
2
0.0954 0.0954
1 2
CH2½

20. Esterification is reversible while neutralization is irreversible1


Esterification catalyst required, while neutralization no catalyst is required1

21. Heat given out


1680Kj – 1mol
? - 0.1mol1
=168Kj
168000J= 1000 x 4.4 x ∆θ1

∆θ= 40o1

22. (i) Many number of reacting particles ½hence rate of reaction faster since collisions are
many½

(ii) ½
II

iii) Temperature, 1concentration1

23. i) Ca1
ii) Mg(s) + 2Ag+ Mg2+ + Ag(s)
iii) Eθ= Ered –Eox
= +0.80-(-2.87)
=3.67V1

24. a) (i) NO3-


(ii) Pb2+1
b) ` Pb(NO3)2aq + 2HClaq PbCl2(s) + 2HNO3aq1

25. To 100cm3 of 0.5M NaOH, add 100cm3 of 0.25M H2SO4 (or any other volume and molarity that
gives 0.025 moles H2SO4) ½. Stir Heat the resulting solution to saturation ½. Cool the
saturated solution ½ to form Na2SO4 crystals.

26. (i) Cannot be decomposed by organisms


3
(ii) Gets stuck in gullets of birds / gets stuck in gullets of animals / blocks drains
27. Liquid: particles sliding over each other / particles moving slower than in gas (1) particles
close together / particles touching (1) gas: particles moving rapidly / particles moving
randomly (1) particles far apart (1)

28. Mark each for any three of:


 heat the flask / heat the mixture
 idea of different boiling points (of materials in flask)
 ethanol evaporates
 different compounds reach the condenser at different times / ethanol collects first in
(collection) flask • ethanol turns to liquid (in condenser)
 solids / plant material remain in flask
29. (a) 2H2S(g) + SO2(g) 2H2O(l)+3S(s)
(b) H2S(g)// hydrogen sulphide

30. (i) Liquid M = water


(ii) CO2  ½ formed by burning candle, slightly soluble  ½ forming an acidic 
solution
(iii) H2O(l) + Na2O2(s) 2 NaOH(aq) + O2(g)

31. 12.8 t½ 6.4 t½ 3.2 t½ 1.6 t½ 0.8

4t ½ = 280
t ½ = 280 = 70 days
4
280 / t ½
Alternatively 0.8 = (1)
No. = 12.8g 12.8 2
N = 0.8g (1)4 = (1)
T = 280 days 2 2
T½=? = 4 = 280
t½

= t ½ 280 = 70 days
4

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